Abstract: A method for producing dicarboxylic acid. The method includes: subjecting a raw material system including a cyclic olefin and a lower monocarboxylic acid to an addition reaction in the presence of an addition reaction catalyst to generate an intermediate product system including cyclic carboxylic acid ester; and subjecting the intermediate product system including cyclic carboxylic acid ester to a ring-opening and oxidation reaction in the presence of an oxidant and an oxidation catalyst to generate a corresponding dicarboxylic acid product. The addition reaction in the dicarboxylic acid synthesis route achieves a high single-pass conversion rate, and the selectivity of the corresponding cyclic carboxylic acid ester is high. The addition-oxidation synthesis route achieves faster reaction rates for both the addition reaction and oxidation reaction, and high yield of corresponding dicarboxylic acid product.

Abstract: A system (5) for regeneration of acidic gas solvent comprises a regeneration cell having a solvent chamber (100) arranged to receive a solvent flow and an internal chamber (92) arranged to receive a steam flow (110). The regeneration cell also includes a gas permeable membrane (95) separating the solvent chamber (100) and internal chamber (92). The regeneration cell is arranged to vent acidic gas stripped from the solvent by the steam. A method for regenerating acidic gas solvent is also provided.

Abstract: Disclosed are a Cu-SAPO molecular sieve with coexisting crystal phases of CHA and GME, a synthesis process therefor and the use thereof in a denitration reaction. A XRD diffraction pattern of the Cu-SAPO molecular sieve shows the characteristic of broad peaks and narrow peaks coexisting. An inorganic framework has the following chemical composition: wCu—(SixAlyPz)O2, wherein x, y and z respectively represent the molar fractions of Si, Al and P; the molar fraction ranges thereof are respectively x=0.01˜0.28, y=0.35˜0.55 and z=0.28˜0.50, with x+y+z=1; w is the molar number of Cu per mole of (SixAlyPz)O2; and w=0.001˜0.124. The synthesized molecular sieve can be used as a catalyst for a selective reduction of NOx.

Abstract: A turbulent fluidized bed reactor, device and method for preparing para-xylene and co-producing light olefins from methanol and/or dimethyl ether and benzene, resolving or improving the competition problem between an MTO reaction and an alkylation reaction during the process of producing para-xylene and co-producing light olefins from methanol and/or dimethyl ether and benzene, and achieving a synergistic effect between the MTO reaction and the alkylation reaction. By controlling the mass transfer and reaction, competition between the MTO reaction and the alkylation reaction is coordinated and optimized to facilitate a synergistic effect of the two reactions, so that the conversion rate of benzene, the yield of para-xylene, and the selectivity of light olefins are increased.

Abstract: The present invention provides a method for preparing acrylic acid and methyl acrylate. The method comprises passing the feed gas containing dimethoxymethane and carbon monoxide through a solid acid catalyst to generate acrylic acid and methyl acrylate with a high conversion rate and selectivity at a reaction temperature in a range from 180 to 400 and a reaction pressure in a range from 0.1 MPa to 15.0 MPa, the mass space velocity of dimethoxymethane in the feed gas is in a range from 0.05 h?1 to 10.0 h?1, and the volume percentage of dimethoxymethane in the feed gas is in a range from 0.1% to 95%.

Abstract: Disclosed are a fluidized bed gas distributor and a fluidized bed reactor, the fluidized bed reactor comprising a first distributor (1) and a second distributor (2), wherein the first distributor (1) is located at the bottom of a fluidized bed, and second distributor (2) is located downstream of a gas from the first distributor (1). Also disclosed is a method for producing a para-xylene and co-producing light olefins, the method comprising the following steps: material stream A enters a reaction zone (3) of a fluidized bed reactor from a first gas distributor (1); material stream B enters the reaction zone (3) of the fluidized bed reactor from a second gas distributor (2); and the reactants are brought into contact with a catalyst in the reaction zone (3) to generate a gas phase stream comprising para-xylene and light olefins.

Abstract: A method for synthesizing a mordenite (MOR) molecular sieve with a modulatable location and distribution of B acid sites, and a product thereof and the use thereof. Provided is a method for synthesizing a mordenite MOR molecular sieve with acid sites located at an 8-membered ring “side pocket” in communication with a 12-membered ring pore channel in the presence or absence of an inorganic base. The method includes introducing an additional reagent and an optional fluorinating reagent which have different structures and charge densities into a synthetic gel, and the B acid sites of the obtained MOR zeolite are located at an 8-membered ring “side pocket” in communication with a 12-membered ring pore channel A catalyst product obtained exhibits an excellent performance in terms of adsorption and catalysis. The synthesis method has broad industrial application, particularly being applied to catalysts for the carbonylation reaction of dimethyl ether.

Abstract: Direct conversion of syngas to light olefins is carried out in a fixed bed or a moving bed reactor with a composite catalyst A+B. The active ingredient of catalyst A is active metal oxide; and catalyst B is one or more than one of zeolite of CHA and AEI structures or metal modified CHA and/or AEI zeolite. A spacing between geometric centers of the active metal oxide of the catalyst A and the particle of the catalyst B is 5 ?m-40 mm. A spacing between axes of the particles is preferably 100 ?m-5 mm, and more preferably 200 ?m-4 mm. A weight ratio of the active ingredients in the catalyst A and the catalyst B is within a range of 0.1-20 times, and preferably 0.3-5.

Abstract: Disclosed is a method for preparing aromatic hydrocarbons, particularly relates to the preparation of the aromatic hydrocarbons by passing methanol and carbon monoxide through a reactor loaded with an acidic ZSM-5 molecular sieve catalyst containing no metal additive under reaction conditions. Compared with the prior art, the method provided by the present invention can improve and stabilize the selectivity to aromatic hydrocarbons, particularly BTX, by adding carbon monoxide in methanol aromatization, and also prolongs the single-pass life of the catalyst. The performance of an inactivated catalyst is not significantly degraded after repeated regenerations. Furthermore, the catalyst preparation process omits the step of adding a metal additive, so that not only the process is simplified, but also costs are greatly reduced, and environmental protection is facilitated.

Abstract: Provided is a method for preparing a lower unsaturated fatty acid ester, which comprises carrying out an aldol condensation reaction between dimethoxymethane (DMM) and a lower acid or ester with a molecular formula of R1—CH2—COO—R2 on an acidic molecular sieve catalyst in an inert atmosphere to obtain a lower unsaturated fatty acid or ester(CH2?C(R1)—COO—R2), wherein R1 and R2 are groups each independently selected from the group consisting of H— and C1-C4 saturated alkyl group.

Abstract: The present application discloses a molecular sieve-based catalyst modification apparatus. The apparatus comprises a feed unit 1, a modification unit 2 and a cooling unit 3 connected in sequence; the feed unit comprises a catalyst feed unit 11 and a modifier feed unit 12, a catalyst and a modifier are introduced into the modification unit 2 respectively by the catalyst feed unit and the modifier feed unit and are discharged from the modification unit after sufficient reaction in modification unit, and then enter the cooling unit 3 for cooling. The present application further discloses a use method for the molecular sieve-based catalyst modification apparatus. The use method comprises: introducing a catalyst and a modifier into the modification unit 2 respectively through the feed unit 1; wherein the catalyst is modified by the modifier in the modification unit 2, and then discharged to the cooling unit 3 to cool until the temperature is lower than 50° C.

Abstract: A catalytic flameless combustion apparatus has a fuel inlet, a combustion-supporting gas inlet, a gas premixer, a combustion plate, an igniter, a gas deflector, a flameless combustion cavity, a catalyst filled in the flameless combustion cavity, a gas collection chamber and an exhaust port. The method for starting the catalytic flameless combustion apparatus includes initially combusting and heating the flameless combustion cavity and the catalyst filled therein with low power flame; and then increasing flow velocity and switching to high power flame for conducting catalytic flameless combustion. The catalytic flameless combustion apparatus can be used for various non-solid fuel combustion and heat extraction processes.

Abstract: A preparation method for a metal-modified SAPO molecular sieve is disclosed, characterized in adding a raw powder of the SAPO molecular sieve to a solution containing metal ions for performing ion exchange, and then washing and drying the obtained solid after ion exchange, so as to obtain the metal-modified SAPO molecular sieve. The metal-modified SAPO molecular sieve prepared has a relatively high degree of crystallinity, and the metal elements occupy the ionic positions in the channels and/or cages of the SAPO molecular sieve, and the metal-modified SAPO molecular sieve shows excellent catalytic performance in the catalytic reaction.

Abstract: A catalyst for preparing chloroethylene by cracking 1,2-dichloroethane and a preparation and regeneration method thereof are disclosed in the present application. A catalyst for preparing chloroethylene by cracking 1,2-dichloroethane includes a carrier and a nitrogen-containing carbon as an active component of the catalyst with the nitrogen-containing carbon being loaded on the carrier. The method for preparing the catalyst includes: supporting an organic matter on an inorganic porous carrier and then performing a carbonization-nitridation process by pyrolysis in an atmosphere containing the nitrogen-containing compound. The method for regenerating the catalyst includes: calcinating the catalyst with deactivated carbon deposit in an oxidizing atmosphere to remove all the carbonaceous portions on the surface, and repeating the above preparation process of the catalyst.

Abstract: A method for synthesizing a nano SAPO-34 molecular sieve, and an SAPO-34 molecular sieve catalyst and application thereof. A nano SAPO-34 molecular sieve is synthesized by adding a microporous templating agent and a templating agent having a functionalized organic silane to hydrothermal synthesis. The nano SAPO-34 molecular sieve is calcined to obtain a nano SAPO-34 molecular sieve catalyst. The catalyst can be used in a reaction for preparing low-carbon olefin from an oxygen-containing compound. The nano SAPO-34 molecular sieve obtained by this method has a pure CHA crystal phase. Moreover, the nano SAPO-34 molecular sieve catalyst obtained by this method has good catalytic performance in a MTO reaction, the service life of the catalyst is significantly prolonged, and the selectivity of the low-carbon olefin is improved.

Abstract: A method for preparing aromatics from syngas, which includes a) contacting a raw material stream containing syngas with a catalyst in a reaction zone under reaction conditions sufficient to convert at least part of the raw material to obtain a reaction effluent; b) separating the reaction effluent to obtain at least a recycle stream containing gas-phase hydrocarbons having 1 to 4 carbon atoms and unconverted syngas and a liquid stream containing hydrocarbons having 5 or more carbon atoms; c) returning the recycle stream to the reaction zone; and d) separating aromatic products from the liquid stream, wherein the catalyst includes at least one of an inert carrier-confined highly dispersed metal oxide material, an acidic molecular sieve, and, optionally, graphite powder and a dispersant.

Abstract: The present application discloses a method for partially regenerating a methanol to olefin catalyst. The method comprises: placing a deactivated methanol to olefin catalyst in a regenerator and carrying out a a partial regeneration reaction to obtain a regenerated catalyst, at least a part of the regenerated catalyst having a carbon deposition of more than 1%. The present application discloses a methanol to olefin process which is carried out in a fluidized bed using a methanol to olefin catalyst, characterized in that at least a part of the regenerated catalyst has a carbon deposition of more than 1%.

Abstract: A method for directly preparing p-xylene from synthetic gas and aromatic hydrocarbon. The method includes contacting the feedstock containing synthetic gas and aromatic hydrocarbon excluding p-xylene with the catalyst in the reaction zone under reaction conditions sufficient to convert at least part of the feedstock to obtain a reaction effluent containing p-xylene; and separating p-xylene from the reaction effluent, where the catalyst includes a highly dispersed metal oxide material confined by an inert carrier, an acidic molecular sieve, and optionally at least one of graphite powder and dispersant, where in the highly dispersed metal oxide material confined by the inert carrier, the inert carrier is at least one of silicon oxide and alumina, and the content of the metal oxide in terms of metal is less than or equal to 10% by mass calculated based on the weight of the highly dispersed metal oxide material confined by the inert carrier.

Abstract: A method for preparing aromatics from syngas, which includes a) contacting a raw material stream containing syngas with a catalyst in a reaction zone under reaction conditions sufficient to convert at least part of the raw material to obtain a reaction effluent; b) separating the reaction effluent to obtain at least a recycle stream containing gas-phase hydrocarbons having 1 to 4 carbon atoms and unconverted syngas and a liquid stream containing hydrocarbons having 5 or more carbon atoms; c) returning the recycle stream to the reaction zone; and d) separating aromatic products from the liquid stream, wherein the catalyst includes at least one of an inert carrier-confined highly dispersed metal oxide material, an acidic molecular sieve, and, optionally, graphite powder and a dispersant.

Abstract: A method for directly producing methyl acetate and/or acetic acid from syngas, carried out in at least two reaction zones, including: feeding a raw material containing syngas into a first reaction zone to contact and react with a metal catalyst; allowing an obtained effluent to enter a second reaction zone directly or after the addition of carbon monoxide so as to contact and react with a solid acid catalyst; separating the obtained effluent to obtain product of acetate and/or acetic acid, and optionally returning a residual part to enter the first reaction zone and/or the second reaction zone to recycle the reaction. This provides a novel method for directly converting syngas into methyl acetate and/or acetic acid. Further, the product selectivity of the product of methyl acetate or acetic acid is greater than 93%, and the quantity of methyl acetate and acetic acid may be adjusted according to processing.