Abstract: In various embodiments, a bimodal polyethylene may include a high molecular weight component and a low molecular weight component. The bimodal polyethylene may have a density of from 0.933 grams per centimeter (g/cm3) to 0.960 g/cm3, a melt index (I2) of from 0.3 decigrams per minute (dg/min) to 1.2 dg/min, a melt flow ratio (MFR21) greater than 80.0, a molecular weight distribution (Mw/Mn) greater than 10, a reverse comonomer distribution, and a shear thinning index of from 5.0 to 20.0. Methods for producing the bimodal polyethylene, articles manufactured from the bimodal polyethylene are also provided.
Type:
Application
Filed:
July 7, 2021
Publication date:
September 28, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
Mohamed Esseghir, Chuan C. He, Mridula Kapur, Andrew T. Heitsch, Theo Geussens, John F. Szul
Abstract: A melt blended composition comprising, in weight percent (wt %) based upon the weight of the composition: (A) 55 to 94.99 wt % of a thermoplastic polymer, (B) 5 to 44.99 wt % of a moisture curable polymer, and (C) 0.01 to 5 wt % of a moisture condensation catalyst exhibits enhanced rheological and mechanical properties as compared to a composition alike in all aspects save for the presence of a moisture curable polymer.
Abstract: Methods for the removal of ionic contaminants from a hydrophilic organic solvent by a mixed bed of ion exchange resins are described. A mixed bed of ion exchange resins with gel-type strong-acid cationic ion exchange resin with a specific moisture holding capacity and gel-type anionic ion exchange resin is used in some embodiments of such methods.
Abstract: The present disclosure provides a fabric laminate. In an embodiment, the fabric laminate includes a fabric sheet, a coating layer, and a tie layer. The fabric sheet is composed of propylene-based polymer fibers. The coating layer is composed of one or more ethylene-based polymers. The tie layer is located between the fabric sheet and the coating layer. The tie layer is composed of at least 50 wt % of a crystalline block composite (CBC) and an optional blend component. The CBC includes (i) an isotactic crystalline propylene homopolymer (iPP); (ii) an ethylene/propylene copolymer; and (iii) a diblock with the formula (EP)-(iPP). The CBC has a block composite index (CBCI) from 0.1 to 1.0. The fabric laminate has a peel force from 20 N/15 mm to 40 N/15 mm.
Type:
Grant
Filed:
August 31, 2018
Date of Patent:
September 19, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
Stefan Ultsch, Yushan Hu, Jozef J.I. Van Dun, Ming Ming
Abstract: The present invention relates to a compound which is a benzophenone substituted with a hydroxyl-terminated alkylene oxide group (R) of formula 1: where R is a combination of from 1 to 13 propylene oxide groups and from 5 to 20 ethylene oxide groups, with the proviso that the sum of the propylene oxide groups and the ethylene oxide groups is not greater than 25. The compound of the present invention provides a non-volatile, non-toxic photoinitiator that provides excellent gloss retention in exterior architectural coatings.
Type:
Grant
Filed:
December 2, 2019
Date of Patent:
September 19, 2023
Assignees:
Dow Global Technologies LLC, Rohm and Haas Company
Inventors:
Matthew E. Belowich, Alvin M. Maurice, Jordan Stracke, Mark D. Westmeyer
Abstract: Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (Ia):
Type:
Application
Filed:
May 28, 2021
Publication date:
September 14, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
Rhett A. Baillie, Hien Q. Do, David M. Pearson, Johnathan E. DeLorbe, Andrew M. Camelio, Philip P. Fontaine
Abstract: A composition comprising at least the following components: A) one or more ethylene/alpha-olefin interpolymers, which comprise ?3.5 wt % of a non-conjugated diene, based on the weight of the one or more ethylene/alpha-olefin interpolymers; B) an acid acceptor selected from the following: MgO, ZnO, or combination thereof.
Type:
Grant
Filed:
February 14, 2019
Date of Patent:
September 12, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
Guang Ming Li, Raymond L. Laakso, Jr., Yuming Lai, Xiaosong Wu
Abstract: A method and a system for analyzing a physical characteristic of a film sample are described herein. The system includes a material holder system configured to hold the film sample; and a tear analysis device configured to tear the film sample and measure a characteristic of the tear. The movable system is configured to move the film sample in the material holder system to the tear analysis device.
Type:
Grant
Filed:
April 30, 2018
Date of Patent:
September 12, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
Sanjay C. Solanki, Donald L. McCarty, II, Robert A. Gunther, Jin Wang, Kyle A. Myers, Scott J. Collick
Abstract: A process of adhering a foam structure to a rubber substrate is provided. The foam structure is composed of a first composition comprising a first ethylene-based polymer having a peak melting temperature TE1. A film composed of a second composition comprising a second ethylene-based polymer having a melt index?10 g/10 min and a peak melting temperature TE2 is applied to the surface of the rubber substrate to form a rubber substrate/film configuration. A compression force is applied at a temperature Tv (38° C.?TE2<Tv) to form a vulcanized rubber/film laminate. The foam structure is applied to a surface of the film of the vulcanized rubber/film laminate to form a vulcanized rubber-film laminate/foam configuration. A compression force is applied at a temperature TL, wherein TE2<TL<TE1, 15° C.?(TE1?TL)?40° C., and 10° C.?(TL?TE2)?70° C., to form a vulcanized rubber-film/foam laminate.
Abstract: A method of forming a carbon molecular sieve membrane includes dissolving a halogenated precursor polymer in a solvent, thereby forming a dissolved halogenated precursor polymer. Homogeneously dehydrohalogenating the dissolved halogenated precursor polymer with an organic amine base to form a partially dehydrohalogenated polymer. Forming a thin film from the partially dehydrohalogenated polymer. Pyrolyzing the thin film to form the carbon molecular sieve membrane.
Abstract: A process to form a crosslinked composition comprising thermally treating a composition at a temperature ? 25° C., in the presence of moisture, and wherein the composition comprises the following components: a) an olefin/silane interpolymer, b) a cure catalyst selected from the following: i) a metal alkoxide, ii) a metal carboxylate, iii) a metal sulfonate, iv) an aryl sulfonic acid, v) a tris-aryl borane, vi) any combination of two or more from i)-v). Also, a composition comprising the following components a and b, as described above. A process to form an olefin/alkoxysilane interpolymer, and the corresponding composition, said process comprising thermally treating a composition comprising the following components: a) an olefin/silane interpolymer, b) an alcohol, and c) a Lewis acid.
Type:
Application
Filed:
June 23, 2021
Publication date:
September 7, 2023
Applicants:
Dow Global Technologies LLC, Dow Silicones Corporation
Inventors:
Jordan C. Reddel, Mark F. Sonnenschein, David S. Laitar, Andrew B. Shah, Bethany M. Neilson, Colin LiPi Shan, David D. Devore, Jozef J. I. Van Dun, Philip D. Hustad, Zhanjie Li, Zachary S. Kean, Ken Kawamoto
Abstract: External thermal insulation composite systems described herein include a concrete or masonry wall and a multilayer thermal insulation board disposed on the concrete or masonry wall. The multilayer thermal insulation board includes at least one closed cell foam layer comprising polyurethane and polyisocyanurate having an open cell volume of less than 20% by volume according to ASTM D 6226 and at least one open cell foam layer comprising polyurethane and polyisocyanurate having an open cell volume of greater than 80% by volume according to ASTM D 6226.
Type:
Grant
Filed:
November 7, 2018
Date of Patent:
September 5, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
Giuseppe Vairo, Elena Ferrari, Luigi Bertucelli, Alberto Fangareggi
Abstract: The present invention provides polymer blends that can be used in a multilayer structure and to multilayer structures comprising one or more layers formed from such blends. In one aspect, a polymer blend comprises a copolymer comprising ethylene and at least one of methyl acrylate and ethyl acrylate having an acrylate content of 5 to 40 weight percent based on the weight of the copolymer and having a melt index (I2) of 1 to 60 g/10 minutes, wherein the total amount of ethylene methyl acrylate copolymer and ethylene ethyl acrylate copolymer comprises 45 to 99 weight percent of the blend based on the total weight of the blend, and a polyolefin having a density of 0.870 g/cm3 or more and having a melt index (I2) of 20 g/10 minutes or less, wherein the polyolefin comprises 1 to 55 weight percent of the blend based on the total weight of the blend.
Type:
Grant
Filed:
November 17, 2017
Date of Patent:
September 5, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
Carmelo Declet Perez, Brian W. Walther, James L. Cooper, Hayley A. Brown
Abstract: Embodiments relate to a method of producing a modified double metal cyanide complex, a method of producing a monol or polyol that includes providing the modified double metal cyanide complex, an alkylene oxide polymerization process that includes providing the modified double metal cyanide complex, a batch, semi-batch, or continuous manufacturing process that includes providing the modified double metal cyanide complex, and a polyether polyol prepared using the batch, semi-batch, or continuous manufacturing process that includes providing the modified double metal cyanide complex.
Type:
Grant
Filed:
May 10, 2018
Date of Patent:
September 5, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
David K. Steelman, David A. Babb, Joost Depicker, Jasmijn Kuijper, Mari S. Rosen
Abstract: Processes of polymerizing olefin monomers. The process includes reacting ethylene and optionally one or more olefin monomers in the presence of a catalyst system, wherein the catalyst system comprises: hydrocarbyl-modified methylaluminoxane having less than 25 mole percent trihydrocarbyl aluminum compounds AlRA1RB1RC1 based on the total moles of aluminum, where RA1, RB1, and RC1 are independently linear (C1-C40)alkyl, branched (C1-C40)alkyl, or (C6-C40)aryl; and one or more procatalysts comprising a metal-ligand complex according to formula (I): (Formula (I)).
Type:
Application
Filed:
February 5, 2021
Publication date:
August 31, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
David M. Pearson, Dharati Joshi Koenigs, Philip P. Fontaine
Abstract: A process to form a crosslinked composition, the process comprising thermally treating a composition that comprises the following components: a) at least one olefin/silane interpolymer comprising at least one Si—H group, b) at least one peroxide, and c) optionally, at least one crosslinking coagent. A composition that comprises the following components: a) at least one olefin/silane interpolymer comprising at least one Si—H group, b) at least one peroxide, and c) optionally, at least one crosslinking coagent.
Type:
Application
Filed:
June 23, 2021
Publication date:
August 31, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
Gaoxiang Wu, Yabin Sun, Shuqi Lai, Bethany M. Neilson, Colin Li Pi Shan, David S. Laitar, Jordan C. Reddel
Abstract: In various embodiments, a thermoplastic composition may comprise from 0.5 wt. % to 75.0 wt. % of recycled polyethylene comprising a blend of polyethylene recovered from post-consumer material, pre-consumer material, or combinations thereof, and from 25.0 wt. % to 99.5 wt. % of virgin raw polyethylene comprising unimodal polyethylene, bimodal polyethylene, or combinations thereof, wherein at least 90.0 wt. % of the thermoplastic composition is comprised of the post-consumer recycled polyethylene and the virgin raw polyethylene. Manufactured articles made from the thermoplastic composition, such as coated conductors, are also provided.
Type:
Application
Filed:
July 7, 2021
Publication date:
August 31, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
Paul J. Brigandi, Mohamed Esseghir, Kumar N. Sanketh, Chuan C. He, Mridula Kapur, Andrew T. Heitsch, John F. Szul
Abstract: Embodiments of the present disclosure are directed towards formulated polyol compositions that include a sucrose propoxylated polyol, a polyether triol, and a propoxylated homopolymer triol.
Abstract: An interpolymer, which comprises at least one siloxane group, and prepared by polymerizing a mixture comprising one or more “addition polymerizable monomers” and at least one siloxane monomer, in the presence of a catalyst system comprising a Group 3-10 metal complex, and the siloxane monomer is selected from the following Formula 1: Aa-Si(Bb)(Cc)(Hh0)—O—(Si(Dd)(Ee) (Hh1)—O)x—Si(Ff)(Gg)(Hh2), described herein. An ethylene/siloxane interpolymer comprising at least one chemical unit of Structure 1, or at least one chemical unit of Structure 2, each described herein. A process to form an interpolymer, which comprises, in polymerized form, at least one siloxane monomer, or at least one silane monomer without a siloxane linkage, said process comprising polymerizing a mixture comprising one or more “addition polymerizable monomers” and at least one monomer of Formula 4, described herein, in the presence of a catalyst system comprising a metal complex from Formula A or Formula B, each described herein.
Type:
Application
Filed:
June 23, 2021
Publication date:
August 24, 2023
Applicants:
Dow Global Technologies LLC, Dow Silicones Corporation, Rohm and Haas Company
Inventors:
Liam Spencer, Zachary S. Kean, David D. Devore, Jordan C. Reddel, Bethany M. Neilson, Matthew Olsen, Zhanjie Li, Phillip D. Hustad