Abstract: A surfactant composition including at least one alkyl alkoxylate sulfate anionic surfactant; a process for preparing the surfactant composition; and an emulsion polymerization process using the surfactant composition.
Abstract: Catalyst compositions are prepared by contacting a palladium source and 1,3,5,7-tetramethyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane and a methoxyocta-diene compound, in a primary aliphatic alcohol, under suitable conditions including a ratio of equivalents of palladium to equivalents of 1,3,5,7-tetramethyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane ranging from greater than 1:1 to 1:1.3. The result is a complex of palladium, a 1,3,5,7-tetramethyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaada-mantane ligand, and a ligand selected from a methoxyoctadiene ligand, an octadienyl ligand, or a protonated octadienyl. Such complexes may, in solution, exhibit surprising solubility and storage stability and are useful in the telomerization of butadiene, which is a step in the production of 1-octene.
Abstract: A two-component solventless adhesive composition is disclosed. The composition comprises an isocyanate component comprising an isocyanate prepolymer that is the reaction product of a polyisocyanate and an isocyanate reactive component comprising at least 40 wt % of a polyester polyol, based upon the dry weight of the isocyanate reactive component, a polyol component having an average functionality between 2.5 and 4.5 and an average molecular weight between 250 and 1,000, and comprising at least 30 wt % of a polyether polyol, based upon the dry weight of the polyol component, and an adhesion promoter. A method for forming laminates comprising the disclosed adhesive compositions is also disclosed.
Abstract: Embodiments are directed to catalyst systems comprising: a procatalyst; and a co-catalyst, the co-catalyst comprising: a non-coordinating borate anion having the formula [B(C6F5)4]1? and a cation according to formula (I).
Type:
Grant
Filed:
March 29, 2019
Date of Patent:
October 17, 2023
Assignees:
Dow Global Technologies LLC, Northwestern University
Inventors:
Tobin J. Marks, Yanshan Gao, Tracy L. Lohr, Matthew D. Christianson, Jerzy Klosin, Edmund M. Carnahan, Andrew J. Young
Abstract: The present disclosure relates to a halogen free flame retardant elastomer composition, a halogen free flame retardant article prepared from the same, and preparation methods thereof.
Abstract: Disclosed herein are feminine hygiene articles and multilayer film structures. According to one or more embodiments disclosed herein, a feminine hygiene article may include a feminine hygiene pad including an absorbent body, an adhesive layer positioned on at least a surface of the absorbent body, and a pouch wrap in contact with the adhesive layer of the feminine hygiene pad. The pouch wrap may include a release layer in direct contact with the adhesive layer. The release layer may include a polymer composition including low density polyethylene covalently bonded to polydimethylsiloxane.
Type:
Application
Filed:
September 15, 2021
Publication date:
October 12, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
Eduardo Alvarez Acedo, Barbara Bonavoglia, Michel Brunetto, Arkady Krasovskiy, Andrew Heitsch
Abstract: Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I): [Formula I]
Type:
Application
Filed:
May 28, 2021
Publication date:
October 12, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
Rhett A. Baillie, Hien Q. Do, Andrew M. Camelio, Johnathan E. Delorbe, Mari S. Rosen, Philip P. Fontaine, David M. Pearson
Abstract: The present disclosure relates to a thermoplastic polyolefin composition comprising: (A) a polypropylene polymer; (B) an elastomer component; (C) an additive component; and (D) a scavenger component comprising a polyacetoacetate compound having the Formula (I) defined herein and an amino alcohol compound having the Formula (II) defined herein. The present disclosure also relates to an article made from the thermoplastic polyolefin composition.
Abstract: Flexible polyurethane foams are characterized in having slow recovery times, low foam densities and very low compression sets. The foams are useful in human comfort applications such as pillows and mattresses.
Type:
Grant
Filed:
April 20, 2020
Date of Patent:
October 10, 2023
Assignee:
Dow Global Technologies LLC
Inventors:
Gianluca Casagrande, Federico La Terra, Antonio Papa
Abstract: The present disclosure relates to a composition comprising: (A) from 40 wt % to 95 wt % of a thermoplastic polyolefin elastomer and (B) from 5 wt % to 60 wt % of a carbon fiber component. In certain embodiments, the composition of the present disclosure reaches a high level of stiffness while exhibiting a high level of toughness. Moreover, a decrease in gloss appearance and an improvement in resistance to abrasion are expected.
Abstract: An aqueous dispersion of a silicone pressure sensitive adhesive base can be combined with a curing agent and cured to form a silicone pressure sensitive adhesive. The aqueous dispersion of the silicone pressure sensitive adhesive base includes a bis-hydroxyl-terminated polydiorganosiloxane; a polyorganosilicate resin; cumene; a surfactant; and water. A curing agent such as a peroxide compound or an aminosilane may be combined with the aqueous disperison of the silicone pressure sensitive adhesive base to form a silicone pressure sensitive adhesive composition. A pressure sensitive adhesive article may be formed by a method including coating a surface of a substrate with the silicone pressure sensitive adhesive composition, removing water, and curing the silicon pressure sensitive adhesive composition to form a silicone pressure sensitive adhesive on the surface of the substrate.
Type:
Grant
Filed:
July 21, 2021
Date of Patent:
October 10, 2023
Assignees:
DOW GLOBAL TECHNOLOGIES LLC, Dow Silicones Corporation
Inventors:
Qiangqiang Yan, Yunlong Guo, Wenjie Chen, Li Ding, Hongyu Chen, Cheng Shen, Ruihua Lu, Yan Zhou, Zhihua Liu
Abstract: Polyethylene compositions are disclosed that may have a density of 0.910 g/cm3 to 0.924 g/cm3 and a melt index (I2) In of 0.1 g/10 minutes to 0.5 g/10 minutes and include a first polyethylene fraction area in the temperature range from 45° C. to 80° C. of an elution profile via improved comonomer composition distribution (iCCD) analysis method; a second polyethylene fraction area in the temperature range from 80° C. to 95° C. of the elution profile, and a third polyethylene fraction area in the temperature range from 95° C. to 110° C. of the elution profile. The second polyethylene fraction area may include at least 5% of the total area of the elution profile. The third polyethylene fraction area may include at least 25% of the total area of the elution profile. A ratio of the first polyethylene fraction area to the second polyethylene fraction area may be from 6 to 15.
Type:
Application
Filed:
February 5, 2021
Publication date:
October 5, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
Peter Hermann Roland Sandkuehler, Sanjib Biswas, David T. Gillespie, Mehmet Demirors, Michael J. Zogg, Jr.
Abstract: Embodiments are directed towards a process for producing a (poly)alkylene glycol monoalkyl ether. The process includes providing an admixture of a crystalline metallosilicate molecular sieve catalyst and an oxide of a metal and reacting in a liquid phase process an olefin and a (poly)alkylene glycol in the presence of the admixture to yield the (poly)alkylene glycol monoalkyl ether. Reacting the olefin and the (poly)alkylene glycol in the presence of the admixture is at a temperature of 80° C. to 200° C.
Type:
Application
Filed:
September 2, 2021
Publication date:
October 5, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
Beata A. Kilos, Aditya Bhan, Amy Wetzel, Wen-Sheng Lee
Abstract: A carbon molecular sieve (CMS) membrane having improved separation characteristics for separating olefins from their corresponding paraffins is comprised of carbon with at most trace amounts of sulfur and a group 13 metal. The CMS membrane may be made by pyrolyzing a precursor polymer devoid of sulfur in which the precursor polymer has had a group 13 metal incorporated into it, wherein the metal is in a reduced state. The pyrolyzing for the precursor having the group 13 metal incorporated into it is performed in a nonoxidizing atmosphere and at a heating rate and temperature such that the metal in a reduced state (e.g., covalently bonded to carbon or nitrogen or in the metal state).
Type:
Grant
Filed:
October 27, 2022
Date of Patent:
October 3, 2023
Assignees:
Dow Global Technologies LLC, Georgia Tech Research Corporation
Inventors:
Yu-Han Chu, William J. Koros, Liren Xu, Mark K. Brayden, Marcos V. Martinez
Abstract: Solvent-based adhesive composition are disclosed, the compositions comprising (A) a polyester-urethane resin, (B) a phosphate ester compound, and (C) an aliphatic isocyanate curing agent. Methods for preparing a solvent-based adhesive composition, the methods comprising providing a polyester-urethane resin, providing a phosphate ester compound, mixing the polyester-urethane resin and phosphate ester compound to form a resin mixture, diluting the resin mixture in a solvent to form a diluted resin mixture having an application solid content of from 25 to 55 weight percent, based on the total weight of the diluted resin mixture, and curing the diluted resin mixture with an aliphatic isocyanate curing agent at a mix ratio (parts by weight resin mixture before dilution:parts by weight aliphatic isocyanate curing agent) of from 100:1 to 100:12. Laminates prepared comprising the solvent-based adhesives and according to the disclosed methods are also disclosed.
Type:
Grant
Filed:
April 4, 2018
Date of Patent:
October 3, 2023
Assignees:
Dow Global Technologies LLC, Rohm and Haas Company
Inventors:
Wenwen Li, Joseph J. Zupancic, Paul Clark, Thorsten Schmidt
Abstract: Adhesive compositions are disclosed comprising acrylic copolymers formed from a monomer mixture comprising, based on the total weight of monomers in the monomer mixture, from 59 to 97.9 weight percent 2-ethylhexyl acrylate, from 0.1 to 10 weight percent styrene, from 0 to 25 weight percent methyl methacrylate, and from 2 to 30 weight percent ethyl acrylate, wherein the ratio of ethyl acrylate to styrene (by weight) is greater than 4.5 to 1. Methods for preparing adhesive compositions are disclosed comprising feeding an aqueous initial charge to a reactor, heating the aqueous initial charge to from about 30 to 110° C., gradually feeding a monomer mixture into the reactor over a period of time (less than 3 hours), in the presence of a free-radical polymerization initiator, thereby forming the acrylic adhesive composition, wherein the amount of free monomer in the reactor does not exceed 17 percent by weight, based on the total weight of the reactor contents, during gradual feeding.
Type:
Grant
Filed:
July 17, 2018
Date of Patent:
October 3, 2023
Assignees:
Dow Global Technologies LLC, Rohm and Hass Company
Abstract: In various embodiments, a bimodal polyethylene may include a high molecular weight component and a low molecular weight component. The bimodal polyethylene may have a density of from 0.933 grams per centimeter (g/cm3) to 0.960 g/cm3, a melt index (I2) of from 0.3 decigrams per minute (dg/min) to 1.2 dg/min, a melt flow ratio (MFR21) greater than 80.0, a molecular weight distribution (Mw/Mn) greater than 10, a reverse comonomer distribution, and a shear thinning index of from 5.0 to 20.0. Methods for producing the bimodal polyethylene, articles manufactured from the bimodal polyethylene are also provided.
Type:
Application
Filed:
July 7, 2021
Publication date:
September 28, 2023
Applicant:
Dow Global Technologies LLC
Inventors:
Mohamed Esseghir, Chuan C. He, Mridula Kapur, Andrew T. Heitsch, Theo Geussens, John F. Szul
Abstract: A melt blended composition comprising, in weight percent (wt %) based upon the weight of the composition: (A) 55 to 94.99 wt % of a thermoplastic polymer, (B) 5 to 44.99 wt % of a moisture curable polymer, and (C) 0.01 to 5 wt % of a moisture condensation catalyst exhibits enhanced rheological and mechanical properties as compared to a composition alike in all aspects save for the presence of a moisture curable polymer.
Abstract: A silicone-polycarbonate copolymer has the formula Xg[ZjYo]c, where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polycarbonate moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is >1, 0?j<2, and 0<o<2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-polycarbonate copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-polycarbonate copolymer and a condensation-reaction catalyst.
Type:
Grant
Filed:
November 16, 2019
Date of Patent:
September 19, 2023
Assignees:
DOW SILICONES CORPORATION, DOW GLOBAL TECHNOLOGIES LLC
Inventors:
Emmanuel Duquesne, Martin Grasmann, Brian Harkness, William Johnson, Elizabeth Santos, Justin Scherzer, Jeanette Young, Bizhong Zhu