Patents Assigned to Didier-Werke AG
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Patent number: 4762689Abstract: A mounting frame for a block-type parallel mounting of catalyst plates is provided. The block mounting has frame members separated by a distance substantially corresponding to the width of the catalyst plates to be mounted. The frame members are provided with a series of guide slots open on top for admission of the catalyst plates. On the bottom edges of the frame members, there are provided base supports for the bottom edges of the catalyst plates. The frame members themselves also form lateral supports for the catalyst plates to prevent movement thereof when mounted in the module. The mounting modules, once loaded with the planar elements, can be combined into a larger frame in a horizontal mode, or they can be vertically stacked, such as in the flue of a combustion furnace itself. The plates are typically pre-coated with a material that is catalytic to further the conversion of the gaseous compounds passing thereby.Type: GrantFiled: November 12, 1986Date of Patent: August 9, 1988Assignee: Didier-Werke AGInventors: Alfred Frey, Daniel Grimm, Hartmut Kainer
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Patent number: 4760039Abstract: Refractory compositions which can be gun-applied, or refractory, unfired shapes containing sintered magnesite and/or sintered dolomite as the principal refractory component, 0.5 to 5% by weight of bentonite, 1 to 5% by weight of aluminum sulfate and 0.5 to 5% by weight of an alkaline earth compound, characterized by the fact that they contain magnesium hydroxide and/or caustic-calcined MgO as the alkaline earth compound. The compositions and shapes of the invention have the advantage that they do not exhibit binder migration, and no damping-reduction cracks or chipping occurs therein.Type: GrantFiled: July 13, 1987Date of Patent: July 26, 1988Assignee: Didier-Werke AGInventor: Hartmut Hlawatschek
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Patent number: 4760047Abstract: A quadrangular catalyst block having a plurality of through-going slots separated by intermediate walls, each of the slots having first and second characterizing dimensions, with one of the characterizing dimensions being significantly greater than the other.Type: GrantFiled: April 9, 1987Date of Patent: July 26, 1988Assignee: Didier-Werke AGInventors: Peter Jeschke, Hartmut Kainer, Blagoje Levkov
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Patent number: 4758545Abstract: A process for the manufacture of catalyst moldings from granular catalyst material, preferably iron ore, chromium ore or a similar ore, with the use of a binder is disclosed. The granular catalyst material is thermally pre-treated in a temperature range of approximately 250.degree. to 1000.degree. C., before it is mixed with dilute and/or concentrated sulfuric acid functioning as the binder.Type: GrantFiled: December 5, 1986Date of Patent: July 19, 1988Assignee: Didier-Werke AGInventors: Daniel Grimm, Hartmut Kainer, Blagoje Levkov
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Patent number: 4758410Abstract: The invention relates to a cartridge to hold catalyst plates, which plates are spaced apart, thereby leaving open slot-shaped channels for the passage of fluids to be cleaned catalytically by the plates. The cartridge is shaped in a parallelepiped or an essentially cubic form. There are recesses which form mountings for the insertion of the catalyst plates on at least two sides facing one another. The recesses are groove-like, into which the edges of the catalyst plates fit. For the simplest possible and most solid fastening of the catalyst plates in the cartridge, the mountings comprise a metal wire mesh as the static element, which is coated with a coating containing vermiculite or a similar material which expands when heated. Zeolite may also be used as the coating material.Type: GrantFiled: September 9, 1986Date of Patent: July 19, 1988Assignee: Didier-Werke AGInventors: Daniel Grimm, Klaus Heil, Hartmut Kainer, Hermann Stein
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Patent number: 4751212Abstract: The invention relates to a process for the manufacture of a catalyst for the reduction of nitrogen oxides in exhaust gases. The catalyst contains a metal oxide. The catalyst is preferably used for catalytic reduction with ammonia. The process comprises screening a natural goethite iron ore to the required grain size and then treating the ore with sulfuric acid. Subsequently, the goethite iron ore is heated to a temperature which approximately equals the temperature at which it will be used in the catalytic reaction.Type: GrantFiled: December 5, 1986Date of Patent: June 14, 1988Assignees: Didier Engineering GmbH, Didier-Werke AGInventors: Claus Flockenhaus, Erich Hackler, Karl H. Laue, Klaus Merkel, Arnold Max, Werner Stender, Johann Jansen, Hartmut Kainer, Daniel Grimm, Blagoje Levkov
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Patent number: 4746483Abstract: In a process for the manufacture of catalyst moldings a natural raw material containing Fe.sub.2 O.sub.3, Cr.sub.2 O.sub.3 or another such catalyst component such as TiO.sub.2, NbO.sub.2, WO.sub.3, V.sub.2 O.sub.5 or MoO.sub.3 is screened to a grain size equal to or less than approximately 0.25 mm. This screened base mixture is thoroughly blended, and then preferably a concentrated sulphuric acid is added. This mixture of material is then pressed into a molding in a hydraulic press with a pressure of approximately 500 bar to produce the molding.Type: GrantFiled: September 9, 1986Date of Patent: May 24, 1988Assignees: Didier Engineering GmbH, Didier Werke AGInventors: Claus Flockenhaus, Karl-Heinz Laue, Klaus Merkel, Erich Hackler, Johann Jansen, Arnold Max, Werner Stender, Reinhard Kruse, Hartmut Kainer, Daniel Grimm, Blagoje Levkov
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Patent number: 4742036Abstract: The invention relates to catalyst plates for reducing nitrogen oxide in exhaust gases. These plates are molded of granular Fe.sub.2 O.sub.3 catalyst material and a binder. To achieve high activity and strength in the plates, these are molded of a combination of a first mixture comprised of Fe.sub.2 O.sub.3 catalyst material and phosphoric acid as binder, and a second, separately-produced mixture comprised of Fe.sub.2 O.sub.3 catalyst material and sulphuric acid as binder. The plates can also be a molding having layers, which layers have alternate layers of the first and second mixtures.Type: GrantFiled: September 5, 1986Date of Patent: May 3, 1988Assignee: Didier-Werke AGInventors: Claus Flockenhaus, Daniel Grimm, Hartmut Kainer, Karl H. Laue
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Patent number: 4737326Abstract: Process for the production of refractory shapes of ceramic fiber-containing mateial, wherein a slurry of refractory fibers and particulate refractory materials is produced in water, the particulate refractory materials are flocculated on the fibers by use of a flocculant, and the desired shape is produced by dewatering the slurry in a suitable mold that enables the water to be removed, and the shape is dried. At least 90% of the fibers have a maximum length of not more than 500 .mu.m; flocculant is added as an aqueous solution to the dispersion of the fibers and particulate refractory material; and pressure is applied to the shape being formed during the dewatering of the slurry to form the desired shape in order to compress the shape.Type: GrantFiled: November 26, 1985Date of Patent: April 12, 1988Assignee: Didier-Werke AGInventors: Ludwig Wirth, Ingo Elstner, Ulrich Hintzen, Rudolf Ganz, Miroslav Rausch, Robert Burger
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Patent number: 4735756Abstract: Method for the production of light-weight molded articles wherein, in a first embodiment, a dispersion of ceramic fibers is flocculated with a cationic flocculating agent, a dispersion of finely divided refractory material and inorganic bonding agent is flocculated with an anionic flocculating agent, the flocculated dispersions are mixed together, and following settling of the mixture and optional removal of excess liquid, the mixture is filled into molds, converted by dewatering into molded articles, and dried. According to a second embodiment, a dispersion of ceramic fibers is flocculated with a cationic flocculating agent, finely divided refractory material and inorganic bonding agent which may be stirred in with water are added to this flocculated dispersion, an aqueous solution of an anionic flocculating agent is mixed into this mixture, and following settling of the mixture and optional removal of excess liquid, the mixture is filled into molds, converted by dewatering into molded articles, and dried.Type: GrantFiled: September 19, 1985Date of Patent: April 5, 1988Assignee: Didier-Werke AGInventor: Miroslav Rausch
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Patent number: 4730754Abstract: A refractory immersion tube has an inner passage through which passes molten metal from a metallurgical vessel into a mold and includes an inlet opening for receiving the molten metal and at least one outlet opening extending from the passage for discharging the molten metal into the mold. A refractory annular member is positioned within the passage to restrict the cross-sectional area thereof, thereby to prevent the flow of the molten metal from the outlet opening from being turbulent and for ensuring that such flow is laminar.Type: GrantFiled: March 2, 1987Date of Patent: March 15, 1988Assignee: Didier-Werke AGInventors: Heinz Buhr, Jacques Brihay, Manfred Winkelmann
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Patent number: 4730812Abstract: An apparatus for shielding from the surrounding air a stream of molten metal being discharged from a discharge sleeve of a metallurgical vessel includes a tuyere-like adapter device mounted about the discharge sleeve. The tuyere-like adapter device is supplied with a pressurized inert gas and is constructed to produce a hollow jet of inert gas having a maximum length of approximately 20 cm as a gaseous shield surrounding a molten metal stream discharged from the discharge sleeve.Type: GrantFiled: October 29, 1984Date of Patent: March 15, 1988Assignee: Didier-Werke AGInventor: Hans Mielke
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Patent number: 4729974Abstract: The invention relates to a refractory brick on the basis of sintered magnesium oxide and MgO.Al.sub.2 O.sub.3 spinel and possibly up to three percent by weight of customary impurities. Such customary impurities are primarily CaO, Fe.sub.2 O.sub.3 and SiO.sub.2, which are included as impurities in the MgO used in the production of the spinel. The refractory brick according to the invention is characterized by the fact that it has a refractoriness under load of more than 1740.degree. C. and a compression settling of -3 to -5% at 1400.degree. C. after 24 hours under a load of 0.2N/mm.sup.2. The refractory brick according to the invention exhibits the advantage that as a result of the combination of its characteristics of gas permeability, pore volume, refractoriness under load and compression settling, it is particularly well suited for use in rotary hearth furnaces for the cement industry.Type: GrantFiled: December 13, 1985Date of Patent: March 8, 1988Assignee: Didier-Werke AGInventors: Morteza Nazirizadeh, Herbert Naefe
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Patent number: 4728128Abstract: A connection assembly for joining two parts having confronting ends with a joint therebetween, particularly ceramic pipes, includes a dimensionally stable coupling member surrounding the joint and at least one of the two confronting ends of the two parts to be joined. The coupling member is dimensioned to define a space with the at least one part end. This space is filled with a ceramic fiber mat material containing a swelling agent capable of volume expansion when subjected to a temperature above a given minimum temperature. As a result, upon being subjected to an operating temperature above such given temperature, the swelling agent swells the ceramic fiber mat material, such that the mat material is compressed between the coupling member and the at least one part end surrounded thereby, thereby connecting the two parts.Type: GrantFiled: October 15, 1986Date of Patent: March 1, 1988Assignee: Didier-Werke AGInventors: Alfred Frey, Robert Burger
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Patent number: 4728013Abstract: A refractory plate assembly includes a refractory plate having therethrough at least one discharge opening and a sheath tightly fitted around the periphery of the plate. The plate is formed of separate plate portions separated along planar surfaces extending outwardly from the discharge opening at positions where cracks would be formed during use of the plate if the plate were of unitary construction. The planar surfaces are separated by compressible refractory packing material, thereby forming expansion joints. The sheath compresses the packing material of the expansion joints.Type: GrantFiled: August 29, 1985Date of Patent: March 1, 1988Assignee: Didier-Werke AGInventors: Manfred Winkelmann, Udo Muschner
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Patent number: 4721287Abstract: The invention relates to a sleeve for blowing solid materials into molten metal baths, specifically molten steel baths, through the wall of a ladle containing the molten metal bath. To improve the characteristics of such a sleeve, the invention proposes that a forward sleeve section, facing the molten metal bath, be made of an insulating material with lower thermal conductivity than that of the material of the middle and rear sleeve section.Type: GrantFiled: February 19, 1986Date of Patent: January 26, 1988Assignee: Didier-Werke AGInventor: Manfred Winkelmann
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Patent number: 4721236Abstract: Refractory parts for valve closures include members which by mutual sliding or rotary action, interrupt the flow of molten metal from a metallurgical vessel. Closed reservoirs filled with an impregnation agent, for example tar, pitch, methane gas, are provided embedded in the refractory parts and disposed adjacent to refractory wearing surfaces which are susceptible to undergo depletion and wear. The impregnation agent, on being heated by molten metal, slowly releases hydrocarbons which percolate through the refractory pores to the refractory wearing surfaces to prevent premature wear to the refractory surface and to provide lubrication for the flow of molten material in contact with the refractory wearing surfaces. The impregnation agent can be replenished in the form of replaceable porous cartridges which can be inserted into the reservoirs.Type: GrantFiled: December 12, 1986Date of Patent: January 26, 1988Assignee: Didier-Werke AGInventor: Udo Muschner
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Patent number: 4721699Abstract: A structure made from catalyst for use in the separation of nitrogen oxides from combustion exhaust gases which contain dust. The catalytic structure has plates with spaces therebetween to carry a flow of the exhaust gas therethrough. The catalyst is constructed of individual ceramic plates. The abrasion or wear resistance of the plates is chosen such that the dust in the exhaust gases flowing through the spaces abrades the plate surface at a rate which is at least equivalent to the deactivation of the catalyst surface by action of the nitrogen oxides, which constantly provides a fresh catalyst surface for reaction with the nitrogen oxides. The movement of the exhaust gas through the catalytic structure carries the dust and abraded material along with it and out of the structure.Type: GrantFiled: August 27, 1986Date of Patent: January 26, 1988Assignees: Didier-Werke AG, Didier Engineering GmbHInventors: Dietrich Wagener, Karl H. Laue, Egmar Wunderlich, Theo Sander, Claus Flockenhaus, Erich Hackler, Blagoje Levkov, Daniel Grimm, Hartmut Kainer, Hermann Stein
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Patent number: 4720376Abstract: A process for the removal of nitrogen oxides and soot from exhaust gases from machines and combustion installations burning heavy fuel oil by means of free-passage catalysts at increased temperatures with the addition of ammonia into the exhaust gas stream ahead of the catalysts. To make the process mre effective, the soot adhering to the catalyst surfaces is removed by burning it off and/or by friction resulting from the admixture of sand, ash or similar abrasive mixtures into the exhaust gas stream ahead of the catalysts.Type: GrantFiled: May 6, 1986Date of Patent: January 19, 1988Assignees: Didier Engineering GmbH, Didier-Werke AGInventors: Karl H. Laue, Claus Flockenhaus, Erich Hackler, Blagoje Levkov, Daniel Grimm, Hartmut Kainer, Hermann Stein, Hans-Eugen Buhler
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Patent number: 4717128Abstract: A refractory plate assembly includes a refractory base structure having therein a recess and a refractory wear and erosion resistant insert positioned within the recess. A frame surrounds the outer periphery of the base structure. The insert and the base structure together define a planar sliding surface. The base structure is formed of at least two components divided along at least one joint extending transverse to the planar sliding surface, each such component defining a respective portion of the recess and surrounding a respective portion of the circumference insert. The insert is elastically clamped within the base structure and may be removed from the base structure for replacement.Type: GrantFiled: October 15, 1986Date of Patent: January 5, 1988Assignee: Didier-Werke AGInventors: Raimund Bruckner, Jurgen Plath, Ernst Luhrsen