Patents Assigned to Casale SA
  • Patent number: 12140307
    Abstract: A burner (1) for the production of synthesis gas, configured to feed a reactant stream and an oxidant stream into a reaction chamber, the burner comprising at least one cooled component (11, 12), wherein said cooled component comprises channels (20) to convey a cooling medium, a cooling medium header (24) and a cooling medium collector (25), wherein said channels, said cooling medium header and said cooling medium collector are integrally formed within said cooled component of the burner.
    Type: Grant
    Filed: August 12, 2022
    Date of Patent: November 12, 2024
    Assignee: Casale SA
    Inventors: Luca Zanichelli, Nicola Panzeri, Fabiano Montini
  • Patent number: 12129170
    Abstract: A dual-pressure plant for the synthesis of nitric acid comprising: a reactor (4) providing a gaseous effluent (15) containing nitrogen oxides; an absorption tower (6) nitrogen oxides react with water providing raw nitric acid and, said absorption tower operating at a pressure greater than the pressure of the reactor; a compressor (5) elevating the pressure of the reactor effluent (15) to the absorption pressure; said plant also comprising a first bleacher (37) and a second bleacher (7), said first bleacher (37) stripping with air (39) nitrogen oxides from the output stream (27) of the absorption tower (6) providing a partially stripped nitric acid stream (40) and a nitrogen oxides-loaded air stream (41), the former being fed to the second bleacher (7) and the latter being recycled to the delivery-side of said compressor (5).
    Type: Grant
    Filed: April 4, 2022
    Date of Patent: October 29, 2024
    Assignee: Casale SA
    Inventors: Iacopo Cerea, Jean Francois Granger
  • Patent number: 12122681
    Abstract: A process for the synthesis of ammonia from a hydrocarbon feedstock, wherein the process includes reforming the hydrocarbon feedstock to produce a make-up gas and converting said make-up gas into ammonia, the process is performed in an ammonia synthesis plant requiring an electric power for operation and also requiring a start-up power (Ps) for start-up, wherein a first electric power (P1) is internally produced in the ammonia plant, and a second electric power (P2) is imported, wherein said second electric power is equal to or greater than said start-up power (Ps).
    Type: Grant
    Filed: July 16, 2019
    Date of Patent: October 22, 2024
    Assignee: CASALE SA
    Inventors: Umberto Rossi, Alessandra Pennati, Raffaele Ostuni, Costantino Bruni
  • Publication number: 20240344968
    Abstract: Method for determining the corrosion rate of a piece of equipment of a urea synthesis plant, the method comprises the provision of electrodes including a working electrode immersed in an aqueous solution containing ammonium carbamate, the method further comprises the determination of polarization data of the working electrode and the determination of the corrosion rate of said piece of equipment based on said polarization data.
    Type: Application
    Filed: October 11, 2022
    Publication date: October 17, 2024
    Applicant: Casale SA
    Inventors: Leonardo Marrone, Marco Ormellese, Silvia Beretta
  • Patent number: 12116335
    Abstract: A process for the production of feed grade urea starting from a liquid urea melt, the process comprising processing the urea melt (6) to promote the formation of biuret until a concentration of at least 3% biuret, and subjecting the so obtained biuret-containing urea melt (8) to a shaping process to obtain a granular urea product.
    Type: Grant
    Filed: September 10, 2021
    Date of Patent: October 15, 2024
    Assignee: Casale SA
    Inventor: Leonardo Marrone
  • Patent number: 12110264
    Abstract: A process for the production of urea wherein: production of pure urea (U) includes the concentration of an aqueous urea solution (23) by crystallization; a urea crystallization purge aqueous phase (32) comprising urea, water and biuret, which is purged from the urea crystallization process, is used in a high-biuret urea processing section (34) for additional production of urea with a high content of biuret.
    Type: Grant
    Filed: November 19, 2021
    Date of Patent: October 8, 2024
    Assignee: Casale SA
    Inventors: Leonardo Marrone, Alberto Benedetti
  • Publication number: 20240328616
    Abstract: A burner (1) for the production of synthesis gas, configured to feed a reactant stream and an oxidant stream into a reaction chamber, the burner comprising at least one cooled component (11, 12), wherein said cooled component comprises channels (20) to convey a cooling medium, a cooling medium header (24) and a cooling medium collector (25), wherein said channels, said cooling medium header and said cooling medium collector are integrally formed within said cooled component of the burner.
    Type: Application
    Filed: August 12, 2022
    Publication date: October 3, 2024
    Applicant: Casale SA
    Inventors: Luca Zanichelli, Nicola Panzeri, Fabiano Montini
  • Patent number: 12103905
    Abstract: Process for the preparation of urea granules comprising the steps of obtaining an aqueous urea solution from one or more synthesis and recovery steps wherein ammonia and carbon dioxide are reacted together, subjecting the aqueous urea solution to an evaporation step wherein water is removed to obtain a urea melt (1), processing and treating said urea melt in a granulation step (7) and optionally in a cooling section (10) to obtain solid urea granules (14); the process further comprises a scrubbing step (3) of granulation offgas and an atmospheric evaporation step (32) to recover a urea solution (2) and a water-saturated air stream (18): the water-saturated air stream is fed back to the scrubbing section (3) without condensation, and the recovered urea solution is conveyed to the granulation step (7).
    Type: Grant
    Filed: April 5, 2022
    Date of Patent: October 1, 2024
    Assignee: Casale SA
    Inventors: Paolo Bertini, Matteo Fumagalli
  • Publication number: 20240294469
    Abstract: A process for purify ing a urea-containing aqueous stream, such as the aqueous stream from the recovery section of a urea plant. comprising a step of removing biuret from the urea-containing stream by reverse osmosis in one or more reverse osmosis stages.
    Type: Application
    Filed: April 26, 2024
    Publication date: September 5, 2024
    Applicant: Casale SA
    Inventors: Leonardo Marrone, Alberto Benedetti, Paolo Bertini
  • Publication number: 20240262798
    Abstract: A process for the synthesis of urea and melamine, wherein urea synthesized in a urea plant is used to produce melamine in a melamine plant connected to the urea plant, according to a high-pressure non-catalytic melamine synthesis process, and offgas (16) liberated during the synthesis of melamine are returned to the urea plant after offgas processing (8) which includes a condensation and a urea formation step so that a urea-containing recycle stream (19) is returned to the synthesis section of the urea plant.
    Type: Application
    Filed: June 30, 2022
    Publication date: August 8, 2024
    Applicant: Casale SA
    Inventors: Paolo Bertini, Matteo Fumagalli
  • Patent number: 12030837
    Abstract: A process for the production of biuret from urea wherein: a urea aqueous solution (24) withdrawn from the recovery section of a urea plant is processed to remove water and obtain a concentrated urea melt (25); said urea melt is processed under biuret-forming conditions to decompose urea into biuret and ammonia and obtain a high-biuret urea melt (26); said high-biuret urea melt (26) is diluted with water or with an aqueous stream obtaining a solution (28); the solution (28) is subject to crystallization and precipitation of a solid phase containing biuret which is separated from the aqueous phase.
    Type: Grant
    Filed: August 31, 2021
    Date of Patent: July 9, 2024
    Assignee: Casale SA
    Inventors: Leonardo Marrone, Alberto Benedetti, Pierdomenico Biasi, Cristina Pizzolitto
  • Publication number: 20240217924
    Abstract: Process for the preparation of urea granules comprising the steps of obtaining an aqueous urea solution from one or more synthesis and recovery steps wherein ammonia and carbon dioxide are reacted together, subjecting the aqueous urea solution to an evaporation step wherein water is removed to obtain a urea melt (1), processing and treating said urea melt in a granulation step (7) and optionally in a cooling section (10) to obtain solid urea granules (14); the process further comprises a scrubbing step (3) of granulation offgas and an atmospheric evaporation step (32) to recover a urea solution (2) and a water-saturated air stream (18): the water-saturated air stream is fed back to the scrubbing section (3) without condensation, and the recovered urea solution is conveyed to the granulation step (7).
    Type: Application
    Filed: April 5, 2022
    Publication date: July 4, 2024
    Applicant: Casale SA
    Inventors: Paolo Bertini, Matteo Fumagalli
  • Publication number: 20240208897
    Abstract: A urea stripper or evaporator provided with fittings in the bottom liquid holder to reduce gas carryover wherein said fittings may include one or more of: perforated screens horizontally arranged or vertically in the bottom liquid holder; a sealed chamber arranged in the liquid holder to reduce the liquid collection volume in the liquid holder: a plurality of blades and/or vertical plates projecting from the inner surface of a bottom domed end of the apparatus to reduce speed of the liquid flow.
    Type: Application
    Filed: April 26, 2022
    Publication date: June 27, 2024
    Applicant: Casale SA
    Inventors: Andrea Beretti, Maddalena Vernier, Riccardo Lanzani, Paolo Bertini
  • Patent number: 12012372
    Abstract: A process for synthesis of urea from ammonia and carbon dioxide wherein: the urea synthesis is performed with a stripping process in a synthesis loop including at least a reactor (1), a stripper (2) and a condenser (3); the reactor effluent is treated in the stripper to remove unreacted ammonia and carbon dioxide; the urea solution (14) from the stripper is sent to a low-pressure recovery section (4); the stripper vapours are split into a first portion (151) directed to the reactor and a second portion (152) sent to the condenser; the condenser (3) is a shell-and-tube kettle condenser where condensation of stripper vapours is performed in the tube side (30); a carbamate-containing effluent (20) from the condenser is returned to the reactor.
    Type: Grant
    Filed: February 9, 2021
    Date of Patent: June 18, 2024
    Assignee: Casale SA
    Inventors: Leonardo Marrone, Paolo Bertini, Matteo Fumagalli
  • Patent number: 12006211
    Abstract: A dual-pressure plant for the synthesis of nitric acid comprising: a reactor (4) providing a gaseous effluent (15) containing nitrogen oxides; an absorption tower (6) nitrogen oxides react with water providing raw nitric acid and, said absorption tower operating at a pressure greater than the pressure of the reactor; a compressor (5) elevating the pressure of the reactor effluent (15) to the absorption pressure; said plant also comprising a first bleacher (37) and a second bleacher (7), said first bleacher (37) stripping with air (39) nitrogen oxides from the output stream (27) of the absorption tower (6) providing a partially stripped nitric acid stream (40) and a nitrogen oxides-loaded air stream (41), the former being fed to the second bleacher (7) and the latter being recycled to the delivery-side of said compressor (5).
    Type: Grant
    Filed: April 4, 2022
    Date of Patent: June 11, 2024
    Assignee: Casale SA
    Inventors: Iacopo Cerea, Jean Francois Granger
  • Patent number: 11987535
    Abstract: A process of granulation of a urea melt, comprising: adding a first additive containing carboxymethyl starch to one or more first stage(s) of the granulation process, to form a carcarboxymethyl starch containing inner layer of urea granules, and adding a second additive containing calcium lignosulfonate to one or more second stage(s) of the granulation process, downstream said first stages, to form granules with a coating containing calcium lignosulfonate.
    Type: Grant
    Filed: January 24, 2022
    Date of Patent: May 21, 2024
    Assignee: Casale SA
    Inventors: Leonardo Marrone, Andrea Beretti
  • Patent number: 11976028
    Abstract: A process for the synthesis of methanol from an input stream of synthesis gas, comprising the following steps: subjecting a portion of said input stream as feed stream to an adiabatic reactive step, providing an effluent containing methanol and unreacted synthesis gas; quenching of said effluent with a further portion of said input stream, providing a quenched stream; subjecting said quenched stream to an isothermal reactive step, providing a methanol-containing product stream.
    Type: Grant
    Filed: June 30, 2017
    Date of Patent: May 7, 2024
    Assignee: Casale SA
    Inventors: Pietro Moreo, Maddalena Lepri
  • Publication number: 20240125472
    Abstract: A method for the control of nitrogen oxides content in the combustion fumes of a thermal power plant is disclosed; the method comprises the on-site production of ammonia by the steps of: electrolysis of water as a source of hydrogen; separation of air as a source of nitrogen, formation of a make-up gas and synthesis of ammonia in a suitable synthesis loop; said on-site produced ammonia, or a solution thereof, is used for a process of reduction of nitrogen oxides in the combustion fumes.
    Type: Application
    Filed: December 21, 2023
    Publication date: April 18, 2024
    Applicant: Casale SA
    Inventors: Raffaele Ostuni, Federico Zardi
  • Patent number: 11925900
    Abstract: Process for reducing the content of NOx and N2O from an input tail gas of a nitric acid process, said input tail gas having a temperature lower than 400° C., the process comprising an abatement stage at least including a deN2O stage and deNOx stage and providing a conditioned tail gas having a temperature greater than the input tail gas, wherein, prior to submission to said abatement stage, said input tail gas is pre-heated to a temperature of at least 400° C. by indirect heat exchange with at least a portion of said conditioned gas.
    Type: Grant
    Filed: February 19, 2019
    Date of Patent: March 12, 2024
    Assignee: CASALE SA
    Inventors: Fabio Laurenzi, Raffaele Ostuni, Jean Francois Granger
  • Publication number: 20240043375
    Abstract: A process for the production of urea wherein: production of pure urea (U) includes the concentration of an aqueous urea solution (23) by crystallization; a urea crystallization purge aqueous phase (32) comprising urea, water and biuret, which is purged from the urea crystallization process, is used in a high-biuret urea processing section (34) for additional production of urea with a high content of biuret.
    Type: Application
    Filed: November 19, 2021
    Publication date: February 8, 2024
    Applicant: Casale SA
    Inventors: Leonardo Marrone, Alberto Benedetti