Abstract: This invention relates to novel preformed stabilizers in which a portion of the polymer control agent is recovered and comprises from 10 to 1500 ppm of an inhibitor. This invention also relates to a process for preparing these preformed stabilizers, and to polymer polyols comprising these novel preformed stabilizers macromers and to a process for preparing polymer polyols comprising these novel preformed stabilizers. The present invention also relates to polyurethane foams comprising these polymer polyols, and to processes for preparing these polyurethane foams.

Abstract: Disclosed are ethylenically unsaturated macromers produced using a residue of an isocyanate manufacturing process. Also disclosed are preformed stabilizers produced using such macromers, polymer polyols produced using such preformed stabilizers, foam-forming compositions produced using such polymer polyols, and foam produced using such compositions.

Abstract: Foam wall structures and methods for making them are described. The wall structures include a frame, a mesh mechanically fastened to a front surface of the frame, a foam panel at least partially abutting and overlying the mesh, and a foam layer disposed in a cavity defined by the frame, the mesh, and the foam panel. Buildings that include such wall structures are also described.

Abstract: Polyol premixes and thermally insulating rigid polyurethane foams, such as those that can be used as a thermal insulation medium in the construction of refrigerated storage devices, are disclosed. A polymer polyol having a OH number of greater than 260 mg KOH/g is utilized. The resulting polyurethane foams can exhibit improved thermal insulation properties without sacrificing other important physical and processing properties.

Abstract: Wall structures and methods of manufacturing wall structures are described. The wall structures include a frame, a foam panel attached to the frame, a brace disposed in a cavity defined by the frame, and a foam layer. The wall structures can impart a high wall racking strength and good thermal performance through the combination of the foam layer, brace, and the foam panels.

Abstract: A waterborne poly(alkynyl carbamate) prepolymer is provided which comprises a reaction product of a polyisocyanate comprising a first portion and a second portion of isocyanate groups; an isocyanate-reactive component comprising 0.1 mol % to 6 mol % of a C10-C50 glycol ether; and 99.9 mol % to 94 mol % of an alkynol, wherein the mol % is based on the moles of isocyanate in the polyisocyanate, wherein the first portion of isocyanate groups reacts with the C10-C50 glycol ether, wherein the second portion of isocyanate groups reacts with the alkynol, and wherein reaction occurs optionally in the presence of a catalyst. The reaction of long chain glycol ethers with the polyisocyanate at a level of from 0.1 mol % to 6 mol % imparts water dispersibility to the prepolymer, and when the prepolymer is dispersed in water, the performance of waterborne alternative polyurethane compositions made therefrom, such as coatings, adhesives, sealants, films, elastomers, castings, foams, and composites, are not compromised.

Abstract: The present invention provides a barrier film comprising a first layer formed from thermoplastic polyurethane (TPU) and a second layer formed from a thermoplastic polymer-based coupling agent containing an ethylene-vinyl acetate (EVA) copolymer and a second polar co-monomer polymer, wherein the barrier film has a total thickness of between 50 ?m (2 mil) and 600 ?m (24 mil), wherein the first layer has a thickness of between 20 ?m (0.8 mil) and 400 ?m (16 mil), and wherein the second layer has a thickness of between 20 ?m (0.8 mil) and 200 ?m (8 mil). The inventive barrier film may find use in colostomy, urostomy, and ileostomy pouches and in other medical applications.

Abstract: Pultrusion processes for producing fiber reinforced polyurethane composites are described. The processes utilize a polyurethane-forming reaction mixture comprises a chelated organometallic/metalorganic catalyst. Polyurethane-forming reaction mixtures suitable for use in such processes are also described.

Abstract: An alternative polyurethane composition is provided which comprises a reaction product of an azidated polyol and a poly(alkynyl carbamate) prepolymer reacted at a temperature of from 20° C. to 120° C., wherein the poly(alkynyl carbamate) prepolymer comprises a reaction product of a polyisocyanate and a stoichiometric equivalent of an alkynol of the formula (I), HC?C—R1R2—OH??(I), and wherein R1 is an electron-withdrawing group selected from the group consisting of carbonyl, ester, amide, and urethane and R2 is a linear or branched alkyl chain having from 1 to 15 carbon atoms. The inventive alternative polyurethane composition position may be used to provide adhesives, sealants, films, elastomers, castings, foams, and composites.

Abstract: The present invention provides an allophanate polymer system made by a method comprising combining a neutralized polyol with a polyuretdione resin in the presence of a reactive reducer comprising a reducing agent and a tertiary amine catalyst to produce a clear-coat, and contacting the clear-coat with a basecoat comprising a tertiary amine catalyst. The reaction between the polyol and the polyuretdione will proceed after the reactive reducer reduces the viscosity of the one component clear-coat formulation to appropriate levels. The inventive allophanate polymer system is particularly applicable in providing coatings, adhesives, castings, composites, and sealants with good performance.

Abstract: This invention relates to improved flexible foams prepared from polymer polyols and to a process for preparing these improved flexible foams.

Abstract: This invention relates to a process for preparing a flexible polyurethane foam in which the isocyanate-reactive component comprises a specific isocyanate-reactive component. The invention also relates to flexible polyurethane foam wherein the isocyanate-reactive comprises the specific isocyanate-reactive component.

Abstract: The present invention provides a reaction mixture comprising a hot blend of a first isocyanate-based uretdione resin and a second isocyanate-based uretdione resin, a neutralized polyol and a tertiary amine catalyst, and optionally, an additive package selected from the group consisting of flow control additives, pigments (colorants), wetting agents, and solvents, wherein the first isocyanate and the second isocyanate are different. The isocyanate-based uretdiones that have been hot blended together produce coatings, adhesives, castings, composites, and sealants, which exhibit better performance properties (such as microhardness) than those coatings, adhesives, castings, composites, and sealants produced from the constituent isocyanate-based uretdiones alone.

Abstract: An alternative polyurethane composition is provided which comprises a reaction product of an azidated polyol and a poly(alkynyl carbamate) prepolymer, wherein reaction occurs at a temperature of from 20° C. to 200° C., optionally in the presence of a CuI-containing catalyst and wherein the poly(alkynyl carbamate) prepolymer comprises a reaction product of a polyisocyanate, an alkynol, and a glycol ether, wherein from 1 mol % to 33 mol % of isocyanate groups are reacted with glycol ether and the remaining isocyanate groups are reacted with the alkynol. The inclusion of glycol ethers into the polyisocyanate chain of the poly(alkynyl carbamate) prepolymer at a level of from 1 mol % to 33 mol %, is efficient in reducing the viscosity of the composition without compromising its performance in coatings, adhesives, sealants, films, elastomers, castings, foams, and composites made with the inventive alternative polyurethane compositions.

Abstract: This invention relates to polymer polyols which comprise one or more base polyols, at least one preformed stabilizer, one or more ethylenically unsaturated monomers, and, in the presence of at least one free radical polymerization catalyst, and optionally, one or more polymer control agents. The base polyol of these polymer polyols comprises one or more amine initiated polyols. The present invention also relates to processes for preparing these polymer polyols, to foams prepared from these polymer polyols, and to processes for producing foams from these polymer polyols.

Abstract: A foam wall structure includes a frame, at least one primary support member, a slab of polyiso board and a foam layer. The frame can include: a first member, a second member spaced apart from the first member; and two side members extending between the first and second members. The frame defining a front frame surface and an opposite rear frame surface. The at least one primary support member can be positioned between the two side members and extend between the first and second member. The primary support member defines a front support surface and an opposite rear support surface. The slab of polyiso board may be attached to the front frame surface. The foam layer can be received within at least a portion of the frame and overlies the front surface of the primary support member. A method of making a foam wall structure and a pre-fabricated wall is also disclosed.