Abstract: Embodiments of the invention include insulated units and methods of producing the insulating units. The insulating units include a first surface, a structural seal disposed on at least portions of the first surface, and a second surface disposed on the structural seal. The structural seal includes the reaction product of at least one first isocyanate, at least one isocyanate reactive side, and at least one adhesion promoter including a reaction product of at least one secondary aminoalkoxy silane and at least one second isocyanate.
Type:
Grant
Filed:
November 10, 2011
Date of Patent:
May 19, 2015
Assignee:
Dow Global Technologies LLC
Inventors:
Bindushree Radhakrishnan, Laura A. Grier, Syed Z. Mahdi
Abstract: An improved process for making ethoxylated amine compounds such as ethanolamines. The improvement comprises the addition of an acid to the amine compound prior to the addition of ethylene oxide to a reactor wherein the ethoxylated amine compound is prepared. The improvement reduces the concentration of undesirable glycol ether and/or vinyl ether ethoxylate byproducts which may contribute to undesirable properties, such as color and foaming, of the ethoxylated amine compounds.
Type:
Grant
Filed:
November 28, 2012
Date of Patent:
May 19, 2015
Assignee:
Dow Global Technologies LLC
Inventors:
Stephen W. King, Daniel A. Aguilar, Christophe R. Laroche
Abstract: The present invention provides methods for making pnictide compositions, particularly photoactive and/or semiconductive pnictides. In many embodiments, these compositions are in the form of thin films grown on a wide range of suitable substrates to be incorporated into a wide range of microelectronic devices, including photovoltaic devices, photodetectors, light emitting diodes, betavoltaic devices, thermoelectric devices, transistors, other optoelectronic devices, and the like. As an overview, the present invention prepares these compositions from suitable source compounds in which a vapor flux is derived from a source compound in a first processing zone, the vapor flux is treated in a second processing zone distinct from the first processing zone, and then the treated vapor flux, optionally in combination with one or more other ingredients, is used to grow pnictide films on a suitable substrate.
Type:
Grant
Filed:
February 10, 2012
Date of Patent:
May 19, 2015
Assignees:
Dow Global Technologies LLC, California Institute of Technology
Inventors:
Gregory M. Kimball, Jeffrey P. Bosco, Harry A. Atwater, Nathan S. Lewis, Marty W. Degroot, James C. Stevens
Abstract: Disclosed are oil-extended olefin block copolymer compositions with precipitated silica. The precipitated silica reduces oil-bleed while maintaining composition softness.
Type:
Grant
Filed:
December 14, 2011
Date of Patent:
May 19, 2015
Assignee:
Dow Global Technologies LLC
Inventors:
Robert T. Johnston, Ashish Batra, Raymond L. Laakso, Jr., Wenbin Liang
Abstract: Polyisocyanate-based polymers are formed by curing a reaction mixture containing at least one polyisocyanate and at least one isocyanate-reactive compound having at least two isocyanate-reactive groups in the presence of a copper catalyst that contains at least one copper atom associated with a polydentate ligand that contains at least one nitrogen-containing complexing site.
Type:
Grant
Filed:
July 5, 2011
Date of Patent:
May 19, 2015
Assignee:
Dow Global Technologies LLC
Inventors:
Richard Keaton, Peter M. Margl, Duane R. Romer, Nathan Wilmot, Rajat Duggal, Rashmi Chamsarkar
Abstract: A coating composition comprising: an aqueous dispersion comprising: the melt-kneading product of (A) a base polymer which comprises one or more thermoplastic polymers, (B) a stabilizing agent which comprises at least one component selected from the group consisting of acrylic acid grafted ethylene-based polymers and maleic anhydride grafted polyolefins; (C) a neutralizing agent; and (D) water; wherein the aqueous dispersion has a volume average particle size of less than about 5 ?m is provided.
Type:
Grant
Filed:
March 5, 2013
Date of Patent:
May 19, 2015
Assignee:
Dow Global Technologies LLC
Inventors:
Marco Amici, Thomas Udhayasingh, Jozef Van Dun
Abstract: A process for manufacturing high aspect ratio silver nanowires is provided, wherein the recovered silver nanowires exhibit an average diameter of 25 to 80 nm and an average length of 10 to 100 ?m; and, wherein the total glycol concentration is <0.001 wt % at all times during the process.
Abstract: A method for preparing a high purity (e.g. greater than 70 wt. %) mono-hydrolyzed acyl halide compound as a precipitate from solution comprising the steps of preparing a solution comprising: i) at least 80 v/v % of a hydrocarbon solvent, ii) water at a molar concentration greater than its solubility limit within the solvent but less that its solubility limit in solution, iii) a tri-hydrocarbyl phosphate compound, and iv) a polyfunctional acyl halide compound at molar ratio to both water and the tri-hydrocarbyl phosphate compound of at least 1:1.
Type:
Grant
Filed:
September 14, 2012
Date of Patent:
May 12, 2015
Assignee:
Dow Global Technologies LLC
Inventors:
XiaoHua S. Qiu, Steven D. Jons, Joseph D. Koob, Martin H. Peery, Steven Rosenberg, Abhishek Roy, Ian A. Tomlinson
Abstract: The present invention generally relates to a process that copolymerizes two or more polymerizable olefins, and to cataclyst comprising a metal-ligand complex (precatalyst). The present invention also generally relates to ligands useful for preparing the metal-ligand complex.
Type:
Grant
Filed:
August 24, 2011
Date of Patent:
May 12, 2015
Assignee:
Dow Global Technologies LLC
Inventors:
Jerzy Klosin, Pulikkottil J. Thomas, Carl N. Iverson, Nermeen W. Aboelella, Kevin A. Frazier
Abstract: A reaction system comprising (a) a polyisocyanate component and (b) an isocyanate reactive component for preparation of a polyurethane foam having high air flow with low compression set is provided. The isocyanate reactive component comprises (i) from 45 to 70% by weight of one or more PO-rich polyols having a combined number average equivalent weight from 210 to 510, (ii) from 20 to 30% by weight of one or more ethylene oxide polyols having a combined number average equivalent weight from 200 to 500, (iii) from 10 to 25% by weight of one or more ethylene oxide-alkylene oxide polyethers having a combined number average equivalent weight from 300 to 800; and (iv) from 0.5 to 15% by weight of one or more PO-rich polyols having a functionality of 1 to 4 and a combined number average equivalent weight of 2,000 to 6,000.
Type:
Grant
Filed:
August 29, 2011
Date of Patent:
May 12, 2015
Assignee:
Dow Global Technologies LLC
Inventors:
Kaoru Aou, Rogelio R. Gamboa, Hongming Ma
Abstract: A skin is applied to a ceramic honeycomb. The skin is formed by applying a skin-forming composition and drying it. The skin-forming composition includes a carrier liquid, colloidal silica and/or colloidal alumina, and an inorganic filler. The filler includes an inorganic fiber. The filler may contain low aspect ratio particles that have the same or nearly the same CTE as the inorganic fiber. The filler may include a small proportion of a low aspect ratio filler particle that has a different CTE than the inorganic fiber.
Type:
Grant
Filed:
June 24, 2010
Date of Patent:
May 12, 2015
Assignee:
Dow Global Technologies LLC
Inventors:
Jun Cai, Aleksander J. Pyzik, Michael T. Malanga, Kwanho Yang, Steve J. Martin
Abstract: A dispersion having from one to sixty percent by weight of total dispersion of a solids component dispersed in an organic continuous phase is useful as a coating for substrates. The solids component contains 40-95 weight-percent of a polyolefin containing only carbon and hydrogen and that has a number average molecular weight that is greater than 400 gram per mole, 5-40 weight-percent of an amine salt of a functionalized polyolefin; and 0-20 weight-percent of optional additives, wherein weight-percent is based on total weight of solids and wherein the dispersed particles have an average particle size of less than 35 micrometers and the organic phase is a dispersion support medium for the polyolefin and amine salt of a functionalized polyolefin.
Type:
Application
Filed:
June 7, 2013
Publication date:
May 7, 2015
Applicant:
Dow Global Technologies LLC
Inventors:
Houxiang Tang, Bernhard Kainz, Liang Hong, Richard A. Lundgard
Abstract: A method for treating liquefied hydrocarbons including acid gases to remove the acid gases while minimizing loss of amine species, the method comprising the step of contacting the liquefied hydrocarbons with an absorbent aqueous solution of a first amine compound, the first amine compound having the structure wherein R1 is hydrogen, propane-2,3-diol, and mixtures thereof and R2 is propane-2,3-diol.
Abstract: A linerless label or tape comprises a substantially biodegradable, natural or synthetic, woven or non-woven substrate impregnated with a formulation including at least 90 weight percent of a polyester amide segmented block copolymer. This label or tape may be conveniently prepared above the melt temperature of the copolymer and is printable. It offers the advantage of being able to be prepared such that it is substantially non-tacky at room or storage temperatures, and yet may be easily affixed to a substrate when heated to a temperature above the melt temperature of the impregnant, preferably ranging from 60° C. to 150° C. “Linerless” is defined as not requiring a separable, wastable layer, and a release coating to facilitate rolling or stacking is also not required.
Abstract: Embodiments of the invention include a phosphorus containing flame retardant which may be the reaction product of a reaction mixture where the reaction mixture includes at least one active hydrogen-containing compound and at least one phosphorus containing compound. The at least one active hydrogen-containing compound is selected from the group of a first polyol having a hydroxyl functionality of at least 3, a polyamine having an amine functionality of at least 2, and an amino alcohol having a combined amine and hydroxyl functionality of at least 2.
Abstract: A process for reductive amination of aliphatic cyanoaldehydes to aliphatic diamines comprising (1) providing a mixture of 1,3-cyanocyclohexane carboxaldehyde and/or 1,4-cyanocyclohexane carboxaldehyde; (2) contacting said mixture with a metal carbonate based solid bed or a weak base anion exchange resin bed at a temperature from 15 to 40 ° C. for a period of at least 1 minute; (3) thereby treating said mixture, wherein said treated mixture has a pH in the range of 6 to 9; (4) feeding said treated mixture, hydrogen, and ammonia into a continuous reductive amination reactor system; (6) contacting said treated mixture, hydrogen, and ammonia with each other in the presence of one or more heterogeneous metal based catalyst systems at a temperature from 80 ° C. to 160 ° C. and a pressure from 700 to 3500 psig; (7) thereby producing one or more cycloaliphatic diamines is provided.
Type:
Grant
Filed:
July 30, 2010
Date of Patent:
May 5, 2015
Assignee:
Dow Global Technologies LLC
Inventors:
Erich J. Molitor, Daniel A. Hickman, Shawn D. Feist, David C. Molzahn, Stacie Santhany, Abraham D. Schuitman
Abstract: The invention provides a composition comprising at least one olefin multi-block interpolymer; at least one functionalized olefin-based polymer; and optionally at least one thermoplastic polyurethane. The invention also provides for articles prepared from the inventive compositions and for methods for making the same.
Type:
Grant
Filed:
October 15, 2012
Date of Patent:
May 5, 2015
Assignee:
Dow Global Technologies LLC
Inventors:
Patricia Ansems, Ashish Batra, Laura B. Weaver, Lawrence J. Effler, H. Craig Silvis, Hamed Lakrout, Laura K. Mergenhagen
Abstract: This invention relates to an epoxy resin composition and its application in marine maintenance and repair coating with improved overcoatability.
Abstract: The present invention discloses the production of panels by a discontinuous process. The panels are produced by injecting a polyisocyanurate foam forming composition into the mold cavity at reduced pressure. The combination of certain polyisocyanurate foam forming formulation and the reduced pressure in the mold cavity allows production of and resulting sandwich panels in a discontinuous process where the produced panels are characterized by improved fire resistance.
Type:
Application
Filed:
May 22, 2013
Publication date:
April 30, 2015
Applicant:
Dow Global Technologies LLC
Inventors:
Luigi Bertucelli, Giuseppe Fantera, Paolo Golini
Abstract: The invention provides a solution polymerization process comprising: A) polymerizing one or more monomers in the presence of a solvent that comprises a heavy hydrocarbon solvent and a light hydrocarbon solvent, to form a polymer solution; B) transferring the polymer solution to a Liquid-Liquid Separator, without adding heat to the solution, and wherein the pressure of the polymer solution is actively reduced in a controlled manner prior to, or within, the Liquid-Liquid Separator, to induce at least two liquid phases, a polymer-rich phase and a solvent-rich phase, and wherein the concentration of polymer in the polymer-rich phase is higher than that in the polymer solution transferred to the Liquid-Liquid Separator; and C) removing the solvent-rich phase.
Type:
Grant
Filed:
July 15, 2010
Date of Patent:
April 28, 2015
Assignee:
Dow Global Technologies LLC
Inventors:
Prasanna K. Jog, Robert D. Swindoll, Nile A. Mead, Pradeep Jain, Alec Y. Wang, Job D. Guzman