Abstract: The present invention provides alternative polyurethane composition comprising the reaction product of an azidated polyol and a poly(alkynyl carbamate) prepolymer, wherein the poly(alkynyl carbamate) prepolymer comprises the reaction product of a polyisocyanate, an alkynol, and an oxysilane. The reaction of the polyol and the prepolymer may occur in the presence of a catalyst or at a temperature of from 20° C. to 120° C. The inventive oxysilane and azido-alkyne hybrid click formulations provide comparable performance, and in some cases better performance, to/than urethane and azido-alkyne control click formulations in terms of pencil hardness, MEK double rubs, and glass transition temperature. The inventive alternative polyurethane compositions may be used to provide coatings, adhesives, sealants, films, elastomers, castings, and composites.

Abstract: A waterborne alternative polyurethane composition is provided which comprises a reaction product of: an azidated polyol; and a waterborne poly(alkynyl carbamate) prepolymer comprising a reaction product of a polyisocyanate and from 1 wt. % to 20 wt. % of an alkynol-polyether having a formula (I), R1—R2—O—R3—OH??(I), wherein, R1=a monovalent group selected from either HC?C— or HC?C—CO—, R2=a divalent alkylene group from 1 to 8 carbon atoms, and may be straight chain or branched and may contain cyclic moieties, and R3=a polyethylene glycol with number average molecular weight from 300-1,200 g/mol, wherein the wt. % is based on the weight of the prepolymer, wherein reaction of the azidated polyol and the waterborne poly(alkynyl carbamate) occurs at a temperature of from 20° C. to 200° C. and optionally in the presence of a catalyst.

Abstract: Foam wall structures and methods for making them are described. The wall structures include a frame, a sheet metal sheathing overlying a front surface of the frame, a foam panel overlying the sheet metal sheathing, and a foam layer disposed in a cavity defined by the frame and the sheet metal sheathing. Buildings that include such wall structures are also described.

Abstract: Foam wall structures and methods for making foam wall structures. The wall structures include a frame, a foam panel overlying a front surface of the frame, a first foam layer disposed in a cavity defined by the frame and the foam panel, in which the first foam layer self-adheres to one or more members of the frame, and a second foam layer disposed in the cavity. The second foam layer self-adheres to the first foam layer and has a density that is less than the density of the first foam layer.

Abstract: An alternative polyurethane composition is provided comprising a reaction product of an azidated polyol and a poly(alkynyl carbamate) allophanate prepolymer, wherein the poly(alkynyl carbamate) allophanate prepolymer comprises a reaction product of a first alkynol and a poly(alkynyl carbamate) prepolymer, in the presence of a metallo-organic compound of the formula: M(acac)n, wherein, M=a metal, acac=an acetylacetonate residue, and n=2 or 3, wherein the poly(alkynyl carbamate) prepolymer comprises a reaction product of a polyisocyanate and a stoichiometric equivalent of a second alkynol, and wherein the polyisocyanate comprises isocyanate groups and uretdione groups. The inventive alternative polyurethane compositions may be used to provide solventborne or waterborne coatings, adhesives, sealants, films, elastomers, castings, foams, and composites.

Abstract: Polyol blends are disclosed that include a saccharide-initiated polyether polyol, an aromatic polyester polyol, and a polyalkylene polyamine-initiated polyether polyol. Also disclosed are foam-forming compositions containing such polyol blends, rigid foams made using such polyurethane foam-forming compositions, and methods for producing such foams, including use of such foams as panel insulation.

Abstract: This invention relates to novel macromers containing dithiocarbonate (or xanthate) groups, novel preformed stabilizers comprising macromers, and novel polymer polyols comprising the novel macromers and/or novel preformed stabilizers. This invention also relates to processes for the preparation of these materials. Other aspects of this invention include foams comprising the novel polymer polyols and a process for preparing foam comprising the novel polymer polyols.

Abstract: Methods for measuring long-term thermal resistance of closed-cell foam. The methods include: (a) placing a stack of slices cut from a sample of the foam between two isothermal plates in a calibrated heat flow meter comprising a heat flux transducer; (b) measuring an initial thermal resistance of the same stack of slices at a plurality of preselected mean temperatures within the temperature range of 10° F. to 150° F. wherein the stack of foam slices stays inside the heat flow meter throughout step (b); (c) at a time calculated to represent a selected aging period of the foam, placing the same stack of slices between two isothermal plates in a calibrated heat flow meter and measuring the thermal resistance of the stack of slices at a plurality of preselected mean temperatures within the temperature range of 10° F. to 150° F.

Abstract: Laminated parts are described that include a core, a fiber layer arranged on each side of the core and impregnated with a polyurethane resin, and an outer layer that at least partially coats at least one of the polyurethane impregnated fiber layers, in which the outer layer is the cured reaction product of a reaction mixture that includes: (1) a polyisocyanate, (2) a polyether polyol having a molecular weight of 800 Da to 25,000 Da and a functionality of 2 to 8, and (3) a fatty acid ester having isocyanate-reactive functionality. Methods of producing such laminated parts are also described.

Abstract: The present invention provides an assembly comprising a thermally conductive thermoplastic polymer as a heat sink to provide thermal management for an electrical/electronic component and a reaction injection molded (RIM) polyurethane to replace the potting compound typically used in such assemblies. In addition to replacing the potting compound, the cured polyurethane forms the part, such as the base of the LED bulb, which heretofore has been a separate component, thus reducing the number of components and saving a production step.

Abstract: Disclosed are processes for In-Mold coating of a substrate. The processes include: introducing a curable composition to a mixhead at a first elevated pressure, the curable composition comprising a first polymeric component and a second polymeric component, the introducing of the curable composition to the mixhead comprising mixing the first and second polymeric components by impingement to form an intermediate composition; introducing the intermediate composition to a secondary mixer, the introducing of the intermediate composition to the secondary mixer comprising mixing the intermediate composition to form a coating composition; and introducing the coating composition into a mold containing a substrate to form a curable coating on a surface of the substrate.

Abstract: Processes for stabilizing toluenediamine residues are disclosed. These processes include adding a low viscosity, low boiling liquid to a toluenediamine residue composition to form a blend, and optionally, continuously monitoring the viscosity of the blend during addition of the low viscosity, low boiling liquid. The low viscosity, low boiling liquid may be added at 5% to 30% by weight based on the total weight of the blend. Further, the low viscosity, low boiling liquid may be added so that the blend has a viscosity of 10,000 cP or less throughout the temperature range of 40° C. to 95° C. Blends of toluenediamine residue compositions and low viscosity, low boiling liquids such as water, and methods of their use as a fuel are also disclosed.

Abstract: The present invention provides an aqueous polyurethane dispersion (PUD) comprising an amorphous polyester having a glass transition temperature (Tg) as determined by differential scanning calorimetry of less than ?30° C.; wherein the aqueous polyurethane dispersion (PUD) has a glass transition temperature (Tg) as determined by differential scanning calorimetry (DSC) of 0° C. to 20° C. and a hard block content of greater than 50%.

Abstract: Disclosed are HCFO-containing isocyanate-reactive compositions, foam-forming compositions containing such isocyanate-reactive compositions, rigid PUR-PIR foams made using such foam-forming compositions, and methods for producing such foams, including use of such foams as insulation in discontinuous foam panel applications. The isocyanate-reactive composition can exhibit a long shelf life, be shelf-stable, and produce a foam with good physical properties.

Abstract: In one or more embodiments, the present invention provides a novel approach to the addition of plasticizers for softening TPUs, i.e., lowering the durometer and the melt viscosity. This approach involves incorporating bonded sulfonate groups with quaternary ammonium counterions into the TPU. In one or more embodiments of the present invention, the softening of TPU is achieved by incorporating an ionic diol, such as N,N-bis (2-hydroxyethyl)-2-aminoethane-sulfonic acid (BES), coupled with various bulky alkyl ammonium cations, during the chain extension step of the TPU synthesis. It is believed that that steric hindrance of the bulky quaternary ammonium groups weakens the dipole-dipole interactions of the sulfonate groups and/or lowers the crystallinity of the hard block, thereby creating additional free volume that softens the polymer and lowers the melt viscosity.

Abstract: This invention relates to a novel polyol composition and a process for preparing these polyol compositions. These novel polyol compositions comprise (a) an in-situ formed polyol blend which comprises (i) one or more polyether monols and (ii) one or more polyether polyols; and (b) a polyether polyol. This invention also relates to a process for preparing an open celled, flexible polyurethane foam in which the isocyanate-reactive component comprises this novel polyol composition, and to a viscoelastic polyurethane foam wherein the isocyanate-reactive comprise the novel polyol composition.