Abstract: A composition contains the following components: (a) 15 to 49.8 volume-percent of a first polysiloxane that is has a viscosity in a range of 50 centiStokes to 550 Stokes as determined according to ASTM D4283-98; (b) 0.2 to 5 volume-percent of an organoclay; (c) 50-74 volume-percent roundish or crushed thermally conductive fillers including: (i) 5 to 15 volume-percent small thermally conductive fillers having a median particle size in a range of 0.1 to 1.0 micrometers; (ii) 10 to 25 volume-percent medium thermally conductive fillers having a median particle size in a range of 1.1 to 5.0 micrometers; (iii) 25 to 50 volume-percent large thermally conductive fillers having a median particle size in a range of 5.1 to 50 micrometers; and (d) 0 to 5 volume-percent of an alkoxy functional linear polysiloxane different from the first polysiloxane and/or an alkoxy functional linear silane; where volume-percent values are relative to composition volume.
Type:
Grant
Filed:
February 11, 2021
Date of Patent:
September 5, 2023
Assignees:
DOW GLOBAL TECHNOLOGIES LLC, DOW SILICONES CORPORATION, ROHM AND HAAS COMPANY
Inventors:
Erica A. Frankel, Andrés E. Becerra, Andrew J. Swartz, Darren Hansen
Abstract: The present invention provides polymer blends that can be used in a multilayer structure and to multilayer structures comprising one or more layers formed from such blends. In one aspect, a polymer blend comprises a copolymer comprising ethylene and at least one of methyl acrylate and ethyl acrylate having an acrylate content of 5 to 40 weight percent based on the weight of the copolymer and having a melt index (I2) of 1 to 60 g/10 minutes, wherein the total amount of ethylene methyl acrylate copolymer and ethylene ethyl acrylate copolymer comprises 45 to 99 weight percent of the blend based on the total weight of the blend, and a polyolefin having a density of 0.870 g/cm3 or more and having a melt index (I2) of 20 g/10 minutes or less, wherein the polyolefin comprises 1 to 55 weight percent of the blend based on the total weight of the blend.
Type:
Grant
Filed:
November 17, 2017
Date of Patent:
September 5, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
Carmelo Declet Perez, Brian W. Walther, James L. Cooper, Hayley A. Brown
Abstract: Embodiments relate to a method of producing a modified double metal cyanide complex, a method of producing a monol or polyol that includes providing the modified double metal cyanide complex, an alkylene oxide polymerization process that includes providing the modified double metal cyanide complex, a batch, semi-batch, or continuous manufacturing process that includes providing the modified double metal cyanide complex, and a polyether polyol prepared using the batch, semi-batch, or continuous manufacturing process that includes providing the modified double metal cyanide complex.
Type:
Grant
Filed:
May 10, 2018
Date of Patent:
September 5, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
David K. Steelman, David A. Babb, Joost Depicker, Jasmijn Kuijper, Mari S. Rosen
Abstract: A process to form a crosslinked composition, the process comprising thermally treating a composition that comprises the following components: a) at least one olefin/silane interpolymer comprising at least one Si—H group, b) at least one peroxide, and c) optionally, at least one crosslinking coagent. A composition that comprises the following components: a) at least one olefin/silane interpolymer comprising at least one Si—H group, b) at least one peroxide, and c) optionally, at least one crosslinking coagent.
Type:
Application
Filed:
June 23, 2021
Publication date:
August 31, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
Gaoxiang Wu, Yabin Sun, Shuqi Lai, Bethany M. Neilson, Colin Li Pi Shan, David S. Laitar, Jordan C. Reddel
Abstract: Processes of polymerizing olefin monomers. The process includes reacting ethylene and optionally one or more olefin monomers in the presence of a catalyst system, wherein the catalyst system comprises: hydrocarbyl-modified methylaluminoxane having less than 25 mole percent trihydrocarbyl aluminum compounds AlRA1RB1RC1 based on the total moles of aluminum, where RA1, RB1, and RC1 are independently linear (C1-C40)alkyl, branched (C1-C40)alkyl, or (C6-C40)aryl; and one or more procatalysts comprising a metal-ligand complex according to formula (I): (Formula (I)).
Type:
Application
Filed:
February 5, 2021
Publication date:
August 31, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
David M. Pearson, Dharati Joshi Koenigs, Philip P. Fontaine
Abstract: In various embodiments, a thermoplastic composition may comprise from 0.5 wt. % to 75.0 wt. % of recycled polyethylene comprising a blend of polyethylene recovered from post-consumer material, pre-consumer material, or combinations thereof, and from 25.0 wt. % to 99.5 wt. % of virgin raw polyethylene comprising unimodal polyethylene, bimodal polyethylene, or combinations thereof, wherein at least 90.0 wt. % of the thermoplastic composition is comprised of the post-consumer recycled polyethylene and the virgin raw polyethylene. Manufactured articles made from the thermoplastic composition, such as coated conductors, are also provided.
Type:
Application
Filed:
July 7, 2021
Publication date:
August 31, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
Paul J. Brigandi, Mohamed Esseghir, Kumar N. Sanketh, Chuan C. He, Mridula Kapur, Andrew T. Heitsch, John F. Szul
Abstract: Embodiments of the present disclosure are directed towards formulated polyol compositions that include a sucrose propoxylated polyol, a polyether triol, and a propoxylated homopolymer triol.
Abstract: An interpolymer, which comprises at least one siloxane group, and prepared by polymerizing a mixture comprising one or more “addition polymerizable monomers” and at least one siloxane monomer, in the presence of a catalyst system comprising a Group 3-10 metal complex, and the siloxane monomer is selected from the following Formula 1: Aa-Si(Bb)(Cc)(Hh0)—O—(Si(Dd)(Ee) (Hh1)—O)x—Si(Ff)(Gg)(Hh2), described herein. An ethylene/siloxane interpolymer comprising at least one chemical unit of Structure 1, or at least one chemical unit of Structure 2, each described herein. A process to form an interpolymer, which comprises, in polymerized form, at least one siloxane monomer, or at least one silane monomer without a siloxane linkage, said process comprising polymerizing a mixture comprising one or more “addition polymerizable monomers” and at least one monomer of Formula 4, described herein, in the presence of a catalyst system comprising a metal complex from Formula A or Formula B, each described herein.
Type:
Application
Filed:
June 23, 2021
Publication date:
August 24, 2023
Applicants:
Dow Global Technologies LLC, Dow Silicones Corporation, Rohm and Haas Company
Inventors:
Liam Spencer, Zachary S. Kean, David D. Devore, Jordan C. Reddel, Bethany M. Neilson, Matthew Olsen, Zhanjie Li, Phillip D. Hustad
Abstract: A liquid laundry additive is provided, comprising a cleaning booster polymer having structural units of a monoethylenically unsaturated carboxylic acid monomer; structural units of an ethylenically unsaturated monomer of formula (I) optionally, structural units of an ethylenically unsaturated monomer of formula (III) and optionally, structural units of an ethylenically unsaturated monomer of formula (IV)
Type:
Grant
Filed:
May 28, 2020
Date of Patent:
August 22, 2023
Assignees:
DOW GLOBAL TECHNOLOGIES LLC, ROHM AND HAAS COMPANY
Inventors:
Asghar A. Peera, Stephen J. Donovan, Marianne Creamer
Abstract: Reaction products of amines and polymers containing saturated heterocyclic moieties may be used as levelers in metal electroplating baths. The reaction products may plate metal with good surface properties and good physical reliability.
Type:
Grant
Filed:
January 17, 2020
Date of Patent:
August 22, 2023
Assignees:
Rohm and Haas Electronic Materials LLC, Dow Global Technologies LLC
Inventors:
Lingli Duan, Chen Chen, Tong Sun, Zukhra I. Niazimbetova, Maria Anna Rzeznik
Abstract: An (electron beam)-curable (EBC) formulation comprising an EBC polyolefin compound having a crystallinity of from 0 to less than 50 weight percent (wt %) and/or having a density of 0.930 gram per cubic centimeter (g/cm3) or less; and an alkenyl-functional monocyclic organosiloxane (“silicon-based coagent”). Also included are a cured polyolefin product prepared by electron-beam irradiating the EBC formulation; methods of making and using the EBC formulation or cured polyolefin product; and articles containing or made from the EBC formulation or cured polyolefin product.
Type:
Grant
Filed:
September 12, 2022
Date of Patent:
August 22, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
Yongyong Yang, Yabin Sun, Kainan Zhang, Jeffrey M. Cogen, Timothy J. Person, Paul J. Caronia
Abstract: A semiconductive composite material consisting essentially of a polar organic copolymer and an electrical conducting effective amount of an ultra-low-wettability carbon black. Also a method of making the composite material; a crosslinked polyethylene product made by curing the composite material; manufactured articles comprising a shaped form of the inventive composite material or product; and methods of using the inventive composite material, product, or articles.
Type:
Grant
Filed:
March 22, 2019
Date of Patent:
August 22, 2023
Assignees:
DOW GLOBAL TECHNOLOGIES LLC, ROHM AND HAAS COMPANY
Inventors:
Tian Lan, Xindi Yu, Michael Q. Tran, Paul J. Brigandi, Jeffrey M. Cogen, Timothy J. Person, Yichi Zhang
Abstract: A two-component polyurethane composition comprising a polyisocyanate and an emulsion polymer having greater than 2.2% of hydroxy groups in the emulsion polymer and comprising structural units of a polymerizable surfactant, a first hydroxy-functional monomer, an acid monomer and/or a salt thereof, an additional monoethylenically unsaturated nonionic monomer, and optionally a second hydroxy-functional alkyl (meth)acrylate; the two-component polyurethane composition providing improved alcohol resistance without compromising both acid and alkali resistance.
Type:
Grant
Filed:
December 6, 2019
Date of Patent:
August 22, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
Xiaohong Yang, Jinfei Wang, Fengzhe Shi
Abstract: A flame retardant epoxy resin composition for preparing a flame retardant fiber composite including: (a) at least one epoxy resin; (b) at least one flame retardant agent for improving the flammability performance of carbon fiber-reinforced epoxy composites; (c) at least one mold release agent; (d) at least one curing agent; and (e) at least one catalyst; a prepreg prepared using the above epoxy resin composition; and a flame retardant fiber composite prepared using the above prepreg.
Type:
Grant
Filed:
January 29, 2020
Date of Patent:
August 22, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
Bharati Balijepalli, David H. Bank, Michael A. Lowe
Abstract: A method for operating an acetylene hydrogenation unit of a steam cracking system that integrates a fluidized catalytic dehydrogenation (FCDh) effluent from a fluidized catalytic dehydrogenation (FCDh) system may include separating a cracked gas from the steam cracking system into at least a hydrogenation feed comprising at least acetylene, CO, and hydrogen, introducing the FCDh effluent to the separation system, combining the FCDh effluent with the cracked gas upstream of the separation system, or both. The method may include hydrogenating acetylene in the hydrogenation feed. Elevated CO concentration in the hydrogenation feed due to the FCDh effluent may reduce a reaction rate of acetylene hydrogenation. The acetylene hydrogenation unit may operate at an elevated temperature relative to normal operating temperatures when the portion of the FCDh effluent is not integrated, such that a concentration of acetylene in the hydrogenated effluent is less than a threshold acetylene concentration.
Type:
Grant
Filed:
June 8, 2020
Date of Patent:
August 22, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
Hangyao Wang, Lin Luo, Yu Liu, Matthew T. Pretz, Andrzej Malek
Abstract: A process for preparing C2 to C3 hydrocarbons may include introducing a feed stream including hydrogen gas and a carbon-containing gas comprising carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor, and converting the feed stream into a product stream comprising C2 to C3 hydrocarbons in the reaction zone in the presence of a hybrid catalyst. The hybrid catalyst may include a metal oxide catalyst component and a microporous catalyst component comprising 8-MR pore openings and may be derived from a natural mineral, the product stream comprises a combined C2 and C3 selectivity greater than 40 carbon mol%.
Type:
Application
Filed:
June 18, 2021
Publication date:
August 17, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
Alexey Kirilin, Dean M. Millar, Adam Chojecki, Joseph F. DeWilde, Glenn Pollefeyt, Davy L.S. Nieskens, Andrzej Malek
Abstract: According to one or more embodiments described herein, a method for dehydrogenating hydrocarbons may include passing a hydrocarbon feed comprising one or more alkanes or alkyl aromatics into a fluidized bed reactor, contacting the hydrocarbon feed with a dehydrogenation catalyst in the fluidized bed reactor to produce a dehydrogenated product and hydrogen, and contacting the hydrogen with an oxygen-rich oxygen carrier material in the fluidized bed reactor to combust the hydrogen and form an oxygen-diminished oxygen carrier material. In additional embodiments, a dual-purpose material may be utilized which has dehydrogenation catalyst and oxygen carrying functionality.
Type:
Application
Filed:
April 26, 2023
Publication date:
August 17, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
Kevin Blann, Alexey Kirilin, Andrzej Malek, Victor Sussman, Matthew T. Pretz, Brien A. Stears, Barry B. Fish, Eric E. Stangland, Brian W. Goodfellow, Manish Sharma
Abstract: According to one or more embodiments described herein, a method for dehydrogenating hydrocarbons may include passing a hydrocarbon feed comprising one or more alkanes or alkyl aromatics into a fluidized bed reactor, contacting the hydrocarbon feed with a dehydrogenation catalyst in the fluidized bed reactor to produce a dehydrogenated product and hydrogen, and contacting the hydrogen with an oxygen-rich oxygen carrier material in the fluidized bed reactor to combust the hydrogen and form an oxygen-diminished oxygen carrier material. In additional embodiments, a dual-purpose material may be utilized which has dehydrogenation catalyst and oxygen carrying functionality.
Type:
Grant
Filed:
August 27, 2019
Date of Patent:
August 15, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
Kevin Blann, Alexey Kirilin, Andrzej Malek, Victor Sussman, Matthew T. Pretz, Brien A. Stears, Barry B. Fish, Eric E. Stangland, Brian W. Goodfellow, Manish Sharma
Abstract: Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I):
Type:
Application
Filed:
May 28, 2021
Publication date:
August 10, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
Rhett A. Baillie, Johnathan E. Delorbe, Andrew M. Camelio, Hien Q. Do, Philip P. Fontaine, David M. Pearson, Mari S. Rosen, Brad C. Bailey
Abstract: A method of preparing a resin infused random fiber mat including the step of forming a liquid dispersion mat of polymeric resin and fiber on a porous substrate.
Type:
Grant
Filed:
February 14, 2018
Date of Patent:
August 8, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
Craig F. Gorin, Manesh Nadupparambil Sekharan, Jason A. Reese, Amit K. Chaudhary, Daniel L. Dermody, Kevin J. Bouck, Rebekah K. Feist, Thomas J. Parsons, David H. Bank