Patents Assigned to Clearwater International
  • Patent number: 9062241
    Abstract: A drilling fluid, spacer fluid and cementing compositions for use in subterranean wells are disclosed along with methods for making using same, where the compositions include a weighting system having an effective amount of a metal silicon alloy, mixtures of metal silicon alloys, or mixtures of metal silicon alloys and conventional weighting agents, to produce compositions having a desired high density, while retaining other fluid properties such as pumpability, gas tight sealing, low tendency to segregate, and reduced high temperature cement strength retrogression.
    Type: Grant
    Filed: September 28, 2010
    Date of Patent: June 23, 2015
    Assignee: Clearwater International LLC
    Inventors: Frank Zamora, Marilyn J. Bramblett, Mario B. Hernandez, Sarkis R. Kakadjian, Ron Powell, Olusegun Matthew Falana
  • Publication number: 20150072901
    Abstract: A lost circulation additive including a guar chaff material. The method of forming a lost circulation fluid includes contacting the lost circulation additive with a base fluid. The method for treating a formation including injecting the loss circulation fluid into a wellbore.
    Type: Application
    Filed: September 4, 2014
    Publication date: March 12, 2015
    Applicant: CLEARWATER INTERNATIONAL LLC
    Inventors: Mathew M. Samuel, Gaston W. Curtis, Shawn Lu
  • Patent number: 8944164
    Abstract: Composition and methods using the compositions are disclosed, where the compositions include heterocyclic aromatic amines, substituted heterocyclic aromatic amines, poly vinyl heterocyclic aromatic amines, co-polymers of vinyl heterocyclic aromatic amine and non amine polymerizable monomers (ethylenically unsaturated mononers and diene monomers), or mixtures or combinations thereof in the absence of phosphate esters, optionally ethoxylated alcohols, and optionally, which form alter self-aggregating properties and/or aggregation propensities of the particles, surfaces, and/or materials.
    Type: Grant
    Filed: September 28, 2011
    Date of Patent: February 3, 2015
    Assignee: Clearwater International LLC
    Inventors: Raynard Veldman, Sarkis R. Kakadjian, Frank Zamora
  • Patent number: 8946130
    Abstract: Methods are disclosed for improved sand control, fines control, load recovery and well productivity, where the compositions comprise reaction products of an amine and a phosphate-containing compound.
    Type: Grant
    Filed: May 12, 2009
    Date of Patent: February 3, 2015
    Assignee: Clearwater International LLC
    Inventors: Frank Zamora, Sarkis R. Kakadjian, Erin Fitzgerald, Tina Garza
  • Patent number: 8932996
    Abstract: Methods relate to using phosphate and/or nitrate brines to reduce hydrate formation in flowlines under conditions conducive for hydrate formation in the absence of the phosphate and/or nitrate brine. The phosphate and/or nitrate brines may include compatible anti-corrosion additives.
    Type: Grant
    Filed: January 11, 2012
    Date of Patent: January 13, 2015
    Assignee: Clearwater International L.L.C.
    Inventors: Olusegun Matthew Falana, Michael Morrow, Frank G. Zamora
  • Publication number: 20150011440
    Abstract: Foamable epoxy-based zonal isolation sealing compositions include epoxy resin and a blowing agent and methods for isolating zones in borehole of oil and gas wells using the compositions, where the foam nature of the cured seals provide sufficient compressibility and resiliency to be used with expandable tubing without substantial loss in sealant integrity and in squeeze operations.
    Type: Application
    Filed: July 11, 2014
    Publication date: January 8, 2015
    Applicant: CLEARWATER INTERNATIONAL, LLC
    Inventors: Frank Zamora, Sarkis R, Kakadjian, Tina Garza
  • Patent number: 8899328
    Abstract: Epoxy-based zonal isolation compositions are capable of being adjusted by varying the epoxy-based compositions for isolating zones in borehole of oil and gas wells under high-temperature, mid-temperature and low-temperature conditions.
    Type: Grant
    Filed: May 20, 2010
    Date of Patent: December 2, 2014
    Assignee: Clearwater International LLC
    Inventors: Frank Zamora, Sarkis R. Kakadjian, Tina Garza
  • Publication number: 20140323362
    Abstract: Defoamer compositions are disclosed and methods for making and using same, where the defoamer has universal applicability at low concentrations. The defoamer compositions include between 40 vol. % and about 80 vol. % distilled water (other waters may be used instead), 10 vol. % and about 30 vol. % of silicon anti-foam agent and between about 10 vol. % and about 30 vol. % of active silicon anti-foam agent. The defoamer compositions are used in amount of less than or equal to 200 ppm in all foamed downhole fluid systems.
    Type: Application
    Filed: July 11, 2014
    Publication date: October 30, 2014
    Applicant: CLEARWATER INTERNATIONAL, LLC
    Inventors: Olusegun Matthew Falana, Edward C, Marshall, Frank Zamora
  • Publication number: 20140323360
    Abstract: Drilling fluids were developed including a base fluid, a weighting agent and/or a bridging agent, and a thickening agent, where the weighting agent and/or the bridging agent includes a particulate strontium carbonate having a desired distribution, for weighting agents, the distribution includes particles between 2? and 5000? and for bridging agents, the distribution is constructed from particles having specific sizes. Methods making and using the drilling fluids were also discovered.
    Type: Application
    Filed: October 31, 2013
    Publication date: October 30, 2014
    Applicant: Clearwater International, LLC
    Inventors: Marcelo Comarin, Maria F. Paramo G, Fred Donham, David P. Kippie, Shawn Lu, Michael C. Barry
  • Publication number: 20140318795
    Abstract: Breaking compositions are disclosed for controlled breaking of borate cross-linked fracturing fluids, and to method for making and using same, where the composition includes an oxidative component and an ester component.
    Type: Application
    Filed: July 11, 2014
    Publication date: October 30, 2014
    Applicant: CLEARWATER INTERNATIONAL, LLC
    Inventors: Joseph E. Thompson, Sr., Sarkis R. Kakadjian, Jose L. Garza, Frank Zamora
  • Publication number: 20140318793
    Abstract: Systems and methods for treating formation intervals including forming a low permeability layer on a surface of the interval and pumping a sand control treating solution through the layer, which diverts the flow into the formation permitting improved treatment uniformity and improved overall internal treatment.
    Type: Application
    Filed: April 21, 2014
    Publication date: October 30, 2014
    Applicant: CLEARWATER INTERNATIONAL, LLC
    Inventors: Ronald van Petergem, Andrew Duncan, Alfredo Mendez Zurita, Kern L. Smith
  • Publication number: 20140315763
    Abstract: New hydrocarbon based slurry compositions and drilling, fracturing, completion and production fluids including the hydrocarbon based slurry composition are disclosed, where the composition includes a hydrocarbon soluble polymer adapted to decrease particle settling rates of particulate materials present in the fluids and in the case of fluids that include hydratable materials to increase hydration properties of such materials.
    Type: Application
    Filed: May 5, 2014
    Publication date: October 23, 2014
    Applicant: Clearwater International, LLC
    Inventors: Sarkis R. Kakadjian, Joseph Earl Thompson, SR.
  • Patent number: 8851174
    Abstract: Foamable epoxy-based zonal isolation sealing compositions include epoxy resin and a blowing agent and methods for isolating zones in borehole of oil and gas wells using the compositions, where the foam nature of the cured seals provide sufficient compressibility and resiliency to be used with expandable tubing without substantial loss in sealant integrity and in squeeze operations.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: October 7, 2014
    Assignee: Clearwater International LLC
    Inventors: Frank Zamora, Sarkis R. Kakadjian, Tina Garza
  • Patent number: 8846585
    Abstract: Defoamer compositions are disclosed and methods for making and using same, where the defoamer has universal applicability at low concentrations. The defoamer compositions include between 40 vol. % and about 80 vol. % distilled water (other waters may be used instead), 10 vol. % and about 30 vol. % of silicon anti-foam agent and between about 10 vol. % and about 30 vol. % of active silicon anti-foam agent. The defoamer compositions are used in amount of less than or equal to 200 ppm in all foamed downhole fluid systems.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: September 30, 2014
    Assignee: Clearwater International, LLC
    Inventors: Olusegun Matthew Falana, Marshall C. Edward, Frank Zamora
  • Patent number: 8841240
    Abstract: Novel slick water fracturing fluid compositions are disclosed, where the compositions including with slick water fracturing compositions including a partially hydrolyzed polyacrylamide polymer system within invert emulsion and an effective amount of a friction reducer booster system, where the effective amount is sufficient to reduce a drag friction of the composition by an additional amount of at least 5% in the first 30 seconds of evaluation in high salinity and low temperature environments.
    Type: Grant
    Filed: March 21, 2011
    Date of Patent: September 23, 2014
    Assignee: Clearwater International, LLC
    Inventors: Sarkis R. Kakadjian, Frank Zamora, Ronald Powell, Erin Fitzgerald
  • Patent number: 8835364
    Abstract: Breaking compositions are disclosed for controlled breaking of borate cross-linked fracturing fluids, and to method for making and using same, where the composition includes an oxidative component and an ester component.
    Type: Grant
    Filed: April 12, 2010
    Date of Patent: September 16, 2014
    Assignee: Clearwater International, LLC
    Inventors: Joseph E. Thompson, Sarkis R. Kakadjian, Jose L. Garza, Frank Zamora
  • Patent number: 8772203
    Abstract: Coacervate gels having excellent shear viscosities and other properties are made with anionic or cationic polymers, a smaller amount of a surfactant having a charge opposite that of the polymer, and a hydrophobic alcohol and an effective amount of a phosphorus-containing compound sufficient to increase the viscosity of coacervate gels up to 3 times as compared to the gels in the absence of the phosphorus-containing compound. The Zeta Potential of the gel is maintained at an absolute value of at least 20. Optional gel promoting additives include betaines and amine oxides. A preferred gel comprises poly diallyl dimethyl ammonium chloride, a lesser amount of sodium lauryl sulfonate, and lauryl alcohol. The gels are particularly useful in well drilling fluids and well fracturing fluids.
    Type: Grant
    Filed: September 7, 2012
    Date of Patent: July 8, 2014
    Assignee: Clearwater International, LLC
    Inventor: Kevin M. Schwartz
  • Publication number: 20140166285
    Abstract: A drilling fluid, spacer fluid and cementing compositions for use in subterranean wells are disclosed along with methods for making using same, where the compositions include a particulate weighted elastomeric composition system including at least one higher density weighting agent and at least one elastomer, where the higher density weighting agents have a density of at least 5.0 g/cm3 and conventional weighting agents, to produce compositions having a desired high density, while retaining other fluid properties such as pumpability, gas tight sealing, low tendency to segregate, and reduced high temperature cement strength retrogression.
    Type: Application
    Filed: December 11, 2013
    Publication date: June 19, 2014
    Applicant: CLEARWATER INTERNATIONAL, LLC
    Inventors: Ashok Santra, Brian Seymour, Ilia Kim Partch
  • Patent number: 8746044
    Abstract: A gelled composition for pipeline, flowline, pipeline jumper or flowline jumper dewatering or preventing ingress of seawater into open pipeline systems or components during tie-in operations of jumpers or additional pipe, valving, manifolds, subsea pipeline architecture or flow conduits operations is disclosed, where the composition includes a concentrated metal formate solution and a hydratable polymer. The gelled formate compositions have improved dewatering properties with 100% or 360 pipe coverage. The gelled formate compositions have can also be reused by breaking and reformulation.
    Type: Grant
    Filed: January 11, 2012
    Date of Patent: June 10, 2014
    Assignee: Clearwater International LLC
    Inventors: Jack Curr, Brian Hallett, Alan Sweeney
  • Patent number: 8728989
    Abstract: New hydrocarbon based slurry compositions and drilling, fracturing, completion and production fluids including the hydrocarbon based slurry composition are disclosed, where the composition includes a hydrocarbon soluble polymer adapted to decrease particle settling rates of particulate materials present in the fluids and in the case of fluids that include hydratable materials to increase hydration properties of such materials.
    Type: Grant
    Filed: June 19, 2007
    Date of Patent: May 20, 2014
    Assignee: Clearwater International
    Inventors: Sarkis R. Kakadjian, Sr., Joseph Earl Thompson, Sr.