Abstract: A process for producing C10-C26 monobranched fatty acids or alkyl esters thereof which includes isomerizing unsaturated C10-C26 fatty acids or alkyl esters thereof in the presence of a catalyst which comprises both a zeolite and a Lewis base. The zeolite can be reused after simple separation from the reaction products without having to regenerate. The process is particularly suitable for producing highly monobranched fatty acids or alkyl esters thereof.

Abstract: Polyamide compositions useful for personal care are disclosed, including film-forming concentrates and emulsions. Ethanol-based concentrates comprise a hydrophobic polyamide, which comprises a reaction product of either (a) a dimerized fatty acid, at least one C2-C4 carboxylic acid, and a polyamine component comprising ethylenediamine and 1 to 30 eq. % of one or more di- or triamines; or (b) a dimerized fatty acid, at least 50 wt. % of a C16-C22 unsaturated carboxylic acid, and at least one C2-C6 diamine. Personal care applications for the concentrates, including continuous sunscreens, fragrant body sprays or splashes, anti-acne medications, are included. Water-in-oil emulsions comprising the hydrophobic polyamides are storage-stable and provide water-resistant SPF for products such as sunscreens and body lotions.

Abstract: A personal care formulation comprising an active compound is operable to reduce the surface friction of hair fibres and promoting inter-fibre movement. The active compound is the reaction product of a fatty acid and a polyamine. The use of the active compound in a personal care formulation works as a friction modifier operable to reduce the surface friction of hair fibres. The invention extends to the active compound and a method of reducing hair-fibre surface friction.

Abstract: Hair is treated with a copolymer of an unsaturated ester and a styrene sulphonate monomer to reducing damage to hair caused by subsequent heat treatment. The styrene sulphonate monomer is desirably sodium styrene sulphonate and the unsaturated ester is desirably of an unsaturated monocarboxylic acid, such as (meth)acrylic acid, or dicarboxylic acid, such as maleic acid, and an alcohol, desirably an alkoxylated alcohol such as ethoxylated lanolin alcohol. Formulations for hair treatment generally include from about 0.5 to about 25% by weight of the copolymer.

Abstract: Described herein is a polyether polyamide block copolymer as well compositions and products containing the polyether polyamide block copolymer. Methods of making and using the copolymer, the compositions, and products are also described herein.

Abstract: Polyglycerol carboxylic acid esters are made by reaction of a, typically C2 to C30, particularly C6 to C22, carboxylic acid with glycerol carbonate, particularly with base catalyst, and desirably at temperatures from 170° C. to 250° C. Other carbonates e.g. cyclic diol carbonates such as ethylene or propylene carbonates, may be used in combination with the glycerol carbonate to make novel mixed polymeric esters. The molar ratio of carboxylic acid group to glycerol carbonate is typically from 2 to 30, but can be up to 100. The base catalyst is desirably alkali metal hydroxide, carbonate or alkoxide. The reaction is desirably carried out in an inert atmosphere, and reducing agent such as phosphorous acid, hypophosphorous acid or borohydride and/or activated carbon, may be included to improve product color.

Abstract: Hard surfaces can be treated to improve soil resistance, particularly resistance to oily soils, by applying a composition of a quaternised, polyamine, polypropoxylate, polyethoxylate. The polyamine can be a polyethyleneimme, desirably having a molecular weight of from 10 to 50 kDa. The average length of the polypropylenoxy chains is desirably from 10 to 100 and the polyethylenoxy chains from 5 to 50 (each per NH group in the polyamine), particularly at a molar ratio of PO:EO of about 3:1. The degree of quaternization of the nitrogen atoms in the polyamine is desirably from 70 to 100%. The polymer will usually be used in solution in water or an aqueous formulation, which may include detergent and other detergent formulation components.

Abstract: An engine lubricant, especially an SAE OW engine lubricant is described. The engine lubricant has at least 15 wt % of at least one monoester and not more than 15 wt % of additives, wherein said at least one monoester, or mixture of said monoesters if more than one is present, has a kinematic viscosity at 100° C. of not more than 3.3, a viscosity index of at least 130 and a Noack evaporation loss of not more than 15 wt %. The monoester is preferably the reaction product of a monohydric alcohol and a monocarboxylic acid wherein said monohydric alcohol is at least one saturated branched-chain aliphatic monohydric alcohol having between 16 and 36, carbon atoms and wherein said monocarboxylic acid is at least one saturated straight-chain aliphatic monocarboxylic acid having between 5 and 10, preferably 5 and 7, carbon atoms. In preferred lubricants, the monoester, or mixtures of monoesters, have a pour point of not more than ?30° C. and a non-polarity index of at least 80.

Abstract: A surfactant composition contains at least one sorbitan ester and at least one sorbitol ester wherein the mean number of carbon atoms of the hydrophobe of the sorbitan ester is greater than that of the sorbitol ester. The surfactant composition is particularly suitable for use in stabilizing emulsions, especially personal care or cosmetic products.

Abstract: Surfactant compounds which include an amine ended polyalkylene glycol hydrophile linked to C22 to C60 mainly hydrocarbyl, particularly composite hydrocarbyl, especially derived from a polymerised fatty acid and/or an aralkyl substituted phenol, hydrophobe, are useful in dispersing solids, particularly active agrochemicals, in aqueous media, or as adjuvants in agrochemical formulations, particularly of water soluble non-selective herbicides. In particular the hydrophobe is derived from polymerised fatty acids, such as dimer and, especially, trimer acids or from aralkyl substituted phenols. Aqueous dispersions using such surfactants can remain stable even with substantial concentrations of electrolyte e.g. in stable agrochemical dispersions including water soluble electrolyte agrochemical, such as glyphosate and/or ammonium sulphate.

Abstract: Gear oil formulations comprising a gear oil and a film forming agent are disclosed. The film forming agent comprises a polymeric ester which is the reaction product of at least one polyfunctional alcohol, a dimer fatty acid, an optional aliphatic dicarboxylic acid having 5 to 18 carbon atoms and one or more ingredients to reduce the acid value of the polymeric ester to below 5 mgKOH/g with the resultant polymeric ester having a kinematic viscosity at 100° C. ranging from 400 to 5000 mm2/s and a weight average molecular weight ranging from 5000 to 20000. When used as an automotive gear oil formulation the specifications for API GL-4 gear oils are at least satisfied. Use of the gear oil formulation in manual transmissions, transfer cases and differentials and use of the gear oil formulation in an industrial gear suitable for lubricating spur, helical, bevel, worm and hypoid gears are disclosed. Methods of lubrication are also disclosed.

Abstract: The invention relates to compositions and articles containing a cross-linked polymer matrix and an immobilized active liquid, as well as methods of making and using the same.

Abstract: A composition capable of phase separation contains an epoxy resin and an impact modifier formed from at least one dimer fatty acid and/or dimer fatty diol. The composition is suitable for use as an adhesive, particularly in microelectronics.

Abstract: A process for producing C10-C26 monobranched fatty acids or alkyl esters thereof which includes isomerising unsaturated C10-C26 fatty acids or alkyl esters thereof in the presence of a catalyst which comprises both a zeolite and a Lewis base. The zeolite can be reused after simple separation from the reaction products without having to regenerate. The process is particularly suitable for producing highly monobranched fatty acids or alkyl esters thereof.

Abstract: An automotive lubricant composition comprising a base fluid and an ashless polymeric dispersant is claimed. The ashless polymeric dispersant has a number average molecular weight of between 500 and 10,000 and comprises a polar tall group which itself comprises a polymeric backbone of 2 to 30 monomeric repeat units, each repeat unit comprising a hydrocarbon chain functionalised by the presence of at least one electronegative element or moiety, the tail group being linked to a polar head group which comprises a polar moiety selected from at least one of acid, ester, amide or alcohol moieties. The dispersant has good dispersancy properties, when used as a sole dispersant or in combination with other dispersants. It provides enhanced seal resistance and has good oxidative stability in automotive applications as compared to current commercial products.

Abstract: Fatty esters of oligoesters of a dicarboxylic acid and a polyol retaining at least one free hydroxyl group, particularly of the formula (I): R1—[OR2O—C(O)—R3—(O)C—]m—R4 (I), where R1 is H, a monocarboxylic acid group, or R6O—[C(O)—R3—(O)C]—; R2s are residues of polyols having at least one substituent free hydroxyl; R3s are hydrocarbylene; R4 is —OH, —OM where M is a salt forming metal, amine or ammonium, —OR6, or —OR2O—R7; R5 is C7 to C21 hydrocarbyl; R6 is C8 to C22 hydrocarbyl; R7 is H, or —C(O)R5; and m is 1 to 20; provided that at least one of R1 and R4 is or includes a C8 to C22 group, are surfactants. A range of surfactant properties can be obtained by varying the molecules within these ranges. Especially where R2 is derived from a higher polyol e.g. sorbitol, R3 is C2 to C6, and the fatty terminal group is C8 to C14, the products can be highly water soluble and effective oil in water emulsifiers.

Abstract: A blend for use in a personal care composition comprises a dialkyl amphiphilic component and an ester of a long chain branched fatty acid and a long chain branched alcohol. The blend can be pastillated and/or flaked, and can be used as the oil phase of an oil-in-water emulsion. The blend can be used in a moisturiser composition for moisturising skin.

Abstract: Novel polyglycerol oligoesters derived from reaction of polyglycerol with a mixture of mono and diacids and also combinations of these novel polyglycerol oligoesters with known polyol monoesters, particularly known polyglycerol monoesters are disclosed. The use of these novel polyglycerol oligoesters and combination of esters as emulsifiers, solubilisers and/or thickeners especially in personal care formulations is also disclosed.

Abstract: Textiles are simultaneously cleaned and conditioned in aqueous laundry cleaning using detergent surfactant and non-ionic fatty amino-amide/ester fabric conditioner. The conditioner particularly includes compound(s) of the formulae (IIa), to (IId), (III), (IV) and/or (V): Formula R1—CO—NH—(CH2)n—NR2—(CH2)n—O2C—R1 and Formula R1—CO—NH—(CH2)n—NR2—(CH2)n—NHCO—R1. Formula (IIc) or formula (IId). R1, R2 and n are defined with R1 and/or R2 including fatty hydrocarbyl; formula [R4—(CH2)p]3—N. R4 is HO—, or R8CO2—; R6 is hydrocarbyl (including fatty hydrocarbyl); and p is 2 to 6; formula R7—N-[(AO)m—R8]2. R7, R8, AO and m are defined with R7 and/or R8 including fatty hydrocarbyl; formula (R1—CONH)q—R10. R1 as in formulae (Ia) or (Ib), R10 is polyalkyleneimine after removal of q primary amino groups; and q is at least 1, desirably at least 2.

Abstract: Lubricant compositions for use in automotive engine oils comprising a combination of a specific base stock or mixture of base stocks and a friction reducing additive to improve fuel economy and fuel economy longevity of the automotive engine oil. The friction reducing additive is a specific partial polyol ester and may also include a specific saturated primary amide.