Patents Assigned to DSM N.V.
  • Patent number: 5364916
    Abstract: The present invention relates to a catalyst and a process for the preparation of an olefin polymer, which catalyst comprises a transition metal component and an organometal component. The transition metal component comprises a transition metal atom onto which an imidoaryl ligand is bound.More specifically the transition metal is vanadium or titanium.
    Type: Grant
    Filed: September 10, 1992
    Date of Patent: November 15, 1994
    Assignee: DSM N.V.
    Inventors: Jacob Renkema, Jeroen H. G. Konings, Bernardus J. Muskens
  • Patent number: 5362760
    Abstract: A microporous film with improved resistance to elevated temperatures from a first, thermoplastic polymer, the internal and external surfaces of the film being provided with a continuous coating layer of a second polymer having a higher softening temperature than the first polymer and process for coating a film of a first polymer with a layer of a second polymer.
    Type: Grant
    Filed: January 15, 1992
    Date of Patent: November 8, 1994
    Assignee: DSM N.V.
    Inventors: Markus J. H. Bulters, Hans K. Van Dijk, Ronald M. A. M. Schellekens
  • Patent number: 5359024
    Abstract: The invention relates to a process for the preparation of a phenol-formaldehyde resin by causing phenol and formaldehyde to condense under the influence of a basic catalyst, the catalyst being an aqueous solution containing alkali metal ions, carbonate ions, ions of carboxylic acids and one or more ions chosen from the group comprising transition metal ions and borates.
    Type: Grant
    Filed: August 17, 1993
    Date of Patent: October 25, 1994
    Assignee: DSM N.V.
    Inventors: Renier H. M. Kierkels, van Kempen Carolien H. M., Henricus A. C. Baur
  • Patent number: 5350849
    Abstract: The invention relates to a selective removal of impurities from the gas stream leaving a melamine synthesis reactor in the preparation of melamine from urea by means of a treatment with steam at elevated temperature in the presence of a catalyst which is shape-selective. For instance a molecular sieve is chosen.
    Type: Grant
    Filed: June 1, 1993
    Date of Patent: September 27, 1994
    Assignee: DSM N.V.
    Inventors: Cornelis G. M. van de Moesdijk, Hendrik J. Janssen, Josephus C. Schroijen
  • Patent number: 5340633
    Abstract: A multilayer antiballistic structure having good antiballistic properties comprises a first layer which comprises ceramic tiles and a second layer of composite material which comprises polyalkene filaments having a tensile modulus of at least 40 GPa and a tensile strength of at least 1 GPa and a matrix which at least partially surrounds the polyalkene filaments, while the antiballistic structure comprises, between the first and the second layer an intermediate layer of a material having a flexural modulus which is higher than the flexural modulus of the composite material of the second layer and is lower than the flexural modulus of the ceramic material.Good results are obtained if the intermediate layer comprises a composite material.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: August 23, 1994
    Assignee: DSM, N.V.
    Inventors: Leonardus L. H. van der Loo, Marcel D. M. Mertens
  • Patent number: 5338413
    Abstract: Method for the preparation of a polymeric shaped article containing an electrically conductive polymer wherein a base shaped article possessing electrically conductive properties is moved along an anode, at least part of the article being in contact with the anode, in the presence of an electrolyte-containing medium containing monomer units, which on polymerization form an electrically conductive polymer and wherein a voltage is applied between the anode and a second electrode which is in contact with the electrolyte-containing medium. It has appeared that, in the method according to the invention, the shaped article does not adhere to the electrode so that the method may be practiced continuously. A further advantage of the shaped article failing to adhere to the electrode is that the method according to the invention generates very little waste.
    Type: Grant
    Filed: July 15, 1993
    Date of Patent: August 16, 1994
    Assignee: DSM N.V.
    Inventors: Hans K. van Dijk, Ronald M. A. M. Schellekens
  • Patent number: 5336805
    Abstract: Process for preparing an a-amino acid having the general formula (1) of ##STR1## where R represents an aryl group or a substituted aryl, cycloalkyl or alkyl group, in which process glyoxylic acid, or a precursor or derivative thereof, is contacted in the presence of sulphamic acid with an unsaturated compound chosen from the group of aromatics, cycloalkenes and alkenes. By applying the process higher efficiencies are obtained.The acid obtained as reaction product can be esterified and amidated without prior isolation.
    Type: Grant
    Filed: August 12, 1992
    Date of Patent: August 9, 1994
    Assignee: DSM N.V.
    Inventors: Wilhelmus H. J. Boesten, Nicolaas A. de Heij
  • Patent number: 5336810
    Abstract: The invention relates to a catalyst that is very suitable for the conversion of a benzoic acid into the corresponding benzaldehyde. The catalyst can be obtained via coprecipitation of a manganese salt, a salt from which an acid support is formed, a zinc salt and optionally a copper salt at a pH between 4 and 10, calcination, after precipitation, of the coprecipitate at a temperature of between 300 and 700.degree. C. and then, optionally, reduction of the calcined coprecipitate with the aid of a hydrogen-containing gas mixture. Using such a catalyst the hydrogenation of a benzoic acid can be carried out at lower temperature resulting in energy-savings and, hence, cost-savings.
    Type: Grant
    Filed: May 7, 1993
    Date of Patent: August 9, 1994
    Assignee: DSM N.V.
    Inventors: Paul C. Van Geem, Xiaoding Xu, Joseph J. F. Scholten
  • Patent number: 5334768
    Abstract: The invention relates to a process for the preparation of cycloalkanone and optionally cycloalkanol by causing a mixture containing cycloalkylhydroperoxide to react with cycloalkene under the influence of a catalyst, characterised in that the reaction is carried out with a short measure of cycloalkene relative to the cycloalkylhydroperoxide, under such conditions that virtually all of the cycloalkene reacts to cycloalkene oxide and optionally cycloalkanol and/or cycloalkanone, after which the mixture, optionally after decomposition of cycloalkylhydroperoxide and distillation of cycloalkane, is subjected to a first separation, in which cycloalkene oxide--and optionally other components--is separated, after which the cycloalkene oxide in the separated mixture is isomerised to substantially cycloalkanone, after which the cycloalkanone obtained--and optionally cycloalkanol--is recovered.
    Type: Grant
    Filed: February 3, 1993
    Date of Patent: August 2, 1994
    Assignee: DSM N.V.
    Inventors: Johannes G. van Hinsberg, Cornelis G. M. van de Moesdijk, Ivo Spaargaren, Otto E. Sielcken
  • Patent number: 5326832
    Abstract: The invention relates to a powder paint, comprising a polyepoxy compound, a polyester resin and customary additives, the polyester resin having an acid number ranging from 15 through 70 and a hydroxyl number of 10 or below and being substantially based on units of dicarboxylic acids, glycols and monomers of functionality three or higher, wherein the dicarboxylic acids are comprised of at least 15 mole % of isophthalic acid and at least 5 mole % of 1,4-cyclohexane dicarboxylic acid and wherein the glycols are comprised of at least 50 mole % of branched aliphatic glycols with 5-11 carbon atoms, which may optionally comprise an ester group, and at most 50 mole % of aliphatic glycol with 2-6 carbon atoms, and wherein the monomers have a functionality three or higher in an amount of at most 8 mole % of dicarboxylic acids plus glycols.
    Type: Grant
    Filed: July 7, 1992
    Date of Patent: July 5, 1994
    Assignee: DSM N.V.
    Inventors: Eimbert G. Belder, Fokeltje A. Koldijk, Frits Visser, Tosko A. Misev, Albertus R. Hofkamp, Marten Houweling
  • Patent number: 5321100
    Abstract: The invention relates to a powder paint, comprising a polyepoxy compound, a polyester resin and customary additives, the polyester resin having an acid number ranging from 15 through 70 and a hydroxyl number of 10 or below and being substantially based on units of dicarboxylic acids, glycols and monomers of functionality three or higher, wherein the dicarboxylic acids are comprised of at least 15 mole % of isophthalic acid and at least 5 mole % of 1,4-cyclohexane dicarboxylic acid and wherein the glycols are comprised of at least 50 mole % of branched aliphatic glycols with 5-11 carbon atoms, which may optionally comprise an ester group, and at most 50 mole % of aliphatic glycol with 2-6 carbon atoms, and wherein the monomers have a functionality three or higher in an amount of at most 8 mole % of dicarboxylic acids plus glycols.
    Type: Grant
    Filed: July 7, 1992
    Date of Patent: June 14, 1994
    Assignee: DSM N.V.
    Inventors: Eimbert G. Belder, Fokeltje A. Koldijk, Frits Visser, Tosko A. Misev, Albertus R. Hofkamp, Marten Houweling
  • Patent number: 5319125
    Abstract: The invention relates to a method for the preparation of a 2-(2-cyanoethyl)-cyclopentanone by reaction of a cyclopentanone which contains at least one .alpha.-H atom with an .alpha.,.beta.-unsaturated nitrile in the presence of a catalytic amount of pyrrolidine as catalyst and optionally also a catalytic amount of an acid compound. A high selectivity and a high catalyst activity are achieved with the method.
    Type: Grant
    Filed: March 30, 1993
    Date of Patent: June 7, 1994
    Assignee: DSM N.V.
    Inventors: Anna M. C. F. Castelijns, Hubertus J. A. Dielemans
  • Patent number: 5319146
    Abstract: The invention relates to a compound having the Formula (I) ##STR1## in which n=1, 2, 3 or 4 and m=1, 2, 3, 4, 5, 6, 7 or 8. The invention also relates to a method for the preparation of the above-described compound by bringing a cycloalkyl hydroperoxide having 5 to 12 carbon atoms into contact with a cycloalkene having 5-8 carbon atoms, under the influence of a metal compound as catalyst, the metal being chosen from groups VIB, VIIB and VIII of the periodic system. The reaction takes place at a temperature of 0.degree.-80.degree. C.
    Type: Grant
    Filed: December 22, 1992
    Date of Patent: June 7, 1994
    Assignee: DSM N.V.
    Inventors: Ubaldus Kragten, Otto E. Sielcken
  • Patent number: 5312568
    Abstract: Process for the manufacture of a polarizing film by drawing a polymer film containing a dichroic dye at a temperature above the glass transition temperature of the polymer, the polymer film consisting mainly of a semicrystalline polyolefine and being drawn at a temperature below the crystalline melting point of the polyolefine, the dye being present in liquid form at that drawing temperature, and a polarizing dye-containing polyolefine film having a dichroic ratio of at least 15.
    Type: Grant
    Filed: August 6, 1993
    Date of Patent: May 17, 1994
    Assignee: DSM N.V.
    Inventor: Cornelis W. M. Bastiaansen
  • Patent number: 5310866
    Abstract: Process for stretching an article substantially consisting of a flexible-chain polymer, which is swollen in a solvent for that polymer, in which process an article substantially consisting of a copolymer of the polymer with a second polymer is swollen in a selective solvent for the flexible-chain polymer, and stretched, and an article containing an oriented flexible-chain polymer with a dichroic ratio of at least 1.1.
    Type: Grant
    Filed: August 31, 1992
    Date of Patent: May 10, 1994
    Assignee: DSM N.V.
    Inventors: Hendrikus J. J. Rutten, Adrianus W. M. Braam
  • Patent number: 5302661
    Abstract: A composition which contains thermosettable monomers from which continuous products can be made without using continuous carrier material, the composition containing bismaleimide monomers and a thermoplastic polymer having a high molecular weight.Products made from a composition of the present invention are suitable for use in those fields where good temperature resistance, good fire resistance and/or good corrosion and solvent resistance are required in addition to good mechanical properties. Examples are cable sheathing, fire-resistant clothing, asbestos substitutes, high-temperature filters, aircraft interiors, precursors for carbon fiber , food packagings (for example, for use in a microwave oven), capacitor films and filament winding products.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: April 12, 1994
    Assignee: DSM N.V.
    Inventor: Cornelius W. M. Bastiaansen
  • Patent number: 5302647
    Abstract: A flame retardant resin composition which includes the following component (A) and component (B) blended in the ratio (A):(B)=100:1-40 parts by weight. Component (A) is a thermoplastic resin including 0-70% by weight of a rubber component and 100-30% by weight of a polymer component formed from monomers comprising a methylated aromatic vinyl monomer and an hydroxylated aromatic vinyl monomer and, optionally, an aromatic vinyl monomer other than the above monomers, a cyanated vinyl monomer, a (meth)acrylic acid ester monomer, maleic anhydride, and a maleimide monomer; graft ratio of the thermoplastic resin being 10-150% when the rubber component is used. Component (B) is a flame retarder.
    Type: Grant
    Filed: July 12, 1991
    Date of Patent: April 12, 1994
    Assignee: DSM N.V.
    Inventors: Masanori Suzuki, Hiroyuki Itoh, Masaaki Mawatari, Tateki Furuyama
  • Patent number: 5298665
    Abstract: The invention relates to a process for preparing an alkanone and/or alkanol by oxidizing an alkane with 3-30 C-atoms, using oxygen, to form an alkyl hydroperoxide, followed by a decomposition of the resulting alkyl hydroperoxide in the presence of a metal compound immobilized on a carrier, which carrier carries aliphatic or aromatic amine groups or sulphide groups. The process is preferably applied to cycloalkanes.
    Type: Grant
    Filed: March 15, 1993
    Date of Patent: March 29, 1994
    Assignee: DSM N.V.
    Inventors: Ludovicus H. W. Janssen, Peter Hoogendoorn, Ubaldus F. Kragten, Henricus A. C. Baur
  • Patent number: 5292459
    Abstract: This invention is a process for the production of a continuous running length of a thermosetting polymer by a continuously extruding a continuous running length of a sheath of a film forming fiber from a die to form a hollow object; b) continuously injecting the monomer of the thermosetting polymer into the hollow of the sheath at or immediately below the plane of the die opening; c) stretching the sheath containing the monomer; and d) polymerizing the monomer to make the continuous running length of fiber of thermosetting polymer.
    Type: Grant
    Filed: July 28, 1992
    Date of Patent: March 8, 1994
    Assignee: DSM N.V.
    Inventors: Franciscus W. M. Gelissen, Cornelis W. M. Bastiaansen
  • Patent number: 5290836
    Abstract: Polymer composition comprising a copolymer of a vinylaromatic compound, a vinyl cyanide and, optionally, a third monomer which copolymer is grafted on a rubber, a flame-retardant phosphorus compound and a charforming component, characterised in that the polymer composition also comprises a polymer P which comprises 1-100 wt. % monomeric units with the following structure, the wt. % being relative to said polymer P ##STR1## where m=1-5. This polymer composition shows improved flame-retardant properties as a result of synergism with respect to the flame-retardant properties between the charformer and polymer P.
    Type: Grant
    Filed: October 23, 1992
    Date of Patent: March 1, 1994
    Assignee: DSM N.V.
    Inventor: Jan H. Truyen