Abstract: A foam-forming composition comprising a mixture of at least one anionic surfactant and at least one cationic surfactant can effectively form a foam in a variety of formations including an oil-wet environment. In particular, this composition can be employed in a method which comprises at least periodically injecting a gas and this foam-forming composition into an oil-bearing formation to drive oil to a production well. In this composition, the ratio of the at least one anionic surfactant to the at least one cationic surfactant is selected so that the surfactants do not form substantial amounts of precipitate when mixed together. In certain environments, e.g., when the formation contains upwards of 20% total dissolved solids and/or a divalent metal ion concentration up to about 20,000 ppm, the composition can further contain at least one salt-tolerance additive, e.g., a nonionic surfactant.
Type:
Grant
Filed:
August 14, 1991
Date of Patent:
September 21, 1993
Assignee:
Chevron Research and Technology Company
Inventors:
Rawls H. Frazier, Jr., Donald L. Kuehne, Willie Horn, Jr., Jeremy Cantor
Abstract: The present invention relates to a process for producing a lube oil having a low pour point and excellent viscosity and viscosity index comprising isomerizing a waxy feed over a catalyst comprising a molecular sieve having generally oval 1-D pores having a minor axis between about 4.2 .ANG. and about 4.8 .ANG. and a major axis between about 5.4 .ANG. and about 7.0 .ANG. and at least one group VIII metal. SAPO-11, SAPO-31, SAPO-41, ZSM-22, ZSM-23 and ZSM-35 are examples of useful catalysts.
Abstract: Disclosed is a grease composition comprising a major amount of a lubricating oil base vehicle, a polyurea gellant in an amount sufficient to thicken the base vehicle to grease consistency, an alkali-metal borate in an amount sufficient to impart extreme-pressure properties to the grease and from 0.1 to 10.0 mass percent of antimony dithiocarbamate.
Abstract: Disclosed is a grease composition comprising a major amount of a lubricating oil base vehicle, a lithium gellant in an amount sufficient to thicken the base vehicle to grease consistency, an alkali-metal borate in an amount sufficient to impart extreme-pressure properties to the grease and from 0.1 to 10.0 mass percent of antimony dithiocarbamate.
Abstract: Essentially chlorine-free lubricating compositions having a TBN of 10-30 designed for use in internal combustion engines having silver bearing parts which provide protection for said bearings via the incorporation therein of certain unsaturated aliphatic carboxylic acids. An additive concentrate for said lubricating compositions is also disclosed.
Abstract: A method for reducing the amount of liquids produced from a selected geologic formation of a gas producing well is disclosed. A solution comprising controlled quantities of a scaling cation brine and scaling anion brine such that a scale will precipitate, and a controlled quantity of a scale inhibitor such that the scale precipitation will be delayed, is injected into the formation. The well is then shut-in long enough to allow the injected mixture to precipitate scale and to reduce the permeability of the formation such that a substantial portion of liquids that had been produced before, no longer are produced upon a resumption of gas production.
Abstract: Disclosed is a catalyst system for the homopolymerization and copolymerization of alpha-olefins having 2-8 carbon atoms, said catalyst system comprising a dimeric or tetrameric cyclopentadienyl Group 6b metal compound in which the metal has an oxidation state of +2, said Group 6b metal compound being supported on an inorganic support. The catalyst system may also contain a Group 2 or Group 3 metal alkyl compound cocatalyst.
Abstract: Disclosed is a process for recovering precious metals using a combination of smelting and an effective utilization of molten salt chlorination. More specifically, disclosed is a process including the steps of (i) contacting, for example, a matte with a chloride salt containing at least one of potassium, cesium or rubidium, but not sodium or lithium to form a matte/salt solids mixture, (ii) introducing the solids mixture into a chloride melt having a temperature ranging from 300.degree. C. to 650.degree. C., said melt containing at least one of potassium, cesium, rubidium, sodium or lithium, (iii) introducing a chlorine containing gas into the melt, and (iv) maintaining the salt ratio in the matte/salt mixture at a stoichiometrically equivalent amount with the precious metals and base metals contained in the matte.
Abstract: A process is disclosed for removing dissolved organics from an aqueous composition, said composition comprising water, carbon dioxide and dissolved organics, and said composition having a pH of 6.5 or less and an inlet organics concentration. The process comprises the steps of feeding said aqueous composition to a centrifugal separation zone, preferably to a hydrocyclone, depressurizing said composition in said centrifugal separation zone to regasify at least a portion of said carbon dioxide. An aqueous product stream is removed from the centrifugal separation zone wherein the concentration of said organics is less than said inlet organics concentration. The process is particularly useful in the cleanup of industrial wastewater, and also for removing organics from water produced in petroleum production operations.
Abstract: A method for improving the sweep efficiency of gas or steam flooding operations by reducing the permeability of relatively high permeability thief zones of an oil bearing subterranean reservoir having heterogeneous and/or fracture permeability and that is penetrated by at least one well is disclosed. A controlled quantity of a surfactant is injected into a high-permeability zone of a reservoir. Controlled quantities of a gas and a subsequent surfactant are then injected, simultaneously or alternatively into the same well, so that a controlled amount of foam having a controlled quality is generated in the high permeability zone, thereby reducing permeability. Following foam emplacement, a chase gas may be injected, and the steps of injecting surfactant and gas may be repeated as necessary to lower the gas-oil ration of non-problem offset producing wells to a preset limit.
Abstract: A process for separation and removal of stable polycyclic aromatic dimer foulants from refinery process streams by blending a paraffinic stream with a portion of heavy effluent from a hydrocracking reactor to induce precipitation of foulant, which may then be separated and removed from the hydrocracker. Additional embodiments include introduction of flocculating agents and adjusting the temperature of the blend.
Type:
Grant
Filed:
August 14, 1990
Date of Patent:
August 3, 1993
Assignee:
Chevron Research and Technology Company
Inventors:
John C. Fetzer, John M. Rosenbaum, Robert W. Bachtel, Dennis R. Cash, David G. Lammel
Abstract: Provided are lubricating oil compositions which contain (a) a mixture comprising an oil-soluble alkali metal compound and certain polyalkenyl succinimide or (b) alkali metal salts of said polyalkenyl succinimides.
Abstract: Disclosed herein is a process for preparing substantially pure crystalline SAPO-31 molecular sieve. In particular, disclosed are methods for preparing SAPO-31 which methods employ specified crystallization media with specified pHs. When such crystallization media are employed, the resulting SAPO-31 is substantially pure and has no contamination from crystalline SAPO-11 silicoaluminophosphate molecular sieve.
Abstract: A method for synthesizing molecular sieves is disclosed. The method comprises preparing an aqueous mixture comprising:a) a source zeolite, wherein said source zeolite contains sodalite substructures and has a tetrahedra atom density of less than about 15 TO.sub.2 per 1000 .ANG..sup.3, and wherein said source zeolite has a silica/alumina mole ratio greater than 200; an alkali metal oxide; and an organic template, and wherein said aqueous mixture has a composition in terms of mole ratios of oxides falling within the following ranges:______________________________________ M+/SiO.sub.2 = 0.01-1.00 OH-/SiO.sub.2 = 0.15-0.80 H.sub.2 O/SiO.sub.2 = 20-120 Q/SiO.sub.2 = 0.10-1.00 SiO.sub.2 /Y.sub.2 O.sub.
Abstract: Methylene and oxymethylene bis-esters are produced by the reaction of an aliphatic ester of a carboxylic acid, formaldehyde and carbon monoxide in the presence of a catalytic amount of a Group VIII noble transition metal compound, an iodide or bromide promoter, and a proton donor.
Abstract: Disclosed is a method for saponifying an ethylene-alkyl acrylate copolymer comprising mixing together an ethylene-alkyl acrylate copolymer and an aqueous solution of an inorganic alkali metal base at a temperature sufficient for saponification to take place and at which the ethylene-alkyl acrylate copolymer undergoes a phase change.
Abstract: A catalyst, and method of preparing and using a catalyst, for the hydrodesulfurization of metal-containing heavy feedstocks, which has improved catalytic life and metals capacity. The catalyst contains Group VIB and Group VIII metals or metal compounds on a support comprising alumina wherein the support has at least 80 percent of said pore volume in pores having a diameter of between 110 and 190 .ANG. and at least 70 percent of said pore volume in pores having a diameter between 130 and 200 .ANG..
Abstract: A spraying device having a sprayer head and an interchangeable, disposable, recyclable and/or biodegradable, and attachable cartridge, capable of diluting and dispensing a chemical. The device has a rotatable barrel valve to select whether to fill the cartridge, spray the diluted chemical, or prevent any flow. The device further has a pair of coupling tubes which permit the easy connection of the sprayer head to the cartridge in a way to cause, by aspiration, the partially diluted chemical to enter the sprayer head for further mixing and discharge. A rupturable or replaceable membrane is placed across the top of the cartridge to contain the concentrated chemical prior to use. A plug closure permits the addition of a chemical to the cartridge.