Abstract: A process for preparation of filler-containing polytetrafluoroethylene fine powder by coagulating polytetrafluoroethylene together with at least one filler selected from the group consisting of polyimide resins, polyamide-imide resins, polyamide resins and carbon fiber powders from their aqueous dispersion, characterized in that a water-insoluble organic liquid having a boiling point of from 30.degree. to 150.degree. C. and a surface tension of not more than 35 dyne/cm at 20.degree. C. is added to the aqueous dispersion under agitation at any stage from the start to the end of the coagulation.
Abstract: Continuous fluorination of carbon is carried out by employing an apparatus for contact reaction of solid powder and reactive gas which comprises a horizontal reactor having a trough provided with weirs (e.g. height: 1 to 6 mm., interval: 5 to 30 cm.) and a vibrating means for vibrating the trough, and in which carbon particles supplied continuously are transported on the trough in a form of thin layer by the vibration of the trough while continuing the reaction by contacting efficiently the carbon particles with a fluorine gas. The contact reaction is efficiently conducted without accumulating the reaction heat to produce the fluorinated carbon in high yields, and the process is useful for the mass production. The apparatus is also useful for various contact reaction of a solid powder and a reactive gas.
Abstract: A process for preparing filler-containing polytetrafluoroethylene fine powder which comprises mixing together an aqueous dispersion of particles of polytetrafluoroethylene and an aqueous dispersion of particles of a filler adsorbed with polyvalent cation at the surfaces so as to be charged positively in the presence of an anionic surfactant and a water-immiscible organic liquid to coagulate the polytetrafluoroethylene particles and the filler particles in combination and recovering the coagulated particles from the resultant dispersion mixture, said filler particles being per se chargeable negatively in water.
Type:
Grant
Filed:
February 18, 1981
Date of Patent:
April 3, 1984
Assignee:
Daikin Kogyo Co., Ltd.
Inventors:
Shoji Kawachi, Katsutoshi Yamamoto, Shinichiro Kai
Abstract: A cross-fin coil type heat exchanger wherein a multiplicity of raised fins of the louver type are formed on the major portion of the surface of a convoluted fin base plate and the area of the portion of the fin base plate reduced in heat transfer performance is minimized, to improve the heat transfer effects achieved by the fins. Means is provided to inhibit the growth of a boundary layer by the front edge effect of the raised fins and promote the conversion of a current of a heat exchange fluid. Ribs are formed in the fins remote from heat transfer tubes to further promote the conversion of the current of the heat exchange fluid into a turbulent flow and also to reinforce the fins. The raised fins of the louver type have a construction that tends itself to good draining, to avoid an increase in the resistance offered to the passage of the current of the heat exchange fluid in wet condition.
Abstract: An absorption refrigerant composition for use in absorption refrigeration systems comprising 1,1,1,2-tetrafluoroethane and an organic solvent capable of dissolving the ethane.
Abstract: A mold release composition consisting essentially of:(A) a fluorine-containing polyether comprising 3-perfluoroalkyl-1,2-epoxypropane having the formula ##STR1## wherein R.sub.f represents a perfluoroalkyl group containing from 5 to 13 carbon atoms and(B) at least one additive selected from the group consisting of a silicone oil, silicone varnish, a wax and a highly fluorinated organic compound having a boiling point above 100.degree. C.
Abstract: A copolymer comprising (a) a monomer having a C.sub.7 to C.sub.21 perfluoroalkyl or perfluoroalkenyl group at one end of the molecule and an ethylenically unsaturated group at the other end of the molecule, and (b) a monomer having a photosensitive group, e.g. an azidobenzoyloxy group, cinnamoyloxy group, benzoylphenyl group or .alpha.,.beta.-unsaturated ketone group. The copolymer has an excellent photosensitivity and excellent water and oil repellent properties, and is useful for various purposes, e.g. as a photosensitive material for dry offset printing plate or resist and as a photo-curable, water and oil repelling coating material.
Abstract: A process for forming a fluoroalkyl acrylate polymer film on a substrate by plasma polymerization. The fluoroalkyl acrylate polymer film has a high sensitivity to high energy rays and an excellent resolving power, and is very useful as a resist film. The plasma polymerized film of the invention has little pinholes, and is endurable to dry etching. A patterned resist film is prepared by irradiating the film with high energy rays to form a latent pattern and developing the latent pattern by either a wet process using a solvent or an oxygen or oxygen-containing gas plasma etching. Also, a pattern can be formed in the film by only electron beam irradiation. The pattern formation can be attained by electron beam delineation without development treatment.
Abstract: A process for forming a fluoroalkyl acrylate polymer film on a substrate by plasma polymerization. The fluoroalkyl acrylate polymer film has a high sensitivity to high energy rays and an excellent resolving power, and is very useful as a resist film. The plasma polymerized film of the invention has little pinholes, and is endurable to dry etching. A patterned resist film is prepared by irradiating the film with high energy rays to form a latent pattern and developing the latent pattern by either a wet process using a solvent or an oxygen or oxygen-containing gas plasma etching. Also, a pattern can be formed in the film by only electron beam irradiation. The pattern formation can be attained by electron beam delineation without development treatment.
Abstract: The present invention relates to a fluorinated resin coating composition comprising (a) a fluorinated resin, (b) micaceous iron oxide and (c) a liquid carrier. When the composition of the invention is used as a primer, an auxiliary agent for adhesion is necessitated as the supplemental component in addition to the components (a), (b) and (c). The composition of the invention can afford an excellent wear-resistance and is especially suitable for coating of inner surfaces of cooking utensils. The scratch-resistance of the coating film formed on a cooking utensil is greatly improved especially when the composition is employed for top coating. Sufficient improvement can be also attained in case of using the composition of the invention as a primer.
Abstract: An apparatus for removing moisture and odors comprising a cylindrical honeycomb structure made by corrugation from paper uniformly containing an adsorbent, including a multiplicity of parallel gas passageways and having deposited thereon a water absorbent at least at one side thereof serving as an outlet for the gas to be treated, a number of the gas passageways being separated as a dehumidifying and deodorizing zone from the other passageways serving as a regenerating zone, the dehumidifying and deodorizing zone being continuously shiftable throughout the entire honeycomb structure circumferentially thereof to render the honeycomb structure serviceable, from portion to portion, as the dehumidifying and deodorizing zone provided by the number of passageways.
Abstract: A process for preparing perfluoro(lower)alkylbenzenes and derivatives thereof which comprises contacting a lower alkylbenzene or the corresponding derivative with hydrogen fluoride in the presence of chlorine in the gaseous phase at an elevated temperature to give the corresponding perfluoro(lower)alkylbenzene or its derivative thereof.
Abstract: Fluorine-containing phenyl benzoate compounds which have the general formula: ##STR1## wherein R is a C.sub.1 -C.sub.12 perfluoroalkyl group, a C.sub.1 -C.sub.12 alkyl group, a C.sub.1 -C.sub.12 alkoxy group, a C.sub.2 -C.sub.13 alkanoyloxy group, a C.sub.2 -C.sub.13 alkoxycarbonyl group, a C.sub.2 -C.sub.13 alkoxycarbonyloxy group or a C.sub.2 -C.sub.13 alkyldioxycarbonyl group and X is a C.sub.1 -C.sub.12 alkyl group, a C.sub.1 -C.sub.12 alkoxy group, a cyano group, a trifluoromethyl group or a nitro group with the proviso that X is trifluoromethyl when R is other than perfluoroalkyl are useful as components of liquid crystals.
Abstract: A process for preparing benzotrifluoride or derivatives thereof by contacting benzotrichloride or the corresponding derivatives with hydrogen fluoride in a gaseous phase in the absence of any catalyst, the contact being carried out in the presence of chlorine at an elevated temperature so as to accelerate the reaction rate.
Abstract: Monofluorobenzene is prepared in a good yield by reacting cyclopentadiene or its dimer of the formula: ##STR1## with fluorohalomethane of the formula:CHFX.sub.2wherein Xs are, same or different, halogen atoms in the presence of a phase transfer catalyst and an acid acceptor.
Abstract: An adhesive composition comprising a low molecular weight fluorine-containing elastomer and fibrillated polytetrafluoroethylene, which is excellent in chemical resistance and weather resistance.
Abstract: A water removing composition suitable for use in treating solid surfaces which comprises (a) a halogenated hydrocarbon solvent, (b) at least one member selected from the group consisting of amines having an oxyalkylene group, their salts with an organic acid of the formula, R.sup.1 COOH, HOOCR.sup.2 COOH, R.sup.1 SO.sub.3 H, R.sup.1 OPO.sub.3 H or (R.sup.1 O).sub.2 PO.sub.2 H, wherein R.sup.1 is an alkyl group having 1 to 20 carbon atoms which may be substituted with a hydroxyl group or an alkylphenyl group having 7 to 26 carbon atoms and R.sup.2 is an alkylene group having 1 to 10 carbon atoms, and quaternary ammonium salts composed of an ammonium having an oxyalkylene group and an acid radical of the above-mentioned organic acids, and (c) at least one substituted amine salt with dialkyl sulfosuccinate of the formula ##STR1## wherein R.sup.1 is as defined above, and R.sup.3, R.sup.4 and R.sup.
Abstract: A process for forming a fluoroalkyl acrylate polymer film on a substrate by plasma polymerization. The fluoroalkyl acrylate polymer film has a high sensitivity to high energy rays and an excellent resolving power, and is very useful as a resist film. The plasma polymerized film of the invention has little pinholes, and is endurable to dry etching. A patterned resist film is prepared by irradiating the film with high energy rays to form a latent pattern and developing the latent pattern by either a wet process using a solvent or an oxygen or oxygen-containing gas plasma etching. Also, a pattern can be formed in the film by only electron beam irradiation. The pattern formation can be attained by electron beam delineation without development treatment.
Abstract: Polytetrafluoroethylene fine powders which have an average molecular weight of not less than 5,000,000, preferably not less than 5,500,000, an amorphous index of not more than 0.1, preferably not more than 0.09, a number average primary particle size of 0.1 to 0.4 micron, preferably 0.15 to 0.38 micron, and a sharp endothermic peak at a temperature between 343.degree. C. and 350.degree. C. on the melting diagram by a differential scanning calorimeter, said sharp peak having an endothermic ratio of not more than 0.3, preferably not more than 0.27, and a half value width of the endothermic peak of not more than 8 degrees, preferably not more than 6 degrees, and a process for producing the polytetrafluoroethylene fine powders. The polytetrafluoroethylene fine powders have an excellent stretchability and are useful for electric wire coating, small diameter tubes, large diameter tubes, sealing tapes and the like.