Abstract: The invention relates to an improved process for controlling the amount of crosslinking in polyolefin based articles such as fibers or films. The invention relates to mixing silane grafted material together with ungrafted material prior to crosslinking. The article can then be formed and cured, optionally with a curing catalyst which can preferably be applied to the surface of a shaped article. The amount of crosslinking will be controlled in part by the level of silane grafting on the grafted silane material as well as the amount of the grafted material in the blend.

Abstract: A process for producing a polyurethane product comprises steps of (a) supplying at least one polyisocyanate (b) supplying at least one polyol composition comprising at least about 5 weight percent based on total weight of polyols of at least one natural oil based polyol (b1) having a hydroxyl number of at most about 300 and a viscosity below about 10000 mPa·os; and (c) exposing the polyisocyanate and the polyol composition to reaction conditions such that urethane bonds are formed, wherein reaction conditions include the presence of at least one bismuth catalyst. Use of bismuth catalysts is particularly applicable to preparation of open celled, flexible polyurethane foams using polyols made from renewable resources, optionally with other polyols. The invention includes foams made by the process, including viscoelastic foams, preferably having a velvet feel.

Abstract: A mixing system is disclosed comprising at least one extensional flow mixer comprising: a generally open and hollow body having a contoured outer surface and having: a single entrance port and a single exit port; a means for compressing a bulk stream flowing through the generally open and hollow body in a direction of flow and at least one injected additive stream introduced at the single entrance port in the direction of flow; and a means for broadening the bulk stream and the at least one injected additive stream such that an interfacial area between the bulk stream and the at least one injected additive stream is increased as the bulk stream and the at least one injected additive stream flow through the generally open and hollow body in the direction of flow to promote mixing of the bulk stream and the at least one injected additive stream, a flow conductor having an axis and having a generally open and hollow flow mixer body secured therein; and a primary additive stream injector positioned at the entra

Abstract: The present invention is premised upon a connector device and method that can more easily electrically connect a plurality of PV devices or photovoltaic system components and/or locate these devices/components upon a building structure. It also may optionally provide some additional sub-components (e.g. at least one bypass diode and/or an indicator means) and may enhance the serviceability of the device.

Abstract: The present invention provides one-step processes for the production of chlorinated and/or fluorinated propenes. The processes provide good product yield with low, e.g., less than about 20%, or even less than 10%, concentrations of residues/by-products. Advantageously, the processes may be conducted at low temperatures relative to conventional processes, so that energy savings are provided, and/or at higher pressures so that high throughputs may also be realized. The use of catalysts may provide enhancements to conversion rates and selectivity over those seen in conventional processes, as may adjustments to the molar ratio of the reactants.

Abstract: A method of adhering a first component to a second component, comprising the steps of: adhering the two components together using a composition comprising a polyurethane and from 20 to 80 weight percent of a particulate metal, metal salt or metal alloy filler, wherein polyurethane is the reaction product of: a) a first polyol, the first polyol having a molecular weight of less than 1000; b) a second polyol, the second polyol having a molecular weight of from 1500 to 10000; c) at least one polyisocyanate; d) at least one curing agent, and wherein the particulate metal, metal salt or metal alloy filler has a thermal conductivity of at least 150 watts/m·° K; and curing the composition.

Abstract: The instant invention provides a method for improving the bubble stability of a polyethylene composition suitable for blown film extrusion process. The method for improving the bubble stability of a polyethylene composition suitable for blown film extrusion process comprises the steps of: (1) providing a polyethylene composition having a density in the range of 0.900 g/cm3 to 0.970 g/cm3 and an relaxation spectrum index (RSI) value in the range of 10 to 100; (2) oxygen tailoring said polyethylene composition; (3) thereby forming an oxygen tailored polyethylene composition, wherein the RSI value of the said oxygen tailored polyethylene composition increases from 10% to 300% of its initial value; (4) thereby improving the bubble stability of said polyethylene composition.

Abstract: This invention relates to bituminous compositions comprising an interpolymer and a bituminous material and methods of making and using same. The interpolymer may comprise ethylene, at least one alpha-olefin, and, optionally, at least one diene and the interpolymer is derived from polymer particles having a surface coating comprising a partitioning agent. Methods of making and using the bituminous compositions are also described.

Abstract: The present invention relates to particular ethylene-based polymer compositions suitable for use in binder fiber applications. The materials are characterized in having a peak recrystallization temperature in the range of from 85° C. to 110 C, and a Comonomer Distribution Constant (“CDC”) of 55 or greater. The materials are also characterized by having a tan delta value at 0.1 rad/sec from about 15 to 50, and a complex viscosity at 0.1 rad/second of 1400 Pa·sec or less.

Abstract: The present invention is a method for increasing the melt strength of a polyethylene resin comprising reacting the polyethylene resin with an alkoxy amine derivative corresponding to the formula: (R1)(R2)N—O—R3 where R1 and R2 are each independently of one another, hydrogen, C4-C42 alkyl or C4-C42 aryl or substituted hydrocarbon groups comprising O and/or N, and where R1 and R2 may form a ring structure together; and where R3 is hydrogen, a hyrdrocarbon or a substituted hydrocarbon group comprising O and/or N. Preferred groups for R3 include —C1-C19alkyl; —C6-C10aryl; —C2-C19akenyl; —O—C1-C19alkyl; —O—C6-C10aryl; —NH—C1-C19alkyl; —NH—C6-C10aryl; —N—(C1-C19alkyl)2. R3 most preferably contains an acyl group.

Abstract: Thermosetting powder coating compositions, wherein the compositions comprise an epoxy-terminated oxazolidinone-isocyanurate polymer and are capable of forming a foam when applied to a substrate in a powder coating process, as well as methods of making and uses of such compositions.

Abstract: Disclosed is an apparatus for synthesizing nitroalkanes by reaction of a hydrocarbon feedstock with aqueous nitric acid. The apparatus may be designed such that it can synthesize more than one nitroalkane using the same equipment.

Abstract: Embodiments of the present disclosure include a process for the production of chlorine gas. For the various embodiments, the process includes compressing a gas mixture of vaporized liquid chlorine and a feed gas containing chlorine to form a compressed gas. Chlorine in the compressed gas is condensed into liquid chlorine. A first portion of the liquid chlorine is vaporized to provide a heat of condensation to condense chlorine from the compressed gas into liquid chlorine. A second portion of the liquid chlorine is vaporized to provide both the vaporized liquid chlorine for the gas mixture and a heat of condensation to cool a tail gas from the process. A chlorine gas product from the vaporized first portion of the liquid chlorine is also produced.

Abstract: The present disclosure provides a Ziegler-Natta catalyst composition comprising a procatalyst, a cocatalyst and a mixed external electron donor comprising a first selectivity control agent, a second selectivity control agent and an activity limiting agent. A polymerization process incorporating the present catalyst composition produces a high-stiffness propylene-based polymer with a melt flow rate greater than about 50 g/10 min. The polymerization process occurs in a single reactor, utilizing standard hydrogen concentration with no visbreaking.

Abstract: A method for multi-dimensional chromatography of a polyolefin polymer, comprising introducing a solution of the polyolefin polymer into a liquid flowing through a first liquid chromatography stationary phase or a field flow fractionation device and subsequently flowing the solution through a second liquid chromatography stationary phase, the second liquid chromatography stationary phase comprising graphitic carbon, the polyolefin polymer emerging from the liquid chromatography stationary phase with a retention factor greater than zero.

Abstract: The present invention relates to an improvement for gas phase olefin polymerization process under two or more different flow regimes. The process involves adding a mixed electron donor system to a reactor having two or more different flow regimes, wherein the mixed electron donor system comprises at least one selectivity control agent and at least one activity limiting agent. The invention is particularly well suited for reactor systems which include a regime characterized by having a low-velocity or high-solid holdup, which have been reported to have operational problems such as particle agglomeration and formation of polymer “chunks”.

Abstract: Viscoelastic polyurethane foam is prepared by using certain additives in the foam formulation. The additives include 1) alkali metal or transition metal salts of carboxylic acids; 2) 1,3,5-tris alkyl- or 1,3,5-tris (N,N-dialkyl amino alkyl)-hexahydro-s-triazine compounds; and 3) C1-12 carboxylate salts of quaternary ammonium compounds. The additives significantly improve processing and in particular permit the use of higher isocyanate indices, which helps to improve foam physical properties.

Abstract: Compounds or polymers that contain carbon-carbon unsaturation are brominated using a quaternary phosphonium tribromide as the brominating agent. The bromination process proceeds easily under mild conditions. The process can be highly selective. When the substrate is a butadiene polymer or copolymer, the brominated product tends to have excellent thermal stability.

Abstract: In an improved process for telomerizing butadiene, contact butadiene and an organic hydroxy compound represented by formula ROH (I), wherein R is a substituted or unsubstituted C1-C20-hydrocarbyl and the organic hydroxy compound is not glycerol, in a reaction fluid in the presence of a palladium catalyst and a phosphine ligand represented by formula PAr3 (II), wherein each Ar is independently a substituted or unsubstituted aryl having a hydrogen atom on at least one ortho position, at least two Ar groups are ortho-hydrocarbyloxyl substituted aryls. The phosphine ligand has a total of two (2), three (3), four (4), five (5), or six (6) substituted or unsubstituted C1-C20-hydrocarbyloxyls, and optionally, any two adjacent substituents on an Ar group can be bonded to form a 5- to 7-membered ring.

Abstract: A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins, said catalyst component containing magnesium, titanium, and halogen, and further containing an internal electron donor having a structure: [R1—O—C(O)—O—]xR2 wherein R1 is independently at each occurrence, an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; x is 2-4; and R2 is an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms, provided that there are from 3 to 4 atoms in the shortest chain connecting a first R1—O—C(O)—O— group and a second R1—O—C(O)—O— group.