Patents Assigned to Daiso Co., Ltd.
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Patent number: 8283039Abstract: The invention provides a vulcanized rubber laminate obtained by firmly bonding an unvulcanized epichlorohydrin rubber layer and an organic peroxide-containing fluororubber layer. The laminate is obtained by thermal adhesion a layer of an unvulcanized epichlorohydrin rubber composition to a layer of an unvulcanized fluororubber composition. The epichlorohydrin rubber composition comprises 1) an unvulcanized epichlorohydrin rubber containing 3 to 15 mol % of allyl glycidyl ether unit, 2) quinoxaline-based vulcanizing agents, mercaptotriazine-based vulcanizing agents or bisphenol-based vulcanizing agents, and 3) 1,8-diazabicyclo(5,4,0)undecene-7 salts, 1,5-diazabicyclo(4,3,0)nonene-5 salts, quaternary ammonium salts, quaternary phosphonium salts, basic white carbons or an alkaline metal salt of higher fatty acid the fluororubber composition comprises an fluororubber and an organic peroxide-based vulcanizing agent.Type: GrantFiled: March 24, 2006Date of Patent: October 9, 2012Assignee: Daiso Co., Ltd.Inventors: Toshiyuki Funayama, Shigeru Shoji, Yasushi Hamura, Toyofumi Otaka
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Patent number: 8258222Abstract: A composition for epihalohydrin vulcanized rubber excellent in heat resistance while keeping good vulcanization rate and store stability, comprising (a) an epihalohydrin robber, (b) a metal soap, (c) an acid acceptor, and (d) a vulcanizing agent, the composition further preferably containing (e) a fatty acid for suppressing vulcanization, or preferably containing (f) an alcohol for accelerating vulcanization.Type: GrantFiled: November 23, 2005Date of Patent: September 4, 2012Assignee: Daiso Co., Ltd.Inventors: Toyofumi Otaka, Shigeru Shoji, Yasushi Hamura, Toshiyuki Funayama
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Patent number: 8246992Abstract: The present invention provides a combination product which comprises: (1) a polyaldehyde obtained by introducing an aldehyde group into a branched glucose in a ?-1,3-glucan, and (2) a polyamine obtained by increasing the molecular weight of a poly-L-lysine. The combination product according to the present invention is useful as a material for a tissue adhesive hydrogel which can be used as a hemostatic agent or the like which exhibits low risks for viral infections and the like, high biodegradability and biocompatibility, excellent safety, a good adhesion rate and a good adhesion strength.Type: GrantFiled: November 4, 2008Date of Patent: August 21, 2012Assignees: Osaka City University, Daiso Co., Ltd.Inventors: Takeshi Nagasaki, Tatsuro Hayashi, Kenji Oohata, Kenichi Ishibashi, Toshio Suzuki, Yoshiro Furukawa
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Publication number: 20120208966Abstract: A composition for a semiconductive rubber, comprising an epichlorohydrin-based rubber (a), an ethylene oxide-modified (meth)acrylate (b), and at least one kind of a crosslinking agent (c) selected from the group consisting of a sulfur-based crosslinking agent, a quinoxaline-based crosslinking agent and a triazine-based crosslinking agent.Type: ApplicationFiled: October 14, 2010Publication date: August 16, 2012Applicant: DAISO CO., LTD.Inventors: Kohji Ohnuki, Yoritaka Yasuda, Taro Ozaki
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Insoluble anode for metal wire electroplating and method of electroplating metal wire using the same
Patent number: 8226805Abstract: An insoluble anode for metal wire electroplating capable of simultaneously electroplating a plurality of metal wires and uniformalizing the electroplating amounts of the metal wires stably for a long time. For realizing these, a plurality of insoluble electrode plates are disposed in a parallel alignment to be placed sandwiching a plurality of wire travel paths from both sides. A plurality of the insoluble electrode plates are tightened and fixed by through-bolts at a plurality of places along the travel path direction. A conductive spacer is interposed in each gap between the insoluble electrode plates at a tightening part by the through-bolt and also a conductive member is provided so as to contact all the electrode plates and the conductive spacers.Type: GrantFiled: June 29, 2007Date of Patent: July 24, 2012Assignees: Daiso Co., Ltd., Bridgestone CorporationInventors: Kenji Kawaguchi, Ryuichi Otogawa, Kenichi Murakami, Yuji Nakamura -
Patent number: 8197658Abstract: In order to solve various problems such as a reduction in a paint resin with the progress of electrodeposition coating treatment and remelting of a coating film or the occurrence of pinholes caused by an increased concentration of an electrolyte as a result of the reduction, upsizing of a hollow electrode with a membrane for electrodeposition coating combined with a barrier membrane (e.g., an ion exchange membrane) and an increase in the number of components should be avoided. In order to realize this, a barrier membrane 20 such as an ion exchange membrane is attached to the exterior surface of an electrode main body 10, which is in a hollow state made of a conductive material and configured so as to allow a liquid to pass through freely between the inside and outside of the electrode serving as a support.Type: GrantFiled: April 13, 2007Date of Patent: June 12, 2012Assignees: Daiso Co., Ltd., AGC Engineering Co., Ltd.Inventors: Shouhei Matsui, Yasushi Yoshida, Nobuyoshi Shoji, Yukio Matsumura
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Publication number: 20120141712Abstract: Disclosed is a vulcanized rubber laminate, wherein a thermoplastic resin layer and an unvulcanized epichlorohydrin rubber composition layer containing a specific maleimide compound, vulcanizing agent, and acid acceptor are heated and bonded. Specifically disclosed is a laminate configured by heating and bonding an unvulcanized epichlorohydrin rubber composition layer (A) and a thermoplastic resin (B), wherein the unvulcanized epichlorohydrin rubber composition contains: an epichlorohydrin rubber (a), a compound containing one or more maleimide group within the molecule (b), a vulcanizing agent (c), and an acid acceptor (d).Type: ApplicationFiled: June 1, 2010Publication date: June 7, 2012Applicant: DAISO CO., LTD.Inventors: Toyofumi Otaka, Koushiro Hamaguchi, Yoritaka Yasuda, Taro Ozaki
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Patent number: 8171835Abstract: [Object] An apparatus for chamfering fold formation tape ends is provided which not only facilitates setting of a workpiece tape but also simultaneously carries out cutting of the tape so as to form acute-angled ends and chamfering of the side faces of the tape ends to perform end processing at two positions at a time.Type: GrantFiled: October 29, 2007Date of Patent: May 8, 2012Assignee: Daiso Co., Ltd.Inventor: Joji Otsuka
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Publication number: 20120091007Abstract: In an insoluble anode for use in an electrolysis step accompanied by oxygen generation, by making the anode exert sufficient durability even in electrolysis accompanied by cathodic polarization besides anodic polarization, a service life of an electrode is prolonged and works of electrode repair, replacement, and the like are reduced. In order to realize this, an active material supporting member made of a porous metal sheet such as an expanded metal, a punching metal, or a bamboo blind-like or net-shaped metal is bonded to a conductive metal as an electrode structure, to configure an electrode substrate. The electrode substrate is coated, on the side to which the supporting member is bonded, with an electrode active material consisting mainly of iridium oxide. Thus, the anode for oxygen generation, which is highly resistant to a cathodization phenomenon, is obtained.Type: ApplicationFiled: April 28, 2010Publication date: April 19, 2012Applicant: DAISO CO., LTD.Inventors: Hiroki Imoto, Shinji Yamauchi, Hirokatsu Shimizu
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Publication number: 20120016120Abstract: The invention relates to a production method of a 2-hydroxymethylmorpholine salt, which includes crystallization from a solution containing 2-hydroxymethylmorpholine of formula (1) 1,4-oxazepane compound of formula (2) and an acid.Type: ApplicationFiled: January 15, 2010Publication date: January 19, 2012Applicant: DAISO CO., LTD.Inventors: Yoshifumi Nagano, Keisuke Yaegashi, Shingo Iwashina
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Publication number: 20110288315Abstract: A 2-aryl-2-halomethyl-4-chloromethyl-1,3-dioxolane (A) can be produced conveniently without decreasing its optical purity by reacting an optically active monochlorohydrin and an aryl (halomethyl) ketone (starting materials) with each other in the presence of an acid catalyst. From the optically active compound (A) thus produced, an optically active carboxylic acid (2-aryl-2-halomethyl-1,3-dioxolan-4-yl)methyl ester and an optically active sulfonic acid (2-aryl-2-halomethyl-1,3-dioxolan-4-yl)methyl ester (both of which are useful intermediates for the production of ketoconazole) can be produced with good efficiency. An optically active trans-carboxylic acid (2-aryl-2-halomethyl-1,3-dioxolan-4-yl)methyl ester can be isomerized into its cis-form in the presence of an acid catalyst.Type: ApplicationFiled: March 23, 2009Publication date: November 24, 2011Applicant: DAISO CO., LTD.Inventors: Yutaka Ishii, Shingo Iwashina, Takahiro Kawase, Yumiko Matsui
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Patent number: 8026007Abstract: A polymer electrolyte composition characterized by comprising: (1) a crosslinked material of a polyether binary copolymer which has a main chain comprising repeating units represented by the formula (i) and crosslinking units represented by the formula (ii) and which has a weight-average molecular weight of 104 to 107, (2) an electrolyte solution comprising an aprotic organic solvent, (3) an additive, as an optical ingredient, which comprises an ether compound having an ethylene oxide unit, and (4) an electrolyte salt compound comprising a lithium salt compound. The composition is excellent in liquid retention and ionic conductivity, is usable in a wide temperature range, and has excellent electrochemical properties.Type: GrantFiled: June 17, 2004Date of Patent: September 27, 2011Assignee: Daiso Co., Ltd.Inventors: Katsuhito Miura, Masato Tabuchi, Shouhei Matsui, Yoshihiko Wada
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Publication number: 20110210296Abstract: The present invention provides a rubber composition, which realizes low hardness and low compression set while maintaining semi-conductivity, and a vulcanizate thereof. Also the rubber composition can be obtained by blending an epichlorohydrin-based rubber having satisfactory semi-conductivity and an acrylonitrile-butadiene-based rubber as a reactive plasticizer, and also blending zinc oxide, a thiuram-based compound and a quinoxaline-based compound.Type: ApplicationFiled: October 28, 2009Publication date: September 1, 2011Applicant: DAISO CO., LTD.Inventors: Yoritaka Yasuda, Toyofumi Otaka, Tadahiro Ono, Koushiro Hamaguchi
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Publication number: 20110160342Abstract: Disclosed is a vulcanizable rubber composition for use in an air spring, which has excellent low-temperature behavior, and a vulcanized rubber formed product for air springs, which is obtained by vulcanization of the rubber composition. Also disclosed is a vulcanizable rubber composition for use in an air spring, comprising: an epihalohydrin-based copolymer comprising 50 to 70 mol % of a constituent unit derived from ethylene oxide and/or propylene oxide, 20 to 50 mol % of a constituent unit derived from epihalohydrin, and 0 to 15 mol % of a constituent unit derived from allyl glycidyl ether; a vulcanizing agent; a plasticizer; and an acid acceptor, and a rubber formed product for air springs, which is obtained by vulcanization of the composition.Type: ApplicationFiled: March 3, 2009Publication date: June 30, 2011Applicant: DAISO CO., LTD.Inventors: Yasuo Matoba, Tadahiro Ono, Motoki Kitagawa
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Patent number: 7943019Abstract: Provided is an economical long-life insoluble anode capable of maintaining an anode function stably for a long time even if it is used in a part where severe consumption occurs to generate a cathodizing phenomenon, and also capable of reducing the amount of an electrocatalyst used as much as possible. To realize this, on the surface of a metal substrate 10 composed of a titanium plate, a porous layer 20 including a sintered body of a spherical titanium powder is formed as a base layer. An electrocatalyst layer 30 is formed from the surface of the porous layer 20 to its inside. A part of the electrocatalyst penetrates into the porous layer 20, which provides an incomparably stronger anchor effect than the case of a blast treatment. Even when parts exposed from the porous layer 20 are peeled off and dropped off, the anode function is maintained by the electrocatalyst left in the porous layer 20.Type: GrantFiled: January 6, 2006Date of Patent: May 17, 2011Assignee: Daiso Co., Ltd.Inventors: Ryuichi Otogawa, Kumiko Ohara, Takashi Onishi
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Publication number: 20100297452Abstract: Disclosed is a vulcanized rubber laminate in which both an unvulcanized epichlorohydrin-based rubber composition layer containing a specific polyfunctional (meth)acrylate compound and a specific vulcanizing agent and an unvulcanized fluororubber composition layer containing a specific vulcanizing agent are heated and bonded, whereby, both rubber layers are firmly bonded.Type: ApplicationFiled: January 28, 2009Publication date: November 25, 2010Applicant: DAISO CO., LTD.Inventors: Toshiyuki Funayama, Shigeru Shoji, Toyofumi Otaka
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Publication number: 20100276280Abstract: In order to solve various problems such as a reduction in a paint resin with the progress of electrodeposition coating treatment and remelting of a coating film or the occurrence of pinholes caused by an increased concentration of an electrolyte as a result of the reduction, upsizing of a hollow electrode with a membrane for electrodeposition coating combined with a barrier membrane (e.g., an ion exchange membrane) and an increase in the number of components should be avoided. In order to realize this, a barrier membrane 20 such as an ion exchange membrane is attached to the exterior surface of an electrode main body 10, which is in a hollow state made of a conductive material and configured so as to allow a liquid to pass through freely between the inside and outside of the electrode serving as a support.Type: ApplicationFiled: April 13, 2007Publication date: November 4, 2010Applicants: Daiso Co., Ltd., AGC Engineering Co., Ltd.Inventors: Shouhei Matsui, Yasushi Yoshida, Nobuyoshi Shoji, Yukio Matsumura
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Patent number: 7750162Abstract: A process for the preparation of a nonnatural amino acid represented by the following formula (C): which is characterized by reacting a compound represented by the following formula (A1), a compound represented by the following formula (A2) and a compound represented by the following formula (A3) (step 1): to form a compound represented by the following formula (B): and then subjecting the compound (B) to deprotection of protective groups of carboxyl groups and to decarboxylation (wherein X1 and X2 are a leaving group, R1 is an aromatic group, an unsaturated heterocyclic group, or R6CO group, R2 and R3 are a protected carboxyl group, R4 is a protected amino group, R5 is hydrogen atom, an aliphatic hydrocarbon group, an aromatic group, or a heterocyclic group, R6 is an aromatic group or an unsaturated heterocyclic group, etc., and p, q and r are an integer of 0 to 10).Type: GrantFiled: April 18, 2005Date of Patent: July 6, 2010Assignee: Daiso Co., Ltd.Inventors: Yutaka Ishii, Ryosuke Fujimoto
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Patent number: 7732646Abstract: An allyl type crosslinking agent for use in production of a super water-absorbent polymer comprising a polymerizable compound having a carbon-carbon double bond or a salt thereof. The crosslinking agent comprises a linear hydroxypolyallyl ether having at least one hydroxyl group and at least two allyl groups obtained by allyletherification of hydroxyl groups in a linear polyol compound selected from the group consisting of erythritol, xylitol and sorbitol. This allyl type crosslinking agent is highly soluble in an aqueous solvent, and can give an excellent super water-absorbent polymer, which cannot be obtained in the prior arts, having high levels of both of water absorptivity under atmospheric pressure and water absorptivity under pressurized conditions.Type: GrantFiled: January 3, 2005Date of Patent: June 8, 2010Assignee: Daiso Co., Ltd.Inventors: Shin-ichiro Nakamura, Yasumi Shimizu, Tohru Matsutomi, Thomas Daniel
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INSOLUBLE ANODE FOR METAL WIRE ELECTROPLATING AND METHOD OF ELECTROPLATING METAL WIRE USING THE SAME
Publication number: 20100025254Abstract: To provide an insoluble anode for metal wire electroplating capable of simultaneously electroplating a plurality of metal wires and uniformalizing the electroplating amounts of the metal wires stably for a long time. For realizing these, a plurality of insoluble electrode plates 20 are disposed in a parallel alignment to be placed sandwiching a plurality of wire travel paths from both sides. A plurality of the insoluble electrode plates 20 are tightened and fixed by through-bolts 40 at a plurality of places along the travel path direction. An conductive spacer 30 is interposed in each gap between the insoluble electrode plates 20 at a tightening part by the through-bolt 40 and also a conductive member 50 is provided so as to contact all the electrode plates 20 and the conductive spacers 30.Type: ApplicationFiled: June 29, 2007Publication date: February 4, 2010Applicants: DAISO CO., LTD., BRIDGESTONE CORPORATIONInventors: Kenji Kawaguchi, Ryuichi Otogawa, Kenichi Murakami, Yuji Nakamura