Patents Assigned to Daiken Chemical Co., Ltd.
  • Patent number: 8999206
    Abstract: Metal nanoparticles having improved migration resistance are provided. The present invention relates to a method for manufacturing composite nanoparticles including obtaining composite nanoparticles containing at least silver and copper in a single particle by heat treating a mixture containing an organic silver compound and an organic copper compound at a temperature of 150° C. or more in a non-oxidative atmosphere in the presence of a tertiary amine compound represented by the general formula R1R2R3N (wherein R1 through R3 are optionally substituted alkyl groups or aryl groups that may be the same or different, R1 through R3 may be linked in a ring, and the number of carbon atoms in each of R1 through R3 is 5 through 18 and may be the same or different).
    Type: Grant
    Filed: August 6, 2009
    Date of Patent: April 7, 2015
    Assignees: Osaka Municipal Technical Research Institute, Daiken Chemical Co., Ltd.
    Inventors: Masami Nakamoto, Mari Yamamoto, Yukiyasu Kashiwagi, Yukio Yoshida, Hiroshi Kakiuchi, Shinsuke Matsumura
  • Patent number: 8784702
    Abstract: Copper-containing nanoparticles with excellent oxidation resistance is provided. The present invention relates to a method for manufacturing copper-containing nanoparticles including obtaining copper-containing nanoparticles that contain an organic component by heat treating an organic copper compound at a temperature equal to or higher than a decomposition initiation temperature of the compound and lower than a complete decomposition temperature of the compound in a non-oxidative atmosphere in the presence of an organic material containing a 1,2-alkanediol having 5 or more carbon atoms and/or a derivative thereof.
    Type: Grant
    Filed: August 6, 2009
    Date of Patent: July 22, 2014
    Assignees: Osaka Municipal Technical Research Institute, Daiken Chemical Co., Ltd.
    Inventors: Masami Nakamoto, Mari Yamamoto, Yukiyasu Kashiwagi, Yukio Yoshida, Hiroshi Kakiuchi, Shinsuke Matsumura
  • Publication number: 20110193034
    Abstract: Copper-containing nanoparticles with excellent oxidation resistance is provided. The present invention relates to a method for manufacturing copper-containing nanoparticles including obtaining copper-containing nanoparticles that contain an organic component by heat treating an organic copper compound at a temperature equal to or higher than a decomposition initiation temperature of the compound and lower than a complete decomposition temperature of the compound in a non-oxidative atmosphere in the presence of an organic material containing a 1,2-alkanediol having 5 or more carbon atoms and/or a derivative thereof.
    Type: Application
    Filed: August 6, 2009
    Publication date: August 11, 2011
    Applicants: OSAKA MUNICIPAL TECHNICAL RESEARCH INSTITUTE, DAIKEN CHEMICAL CO., LTD.
    Inventors: Masami Nakamoto, Mari Yamamoto, Yukiyasu Kashiwagi, Yukio Yoshida, Hiroshi Kakiuchi, Shinsuke Matsumura
  • Publication number: 20110193033
    Abstract: Metal nanoparticles having improved migration resistance are provided. The present invention relates to a method for manufacturing composite nanoparticles including obtaining composite nanoparticles containing at least silver and copper in a single particle by heat treating a mixture containing an organic silver compound and an organic copper compound at a temperature of 150° C. or more in a non-oxidative atmosphere in the presence of a tertiary amine compound represented by the general formula R1R2R3N (wherein R1 through R3 are optionally substituted alkyl groups or aryl groups that may be the same or different, R1 through R3 may be linked in a ring, and the number of carbon atoms in each of R1 through R3 is 5 through 18 and may be the same or different).
    Type: Application
    Filed: August 6, 2009
    Publication date: August 11, 2011
    Applicants: OSAKA MUNICIPAL TECHNICAL RESEARCH INSTITUTE, DAIKEN CHEMICAL CO., LTD.
    Inventors: Masami Nakamoto, Mari Yamamoto, Yukiyasu Kashiwagi, Yukio Yoshida, Hiroshi Kakiuchi, Shinsuke Matsumura
  • Patent number: 7719198
    Abstract: A power supply circuit for plasma generation by which a large quantity of generated plasma can be smoothly obtained without increasing the sizes of an apparatus. An electric discharge generating electrode is composed of two or more first electrodes and one or more second electrodes. An LC series circuit is provided by connecting a capacitor C and a coil L in series between one of outputs of an alternating high voltage generating circuit which generates an alternating high voltage to be applied between the electrodes of electric discharge generating electrode, and the first electrode. When electricity is discharged in one of the electrode pair, voltage drop is suppressed by the coil, and since electric discharge from the other electrode pair is induced without being disturbed, a large quantity of plasma can be smoothly generated by common use of the alternating high voltage generating circuit.
    Type: Grant
    Filed: February 17, 2005
    Date of Patent: May 18, 2010
    Assignees: Daiken Chemical Co., Ltd.
    Inventors: Hirofumi Takikawa, Yoshimi Nishimura, Akio Harada
  • Patent number: 7648554
    Abstract: The main object of the present invention is to manufacture, on an industrial scale, metal nanoparticles with excellent dispersion stability, and therefore provides metal nanoparticles containing a metal component, further containing at least one of phosphorus, nitrogen, and oxygen, and the average particle size being from 1 to 100 nm.
    Type: Grant
    Filed: August 1, 2003
    Date of Patent: January 19, 2010
    Assignees: Daiken Chemical Co., Ltd., Osaka Municipal Technical Research Institute
    Inventors: Masami Nakamoto, Mari Yamamoto, Akio Harada
  • Publication number: 20090283013
    Abstract: Diamond fine particles having porous structure known in a high thermal resistance and low dielectric constant film has a high thermal conductivity and is expected as an insulating film for multiplayer wirings of a semiconductor integrated circuit device. A liquid composition of diamond fine particles, which are raw material of the film, is unstable as colloid, resulting in low reproducibility and yield in the production of films. It becomes possible to impart a very low viscosity and improved stability to the colloid liquid composition of diamond fine particles by containing a small amount of amine. If necessary, a thickener may be used to adjust the viscosity appropriately, so that various kinds of application systems can be used. A low dielectric constant film having a relative dielectric constant of about 2.5 can be thus obtained. Further, the liquid composition may be utilized as an abrasive for finishing.
    Type: Application
    Filed: July 17, 2009
    Publication date: November 19, 2009
    Applicants: Rorze Corporation, Daiken Chemical Co., Ltd.
    Inventors: Takayuki Takahagi, Hiroyuki Sakaue, Shoso Shingubara, Hiroyuki Tomimoto, Toshio Sakurai, Masahiko Uchiyama, Sachiko Ishikawa
  • Patent number: 7511270
    Abstract: The present invention realizes a nanotube probe with high durability that can be manufactured in short time with less impurities adhered to the holder sustaining the nanotube. The nanotube probe according to this invention is constructed by fastening a nanotube 8 on the protruded portion 4 of a cantilever by way of at least two partial coating films 12a and 12b. One or more additional partial coating films may be formed in the intermediate area between these two partial coating films. Each partial coating film is formed by irradiating electron beam 10 on the position where the nanotube 8 is in contact with the protruded portion 4 of the cantilever. The partial coating films are separated not to overlap each other. By minimizing the size of partial coating film as well as by narrowing down the beam diameter, coating time may be further shortened. With the beam diameter narrowed down, excessive deposit of impurities can be put under control.
    Type: Grant
    Filed: September 8, 2004
    Date of Patent: March 31, 2009
    Assignees: Daiken Chemical Co., Ltd.
    Inventors: Yoshikazu Nakayama, Takashi Okawa, Shigenobu Yamanaka, Akio Harada
  • Patent number: 7405178
    Abstract: A catalyst for manufacturing carbon substances, such as carbon nanotube that has a diameter of 1000 nm or less, the catalyst containing at least iron, cobalt or nickel of a first element group and tin or indium of a second element group. The catalyst can be formed by at least tin and indium in addition to cobalt or nickel. The former catalyst provides a 2-component type catalyst and a multi-component type catalyst that is composed on the basis of the 2-component type catalyst, and the later catalyst provides a 3-component type catalyst and a multi-component type catalyst that is composed on the basis of the 3-component type catalyst.
    Type: Grant
    Filed: December 23, 2002
    Date of Patent: July 29, 2008
    Assignees: Daiken Chemical Co., Ltd.
    Inventors: Xu Li, Youchang Wang, Takashi Okawa, Akio Harada, Yoshikazu Nakayama
  • Patent number: 7398678
    Abstract: A scanning microscope probe in which a palladium covering film is formed on the surface of the protruding portion of a cantilever, and the base end portion of a nanotube is disposed in contact with the palladium covering film with the tip end portion of the nanotube protruding to the outside, thus allowing the tip end to be used as a probe needle end for detecting signals. A coating film is formed to cover all or part of the surface of this base end portion, and the nanotube is thus firmly fastened to the cantilever. Since the base end portion adheres tightly to the palladium covering film, both of them are electrically continuous. This palladium covering film allows, as an electrode film, the application of a voltage to the nanotube or the passage of an electric current through the nanotube, showing also good adhesion to the nanotube and cantilever.
    Type: Grant
    Filed: June 6, 2005
    Date of Patent: July 15, 2008
    Assignees: Daiken Chemical Co., Ltd., SII Nanotechnology, Inc.
    Inventors: Yoshikazu Nakayama, Takashi Okawa, Shigenobu Yamanaka, Akio Harada, Masatoshi Yasutake, Yoshiharu Shirakawabe
  • Publication number: 20070278457
    Abstract: An object of the present invention is to manufacture of an industrial scale noble metal nanoparticles with superior dispersion stability. The present invention relates to a noble metal nanoparticle controlled to a mean particle size of 20 nm or less that is a metal nanoparticle comprising a noble metal component, and that contains at least one type of an organic component containing N and an organic component containing S.
    Type: Application
    Filed: March 8, 2005
    Publication date: December 6, 2007
    Applicants: OSAKA MUNICIPAL GOVERNMENT, DAIKEN CHEMICAL CO., LTD.
    Inventors: Masami Nakamoto, Mari Yamamoto, Akio Harada
  • Publication number: 20070107317
    Abstract: Diamond fine particles having porous structure known in a high thermal resistance and low dielectric constant film has a high thermal conductivity and is expected as an insulating film for multiplayer wirings of a semiconductor integrated circuit device. A liquid composition of diamond fine particles, which are raw material of the film, is unstable as colloid, resulting in low reproducibility and yield in the production of films. It becomes possible to impart a very low viscosity and improved stability to the colloid liquid composition of diamond fine particles by containing a small amount of amine. If necessary, a thickener may be used to adjust the viscosity appropriately, so that various kinds of application systems can be used. A low dielectric constant film having a relative dielectric constant of about 2.5 can be thus obtained. Further, the liquid composition may be utilized as an abrasive for finishing.
    Type: Application
    Filed: October 21, 2004
    Publication date: May 17, 2007
    Applicants: JAPAN SCIENCE AND TECHNOLOGY AGENCY, RORZE CORPORATION, DAIKEN CHEMICAL CO., LTD.
    Inventors: Takayuki Takahagi, Hiroyuki Sakaue, Shoso Shingubara, Hiroyuki Tomimoto, Toshio Sakurai, Masahiko Uchiyama, Sachiko Ishikawa
  • Patent number: 7138627
    Abstract: A nanotube probe assembled under real-time observation inside an electron microscope, the probe including a nanotube; a holder for holding the nanotube; and a fastening means for fastening the nanotube at a base end portion thereof to the holder; and the tip end portion of the nanotube protrudes from the holder. The method for manufacturing a nanotube probe includes the steps of setting up a nanotube and a holder inside an electron microscope; allowing a base end portion of the nanotube, with a tip end portion thereof protruding, to come into contact with the holder; and irradiating electron beam to the base end portion of the nanotube to form a carbon film at the base end portion of the nanotube, or forming a fused part at the base end portion of the nanotube, thus fastening the base end portion of the nanotube to the holder by the carbon film.
    Type: Grant
    Filed: June 29, 2005
    Date of Patent: November 21, 2006
    Assignees: Daiken Chemical Co., Ltd., Yoshikazu Nakayama
    Inventors: Yoshikazu Nakayama, Akio Harada, Seiji Akita
  • Patent number: 7073937
    Abstract: A heat emitting probe including a conductive nanotube probe needle with its base end fastened to a holder and its tip end protruded, a heat emitting body formed on the probe needle, a conductive nanotube lead wire fastened to the heat emitting body, and an electric current supply that causes an electric current to pass through the conductive nanotube lead wire and both ends of the probe needle. The tip end of the probe needle is thus heated by an electric current flowing through the heat emitting body. A heat emitting probe apparatus includes the above-described heat emitting probe, a scanning mechanism that allows the heat emitting probe to scan over a thermal recording medium, and a control circuit that causes the tip end of the probe needle to emit heat, thus recording extremely small hole patterns in the surface of a thermal recording medium.
    Type: Grant
    Filed: February 13, 2002
    Date of Patent: July 11, 2006
    Assignees: Yoshikaza Nakayama, Daiken Chemical Co., Ltd.
    Inventors: Yoshikazu Nakayama, Akio Harada
  • Patent number: 7066513
    Abstract: The operation method of nanotweezers including the steps of: confirming the position of a nanoscale material by way of imaging the surface of a specimen by a scanning type probe microscope; moving the nanotweezers to the position over the nanoscale material; descending the nanotweezers which are in an opened state and then closing the nanotweezers so as to hold the nanoscale material; raising the nanotweezers that hold the nanoscale material and then moving the nanotweezers to an objective position; and descending the nanotweezers that hold the nanoscale material and then opening the nanotweezers, thus releasing the nanoscale material on the objective position which is on the surface of the specimen and is where a nanoscale construction is constructed.
    Type: Grant
    Filed: February 12, 2003
    Date of Patent: June 27, 2006
    Assignees: Daiken Chemical Co., Ltd., Yoshikazu Nakayama
    Inventors: Shigenobu Yamanaka, Akio Harada, Yoshikazu Nakayama
  • Patent number: 7064341
    Abstract: The coated nanotube surface signal probe constructed from a nanotube, a holder which holds the nanotube, a coating film fastening a base end portion of the nanotube to a surface of the holder by way of adhering the base end portion on the surface of holder in a range of a base end portion length with an electric contact state and covering a specified region including the base end portion with the coating film maintaining the electric contact state between the nanotube and the holder, a tip end portion of the nanotube being caused to protrude from the holder; and the tip end portion is used as a probe needle so as to scan surface signals. The coated nanotube surface signal probe can be used as a probe in AFM (Atomic Force Microscope), STM (Scanning Tunneling Microscope) other SPM (Scanning Probe Microscope).
    Type: Grant
    Filed: March 4, 2004
    Date of Patent: June 20, 2006
    Assignees: Daiken Chemical Co., Ltd.
    Inventors: Yoshikazu Nakayama, Akio Harada, Seiji Akita
  • Patent number: 7049258
    Abstract: Various high quality microwave dielectric composite compositions are prepared by replacing a part of Ba, La or Ti with another element in a dielectric material represented by BanLa4Ti3+nO12+3n. A first embodiment thereof comprises a ceramic composition represented by (Ba1?xAx)nLa4Ti3+nO12+3n, wherein A is an alkaline earth metal element except Ba, and 0.5<n<5 and 0<x<0.5, which is a composite composition being homologous as the former dielectric material and having a chemical formula obtained by replacing a part of Ba with an alkaline earth metal element except Ba. Similarly, a part of La and a part of Ti can be replaced with a rare earth element except La and an element except Ti, respectively. The above various microwave dielectric composite compositions can be used for adjusting microwave dielectric characteristics of a material through replacing a part of a constituent element with another element and thus increasing the variety of the material for a dielectric resonator.
    Type: Grant
    Filed: July 4, 2002
    Date of Patent: May 23, 2006
    Assignees: Daiken Chemical Co., Ltd.
    Inventors: Hitoshi Ohsato, Akio Harada, Takashi Okawa, Hiroki Okabe
  • Patent number: 7014830
    Abstract: A method for manufacturing carbon nanocoils that uses a reactor, including the steps of: heating an interior of the reactor, causing a hydrocarbon gas to flow in the reactor, dispersing an indium/tin/iron-based catalyst in a form of particles in the hydrocarbon gas, and allowing carbon nanocoils to grow on a surface of the catalyst while decomposing the hydrocarbon near the catalyst. The method can be comprised of the steps of: disposing a rotor inside a reactor, heating an area near the peripheral surface of the rotor, causing a hydrocarbon gas to flow in the reactor, coating a part of the peripheral surface of the rotor with an indium/tin/iron-based catalyst that is in a form of particles, allowing carbon nanocoils to grow on a surface of the catalyst coated on the rotating rotor, and collecting carbon nanocoils, which are grown during a rotation of the rotor, from the rotor.
    Type: Grant
    Filed: July 10, 2002
    Date of Patent: March 21, 2006
    Assignees: Daiken Chemical Co., Ltd.
    Inventors: Yoshikazu Nakayama, Akio Harada
  • Patent number: 7008754
    Abstract: By using a novel method, the exposure time of the photosensitive paste layer is reduced and the exposure fineness of the layer is improved, thereby developing a highly fine circuit substrate of high density having a thermal resistance at a reasonable cost. A circuit substrate is manufactured as follows. A photosensitive paste containing photoresist and a circuit material is applied onto a substrate surface so as to form a photosensitive paste layer (4). This photosensitive paste layer (4) is plotted by a laser beam (8) so as to form a plotted area (7). The photosensitive paste layer (4) is developed and an exposed area (4a) or an unexposed area (4b) is removed so as to form a circuit pattern (17). This circuit pattern (17) is sintered to form a circuit pattern (20) composed of the circuit material. It is possible to form a highly fine circuit pattern of high density by laser beam plotting.
    Type: Grant
    Filed: July 18, 2002
    Date of Patent: March 7, 2006
    Assignee: Daiken Chemical Co., Ltd.
    Inventors: Masatoshi Kato, Akio Harada
  • Patent number: 6981727
    Abstract: Diode-type nanotweezers including a first arm and a second arm that project from a holder and are opened and closed by an electrostatic force so as to hold a nanosubstance. The first arm is formed by a gate nanotube fastened at its base end to the holder, and its tip end protrudes from the holder. The second arm is formed by a nanotube diode fastened at its two base ends to the holder and have a diode characteristic portion at its tip end. Diode current and diode voltage applied between the base ends of the arms shows a non-linear diode characteristic such as varistor and rectification. When a gate voltage is applied between the gate nanotube and the nanotube diode, the arms are controlled and a grip strength for a nanosubstance held by the arms is detected by changes in the gate voltage or the diode current.
    Type: Grant
    Filed: January 31, 2003
    Date of Patent: January 3, 2006
    Assignees: Daiken Chemical Co., Ltd.
    Inventors: Yoshikazu Nakayama, Akio Harada