Abstract: The present invention is directed to a method and a system for the production of at least one polymeric yarn comprising means for mixing a polymer (1) with a first solvent yielding a mixture; means for homogenizing the mixture; means for rendering the mixture inert (21, 22, 23); means for dipping the mixture into a quenching bath (30), wherein an air gap is maintained before the mixture reaches the quenching bath (30) liquid surface forming at least one polymeric yarn; means for drawing (41) the at least one polymeric yarn at least once; means for washing (5) the at least one polymeric yarn with a second solvent that is more volatile than the first solvent; means for heating the at least one polymeric yarn (6); means for drawing at room temperature (7) the at least one polymeric yarn at least once; and means for heat drawing (8) the at least one polymeric yarn at least once.
Type:
Grant
Filed:
March 20, 2020
Date of Patent:
April 30, 2024
Assignee:
Braskem America, Inc.
Inventors:
Marcos Roberto Paulino Bueno, Andre Penaquioni, Alessandro Bernardi, Sergio Luiz Dias Almeida, Leandro Ohara Oliveira Santa Rosa, Patricia Freitas Oliveira Fialho, Daniela Zaira Rauber
Abstract: A compounded polymer composition suitable for manufacturing of isotropic three-dimensional printed articles may include an impact copolymer, a low crystalline ethylene/?-olefin copolymer; a nucleating agent; and filler, where the impact copolymer may include a matrix phase comprising a propylene-based polymer or copolymer; and a dispersed phase in the matrix phase, the dispersed phase comprising an ethylene-based copolymer, the ethylene-based copolymer having a C3-C12 comonomer, wherein the dispersed phase has a different composition than the matrix phase.
Type:
Grant
Filed:
May 14, 2021
Date of Patent:
February 27, 2024
Assignee:
Braskem America, Inc.
Inventors:
Juliana Breda Soares, Michelle K. Sing, Jacob Fallon, Alexandre di Pintor da Luz, Leonardo Ito, Hadi Mohammadi
Abstract: The present invention is directed to a method and a system for the production of at least one polymeric yarn comprising means for mixing a polymer (1) with a first solvent yielding a mixture; means for homogenizing the mixture; means for rendering the mixture inert (21, 22, 23); means for dipping the mixture into a quenching bath (30), wherein an air gap is maintained before the mixture reaches the quenching bath (30) liquid surface forming at least one polymeric yarn; means for drawing (41) the at least one polymeric yarn at least once; means for washing (5) the at least one polymeric yarn with a second solvent that is more volatile than the first solvent; means for heating the at least one polymeric yarn (6); means for drawing at room temperature (7) the at least one polymeric yarn at least once; and means for heat drawing (8) the at least one polymeric yarn at least once.
Type:
Application
Filed:
October 2, 2023
Publication date:
January 25, 2024
Applicant:
Braskem America, Inc.
Inventors:
Marcos Roberto Paulino Bueno, Andre Penaquioni, Alessandro Bernardi, Sergio Luiz Dias Almeida, Leandro Ohara Oliveira Santa Rosa, Patricia Freitas Oliveira Fialho, Daniela Zaira Rauber
Abstract: The present invention is directed to a method and a system for the production of at least one polymeric yarn comprising means for mixing a polymer (1) with a first solvent yielding a mixture; means for homogenizing the mixture; means for rendering the mixture inert (21, 22, 23); means for dipping the mixture into a quenching bath (30), wherein an air gap is maintained before the mixture reaches the quenching bath (30) liquid surface forming at least one polymeric yarn; means for drawing (41) the at least one polymeric yarn at least once; means for washing (5) the at least one polymeric yarn with a second solvent that is more volatile than the first solvent; means for heating the at least one polymeric yarn (6); means for drawing at room temperature (7) the at least one polymeric yarn at least once; and means for heat drawing (8) the at least one polymeric yarn at least once.
Type:
Grant
Filed:
March 20, 2020
Date of Patent:
January 9, 2024
Assignee:
Braskem America, Inc.
Inventors:
Marcos Roberto Paulino Bueno, Andre Penaquioni, Alessandro Bernardi, Sergio Luiz Dias Almeida, Leandro Ohara Oliveira Santa Rosa, Patricia Freitas Oliveira Fialho, Daniela Zaira Rauber
Abstract: A foamable composition including a polypropylene-based copolymer and a polyolefin is disclosed. The composition can be used to make a stiff foam with a high closed-cell content. Methods for producing the composition and the foam are provided.
Type:
Grant
Filed:
February 1, 2023
Date of Patent:
January 2, 2024
Assignee:
BRASKEM AMERICA, INC.
Inventors:
Kimberly Miller McLoughlin, Kevin Herrington
Abstract: A catalyst composition includes a metal catalyst dispersed in a molten eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides. A process for the catalytic cracking of hydrocarbons includes contacting in a reactor system a carbon-containing feedstock with at least one catalyst in the presence of oxygen to generate olefinic and/or aromatic compounds; and collecting the olefinic and/or aromatic compounds; wherein: the at least one catalyst includes a metal catalyst dispersed in a molten eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides. A process for preparing the catalyst includes mixing metal catalyst precursors selected from transition metal compounds and rare-earth metal compounds and a eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides and heating it. A use of the catalyst in the catalytic cracking process of hydrocarbons.
Type:
Grant
Filed:
January 11, 2023
Date of Patent:
December 5, 2023
Assignee:
Braskem America, Inc.
Inventors:
Vladimir Pushkarev, Uriah Kilgore, Charles Ambrass, Scott Mitchell, Ishant Khurana
Abstract: This invention relates to an elastomer composition comprising: about 10-85 wt % of ethylene-vinyl acetate copolymer, optionally based on ethylene produced from a bio-based carbon source; about 15-90 wt % of thermoplastic polyurethane; and about 0-10 wt % of a compatibilizer. This invention also relates to a molding product formed from the elastomer composition.
Abstract: A composition comprising polypropylene having a high melt strength suitable for an injection stretch blow molding (ISBM) process is provided. Such a composition includes a polypropylene (PP) copolymer having a branched structure. The PP copolymer is a random copolymer derived from propylene and at least one comonomer selected from ethylene, any C4-C8 alpha-olefin, or any combinations thereof. The composition has a melt flow index in a range of from 8 g/10 minutes to 30 g/10 minutes. A resulting fabricated article, a method of making the composition, and a method of using the composition are also provided.
Type:
Grant
Filed:
November 21, 2019
Date of Patent:
October 17, 2023
Assignee:
BRASKEM AMERICA, INC.
Inventors:
Kevin Herrington, Kimberly Miller McLoughlin
Abstract: A composition for three-dimension (3D) printing, a method for 3D printing, and a resulting article having porous structure are provided. Such a composition includes from 50% to 100% by weight of a base polymer comprising polyolefin (such as ultra-high molecular weight polyethylene), from 0% to 50% by weight of a glue polymer (such as HDPE or PP), and optionally additive. A composition can be applied in a layer, and the base polymer and the glue polymer each has a predetermined size or size distribution. The composition is sintered in a selected area to form a layer of a solid article, which has a predetermined pore size or pore size distribution. The predetermined particle size or size distribution for each of the base polymer and the glue polymer is determined through computer simulation based on the predetermined pore size or pore size distribution in the layer of the solid article.
Type:
Application
Filed:
June 6, 2023
Publication date:
October 5, 2023
Applicant:
Braskem America, Inc.
Inventors:
Alessandro Bernardi, Peter Dias, Barbara Iria Mano, Juliana Breda Soares
Abstract: A mixture of gas and solid particles are conveyed through a piping circuit connected between initial and terminal points. The gas is introduced at the initial point and the particles are introduced between the initial and terminal points. A diameter of the piping circuit increases downstream of where the particles are introduced, and a velocity of the gas is at least as great as a pick-up velocity of the particles at the point where the particles are introduced into the piping circuit. In addition to the above constraints, the piping circuit is sized so that total pressure losses due to flow in the piping circuit between the initial and terminal points are within a designated amount.
Abstract: This invention relates to the use of ethylene/propylene random copolymers for the production of films having low-haze. In particular, the present invention involves the use of ethylene/propylene random copolymer comprising 90-96.5 wt % propylene and 3.5-10 wt % ethylene demonstrated to have low haze. This invention also relates to an ethylene/propylene random copolymer composition comprising about 3.5-10 wt % ethylene content and about 90-96.5 wt % propylene content, for production of a low-haze film.
Abstract: A composition for three-dimension (3D) printing, a method for 3D printing, and a resulting article having porous structure are provided. Such a composition includes from 50% to 100% o by weight of a base polymer comprising polyolefin (such as ultra-high molecular weight polyethylene), from 0% to 50% by weight of a glue polymer (such as HDPE or PP), and optionally additive. A composition can be applied in a layer, and the base polymer and the glue polymer each has a predetermined size or size distribution. The composition is sintered in a selected area to form a layer of a solid article, which has a predetermined pore size or pore size distribution. The predetermined particle size or size distribution for each of the base polymer and the glue polymer is determined through computer simulation based on the predetermined pore size or pore size distribution in the layer of the solid article.
Type:
Grant
Filed:
December 21, 2018
Date of Patent:
August 8, 2023
Assignee:
Braskem America, Inc.
Inventors:
Alessandro Bernardi, Peter Dias, Barbara Iria Mano, Juliana Breda Soares
Abstract: Impact copolymer (ICP) compositions may include those having a melt strength (MS) and melt flow rate (MFR) described according to the formula: MS?325×MFR?1.7, wherein the MS is greater than 1 cN. Methods of producing an impact copolymer (ICP) composition may include coupling the ICP composition with a coupling agent, wherein the ICP composition includes a matrix polymer and a dispersed component; wherein the ICP composition possesses a measurable melt strength (MS) and melt flow rate (MFR) satisfying the equation: MS?325×MFR?1.7, wherein the MS is greater than 1 cN.
Type:
Application
Filed:
January 12, 2023
Publication date:
June 1, 2023
Applicant:
Braskem America, Inc.
Inventors:
Joel Carr, Gerd Lohse, Rajendra Krishnaswamy, William Scott Miller, Rita Majewski
Abstract: A catalyst composition includes a metal catalyst dispersed in a molten eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides. A process for the catalytic cracking of hydrocarbons includes contacting in a reactor system a carbon-containing feedstock with at least one catalyst in the presence of oxygen to generate olefinic and/or aromatic compounds; and collecting the olefinic and/or aromatic compounds; wherein: the at least one catalyst includes a metal catalyst dispersed in a molten eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides. A process for preparing the catalyst includes mixing metal catalyst precursors selected from transition metal compounds and rare-earth metal compounds and a eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides and heating it. A use of the catalyst in the catalytic cracking process of hydrocarbons.
Type:
Application
Filed:
January 11, 2023
Publication date:
June 1, 2023
Applicant:
Braskem America, Inc.
Inventors:
Vladimir Pushkarev, Uriah Kilgore, Charles Ambrass, Scott Mitchell, Ishant Khurana
Abstract: This invention relates to a process for forming an azide-grafted polymer. The process comprises mixing a free-radical-reactive polymer with a free-radical initiator and an azide monomer that contains at least one unsaturated C?C bond capable of reacting with a radical, under solid-state grafting conditions, to form an azide-grafted polymer. The formed azide-grafted polymer can be used to prepare a long-chain branched or cross-linked polymer.
Abstract: A catalyst composition includes a metal catalyst dispersed in a molten eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides. A process for the catalytic cracking of hydrocarbons includes contacting in a reactor system a carbon-containing feedstock with at least one catalyst in the presence of oxygen to generate olefinic and/or aromatic compounds; and collecting the olefinic and/or aromatic compounds; wherein: the at least one catalyst includes a metal catalyst dispersed in a molten eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides. A process for preparing the catalyst includes mixing metal catalyst precursors selected from transition metal compounds and rare-earth metal compounds and a eutectic mixture of alkali metal or alkaline earth metal carbonates or hydroxides and heating it. A use of the catalyst in the catalytic cracking process of hydrocarbons.
Type:
Grant
Filed:
May 28, 2021
Date of Patent:
March 7, 2023
Assignee:
Braskem America, Inc.
Inventors:
Vladimir Pushkarev, Uriah Kilgore, Charles Ambrass, Scott Mitchell, Ishant Khurana
Abstract: A foamable composition including a polypropylene-based copolymer and a polyolefin is disclosed. The composition can be used to make a stiff foam with a high closed-cell content. Methods for producing the composition and the foam are provided.
Type:
Grant
Filed:
August 17, 2021
Date of Patent:
February 28, 2023
Assignee:
BRASKEM AMERICA, INC.
Inventors:
Kimberly Miller McLoughlin, Kevin Herrington
Abstract: This invention relates to a polyolefin blend composition comprising a polyolefin base polymer component and a functionalized polybutadiene component. The polyolefin blend exhibits both i) an increased melt flow and ii) an increased impact toughness and/or melt elasticity, as compared to the same composition without the functionalized polybutadiene. This invention also relates to a method of increasing the melt flow of a polyolefin and simultaneously increasing the impact toughness and/or the melt elasticity of the polyolefin by blending a polyolefin base polymer component and a functionalized polybutadiene component.
Abstract: A solid catalyst component for use in olefinic polymerization, includes titanium, magnesium, a halogen, and an internal electron donor compound; wherein: the internal electron donor compound is at least one compound represented by Formula (I)):
Abstract: A colloidal suspension includes an organic phase and a complex of Formula I as precursor for Ziegler-Natta catalyst synthesis: XTiClp(OR1)4-p.YMg(OR2)q(OR3)t??(I). In Formula I, a molar ratio of X to Y (X/Y) is from 0.2 to 5.0, p is 0 or 1, 0<q<2, 0<t<2, the sum of q and t is 2, R1, R2, and R3 are each independently a linear or branched alkyl, a linear or branched heteroalkyl, a cycloalkyl, a substituted cycloalkyl, a substituted heterocycloalkyl, a substituted aryl, or a (heteroaryl)alkyl; and R2 is not the same as R3.
Type:
Grant
Filed:
June 18, 2020
Date of Patent:
May 17, 2022
Assignee:
Braskem America, Inc.
Inventors:
Jonas Alves Fernandes, George S. Ostace, Dana Hess