Abstract: The invention concerns a superconducting high-field magnet system (1) for a high-resolution magnetic resonance spectrometer, comprising a magnet coil (4) which is superconductingly short-circuited during operation, and generates a homogeneous temporally stable magnetic field during operation that meets the requirements for taking a high-resolution magnetic resonance spectrum. The magnet coil (4) comprises an LTS partial coil (4b, 4c) and an HTS partial coil (4a, 4d). The LTS partial coil (4b, 4c) can be separately short-circuited in a pure LTS circuit (14b) via an LTS switch (15b), and the HTS partial coil (4a, 4d) can be separately short-circuited in a pure HTS circuit (14) via an HTS switch (15a) and both partial coils (4a, 4d; 4b, 4c) are connected via an LTS-HTS joint (20) and are charged by the same power supply.

Abstract: A cryostat (1) with a first helium tank (4) which contains helium at an operating temperature T1<3 K, and a second helium tank (2) which is connected to the first helium tank (4) and contains liquid helium at an operating temperature T2>3 K, wherein a cooling means (6) is provided in the first helium tank (4) which generates an operating temperature T1<3 K in the first helium tank (4), wherein the cooling means (6) is designed as a Joule-Thomson valve with downstream heat exchanger from which pumped helium is transported to a room temperature region outside of the cryostat (1) is characterized in that a refrigerator (11) is provided whose cold end (19) projects into the second helium tank (2) and the supplied helium is returned during normal operation in a closed loop along the refrigerator (11) and into the second helium tank (2), thereby being pre-cooled and liquefied at the cold end (19) of the refrigerator (11).

Abstract: A co-axial magnet configuration for the production of a magnetic field and investigational volume which is suitable for measurement of magnetic resonance has at least one superconducting solenoid coil or solenoid coils which are radially nested within each other, wherein the windings of the solenoid coil(s) in a radial region about the axis of the magnetic configuration are disposed between r1 and r2, wherein r1<r2 is characterized in that the windings are surrounded by at least one rotationally symmetric magnet body made from ferromagnetic material which extends over a radial region between r3 and r4 wherein r3<r4 wherein r2<r3<1.3 r2 and r4>1.

Abstract: A superconducting magnet coil configuration comprising at least one section of a superconducting strip conductor, which is continuously wound in a cylindrical winding chamber (1) between two end flanges (2, 3) in several solenoid-like layers is characterized in that the section comprises an axial region of reduced current density (=notch region (12)), and the winding chamber (1) in the notch region (12) contains a first separating body (4) with a truncated conical envelope (5) which axially divides the winding chamber (1) into two partial chambers (6, 7), the superconducting strip conductor being guided over the truncated conical envelope (5) of the first separating body (4) from one partial chamber (6) into the other partial chamber (7) via a single-layer transfer winding (9), and a second separating body (10) is provided which supplements the first separating body (4) in the notch region (12) in a radial outer direction to form a circular cylinder, wherein the single-layer transfer winding (9) is disposed b

Abstract: The invention concerns a method for charging an actively shielded magnet coil arrangement (20) comprising a first partial region (21) which can be superconductingly short-circuited using an additional switch (23), and a second partial region (22), wherein the two partial regions (21, 22) generate dipole moments of different signs. The magnetic fringe field B* is measured close to the desired operating state of the arrangement (20) and operating currents are determined for each of the two partial regions (21, 22) at which the overall magnetic field B is free from an additional dipole moment caused by production tolerances to permit setting of the theoretically optimum fringe field, irrespective of production tolerances.

Abstract: A method for introducing a liquid sample into an NMR spectrometer to measure an NMR spectrum of the liquid sample, wherein the liquid sample is injected into a supply line and wherein further liquids are supplied into the supply line following the liquid sample, which are separated from each other and from the liquid sample by gas bubbles is characterized in that the liquid sample is supplied via an injection inlet to a valve configuration whose output side can be connected to the supply line and the further liquids and gas are supplied to the valve configuration via supply lines, wherein a desired sequence of sample segments, gas bubbles and further liquid segments is generated through temporally matched switching of the valve configuration in the supply line and is supplied to the NMR spectrometer. The inventive method realizes supply of a liquid sample into an NMR spectrometer with rapid sample transfer while thereby preventing mixing and dilution of the individual segments.

Abstract: The invention concerns an NMR apparatus (1) comprising an NMR spectrometer (2) for sequential investigation of several samples in sample containers (6) of substantially identical geometrical design, at a measuring position (10) in the NMR spectrometer (2) comprising a supply line (8) for pneumatic supply of the sample containers (6) from a magazine (3) to the measuring position (10). The apparatus is characterized in that the magazine (3) is disposed within a temperature-controlled cabinet, in particular, a cold chamber (4) and the supply line (8) can be heated. This substantially increases the throughput of samples of the NMR apparatus (1) with simple technical means.

Abstract: A method is described for determination of the content of at least one component of a sample by means of a nuclear magnetic resonance pulse spectrometer, with the magnetization of the sample being influenced by a sequence of radio-frequency pulses such that the signal amplitudes to be observed can be determined. The magnetization of the sample is initially saturated, and the signal amplitudes which are determined at each time by the longitudinal and transverse relaxation times T1 and T2 and/or T2* and/or T1p, from which a value for the content of the at least one component is determined, are measured at the same time in a cohesive experimental procedure.

Abstract: A description is given of a method for determining the content of a first component of a sample, which first component provides a first NMR signal and has a first self-diffusion coefficient D1, the sample additionally containing at least one further component which provides a further NMR signal and has a larger self-diffusion coefficient D2, in particular for determining the fat content of a hydrous sample, with the aid of a low-resolution nuclear magnetic resonance (NMR) pulse spectrometer, the sample being excited by a radio-frequency (RF) excitation pulse and being exposed to a magnetic gradient field and to a sequence of further refocusing RF pulses for generating spin echo signals, the spin echo signals being detected and their amplitude values being determined, from which a value for the content of the first component of the sample is determined. The magnetic gradient field is not switched off during the sequence of further refocusing RF pulses.

Abstract: The invention concerns a method for charging a magnet arrangement (20) comprising a first partial region (21) which can be superconductingly short-circuited via an additional switch (23), and a second partial region (22), wherein the two partial regions (21, 22) generate, in an investigational volume (8), gradients of second order having different signs. A magnetic field dependence B* is measured close to the desired operating state of the magnet arrangement (20) and operating currents are determined for each of the two partial regions (21, 22) at which the overall magnetic field B in the volume (8) under investigation is freed from a magnetic field gradient of second order. These operating currents are set thereby taking into consideration the inductive coupling of the partial regions (21, 22) through initially charging of the overall magnet arrangement (20) and, after closing of the additional switch (23), through continuation of charging only in the second partial region (22).

Abstract: A magnet system of a magnetic resonance apparatus for generating a magnetic field which is homogeneous and temporally highly stable within a volume under investigation and which extends along a z-axis, with a superconducting magnet coil (3) which is disposed in a cryostat (1) and with a periodically operated refrigerator (2) having a magnetic regenerator material which is disposed in a regenerator housing (5) within the cryostat (1) in the stray field of the magnet coil (3), and which is provided with a device (4) for shielding or compensating a magnetic disturbing field in the volume under investigation generated by the periodic operation of the refrigerator (2) due to regenerator magnetization changes is characterized in that the regenerator housing (5) is surrounded by a compensation coil arrangement (4) which can be superconductingly short-circuited and which is made from a plurality of conductor loops (6, 7a, 7b) which are separately short-circuited during measurement to keep a plurality of magnetic flux

Abstract: The invention concerns a method for spectrometric investigation of a plurality of samples dissolved in a solvent, comprising the following steps: (a) guiding a first solvent with a sample through an SPE cartridge (5) for concentrating the sample in the cartridge (5); (b) positioning the cartridge (5) in a carrier (4) for a plurality of cartridges (5); (c) repeating steps (a) and (b) for a desired number of samples; (d) drying the concentrated samples through removal of the residual first solvent, in particular, dehydration or evaporation; (e) dissolving each sample in a second solvent, transferring these dissolved samples from the cartridges (5) to a spectrometer and acquiring a spectrum of each sample. The method is characterized in that all samples are dried together in step (d) subsequent to steps (b) and (c) while the cartridges (5) with samples are positioned in the carrier (4). The drying process is thereby considerably accelerated in a straightforward technical manner.

Abstract: A superconducting magnet system with an operating temperature T1<3K which is disposed in a first helium tank (4) of a cryostat (1), wherein a second helium tank (2) is provided which is connected to the first helium tank (4) and contains liquid helium at an operating temperature T2>3K, wherein a cooling means is provided in the first helium tank (4) which generates an operating temperature T1<3K in that first helium tank (4) is characterized in that the cooling means is the cold end (19) of a pulse tube cooler (11) whose warm end (10) is disposed outside of the cryostat (1). The inventive magnet system minimizes the helium consumption thereby providing continuous measuring operation.

Abstract: The system describes a means and a method for stabilizing the magnetic field generated in the measuring volume of a high-resolution magnetic resonance spectrometer having an actively shielded magnet coil (4) which is located in a cryostat (2) and which is superconductingly short-circuited. The system comprises a compensation coil (12) which is decoupled from the magnet coil (4), and is disposed on the shielding coil (4b) of the magnet coil (4).

Abstract: A flat multi-layer arrangement (1; 1a-1f) of superconducting wires (4,5) with normally conducting substrate (17) and at least one fiber (16) which is electrically conductingly connected to the substrate (17) and is superconducting under predetermined operating conditions is characterized in that the superconducting wires (4, 5) in a respective layer (2, 3; 22, 23) are substantially disposed such that they do not cross. A resistive electric contact is provided between the superconducting wires (4, 5) of different layers (2,3; 22, 23) and the superconducting wires (4, 5) of at least two neighboring layers (2, 3; 22, 23) do cross, wherein no closed superconducting loops are present in the arrangement (1; 1a-1f). This arrangement permits shielding of the working volume of a magnet coil arrangement against low-frequency stray fields in an efficient and reliable manner.

Abstract: An actively shielded superconducting magnet coil system (1) for generating a magnetic field in a working volume (6), which is rotationally symmetric about a z-axis, comprising a radially inner main field winding (5) and a radially outer shielding winding (7), and an electrically highly conductive shielding cylinder (radially inner shielding cylinder) (8a/8b) which is disposed radially inside the main field winding (5) or between main field winding (5) and the shielding winding (7) is characterized in that at least one further electrically highly conductive shielding cylinder (9) is disposed radially outside the shielding winding (7). The inventive magnet coil system prevents generation of a fringe field flash in the outer region of the magnet coil system in case of a quench.

Abstract: In an arrangement for adjusting the spatial dependence of a magnetic field in a working volume of a main field magnet (19) by means of ferromagnetic field shaping elements (16), the field shaping elements (16) are formed from foils (1, 5, 7, 8) and/or sheet metals (10) having openings (2, 3) whose shape, position and size are selected such that the shape and the amount of the remaining ferromagnetic material produces a desired spatial dependence of the magnetic field in the working volume of the main field magnet for appropriate positioning of the foils (1, 5, 7, 8) and/or sheet metals (10) relative to the working volume of the main field magnet.

Abstract: The invention concerns a method for charging an actively shielded magnet coil arrangement (20) comprising a first partial region (21) which can be superconductingly short-circuited using an additional switch (23), and a second partial region (22), wherein the two partial regions (21, 22) generate dipole moments of different signs. The magnetic fringe field B* is measured close to the desired operating state of the arrangement (20) and operating currents are determined for each of the two partial regions (21, 22) at which the overall magnetic field B is free from an additional dipole moment caused by production tolerances to permit setting of the theoretically optimum fringe field, irrespective of production tolerances.

Abstract: The invention refers to a method of resonance spectroscopy for the analysis of statistical properties of samples, comprising the following steps: a) recording of a complex resonance frequency spectrum of each sample by means of phase sensitive quadrature detection; b) numerical differentiation of the recorded complex resonance frequency spectra versus frequency; c) determination of the absolute value of each differentiated complex resonance frequency spectrum (=fingerprint); d) allocation of each fingerprint to a point of a multidimensional point set; and e) performing a pattern analysis of the generated points for characterizing the statistical properties of the samples. The inventive method tolerates unintended variances of measurement in the recorded resonance. frequency spectra, in particular caused by phase errors, and allows reliable automated spectral analysis.

Abstract: The invention concerns a method for charging a magnet arrangement (20) comprising a first partial region (21) which can be superconductingly short-circuited via an additional switch (23), and a second partial region (22), wherein the two partial regions (21, 22) generate, in an investigational volume (8), gradients of second order having different signs. A magnetic field dependence B* is measured close to the desired operating state of the magnet arrangement (20) and operating currents are determined for each of the two partial regions (21, 22) at which the overall magnetic field B in the volume (8) under investigation is freed from a magnetic field gradient of second order. These operating currents are set thereby taking into consideration the inductive coupling of the partial regions (21, 22) through initially charging of the overall magnet arrangement (20) and, after closing of the additional switch (23), through continuation of charging only in the second partial region (22).