Abstract: Impact copolymer (ICP) compositions may include those having a melt strength (MS) and melt flow rate (MFR) described according to the formula: MS?325×MFR?1.7, wherein the MS is greater than 1 cN. Methods of producing an impact copolymer (ICP) composition may include coupling the ICP composition with a coupling agent, wherein the ICP composition includes a matrix polymer and a dispersed component; wherein the ICP composition possesses a measurable melt strength (MS) and melt flow rate (MFR) satisfying the equation: MS?325×MFR?1.7, wherein the MS is greater than 1 cN.
Type:
Application
Filed:
December 21, 2018
Publication date:
June 27, 2019
Applicant:
Braskem America, Inc.
Inventors:
Joel Carr, Gerd Lohse, Rajendra Krishnaswamy, William Scott Miller, Rita Majewski
Abstract: This invention relates to a process for forming a long-chain branched polymer and a long-chain branched polymer resulting from the process. The process comprises reacting (a) a polyolefin base polymer with (b) a coupling agent comprising a polymeric coupling agent, optionally blended with a molecular coupling agent, the polymeric coupling agent being a modified polyolefin having a reactive coupling group at one or more terminal ends of the modified polyolefin chain, to couple the polyolefin base polymer (a) with the coupling agent (b) to form a long-chain branched polymer having a long-chain branching and/or higher surface energy relative to the polyolefin base polymer.
Abstract: The present invention is related to a pipe support system comprising a sleeper, a metallic bar and a polymeric material pad coating said metallic bar or, optionally, a polymeric material support on which the pipe is supported, wherein said polymeric material support is attached on both sides by bars welded to the sleeper.
Type:
Grant
Filed:
September 26, 2013
Date of Patent:
June 18, 2019
Assignee:
Braskem America, Inc.
Inventors:
Javier Pac Luis Ferraz, Ivo Andrei Oliveira Lino Lima, Diercio Galdino da Silva Neto, Alessandro Bernardi
Abstract: A composition includes (a) a polypropylene or a polypropylene copolymer, (b) a polyol, and (c) optionally an organic peroxide. The polyol (b) is in the range of from about 0.01 wt. % to about 25 wt. % of the total weight of (a), (b) and (c). The method of making such a polymer composition, the method of using such a polymer composition, and a sheet or a fabricated article comprising such a polypropylene composition, are also provided.
Abstract: This invention relates to a process for forming a long-chain branched polymer and a long-chain branched polymer resulting from the process. The process comprises reacting (a) a polyolefin base polymer with (b) a coupling agent comprising a polymeric coupling agent, optionally blended with a molecular coupling agent, the polymeric coupling agent being a modified polyolefin having a reactive coupling group at one or more terminal ends of the modified polyolefin chain, to couple the polyolefin base polymer (a) with the coupling agent (b) to form a long-chain branched polymer having a long-chain branching and/or higher surface energy relative to the polyolefin base polymer.
Abstract: A polymer sheet includes a core layer containing a propylene impact copolymer (ICP), and a first additional layer comprising a first polymer composition. The propylene impact copolymer (ICP) in the core layer includes a matrix and a dispersed phase. The matrix comprises a polypropylene homopolymer or a propylene/alpha-olefin random copolymer which includes greater than 50 wt. % of units derived from propylene monomer. The dispersed phase includes a copolymer of ethylene and a C3-C8 ?-olefin. The ICP has a first melting point being greater than 100° C. (e.g., in the range of from 100° C. to 130° C.) and a second melting point. The polymer sheet can also include a second additional layer containing a second polymer composition.
Abstract: A polymer sheet includes a core layer containing a propylene impact copolymer (ICP), and a first additional layer comprising a first polymer composition. The propylene impact copolymer (ICP) in the core layer includes a matrix and a dispersed phase. The matrix comprises a polypropylene homopolymer or a propylene/alpha-olefin random copolymer which includes greater than 50 wt. % of units derived from propylene monomer. The dispersed phase includes a copolymer of ethylene and a C3-C8 ?-olefin. The ICP has a first melting point being greater than 100° C. (e.g., in the range of from 100° C. to 130° C.) and a second melting point. The polymer sheet can also include a second additional layer containing a second polymer composition.
Abstract: This invention relates to a non-phthalate catalyst system for olefin polymerization. The non-phthalate catalyst system comprises (a) a solid Ziegler-Natta catalyst composition comprising a transition metal, a Group 2 metal, and one or more halogens; and one or more internal electron donor compounds; and (b) one or more external electron donor compounds.
Abstract: A composition includes (a) a polypropylene or a polypropylene copolymer, (b) a polyol, and (c) optionally an organic peroxide. The polyol (b) is in the range of from about 0.01 wt. % to about 25 wt. % of the total weight of (a), (b) and (c). The method of making such a polymer composition, the method of using such a polymer composition, and a sheet or a fabricated article comprising such a polypropylene composition, are also provided.
Abstract: A polymer composition providing optical clarity and impact resistance includes from about 40 weight percent (wt. %) to about 99.9 wt. % (e.g., 50-95 wt. %) of a continuous matrix, and from about 0.01 wt. % to about 60 wt. % (e.g., 5-50 wt. %) of a dispersed phase. The weight percentages of the matrix phase and the dispersed phase are based on the total weight of the matrix phase and the dispersed phase. The matrix phase may comprise a polypropylene polymer comprising from 0 to 7 mole percent (mol. %) of units derived from ethylene, a C4-C10 alpha olefin or combinations thereof. The dispersed phases may be a propylene/alpha olefin copolymer having from 10 mol. % to 70 mol. % of units derived from ethylene or a C4-C10 alpha olefin or combinations thereof.
Type:
Grant
Filed:
December 23, 2016
Date of Patent:
October 30, 2018
Assignee:
Braskem America, Inc.
Inventors:
Leslie Bockman, Elliot Carnevale, Jon Scott Larson, Kevin Herrington
Abstract: This invention relates to a process for forming a long-chain branched polymer and a long-chain branched polymer resulting from the process. The process comprises reacting (a) a polyolefin base polymer with (b) a coupling agent comprising a polymeric coupling agent, optionally blended with a molecular coupling agent, the polymeric coupling agent being a modified polyolefin having a reactive coupling group at one or more terminal ends of the modified polyolefin chain, to couple the polyolefin base polymer (a) with the coupling agent (b) to form a long-chain branched polymer having a long-chain branching and/or higher surface energy relative to the polyolefin base polymer.
Abstract: A polypropylene impact copolymer is disclosed. The propylene impact copolymer composition comprises from 60 to 90 percent by weight of the impact copolymer composition of a matrix phase, which can be a homopolymer polypropylene or random polypropylene copolymer having from 0.1 to 7 mol percent of units derived from ethylene or C4-C10 alpha olefins. The propylene impact copolymer composition also comprises from 10 to 40 percent by weight of the impact copolymer composition of a dispersed phase, which comprises a propylene/alpha-olefin copolymer having from 6 to 40 mol percent of units derived from ethylene or C4-C10 alpha olefins, wherein the dispersed phase has a comonomer content which is greater than the comonomer content in the matrix phase. The propylene impact copolymer composition is further characterized by having the ratio of the dispersed phase intrinsic viscosity (IV) to the matrix phase IV being 0.95 or less.
Type:
Grant
Filed:
August 19, 2010
Date of Patent:
June 20, 2017
Assignee:
Braskem America, Inc.
Inventors:
John Kaarto, Alechia Crown, Li-Min Tau, Gert J. Claasen
Abstract: The present invention relates to a process for the preparation of catalytic support and the supported bimetallic catalysts, used in the production of ethylene homopolymers and ethylene copolymers with ?-olefins, of high and ultra high molecular weight with broad molecular weight distribution, in gas or liquid phase polymerization processes, the latter being in slurry, bulk or suspension, and the products obtained from these processes.
Type:
Grant
Filed:
March 4, 2011
Date of Patent:
October 4, 2016
Assignee:
Braskem America, Inc.
Inventors:
Marcia Silva Lacerda Miranda, Fernanda Oliveira Vieira da Cunha
Abstract: A foamable composition includes a semi-crystalline polyolefin having a crystallinity of at least 50% and a poly(sulfonyl azide) of at least 500 ppm based on the total weight of the foamable composition. The foamable composition has a melt strength of at least 20 cN, a melt drawability of at least 100 mm/s, flexural modulus is greater than about 240,000 psi. Such a composition can be used to make a low density foam having a density in the range from 0.005 g/cm3 to 0.6 g/cm3. A resulting foam or a fabricated article, the methods of the composition and the foam are also provided.
Type:
Application
Filed:
January 29, 2016
Publication date:
August 4, 2016
Applicant:
Braskem America, Inc.
Inventors:
Kimberly Miller McLoughlin, William Scott Miller, Michael Robert Stephans, Steven Michael Krupinski
Abstract: Process for the preparation of catalytic support and supported bimetallic catalysts for production of homopolymers and copolymers of ethylene with ?-olefins, of high and ultra high molecular weight and with broad molecular weight distribution in slurry, bulk and gas phase processes and products thereof. The present invention relates to a process for the preparation of catalytic support and the supported bimetallic catalysts, used in the production of ethylene homopolymers and ethylene copolymers with ?-olefins, of high and ultra high molecular weight with broad molecular weight distribution, in gas or liquid phase polymerization processes, the latter being in slurry, bulk or suspension, and the products obtained from these processes.
Type:
Grant
Filed:
July 3, 2008
Date of Patent:
December 15, 2015
Assignee:
Braskem America, Inc.
Inventors:
Marcia Silva Lacerda Miranda, Fernanda Oliveira Vieira da Cunha
Abstract: The present invention relates to polymer compositions comprising a propylene impact copolymer and a processing aid, as well as corrugated boards made from such compositions. The impact copolymer has a melt flow range of from 1.5 to 3.5 g/10 min and a dispersed phase content of from 5 to 30% by weight. The dispersed phase of the impact copolymer has an ethylene content of from 30- to 70% by weight of the dispersed phase. The matrix phase of the impact copolymer is a propylene homopolymer or a random copolymer comprising units derived from propylene and a second copolymer selected from either ethylene or 1-butene wherein the units derived from the second copolymer comprise from 0 to 5% by weight of the dispersed phase.
Abstract: The present invention relates to polymer compositions comprising a propylene impact copolymer and a processing aid, as well as corrugated boards made from such compositions. The impact copolymer has a melt flow range of from 1.5 to 3.5 g/10 min and a dispersed phase content of from 5 to 30% by weight. The dispersed phase of the impact copolymer has an ethylene content of from 30- to 70% by weight of the dispersed phase. The matrix phase of the impact copolymer is a propylene homopolymer or a random copolymer comprising units derived from propylene and a second copolymer selected from either ethylene or 1-butene wherein the units derived from the second copolymer comprise from 0 to 5% by weight of the dispersed phase.
Abstract: Propylene impact copolymers (ICPs) are provided which comprise: (a) a matrix phase which comprises from 60 to 95 weight % of a polypropylene polymer containing from 0 to 6 mole % of units derived from one or more alpha-olefins other than propylene, and (b) a dispersed phase which comprises from 5 to 40 weight % of a copolymer derived from a first comonomer which can be either propylene or ethylene together with a second alpha-olefin comonomer. The ICP is further characterized by having a beta/alpha ratio less than or equal to 1.1. The ICPs of the present invention are particularly well suited for applications requiring clear, tough polymers such as thin walled injection molded articles for frozen food packaging applications.
Type:
Grant
Filed:
January 9, 2013
Date of Patent:
October 28, 2014
Assignee:
Braskem America, Inc.
Inventors:
Peter S. Dias, Jonathan D. Kersey, Peter S. Martin, Thomas R. Cuthbert
Abstract: Disclosed is a multimodal propylene impact copolymer composition with improved stiffness while maintaining good impact strength. The continuous phase has a broad PI and provides the multimodal propylene impact copolymer composition with excellent processability. Thermoformed articles made from the multimodal propylene impact copolymer exhibit improved rigidity and good impact strength.
Type:
Grant
Filed:
April 28, 2011
Date of Patent:
August 19, 2014
Assignee:
Braskem America, Inc.
Inventors:
Alechia Crown, Debra R. Wilson, John Kaarto
Abstract: Propylene impact copolymers (ICPs) are provided which comprise: (a) a matrix phase which comprises from 60 to 95 weight % of a polypropylene polymer containing from 0 to 6 mole % of units derived from one or more alpha-olefins other than propylene, and (b) a dispersed phase which comprises from 5 to 40 weight % of a copolymer derived from a first comonomer which can be either propylene or ethylene together with a second alpha-olefin comonomer. The ICP is further characterized by having a beta/alpha ratio less than or equal to 1.1. The ICPs of the present invention are particularly well suited for applications requiring clear, tough polymers such as thin walled injection molded articles for frozen food packaging applications.
Type:
Application
Filed:
January 9, 2013
Publication date:
July 10, 2014
Applicant:
BRASKEM AMERICA, INC.
Inventors:
Peter S. Dias, Jonathan D. Kersey, Peter S. Martin, Thomas R. Cuthbert