Abstract: Froth flotation processes, useful for beneficiating base metal mineral values from metal sulfide ore, utilize a collector comprising an N-butoxycarbonyl-O-alkylthionocarbamate selected from the group consisting of N-butoxycarbonyl-O-methylthionocarbamate, N-butoxycarbonyl-O-ethylthionocarbamate, N-butoxycarbonyl-O-propylthiononocarbamate, N-butoxycarbonyl-O-butylthionocarbamate, N-butoxycarbonyl-O-pentylthionocarbamate, and N-butoxycarbonyl-O-hexylthionocarbamate.
Abstract: Materials and a process are provided whereby polymers with the pendant group or end group containing —Si(OR″)3 (where R″ is H, an alkyl group, Na, K, or NH4) are used to control aluminosilicate scaling in a Bayer process. When materials of the present invention are added to the Bayer liquor before the heat exchangers, they reduce and even completely prevent formation of aluminosilicate scale on heat exchanger walls. The present materials are effective at treatment concentrations that make them economically practical.
Type:
Grant
Filed:
July 22, 2002
Date of Patent:
November 9, 2004
Assignee:
Cytec Technology Corp.
Inventors:
Donald P. Spitzer, Alan S. Rothenberg, Howard I. Heitner, Frank Kula
Abstract: The present invention relates to a process for improving the shelf life of a hindered phenol antioxidant comprising the step of intimately mixing the hindered phenol antioxidant with a sulfur-containing peroxide decomposer. The inventors have discovered that mixing the peroxide decomposer with the hindered phenol antioxidant reduces the tendency of hindered phenols to yellow with age. This increases the desirability of the hindered phenol because it will not impart color to polymer systems. The present invention also relates to a composition produced from the process described above, and stabilized compositions and additive packages containing the composition produced from the above-described process.
Type:
Grant
Filed:
April 24, 2002
Date of Patent:
October 19, 2004
Assignee:
Cytec Technology Corp.
Inventors:
Brent M. Sanders, Darryl R. Kincaid, Sari-Beth Samuels
Abstract: The present invention relates to novel red-shifted UV absorbers comprising 1,3,5-triazine structures containing a 2-naphthol-derived substituent. The present invention also relates to a method for stabilizing a material by incorporating into such material, e.g., organic material, the novel red-shifted triazine compounds in an amount effective to stabilize the material against the effects of actinic radiation.
Type:
Grant
Filed:
September 27, 2001
Date of Patent:
October 5, 2004
Assignee:
Cytec Technology Corp.
Inventors:
Ram Baboo Gupta, Hargurpreet Singh, Russell C. Cappadona
Abstract: The present invention relates to benzoxazinone compounds having a yellow index less than about 0, and a sodium concentration less than about 50 ppm. This invention also relates to a process for preparing these compounds comprising the step of reacting an isatoic anhydride with approximately stoichiometric amounts of an acylating compound, where the isatoic anhydride is purified by re-crystallization or other purification methods.
Abstract: Collector compositions of a mixture of a C6 to C22 fatty hydroxamic acid and an oil for use in a method the removal of impurities from mineral ores by the froth flotation method. The collectors are prepared by reacting an ester of a C6 to C22 fatty acid with a hydroxylamine salt and a base in the presence of an oil and water to produce an alkyl hydroxamate salt; acidifying the alkyl hydroxamate salt, forming an organic layer and an aqueous layer, wherein the organic layer contains a C6 to C22 fatty hydroxamic acid substantially free of starting esters and hydrolysis and transesterification products of the ester; and separating the organic layer from the aqueous layer to provide a collector composition of the C6 to C22 fatty hydroxamic acid and the oil.
Type:
Grant
Filed:
April 5, 2002
Date of Patent:
May 25, 2004
Assignee:
Cytec Technology Corp.
Inventors:
Alan S. Rothenberg, Lino Giovanni Magliocco
Abstract: A solvent extraction composition is provided which comprises one or more orthohydroxyarylaldoxime or orthohydroxyarylketoxime and at least one dialkyl ester of an optionally substituted ethylene or polyethylene glycol and preferably a water immiscible organic solvent. The orthohydroxyarylaldoximes, or orthohydroxyarylketoximes commonly are of Formula (1),
wherein R1 is hydrogen or a hydrocarbyl group, and R2 is an ortho-hydroxyaryl group; and the dialkyl esters of an optionally substituted ethylene or polyethylene glycol commonly are of Formula (2),
wherein R7 and R8 are each independently an optionally substituted alkyl group; R9 to R20 are each independently hydrogen or optionally substituted hydrocarbyl; m, n and p are each independently 0, 1, 2, 3 or 4 provided that m+n+p is greater than or equal to 1; and q is 1, 2 or 3.
Type:
Grant
Filed:
November 27, 2001
Date of Patent:
May 11, 2004
Assignee:
Cytec Technology Corp.
Inventors:
Alan David Sugarman, Domenico Carlo Cupertino
Abstract: Froth flotation processes, useful for beneficiating base metal mineral values from metal sulfide ore, utilize a collector comprising N-butoxycarbonyl-O-butylthionocarbamate.
Abstract: It has been now surprisingly discovered after extensive research that 2-halo-4,6-bisaryl-1,3,5-triazine can be prepared with unprecedented selectivity, efficiency, mild conditions, and in high yield by the reaction of cyanuric halide with aromatics in the presence of at least one Lewis acid and at least one reaction promoter. This reaction is also unprecedently general as a variety of aromatics can be used to produce a wide selection of 2-halo-4,6-bisaryl-1,3,5-triazines. The novel approach includes the use of the reaction promoters in combination with at least one Lewis acid under certain reaction conditions to promote the formation of 2-halo-4,6-bisaryl-1,3,5-triazine compounds from cyanuric halide. Preferably, the Lewis acids and reaction promoters are combined to form a complex. 2-Halo-4,6-bisaryl-1,3,5-triazines are key intermediates for making 2-(2-oxyaryl)-4,6-bisaryl-1,3,5-triazine class of UV absorbers.
Type:
Grant
Filed:
February 9, 2001
Date of Patent:
May 4, 2004
Assignee:
Cytec Technology Corp.
Inventors:
Ram B. Gupta, Dennis J. Jakiela, Sampath Venimadhavan, Russell C. Cappadona, Venkatrao K. Pai
Abstract: Polymeric articles containing at least one polymeric material and a sufficient amount of at least one novel hindered amine light stabilizers to inhibit at least one of photo- or thermal degradation. The hindered amine light stabilizer may be a monomeric or an oligomeric hindered amine light stabilizer.
Abstract: A solvent extraction composition is provided which comprises one or more orthohydroxyarylaldoximes or orthohydroxyarylketoximes and one or more esters substituted with a hydroxyl group, and preferably a water immiscible organic solvent. The orthohydroxyarylaldoximes, or orthohydroxyarylketoximes commonly have Formula (1),
wherein R1 is hydrogen or a hydrocarbyl group, and R2 is an ortho-hydroxyaryl group; and the esters substituted with a hydroxyl group are of Formula (2),
wherein one of R7 or R8 is a substituted hydrocarbyl group with at least one hydroxyl group and the other is an optionally substituted hydrocarbyl group. Preferred orthohydroxyarylaldoximes are 5-(C9 to C14 alkyl)-2-hydroxybenzaldoximes and preferred orthohydroxyarylketoximes are 5-(C9 to C14 alkyl)-2-hydroxyacetophenone oximes. Preferred esters substituted with a hydroxy group are highly-branched alkyl esters comprising from 5 to 51 carbon atoms, wherein the hydroxy group resides on R8.
Abstract: The invention relates to a process for preparing a liquid melamine urea formaldehyde resin that has long term stability. The invention also relates to a liquid MUF resin with a high formaldehyde and melamine content. The invention further relates to a liquid suspension hardener including a catalyst, a thickener, a filler, and water. The invention also relates to a adhesive composition for use in wood bonding that is made by adding a hardener to the resin.
Type:
Grant
Filed:
February 25, 2003
Date of Patent:
April 20, 2004
Assignee:
Cytec Technology Corp.
Inventors:
Huide Dennis Zhu, William Jacobs, III, Robert G. Lees, Luis Mendonca, Roger C. Rasch
Abstract: It has been now surprisingly discovered after extensive research that 2-halo-4,6-bisaryl-1,3,5-triazine can be prepared with unprecedented selectivity, efficiency, mild conditions, and in high yield by the reaction of cyanuric halide with aromatics in the presence of at least one Lewis acid and at least one reaction promoter. This reaction is also unprecedently general as a variety of aromatics can be used to produce a wide selection of 2-halo-4,6-bisaryl-1,3,5-triazines. The novel approach includes the use of the reaction promoters in combination with at least one Lewis acid under certain reaction conditions to promote the formation of 2-halo-4,6-bisaryl-1,3,5-triazine compounds from cyanuric halide. Preferably, the Lewis acids and reaction promoters are combined to form a complex. 2-Halo-4,6-bisaryl-1,3,5-triazines are key intermediates for making 2-(2-oxyaryl)-4,6-bisaryl-1,3,5-triazine class of UV absorbers.
Type:
Grant
Filed:
February 9, 2001
Date of Patent:
March 23, 2004
Assignee:
Cytec Technology Corp.
Inventors:
Ram B. Gupta, Dennis J. Jakiela, Sampath Venimadhavan, Russell C. Cappadona, Venkatrao K. Pai
Abstract: Oligomeric compounds and methods of making the compound having the formula:
T—&Parenopenst;E—F&Parenclosest;i—&Parenopenst;E—F′&Parenclosest;j—&Parenopenst;E′—F&Parenclosest;k—&Parenopenst;E′—F′&Parenclosest;l—S (II)
wherein i, j, k, and l are integers from about 0 to 300 and the sum of i, j, k, and l is greater than 2, wherein the units F, F′ and T are derived from one or more multi-functional carbonyl compounds of general structure
DO—CO—CRaRb—(—CRcRd—)n—NH—(Y)m—CO—OD (IV)
wherein n is an integer from 1 to 15, m is either 0 or 1; Ra, Rb, Rc, and Rd, are each a hydrogen or a hydrocarbyl group; Y is CO—(CReRf)p, wherein Re and Rf are each a hydrogen or hydrocarbyl group and p is zero or an integer from 1 to 20 or CO—C6H4—, wherein the substitution pattern on the phenylene group is an ortho, meta, or para substitution pattern, and
Abstract: Polymer compositions comprised of small, dry polyacrylamide particles may be dispersed into water at industrially useful rates to form aqueous compositions, by separating the particles from each other and bringing them into contact with a moving stream of water in the manner described herein. The resulting aqueous compositions may be used as a treating solution in diverse applications such as flocculants in water treating, papermaking, mining, oil field, and biotechnological separations.
Type:
Grant
Filed:
June 26, 2000
Date of Patent:
November 4, 2003
Assignee:
Cytec Technology Corp.
Inventors:
John Harlukowicz, Morris Lewellyn, Roderick G. Ryles
Abstract: This invention relates to a novel, efficient, economic and general-purpose process for isolating monophenolic-bisaryl triazine compounds from polyphenolic-triazines compounds and other impurities. More specifically, this invention relates to a process for isolating the monophenolic-bisaryl triazine compounds by contacting it with a base, an alcohol or a hydrocarbon solvent.
Type:
Grant
Filed:
June 22, 2001
Date of Patent:
October 14, 2003
Assignee:
Cytec Technology Corp.
Inventors:
Ram Baboo Gupta, Hargurpreet Singh, Russell C. Cappadona
Abstract: A process for preparing blocked derivatives of m- or p- isopropenyl-&agr;,&agr;-dimethylbenzyl isocyanates, comprising reacting a meta- or a para-isopropenyl-&agr;,&agr;-dimethylbenzyl carbamate ester with hydroxy functional blocking group, such as hydroxyethylene-ethyleneurea, hydroxyethylenepropylene urea, dialkylaminoethanol and dialkylamino propanol