Patents Assigned to Ciba Corporation
  • Publication number: 20100284950
    Abstract: The instant invention refers to the use of a concentrated aqueous polymer dispersion with an average particle size of less than 1000 nm comprising (a) a polymer carrier prepared by heterophase radical polymerization of at least one ethylenically unsaturated monomer in the presence of (b) an oil-soluble organic UV absorber selected from the class of p-aminobenzoic acid derivatives; salicylic acid derivatives; benzophenone derivatives; diphenyl acrylate derivatives; benzofuran derivatives; polymeric UV absorbers, comprising one or more organosilicon radicals; cinnamic acid derivatives; camphor derivatives; s-triazine derivatives; trianilino-s-triazine derivatives; menthyl anthranilates; and benzotriazole derivatives; wherein the weight ratio of the oil-soluble organic UV absorber (b) to polymer carrier (a) is greater than 50 parts UV absorber per 100 parts of carrier; for the protection of human and animal hair and skin against the damaging effect of UV radiation.
    Type: Application
    Filed: June 30, 2008
    Publication date: November 11, 2010
    Applicant: CIBA CORPORATION
    Inventors: Stefan Müller, Brigitte Lindemann, Bernd Herzog
  • Patent number: 7828858
    Abstract: Disclosed are mixtures of sulfide dyes and dyeing compositions comprising mixtures of sulfide dyes. The dye mixtures are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
    Type: Grant
    Filed: September 13, 2006
    Date of Patent: November 9, 2010
    Assignee: Ciba Corporation
    Inventors: Christian Cremer, Victor Paul Eliu, Beate Fröhling, Olof Wallquist
  • Publication number: 20100280183
    Abstract: The invention relates to a liquid dispersant based on polyamine-graft-polyacrylate blend, its preparation and its use in solvent borne systems, especially to a polyamine-g-polyacrylate grafted copolymer blend of the general formula (1) or a mixture of formula (1) and YT-(A1,A2)-Y1 wherein T is a polyamine or polyimine, A1 is a bridging bond which is selected from amide or amide, A2 is a —N—C— bridging bond, Y is an acrylate residue of the general formula (2), wherein, R1 and R2 are, independently, hydrogen or C1-20alkyl, aryl, heteroaryl, substituted aryl. n is a number of 1-1000, wherein the polyamine-g-polyacrylate grafted copolymer blend has an average molecular weight of 50 000 g/mol to 150 000 g/mol and a polydispersity Mw/Mn is greater than 3.
    Type: Application
    Filed: February 25, 2008
    Publication date: November 4, 2010
    Applicant: CIBA CORPORATION
    Inventors: Huiguang Kou, Yanfei Liu
  • Patent number: 7824575
    Abstract: The present invention provides for liquid antioxidant mixtures of octylated/butylated diphenylamine, phenothiazine and octadecyl (3,5-di-tert-butyl-4-hydroxyphenyl)-propionate. The antioxidant mixtures are useful for polyurethane stabilization.
    Type: Grant
    Filed: July 31, 2008
    Date of Patent: November 2, 2010
    Assignee: Ciba Corporation
    Inventor: Walid Al-Akhdar
  • Patent number: 7820865
    Abstract: The instant invention relates to new photolatent compounds of the formula I wherein R1 and R2 are each independently of the other C1-C10alkyl or C3-C8cycloalkyl, R3 is hydrogen or C1-C4alkyl, and wherein the photochemically cleaved group R4OH is selected from the group consisting of fragrances, UV absorbers, anti-microbials, anti-fogging agents and clarifiers; with the proviso that, when R1 and R2 are tert-butyl and R3 is hydrogen, R4 is not methyl or phenyl.
    Type: Grant
    Filed: October 30, 2006
    Date of Patent: October 26, 2010
    Assignee: Ciba Corporation
    Inventors: Katharina Fritzsche, Walter Fischer, Johannes Benkhoff, Karin Powell, Dirk Simon
  • Patent number: 7812100
    Abstract: The invention relates to new alkoxyamines suitable for hydrosilylation reactions, to siloxane modified alkoxamines and to siloxane modified polymers as well as to their use. The alkoxamines are compounds of formula (I) or (II) wherein A is a group capable of forming a stable free nitroxyl radical A. which is bound via its oxygen atom to the carbon atom; R.sub.1 and R.sub.2 independently of one another are hydrogen, C.sub.1-C.sub.18-alkyl, C.sub.3-C.sub.8cycloalkyl or phenyl which are unsubstituted or substituted by NO.sub.2, halogen, amino, hydroxy, cyano, carboxy, C.sub.1-C.sub.4alkoxy, C.sub.1-C.sub.4alkylthio, C.sub.1-C.sub.4alkylamino or di(C.sub.1-C.sub.4alkyl)amino; R.sub.3, R.sub.4 and R.sub.5 independently of one another are hydrogen or C.sub.1-C.sub.18alkyl or phenyl; or R.sub.3 and R.sub.5 together with the linking group C.dbd.C form a 5 to 12 membered ring; R.sub.6 is X hydrogen or C.sub.1-C.sub.l8alkyl or phenyl; X is O, NH or NR.sub.7, wherein R.sub.7 is C.sub.1-C.sub.18alkyl, C.sub.3-C.sub.
    Type: Grant
    Filed: October 16, 2006
    Date of Patent: October 12, 2010
    Assignee: Ciba Corporation
    Inventors: Lothar Alexander Engelbrecht, Peter Nesvadba
  • Publication number: 20100252820
    Abstract: Electroneutral metal complexes of the formula L Cu A, wherein L stands for an, especially bidentate, neutral ligand and A stands for an, especially bidentate, monoanionic ligand binding to Cu by at least one heteroatom selected from N, P, S; or wherein the ligands L and A with the above features are interconnected by at least one chemical bond to form one common tetradentate ligand; or protonated or alkylated forms or salts thereof show good light emitting efficiency in electroluminescent applications.
    Type: Application
    Filed: June 13, 2008
    Publication date: October 7, 2010
    Applicant: CIBA CORPORATION
    Inventors: Luisa De Cola, Yinghui Sun, Franz Schwarzenbach, Roger Pretot
  • Publication number: 20100255326
    Abstract: A method is provided for enhancing the gas barrier properties of substrates such as materials used in packaging, by applying a composition comprising a vinyl alcohol/vinyl amide copolymer, a cross linker and, optionally, a diacrylate or other polyacrylate and a photo initiator to the material and curing the composition by irradiation with UV light, visible light, IR irradiation and/or electron beam or by exposure to heat. The method includes the optional step of subjecting the material to a low-temperature plasma discharge or a corona discharge prior to applying the composition. The method provides, for example, packaging materials, such as, flexible packaging materials such as plastic films producing packaging materials with excellent gas barrier properties, for example oxygen barrier properties, which are readily printed upon.
    Type: Application
    Filed: October 5, 2009
    Publication date: October 7, 2010
    Applicant: CIBA CORPORATION
    Inventors: Emanuela Chiappini, Stefano Gardi, Andrew J. Naisby, Rosanna Telesca, Walter Taplin, Neil Forsythe
  • Patent number: 7803197
    Abstract: Disclosed are thiol dyes of formula (1) wherein L1 is hydrogen; C1-C12alkyl; or phenyl-C1-C4alkyl; X is C1-C12alkylene, C2-C12alkenylene, C5-C10cycloalkylene, C5-C10arylene, or C5-C10arylene-C1-C10alkylene, which may by interrupted by —O—, —NH—, —S—, —CO—, o-SO2—; Y is the residue of an organic dye Z is a group of formula (1b) or —C?N; wherein A is O; S; or N-L2; B is L3; —OL3; —NL3L4; or —SL3; and L2, L3 and L4, independently from other are hydrogen; C1-C12alkyl; C5-C12aryl-C1-C12alkyl. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
    Type: Grant
    Filed: August 8, 2007
    Date of Patent: September 28, 2010
    Assignee: Ciba Corporation
    Inventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann
  • Publication number: 20100239642
    Abstract: Described are coating compositions for marking substrates comprising a) a solvent, b) a salt of a phosphorus or boron containing acid and an amine or imine, c) a salt of a non-phosphorus and non-boron containing acid and an amine or imine, d) a binder, and e) optionally additional ingredients, their manufacture and use, wherein the above-mentioned salts can also be present in an encapsulated form as a kind of pseudo-pigment. Substrates coated by the above compositions can be marked by laser irradiation.
    Type: Application
    Filed: July 3, 2008
    Publication date: September 23, 2010
    Applicant: CIBA CORPORATION
    Inventors: Jonathan Campbell, Adolf Kaeser, Kathleen Hoekstra, Kishor Kumar Mistry
  • Patent number: 7799951
    Abstract: The instant invention discloses a process for preventing contact discoloration of substrates coming into contact with elastomers and stabilizing elastomers to prevent oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, which comprises incorporating into the elastomers, or applying to these, at least a compound of the formula (I) wherein R1 is C1-C12alkyl, R2 is C1-C12alkyl, or R1 and R2 together with the carbon atom to which they are attached form an unsubstituted or with C1-C4alkyl substituted C5-C12cycloalkyl ring; R3 is hydrogen or —CH2—S(O)m—R5, R4 and R5 independently of each other are unsubstituted or with cyano substituted C5-C18-alkyl; C7-C9phenylalkyl, unsubstituted or with halogen, hydroxyl, cyano or C1-C4alkyl substituted phenyl or naphthyl; benzothiazolyl or —R6—CO2—R7, R6 is C1-C18alkylene, R7 is C1-C18alkyl, and m is 0, 1 or 2.
    Type: Grant
    Filed: October 2, 2006
    Date of Patent: September 21, 2010
    Assignee: Ciba Corporation
    Inventors: Michèle Gerster, Hans-Rudolf Meier, Gerrit Knobloch, Pierre Rota-Graziosi
  • Publication number: 20100233405
    Abstract: Disclosed are stabilized blends of polyester and polyamide. The polymer blends are stabilized with A) a combination of stabilizers a) acetaldehyde scavengers and b) stabilizers selected from phenolic antioxidants, organic phosphorus stabilizers and lactone stabilizers or B) a combination of c) lactone stabilizers and d) stabilizers selected from phenolic antioxidants and organic phosphorus stabilizers. The present blends exhibit reduced color formation, a high level of whiteness/brightness and acceptably low haze formation upon heat treatment. The blends are useful to make bottles, containers and films for drinks, food and cosmetics and the like. The polyester is in particular polyethylene terephthalate, PET, and the polyamide is in particular polyamide-MXD6. Heat treatment is for example melt extrusion or solid state polymerization, SSP.
    Type: Application
    Filed: March 11, 2010
    Publication date: September 16, 2010
    Applicant: CIBA CORPORATION
    Inventors: Stephen M. Andrews, Paul A. Odorisio, Yijun Ye
  • Publication number: 20100233447
    Abstract: The present invention provides polymeric particles comprising a polymeric matrix comprising one or more water-insoluble polymers and a laser-sensitive system encapsulated in the polymeric matrix. It also provides a process for the preparation of the polymeric particles, a composition comprising the polymeric particles, a process for the preparation of this composition, a process for forming a laser-sensitive coating layer on a substrate using this composition, a coated substrate obtainable by the coating process, a process for preparing a marked substrate and a marked substrate obtainable by the marking process.
    Type: Application
    Filed: July 4, 2008
    Publication date: September 16, 2010
    Applicant: CIBA CORPORATION
    Inventor: Jonathan Campbell
  • Publication number: 20100233406
    Abstract: Disclosed are stabilized blends of polyester and polyamide. The polymer blends are stabilized with A) one or more lactone stabilizers, B) one or more di-hydrocarbyl hydrogen phosphonates or one or more di-hydrocarbyl hydrogen phosphonites or C) one or more monoacrylate esters of 2,2?-alkylidenebisphenol antioxidants. The present blends exhibit reduced color formation, a high level of whiteness/brightness and acceptably low haze formation upon heat treatment. The blends are useful to make bottles, containers and films for drinks, food and cosmetics and the like. The polyester is in particular polyethylene terephthalate, PET, and the polyamide is in particular polyamide-MXD6. Heat treatment is for example melt extrusion or solid state polymerization, SSP.
    Type: Application
    Filed: March 11, 2010
    Publication date: September 16, 2010
    Applicant: CIBA CORPORATION
    Inventors: Stephen M. Andrews, Paul A. Odorisio, Yijun Ye
  • Publication number: 20100234495
    Abstract: The present invention relates to flame retardant polymer compositions which comprise mixtures of phosphinic acid salts and dihydro-oxa-phospho-phenantrene derivatives. The compositions are especially useful for the manufacture of flame retardant compounds based on polycondensates like polyesters, polyamides and polycarbonates.
    Type: Application
    Filed: March 25, 2008
    Publication date: September 16, 2010
    Applicant: CIBA CORPORATION
    Inventor: Michael Roth
  • Patent number: 7794509
    Abstract: Disclosed are tricationic dye compounds, useful for dyeing hair, wool, leather, silk, cellulose or polyamides. The dye compounds are of formula (1), where the groups are as defined in the specification and claims.
    Type: Grant
    Filed: June 4, 2007
    Date of Patent: September 14, 2010
    Assignee: Ciba Corporation
    Inventors: Christian Cremer, Olof Wallquist, Victor Paul Eliu, Kishor Ramachandra Nivalkar
  • Patent number: 7790769
    Abstract: Disclosed are merocyanine derivatives of formula (1), wherein R1 and R2 independently from each other are branched C4-C22alkyl; or branched C4-C12 alkenyl; R3 and R4 independently from each other are cyano; COR7, COOR7; CONR7R8; SO2(C6-C12)aryl; C2-C12alk-1-enyl; C3-C12cycloalk-1-enyl; C2-C12alk-1-inyl; C2-C12heteroalkyl; C3-C5heterocycloalkyl; C6-C10aryl; or C1-C9heteroaryl; wherein at least one of R3 and R4 is cyano; R5 and R6 independently from each other are hydrogen; C1-C6alkyl; C5-C8cycloalkyl which may be substituted by one or more than one C1-C4alkyl; and R7 and R8 independently from each other are hydrogen; C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; —(CH2)tCOOH; C7-C12aralkyl; C1-C12heteroalkyl; C2-C11heteroaralkyl; C6-C10aryl; C1-C9heteroaryl. The compounds are useful as UV absorbers for protecting human hair and skin against the damaging effect of UV radiation.
    Type: Grant
    Filed: December 11, 2006
    Date of Patent: September 7, 2010
    Assignee: Ciba Corporation
    Inventors: Barbara Wagner, Astrid Walther, Bernd Herzog
  • Patent number: 7789916
    Abstract: Disclosed are triarylmethane dye compounds of formula (2) wherein R8 is C1-C12alkyl, C1-C12alkoxy, phenyl, hydroxy, halogen, sulfonic acid, carboxylate, or the radical —NR6R7 or —OR8; B1 and B2, independently from each other are C6-C10aryl; or a 5-7-membered heterocyclic compound, which may be substituted by C1-C12alkyl, C1-C12alkoxy, phenyl, hydroxy, halogen, sulfonic acid, carboxylate, or by the radical —NR6R7 or —OR6; and R6 and R7 independently from each other are hydrogen; or C1-C12alkyl, which may be substituted by hydroxy or C6-C10aryl.
    Type: Grant
    Filed: September 27, 2006
    Date of Patent: September 7, 2010
    Assignee: Ciba Corporation
    Inventors: Christian Cremer, Olof Wallquist
  • Patent number: 7789957
    Abstract: Solid, low dust pigment compositions are formed i by mixing pigments with certain polymer stabilizers under conditions wherein the stabilizers are in a liquefied state. The pigment compositions are easily handled and have a high color yield when incorporated into polymer substrates. In many cases, the color development attained is not readily achievable using pigment compositions comprising conventional carriers.
    Type: Grant
    Filed: February 15, 2008
    Date of Patent: September 7, 2010
    Assignee: Ciba Corporation
    Inventors: John Adams, Roger Reinicker, Damien Thurber Cole, Gerard Finnegan
  • Publication number: 20100222454
    Abstract: Disclosed are a method for improving the degradation of natural and/or synthetic polymers or a polymer article made from such polymer(s) by light and/or heat and/or humidity, comprising the incorporation of a compound of formula (I) into said natural and/or synthetic polymers: Formula (I); wherein m is 1 or 2, n is 1 to 100, X is selected from certain benzophenone-derived moieties and R, R1; R2 are each selected from list of certain residues; novel compounds of said formula (I) and polymeric articles of improved degradability in the presence of light and/or heat and/or humidity being made of a composition comprising: A) a natural and/or a synthetic polymer and B) a degradation accelerator being a compound of said formula (I).
    Type: Application
    Filed: July 24, 2008
    Publication date: September 2, 2010
    Applicant: CIBA CORPORATION
    Inventors: Massimiliano Sala, Wiebke Wunderlich-Wippert, Stefano Gardi