Patents Assigned to Chlorine Engineers Corp., Ltd.
  • Patent number: 5378317
    Abstract: The method for removing organic film according to the present invention is very effective for removing a photo resist film in a process for manufacturing semiconductor device. A substrate (32) having a photo resist film (31) formed on it is processed in a wet processing tank (34) filled with a processing solution such as a mixed solution containing sulfuric acid and hydrogen peroxide or by a dry processing using oxygen plasma. Then, it is processed in an ozone processing tank (34) filled with a solution where ozone or ozone water has been infused, and the organic film is removed.
    Type: Grant
    Filed: August 23, 1993
    Date of Patent: January 3, 1995
    Assignee: Chlorine Engineers Corp., Ltd.
    Inventors: Masaharu Kashiwase, Terumi Matsuoka
  • Patent number: 5360526
    Abstract: An electrode (14) is joined to ridges (12) or ribs of a partition (11) by means of spring members (13), each being in comb form and bent at the toothed portions (16) thereof, so that, while the electrode surface is kept flat, the toothed portions (16) can be held with any desired distance with respect to electrode-supporting portions such as the partition or its ribs, but without causing damage to an ion-exchange membrane.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: November 1, 1994
    Assignee: Chlorine Engineers Corp. Ltd.
    Inventors: Osamu Arimoto, Shinji Katayama, Yoshinari Take
  • Patent number: 5354434
    Abstract: Waste solution of developer, used as developer for a positive type photo resist and containing tetraalkylammonium hydroxide is neutralized with carbon dioxide, and it is filtered through a separation membrane. After removing precipitates of insoluble organic substances, it is sent to an anode chamber of an electrolytic cell divided by a cation exchange membrane, and electrolysis is performed. Low grade organic compounds in aqueous solution of tetraalkylammonium hydroxide obtained from a cathode chamber of a first stage electrolytic cell are oxidized and decomposed and are then supplied to an anode chamber of the next stage electrolytic cell, and high purity tetraalkylammonium hydroxide aqueous solution is obtained from the cathode chamber.
    Type: Grant
    Filed: December 15, 1993
    Date of Patent: October 11, 1994
    Assignee: Chlorine Engineers Corp. Ltd.
    Inventors: Hitoshi Satoh, Motoko Fukui, Chisako Kawakami
  • Patent number: 5314591
    Abstract: An electrolyzer includes a stack composed of a plurality of upright electrolytic cell units, each unit including an electrolytic cell unit frame bounding a pair of electrode sheets. Each pair of electrode sheets are anode-side and cathode-side partitions having opposed recesses and projections that are engaged in nesting relationship with each other. A gas-liquid separation chamber is provided which is integral with an upper edge of the electrolytic cell unit frame.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: May 24, 1994
    Assignee: Chlorine Engineers Corp., Ltd
    Inventors: Shinji Katayama, Yoshinari Take
  • Patent number: 4775452
    Abstract: Disclosed herein is a process for dissolving and recovering noble metals form used catalysts. Noble metal components are leached out from particles supporting or containing at least one noble metal or noble metal compound by subjecting particles them to electrolysis, with the electrolyte being an acid, in the anode compartment of an electrolytic cell which divided by a diaphragm into anode and cathode compartments, and the resulting solution containing noble metals is subjected to electrolysis in a fluidized bed electrolytic cell, thereby causing the noble metals to separate out on to the fluidizing cathode particles. The thus deposited noble metals are again leached out in an electrolytic cell.
    Type: Grant
    Filed: December 23, 1986
    Date of Patent: October 4, 1988
    Assignee: Chlorine Engineers Corp. Ltd.
    Inventors: Tadashi Kuninaga, Hiroshi Daidoji, Nobutaka Goto
  • Patent number: 4663013
    Abstract: A method of bonding a cation exchange membrane of the type having a perfluorosulfonic acid group on one face and a perfluorocarboxylic acid group on the other face, with a reinforcing mesh material embedded therein and a fluorine-containing resin sheet is disclosed.
    Type: Grant
    Filed: May 1, 1985
    Date of Patent: May 5, 1987
    Assignee: Chlorine Engineers Corp. Ltd.
    Inventors: Isao Kumagai, Makoto Kataoka, Yuji Kinoshita
  • Patent number: 4654135
    Abstract: A cell is disclosed whereby sea water is electrolyzed to form an aqueous hypochlorite solution with reduced formation of interfering deposits on the electrodes. The cell comprises a plurality of electrolytic cell units having a pair of cathodes and an anode placed between said cathodes, an electrolyte inlet at the lower part of an end frame, an electrolyte outlet at the upper part of an end frame. One of a pair of cathodes has an aperture at a position corresponding to the inlet, and the other cathode has an aperture at a position corresponding to the outlet. The anode has apertures at the position corresponding to the inlet and outlet.
    Type: Grant
    Filed: December 16, 1985
    Date of Patent: March 31, 1987
    Assignee: Chlorine Engineers Corp. Ltd.
    Inventors: Shinichiro Yamamoto, Shigeki Sudo, Tsuyoshi Ohmizu
  • Patent number: 4626331
    Abstract: In an electrolytic cell of the type which includes a cylindrical electrolytic cell main body divided into a main electrode chamber and an auxiliary electrode chamber by a diaphragm, and having main electrode particles in the main electrode chamber, which are maintained in the fluidized state by an electrolyte supplied to the main electrode chamber, an improvement is disclosed wherein an electrolyte supply port and an electrolyte discharge port are provided to enable flow of electrolyte through said cell to maintain the fluidized state of said particles, and a porous auxiliary electrode is provided in contact with the diaphragm on the side thereof facing said auxiliary electrode chamber, to facilitate flow of gas generated on the auxiliary electrode in the direction of the auxiliary chamber.
    Type: Grant
    Filed: November 21, 1985
    Date of Patent: December 2, 1986
    Assignee: Chlorine Engineers Corp., Ltd.
    Inventors: Nobutaka Goto, Nobuyasu Ezawa
  • Patent number: 4622113
    Abstract: Process or producing caustic alkalis or alkali hydroxides by electrolysis, employing a double electrode-type electrolysis tank in which a cation exchange membrane is provided to divide the inside of the tank into cathode and anode compartments, supplying to the anode compartment an alkali chloride, supplying water or a dilute solution of an alkali hydroxide into the cathode compartment, and taking away the alkali hydroxide and the hydrogen gas produced by electrolysis, in a mixed state of gas and liquid from the cathode compartment. The electrolysis tank comprises a number of finger-anodes extending from one of the walls of the tank and a number of finger-like hollow cathodes extending from the other wall of the tank, into which the finger-anodes project to form a gap therebetween, and a cation exchange membrane extending through the gap to divide the inside of the tank into cathode and anode compartments.
    Type: Grant
    Filed: November 19, 1984
    Date of Patent: November 11, 1986
    Assignees: Toyo Soda Manufacturing Co., Ltd., Chlorine Engineers Corp., Ltd.
    Inventors: Takao Satoh, Masaki Murakami, Nobuhiro Kawasaki, Teruo Ichisaka, Shinji Katayama
  • Patent number: 4605685
    Abstract: A method for the preparation of a graft polymer membrane comprising an inactive polymer film having TFS as a graft chain. The inactive polymer film is irradiated with ionizing radiation, and the resulting irradiated film is graft-polymerized by contacting said film with TFS.This product may then be sulfonated to provide a cation exchange membrane; or the obtained graft polymer may be haloalkylated, and quarternary aminated to provide an anion exchange membrane; or the graft polymer membrane may be used to prepare a weakly acidic cation exchange membrane by substituting at least part of the benzene rings of the graft polymer by one of the groups among hydroxyl groups, carboxylic acid groups, phosphoric acid groups and phosphorous acid groups.The polymeric membrane products are also disclosed and claimed.
    Type: Grant
    Filed: September 6, 1984
    Date of Patent: August 12, 1986
    Assignee: Chlorine Engineers Corp., Ltd.
    Inventors: Takashi Momose, Kazuo Tomiie, Hiroyuki Harada, Hiroshi Miyachi, Hiroko Kato
  • Patent number: 4569729
    Abstract: In an electrolytic cell of the type which includes a cylindrical electrolytic cell main body divided into a main electrode chamber and an auxiliary electrode chamber by a diaphragm, and having main electrode particles in the main electrode chamber, which are maintained in the fluidized state by an electrolyte supplied to the main electrode chamber, an improvement is disclosed wherein an electrolyte supply port and an electrolyte discharge port are provided to enable flow of electrolyte through said cell to maintain the fluidized state of said particles, and a porous auxiliary electrode is provided in contact with the diaphragm on the side thereof facing said auxiliary electrode chamber, to facilitate flow of gas generated on the auxiliary electrode in the direction of the auxiliary chamber.
    Type: Grant
    Filed: November 19, 1984
    Date of Patent: February 11, 1986
    Assignees: Chlorine Engineers Corp., Ltd., Tanaka Kikinzoku Kogyo K.K.
    Inventors: Nobutaka Goto, Nobuyasu Ezawa
  • Patent number: 4543265
    Abstract: A cathode for use in electrolysis comprising (1) a corrosion-resistant electrically conductive substrate; and (2) a coating thereon of a mixture of fine particles of (a) nickel or an alloy of nickel, and (b) fine particles of a platinum-group metal oxide uniformly dispersed in the nickel or the alloy of nickel in an amount of about 0.1% to about 50% by weight; and a method for the production thereof.
    Type: Grant
    Filed: February 29, 1984
    Date of Patent: September 24, 1985
    Assignee: Chlorine Engineers Corp. Ltd.
    Inventor: Kazuki Kasuya
  • Patent number: 4465580
    Abstract: A cathode for use in electrolysis comprising (1) a corrosion-resistant electrically conductive substrate; and (2) a coating thereon of (a) nickel or an alloy of nickel, and (b) fine particles of a platinum-group metal, a platinum-group metal oxide or a mixture thereof uniformly dispersed in the nickel or the alloy of nickel, the particles being present in the coating in an amount of about 0.1% to about 50% by weight; and a method for the production thereof.
    Type: Grant
    Filed: February 2, 1979
    Date of Patent: August 14, 1984
    Assignee: Chlorine Engineers Corp. Ltd.
    Inventor: Kazuki Kasuya
  • Patent number: 4448664
    Abstract: An anode for electrolysis includes an electrically conductive bar erected on an electrolytic cell bottom plate, opposed anode bodies connected to the electrically conductive bar through anode supporting bodies, and reinforcing bodies provided between the opposed anode bodies and outside the anode supporting bodies.
    Type: Grant
    Filed: June 6, 1983
    Date of Patent: May 15, 1984
    Assignee: Chlorine Engineers Corp., Ltd.
    Inventors: Tadao Ikegami, Takeshi Miyamoto
  • Patent number: 4421614
    Abstract: The method for bypassing the electric current of at least one cell of an electrolytic apparatus includes a series combination of a resistor and a switch connected in parallel to the terminals of the cell to be repaired or replaced. In another embodiment a plurality of said series combinations may be connected in parallel to each other and be connected in parallel to the terminals of the cell to be bypassed.
    Type: Grant
    Filed: December 2, 1981
    Date of Patent: December 20, 1983
    Assignee: Chlorine Engineers Corp. Ltd.
    Inventors: Kenzo Yamaguchi, Yoshinari Take, Akiyoshi Manabe
  • Patent number: 4417970
    Abstract: An electrolytic cell having a plurality of porous and tubular cathodes, a plurality of porous anodes and a plurality of bag-shaped molds being formed by a cation exchange membrane in at least the portions facing and between the vertical faces of the anode and cathodes. The anode accommodating bag-shaped molds have apertures at the bottom through which anode connected electroconductive bars extend, said bars being inserted through and secured at corresponding cell bottom plate apertures by flanges. A partition plate, on the top of the cell main body, has a plurality of openings which correspond to the open tops of the bag-shaped molds. The open top edges of the bag-shaped molds are secured to the partition plate openings by a plurality of lid members.
    Type: Grant
    Filed: October 29, 1982
    Date of Patent: November 29, 1983
    Assignee: Chlorine Engineers Corp. Ltd.
    Inventors: Kenzo Yamaguchi, Teruo Ichisaka, Tadao Ikegami, Isao Kumagai
  • Patent number: 4409084
    Abstract: An electrolytic cell for the ion exchange membrane method, which comprises:(a) an electrolytic cell main body;(b) a lid covering the(c) porous and hollow tubular cathodes disposed in the body;(d) a bottom plate having apertures through which an electrically conductive bar can be extended;(e) electrically conductive bars provided with a flange at a lower portion thereof, each inserted through the apertures of the bottom plate into the interior of the body and secured to the bottom plate by the flange;(f) porous anodes each connected to the electrically conductive bar and placed vertically in a face-face relation to the cathode, and disposed between the cathodes;(g) bag-shaped elements, portions of which facing the anodes and the cathodes are formed by a cation exchange membrane, the bottom of which has at least one aperture through which the electrically conductive bar can be extended, and which have each an open top; and(h) a partition plate having openings, which plate is on the top of the body,whereinone or
    Type: Grant
    Filed: August 13, 1981
    Date of Patent: October 11, 1983
    Assignee: Chlorine Engineers Corp. Ltd.
    Inventors: Kenzo Yamaguchi, Teruo Ichisaka, Tadao Ikegami
  • Patent number: 4396727
    Abstract: A uniform cation exchange membrane having a certain fluorovinyl sulfonic acid monomer grafted onto a certain high-molecular substrate film which exhibits small electrical resistance and great physical strength is herein disclosed.
    Type: Grant
    Filed: November 9, 1981
    Date of Patent: August 2, 1983
    Assignees: Japan Atomic Energy Research Institute, Chlorine Engineers Corp., Ltd.
    Inventors: Isao Ishigaki, Jiro Okamoto, Hiroyuki Harada
  • Patent number: 4384941
    Abstract: A process is, herein, disclosed for electrolysis or pure water in an electrolytic cell which is divided into an anode compartment and a cathode compartment by a cation exchange membrane and in which pure water is supplied to the anode compartment for electrolysis to generate oxygen in the anode compartment and hydrogen in the cathode compartment, said cation exchange membrane being produced by grafting a fluorovinyl sulfonic acid monomer onto a membranous polymeric substrate having a monomer unit of the formula: ##STR1## (wherein X is hydrogen, fluorine or CH.sub.3 ; and Y is hydrogen or fluorine), said cation exchange membrane being used in close contact with an anode and a cathode.
    Type: Grant
    Filed: February 3, 1982
    Date of Patent: May 24, 1983
    Assignees: Japan Atomic Energy Research Institute, Chlorine Engineers Corp. Ltd.
    Inventors: Jiro Okamoto, Isao Ishigaki, Hiroyuki Harada
  • Patent number: 4317709
    Abstract: In an apparatus for electrolyzing an aqueous solution, which includes a plurality of electrolytic cells disposed at a plurality of vertically spaced levels and divided by partitions from one another, each of said cells having at least one anode and at least one cathode, said cells including an uppermost cell having an inlet for said solution, and a lowermost cell having an outlet for said solution, the improvement wherein:(a) each cell being separated into at least two horizontally adjacent cell units;(b) the separation adapted to direct the solution flow from the top of one unit into the bottom of the adjacent unit enabling solution flow successively through each unit;(c) a last unit of each cell provided with a passage extending from the top of the last unit to the bottom of the unit at a lower level to direct solution flow downwardly;(d) the anode and cathode being vertical in each unit opposite each other forming a bipolar electrode assembly; and(e) each unit with a gas collecting zone above the anode and
    Type: Grant
    Filed: June 26, 1980
    Date of Patent: March 2, 1982
    Assignee: Chlorine Engineers Corp., Ltd.
    Inventors: Teruo Ichisaka, Yoshitugu Shinomiya