Patents Assigned to Clearwater International
  • Patent number: 8714283
    Abstract: A new multi-purpose foaming composition having applications in oil field application, industrial applications, waste management applications, or other applications that can be benefited by a foam, is disclosed, where the composition includes a surfactant, a sulfur scavenger and optionally an additive, where the sulfur scavenger and/or additive improve foam characteristics and/or the foam improves an activity of the sulfur scavenger and/or the additives. Method for using and making the foaming compositions are also disclosed, especially, coiled and capillary coiled tubing downhole applications.
    Type: Grant
    Filed: July 4, 2011
    Date of Patent: May 6, 2014
    Assignee: Clearwater International, LLC
    Inventors: Larry W. Gatlin, Jack Curr, Kevin Smith, Steve Turk
  • Publication number: 20130331301
    Abstract: Methods for using complementary surfactant systems and downhole fluids, where the systems are tailored to foam the fluids, which include the analyzed crude and/or condensate.
    Type: Application
    Filed: August 13, 2013
    Publication date: December 12, 2013
    Applicant: Clearwater International, LLC
    Inventors: Olusegun M. Falana, Edward C. Marshall, Frank Zamora
  • Patent number: 8563481
    Abstract: A corrosion control system is disclosed including an anionic oxygen inhibitor, a cationic acid inhibitor or dispersant, and a noxious species inhibitor or scavenger for use in a fluid in contact with a metallic surface at low temperature, moderate temperature and especially at high temperature. A drilling fluid, a completion fluid, a production fluid and a geothermal fluid including an effective amount of the corrosion control system is also disclosed as well as methods for making and using same.
    Type: Grant
    Filed: February 25, 2005
    Date of Patent: October 22, 2013
    Assignee: Clearwater International LLC
    Inventors: Larry W. Gatlin, Khalid Ali Shah
  • Patent number: 8562820
    Abstract: 1,3,5-(2H2,4H2,6H2)tripropanediamine N,N,N?,N?,N?,N? hexamethyl is used to scavenge sulfur compounds from hydrocarbons. A novel method of making the triazine comprises autocondensing (CH3)2NCH2CH2CH2N?CH2.
    Type: Grant
    Filed: May 1, 2007
    Date of Patent: October 22, 2013
    Assignee: Clearwater International, L.L.C.
    Inventor: Larry W. Gatlin
  • Patent number: 8539821
    Abstract: Method for dewatering, pressure testing, hydrotreating, suppressing methane hydrate formation and suppressing solution freezing point in pipeline operations have been disclosed, where the solution used in the operations includes an effective amount of a metal formate salt. The metal formate salt solutions have a low viscosity, have a high density, have a low metals corrosivity, are non-volatile, have a low solubility in hydrocarbons, are readily biodegradable, have a low toxicity, are non-hazardous, have a low environmental impact, have a freezing point depression property forming water/formate eutectic point mixtures, and have a water-structuring and water activity modification property.
    Type: Grant
    Filed: November 14, 2011
    Date of Patent: September 24, 2013
    Assignee: Clearwater International LLC
    Inventors: Alan Sweeney, Brian Hallett
  • Patent number: 8530394
    Abstract: An new class of oil-soluble, sulfur scavengers or converts are disclosed where the scavengers include substantially monomeric aldehyde-amine adducts from the reaction of at least one sterically hindered primary or secondary amine and a molar excess of at least one aldehyde. Methods are also disclosed for reducing, reducing below a given level or eliminating noxious sulfur species from fluids using the inventive scavengers and for making the inventive scavengers.
    Type: Grant
    Filed: April 7, 2009
    Date of Patent: September 10, 2013
    Assignee: Clearwater International LLC
    Inventor: Larry W. Gatlin
  • Patent number: 8524639
    Abstract: Complementary surfactant systems and downhole fluids made using the systems are disclosed along with methods for making and using same, where the surfactant systems include from 0 wt. % to 100 wt. % of a first surfactant subsystem, from 100 wt. % to 0 wt. % of a second surfactant subsystem, and from 0 wt. % to 100 wt. % of a solvent subsystem based on the wt. % of the surfactant subsystems, where the system is tailored to foam the fluid including the analyzed crude and/or condensate.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: September 3, 2013
    Assignee: Clearwater International LLC
    Inventors: Olusegun Matthew Falana, Edward C. Marshall, Frank Zamora
  • Patent number: 8507413
    Abstract: Clay is stabilized in methods for drilling of wells and other formation treatment for hydrocarbon production by the addition to the drilling or other fluid including a choline compound together with an formation control additive.
    Type: Grant
    Filed: January 17, 2012
    Date of Patent: August 13, 2013
    Assignee: Clearwater International, LLC
    Inventor: Thomas P. Wilson, Jr.
  • Patent number: 8507412
    Abstract: New fluids are disclosed for use in servicing subterranean formations containing oil and gas. In particular, an improved chemical gelling additive for hydrocarbon based fracturing fluids is disclosed having reduce, negligible or no volatile phosphorus at temperatures below about 250° C.
    Type: Grant
    Filed: December 27, 2011
    Date of Patent: August 13, 2013
    Assignee: Clearwater International LLC
    Inventors: Brent Lukocs, Shaun Mesher, Thomas P. Wilson, Jr., Tina Garza, Wayne Mueller, Frank Zamora, Larry W. Gatlin
  • Patent number: 8505362
    Abstract: Method for dewatering, pressure testing, hydrotreating, suppressing methane hydrate formation and suppressing solution freezing point in pipeline operations have been disclosed, where the solution used in the operations includes an effective amount of a metal formate salt. The metal formate salt solutions have a low viscosity, have a high density, have a low metals corrosivity, are non-volatile, have a low solubility in hydrocarbons, are readily biodegradable, have a low toxicity, are non-hazardous, have a low environmental impact, have a freezing point depression property forming water/formate eutectic point mixtures, and have a water-structuring and water activity modification property.
    Type: Grant
    Filed: November 14, 2011
    Date of Patent: August 13, 2013
    Assignee: Clearwater International LLC
    Inventors: Alan Sweeney, Brian Hallett
  • Publication number: 20130175477
    Abstract: Corrosion inhibiting and management systems and for methods of making and using same are presented, where the corrosion systems comprise a reaction product or mixture of reaction products of medium to high carbon count phosphate ester or mixture of medium to a high carbon count phosphate esters and an amine or mixture of amines and where the reaction product or products form a partial or complete coating on surfaces of pipe, piping, pipeline, flowline, and other downhole equipment in contact with aqueous and non-aqueous fluids to protect the surfaces from corrosion at temperature up to up to 750° F. (398.9° C.), and especially, for use in applications using low to moderate temperature geothermal fluids.
    Type: Application
    Filed: January 11, 2012
    Publication date: July 11, 2013
    Applicant: Clearwater International, LLC
    Inventors: Olusegun Matthew Falana, Khalid Ali Shah, Thomas P. Wilson, JR., Frank Zamora
  • Publication number: 20130178399
    Abstract: Methods relate to using phosphate and/or nitrate brines to reduce hydrate formation in flowlines under conditions conducive for hydrate formation in the absence of the phosphate and/or nitrate brine. The phosphate and/or nitrate brines may include compatible anti-corrosion additives.
    Type: Application
    Filed: January 11, 2012
    Publication date: July 11, 2013
    Applicant: Clearwater International, LLC
    Inventors: Olusegun Matthew Falana, Michael Morrow, Frank G. Zamora
  • Patent number: 8475585
    Abstract: A foamed cement composition is disclosed for utilization in performing a variety of well cementing operations, and to methods for making and using same. The foamed cement composition basically includes a cement, water sufficient to form a pumpable slurry, a gas sufficient to foam the slurry, a foaming agent and optionally a foam stabilizing agent.
    Type: Grant
    Filed: October 10, 2012
    Date of Patent: July 2, 2013
    Assignee: Clearwater International, LLC
    Inventors: Frank Zamora, Marilyn J. Bramblett, Sarkis R. Kakadjian
  • Patent number: 8466094
    Abstract: A method for treating solid materials is disclosed, where the treating compositions coats surfaces or portions of surfaces of the solid materials changing an aggregation or agglomeration propensity of the materials. Treating composition and treated solid materials are also disclosed. The methods and treated materials are ideally suited for oil field applications.
    Type: Grant
    Filed: May 13, 2009
    Date of Patent: June 18, 2013
    Assignee: Clearwater International, LLC
    Inventors: Sarkis R. Kakadjian, Raynard Veldman, Frank Zamora, Erin Fitzgerald, Tina Garza
  • Publication number: 20130081820
    Abstract: Foam systems including a surfactant subsystem including one alpha-olefin sulfonic acid or a plurality of alkali metal alpha-olefin sulfonic acid salts and optionally, one ethoxylated alcohol sulfonate or a plurality of ethoxylated alcohol sulfonates, optionally, a pour point depressant subsystem including one glyme or a plurality of glymes and optionally, a corrosion inhibiting subsystem including one corrosion inhibitor or a plurality of corrosion inhibitors, where the system is thermally or heat stable up to 450° F., the system is environmentally benign, the system is capable of producing a foam in an aqueous medium including high amounts of crude oil, the system is efficient at low usage levels and the system is capable of reuse or at least on foam-defoam cycle. Methods for making and using including preparation of the foam systems, drilling, fracturing, completion and producing using the systems in conjunction with a gas.
    Type: Application
    Filed: September 30, 2011
    Publication date: April 4, 2013
    Applicant: CLEARWATER INTERNATIONAL, LLC
    Inventors: Olusegun Matthew Falana, Frank G. Zamora, Daniel R. Dostie, Edward C. Marshall, Sarkis R. Kakadjian
  • Publication number: 20130075100
    Abstract: Composition and methods using the compositions are disclosed, where the compositions include heterocyclic aromatic amines, substituted heterocyclic aromatic amines, poly vinyl heterocyclic aromatic amines, co-polymers of vinyl heterocyclic aromatic amine and non amine polymerizable monomers (ethylenically unsaturated mononers and diene monomers), or mixtures or combinations thereof in the absence of phosphate esters, optionally ethoxylated alcohols, and optionally, which form alter self-aggregating properties and/or aggregation propensities of the particles, surfaces, and/or materials.
    Type: Application
    Filed: September 28, 2011
    Publication date: March 28, 2013
    Applicant: CLEARWATER INTERNATIONAL, LLC
    Inventors: Raynard Veldman, Sarkis R. Kakadjian, Frank Zamora
  • Publication number: 20130076732
    Abstract: Processes, machines, and computer-readable media are provided for expanding and simplifying a polygon or reducing and simplifying a polygon. Polygon expanding or reducing logic receives information that represents a polygon having a set of vertices. The polygon expanding or reducing logic determines another polygon having another set of vertices, such that the other polygon encompasses or is encompassed by the polygon, by determining, for each vertex of the set of vertices, a new set of vertices that are derived from the vertex and are at least a particular distance outside or inside the polygon. The vertex reducing logic determines whether an intermediate vertex is within the particular distance of a proposed segment between two other vertices of the other set of vertices, even though the intermediate vertex is not on the proposed segment, and, if so, removing the intermediate vertex from the other set of vertices.
    Type: Application
    Filed: September 28, 2011
    Publication date: March 28, 2013
    Applicant: Clearwater International, LLC
    Inventors: Daniel P. Cervelli, John A. Carrino
  • Publication number: 20130046035
    Abstract: A foamed cement composition is disclosed for utilization in performing a variety of well cementing operations, and to methods for making and using same. The foamed cement composition basically includes a cement, water sufficient to form a pumpable slurry, a gas sufficient to foam the slurry, a foaming agent and optionally a foam stabilizing agent.
    Type: Application
    Filed: October 10, 2012
    Publication date: February 21, 2013
    Applicant: CLEARWATER INTERNATIONAL, LLC
    Inventors: Frank Zamora, Marilyn J. Bramblett, Sarkis R. Kakadjian
  • Patent number: 8362298
    Abstract: Hydrolyzed nitrilotriacetonitrile compositions are disclosed prepared by a method characterized by a one-shot addition of an amount of nitrilotriacetonitrile to a solution containing an acid catalyst, where the reaction is complete in a time period of less than an hour. The method is also characterized by adjusting the pH of the reaction mixture to a pH of at least 8. The method is also characterized by oxidatively removing free cyanide to a desired low level through the addition of an oxidizing agent the produces environmentally benign by-products to the crude hydrolyzed NTAN to form hydrolyzed NTAN compositions having minimized, negligible, or substantially no free cyanide levels.
    Type: Grant
    Filed: May 20, 2011
    Date of Patent: January 29, 2013
    Assignee: Clearwater International, LLC
    Inventors: Olusegun M. Falana, Aziz Hikem, Sarkis R. Kakadjian, Frank Zamora
  • Publication number: 20120325329
    Abstract: Coacervate gels having excellent shear viscosities and other properties are made with anionic or cationic polymers, a smaller amount of a surfactant having a charge opposite that of the polymer, and a hydrophobic alcohol and an effective amount of a phosphorus-containing compound sufficient to increase the viscosity of coacervate gels up to 3 times as compared to the gels in the absence of the phosphorus-containing compound. The Zeta Potential of the gel is maintained at an absolute value of at least 20. Optional gel promoting additives include betaines and amine oxides. A preferred gel comprises poly diallyl dimethyl ammonium chloride, a lesser amount of sodium lauryl sulfonate, and lauryl alcohol. The gels are particularly useful in well drilling fluids and well fracturing fluids.
    Type: Application
    Filed: September 10, 2012
    Publication date: December 27, 2012
    Applicant: CLEARWATER INTERNATIONAL, LLC
    Inventor: Kevin M. Schwartz