Patents Assigned to Ecolab
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Patent number: 10244751Abstract: Methods and systems for temperature-controlled, on-site generation of peracids, namely peroxycarboxylic acids and peroxycarboxylic acid forming compositions are disclosed. In particular, methods for using an adjustable biocide formulator or generator system overcome the limitations of temperature on the kinetics of the peracid generation and/or peracid decomposition inside an adjustable biocide formulator or generator system. The methods include the controlling of the temperature of at least one raw starting material, namely water, to improve upon methods of on-site generation of peracids. The methods allow for the generation of user-selected chemistry without regard to the ambient temperatures of the raw starting materials and/or the biocide formulator or generator system.Type: GrantFiled: March 22, 2018Date of Patent: April 2, 2019Assignee: Ecolab USA Inc.Inventors: Brandon Herdt, Richard Staub, Thomas C. Rustad, Junzhong Li, David D. McSherry, Paul R. Kraus, Richard Walsh
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Patent number: 10246666Abstract: Methods for using in situ cleaning systems which reduce water hardness and minimize chemical additives are provided. According to the methods and systems, the methods of using may comprise providing feed water to an in situ cleaning system including water treatment components, oxidizing agent generating components and/or alkalinity generating components, contacting one or more articles with a use solution generated by the in situ cleaning system, and washing the one or more articles in a washing system. In addition to the methods of using, the systems for in situ cleaning are provided.Type: GrantFiled: July 21, 2016Date of Patent: April 2, 2019Assignee: Ecolab USA Inc.Inventors: Kim R. Solomon, Keith E. Olson, Erik C. Olson, Michael S. Rischmiller
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Patent number: 10246667Abstract: The invention relates to a concentrated detergent composition comprising an alkali metal carbonate, methylglycinediacetic acid, glutamic acid N,N-diacetic acid, and alkali metal tripolyphosphate. The composition is particularly suited to remove tea and coffee soil in warewashing applications.Type: GrantFiled: June 13, 2018Date of Patent: April 2, 2019Assignee: Ecolab USA Inc.Inventors: Tobias Foster, David W. Gohl, Sven Klose, Dirk Kullwitz, John Mansergh, Timothy Meier, Beana Pathicheril
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Patent number: 10246665Abstract: Alkaline or neutral viscoelastic cleaning compositions are disclosed which use non polymer thickening agents. According to the invention, cleaning compositions have been developed using viscoelastic surfactants in a neutral, acidic or alkaline cleaning formulations. These provide the dual benefit of thickening as well as an additional cleaning, thereby improving performance. Applicants have also identified several pseudo linking agents which when, used with viscoelastic surfactants provide viscoelasticity in alkaline cleaning compositions.Type: GrantFiled: August 10, 2017Date of Patent: April 2, 2019Assignee: Ecolab USA Inc.Inventors: Victor Fuk-Pong Man, Michael Charles Denoma, Yvonne Marie Killeen, Susan Maloney Viall
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Patent number: 10246629Abstract: Corrosion inhibitor blends including one or more ether compounds, one or more quaternary ammonium compounds, and one or more fatty acid amine condensates are disclosed. The corrosion inhibitor blends can be used in methods of inhibiting corrosion of a metallic surface in a geothermal process. In one method, an effective amount of a corrosion inhibitor blend may be added to a production well in a geothermal process. In another method, an effective amount of a corrosion inhibitor blend may be added to a geothermal medium, which could be, for example, steam or liquid brine.Type: GrantFiled: May 23, 2017Date of Patent: April 2, 2019Assignee: ECOLAB USA INC.Inventor: Jasbir S. Gill
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Patent number: 10238108Abstract: Methods and compositions for biofilm remediation are disclosed. Biofilm is reduced and removed from soiled surfaces by providing to a surface in need an effective amount of a composition comprising a biocidal surfactant and at least one organic solvent. According to the invention, the biofilm remediation compositions reduce and remove biofilm formation by administering a one-step cleaner and disinfectant. The biofilm remediation compositions are stable and effective in concentrated and diluted ready-to-use formulations comprising an anionic sulfated or sulfonated surfactant that is not an organocarboxylic acid, a sparingly soluble organic solvent and optionally a soluble organic solvent.Type: GrantFiled: August 23, 2018Date of Patent: March 26, 2019Assignee: Ecolab USA Inc.Inventors: Gregory G. Griese, Mark Levitt, Richard K. Staub, Stefanie Gilbreth
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Patent number: 10240081Abstract: Disclosed herein are crosslinker compositions for aqueous hydroxyl functional polymers. The compositions include at least one borate species, about 0.05 wt % to 10 wt % of a synthetic layered silicate, and a water source. The compositions are characterized by shelf stability, wherein the sparingly soluble borate does not undergo sedimentation. The crosslinker compositions are usefully added to aqueous polymer solutions of hydroxyl functional polymers to form injectable compositions for hydraulic fracturing.Type: GrantFiled: May 11, 2016Date of Patent: March 26, 2019Assignee: Ecolab USA Inc.Inventors: Olga Shchepelina, Houston Perry, Pious Kurian
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Patent number: 10233407Abstract: The invention includes a method of conditioning fabrics, comprising contacting fabric with a liquid composition comprising an amino-functional silicone and a quaternary ammonium, and drying said fabric at 200 degrees F. or greater. The invention includes a method of conditioning fabrics, comprising washing fabric in a detergent having a wash pH of greater than 10, contacting fabric with a liquid composition comprising an amino-functional silicone and a quaternary ammonium, and drying said fabric at less than 200 degrees F. The invention further provides a method of conditioning fabrics wherein softness, anti-static, and anti-wrinkle properties are imparted to the fabric wherein the conditioned fabric resists yellowing in industrial and institutional conditions wherein the wash pH is greater than 9 and/or the fabric temperature is 200 degrees Fahrenheit or greater.Type: GrantFiled: December 19, 2016Date of Patent: March 19, 2019Assignee: Ecolab USA Inc.Inventors: Charles A. Hodge, Julio R. Panama, Amanda R. Blattner, Nicholas Popp, David W. Gohl
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Patent number: 10233149Abstract: The present invention relates generally to methods for forming peroxyformic acid, comprising contacting formic acid with hydrogen peroxide. The methods for forming peroxyformic acid can include adding formic acid with a relatively lower concentration of hydrogen peroxide, or adding formic acid to a peroxycarboxylic acid composition or forming composition to react with hydrogen peroxide in the compositions. The present invention also relates to peroxyformic acid formed by the above methods. The present invention further relates to the uses of peroxyformic acid for treating a variety of targets, e.g., target water, including target water used in connection with oil- and gas-field operations. The present invention further relates to methods for reducing or removing H2S or iron sulfide in the treated water source, improving clarity of the treated water source, or reducing the total dissolved oxygen or corrosion in the treated water source, using peroxyformic acid, including peroxyformic acid generated in situ.Type: GrantFiled: October 11, 2017Date of Patent: March 19, 2019Assignee: ECOLAB USA INC.Inventors: Ramakrishnan Balasubramanian, Junzhong Li, Richard Staub, Victor Keasler, Brian Bennett, Allison Brewster
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Patent number: 10233273Abstract: Disclosed herein are graphene quantum dot tagged paraffin suppressants such as graphene tagged paraffin inhibitors and paraffin dispersants and methods of making and using thereof. The graphene quantum dots are covalently bound to residues of paraffin inhibitors or dispersed with paraffin dispersants to form tagged paraffin suppressants active in inhibiting paraffin crystallization or dispersing crystalized paraffin wax in crude oils and compositions comprising crude oils. The dots can be tailored to fluoresce at wavelengths with minimized correspondence to the natural fluorescence of crude oils, enabling the measurement of the concentration of the paraffin suppressants in crude oils or compositions comprising crude oils.Type: GrantFiled: June 8, 2017Date of Patent: March 19, 2019Assignee: Ecolab USA Inc.Inventors: Kousik Kundu, Jeremy Moloney
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Patent number: 10227731Abstract: The present disclosure provides for a method of preparing and using an emulsion for treating a papermaking process. The emulsion is an oil-in-water emulsion of alkenyl succinic anhydride emulsified with a polymer comprising at least one primary or secondary amine containing monomer. The method comprises adding an oil-in-water emulsion to the papermaking process; wherein the oil-in-water emulsion comprises alkenyl succinic anhydride emulsified with a polymer comprising at least one primary or secondary amine containing monomer; and wherein the oil-in-water emulsion is added in an amount sufficient to improve sizing of the paper produced by the papermaking process. The primary or secondary amine may be a secondary amine comprising diallylamine, and the polymer may be a diallylamine-acrylamide copolymer.Type: GrantFiled: April 12, 2017Date of Patent: March 12, 2019Assignee: Ecolab USA Inc.Inventors: Michael R. St. John, David J. Castro, Mei Liu
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Patent number: 10227549Abstract: A detergent emulsifier for laundry and other hard surface cleaning using an APE-free surfactant blend is disclosed. The emulsifier system is efficacious for removal of oily soils and greasy food removal. The compositions according to the invention include linear and branched fatty alcohol ethoxylates and ethoxylate propoxylate block copolymers. Methods of using the same are disclosed.Type: GrantFiled: December 9, 2016Date of Patent: March 12, 2019Assignee: Ecolab USA Inc.Inventors: Sukhwan Soontravanich, Stephen Hubig, Yang Zhang
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Patent number: 10227238Abstract: A method of preparing a particulate material comprising the steps of adding silicic acid solution, optionally doped with aluminum, optionally added to a slurry of pre-existing nanoparticles at a neutral to slightly acidic pH of no more than seven, and at a temperature of about 20° to 30° C. This yields a polysilicate particulate dispersion. Then, the pH of the dispersion is raised to greater than seven, to stabilize/reinforce particles of the particulate dispersion. Optionally, the particles may be dried, and have increased porosity and surface area.Type: GrantFiled: April 4, 2006Date of Patent: March 12, 2019Assignee: Ecolab USA Inc.Inventors: Francois Batllo, Brian T. Holland, John M. Krasniewski, Kim M. Long, Michael A. Romba, Sascha Welz, David P. Workman
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Patent number: 10227249Abstract: The present invention relates to mixing apparatus for crushing sludge comprising a motor part in which a rotary shaft is inserted into the motor part and the motor part is rotated, a moving part formed to penetrate the motor part from one side to another side and move a chemical which is flowed through an outside chemical feeder to the another side, and a paddle mounted on the another side of the motor part to rotate based on the rotation of the motor part and spray the chemical.Type: GrantFiled: December 9, 2016Date of Patent: March 12, 2019Assignee: Ecolab USA Inc.Inventors: Seung-Nyung Huh, Jin Nyung Huh
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Patent number: 10227248Abstract: An apparatus for treating slurries, in particular biogenic or industrial slurries, can include at least one treatment rotor which is arranged or can be arranged in the slurry and which rotates or is rotatable about an axis of rotation (R), with treatment elements which project outward, as seen from the axis of rotation (R), and between which interspaces are formed, at least some of the treatment elements having, at—at least one, preferably each—adjacent interspace, in each case at least one treatment edge, preferably at least two treatment edges spaced apart from one another, each of these treatment edges running from the inside outward, as seen from the axis of rotation. Methods for treating slurries are also disclosed, including methods using the apparatus for treating slurries.Type: GrantFiled: January 18, 2016Date of Patent: March 12, 2019Assignee: Ecolab USA Inc.Inventor: Jochen Friedrich Knauer
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Patent number: 10221376Abstract: The invention includes a solid rinse aid that is particularly designed for extrusion solid formation and which is effective for creating spotless surfaces after rinsing. According to the invention, application has identified the critical combination of solid surfactants, coupling agents, hydrotrope, and hardening agents that is acceptable in the extrusion process to create a solid. The hydrotrope includes one or more short-chain alkylbenzene and/or alkyl naphthalene sulfonates. The composition hardens quickly but not so quick as to negatively impact the extrusion process. The compositions may also be used to form pressed or cast solids.Type: GrantFiled: April 18, 2016Date of Patent: March 5, 2019Assignee: Ecolab USA Inc.Inventors: Janel M. Kieffer, Katherine Molinaro, Gary Becker, Tobias Foster, Karina Labusga
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Patent number: 10220421Abstract: Alkaline sprayable aqueous compositions are disclosed. In particular, sprayable alkaline aqueous chlorine compositions including a surfactant system for modifying the viscosity of the composition, are combined with an alkalinity source and a chlorine source. Methods of cleaning having reduced amounts of airborne particulates of the composition during spray applications are also provided according to the invention, namely reduction of airborne particulates having a micron size of 10 or less within a breathing zone of a user of less than or equal to 60 particles/cm3.Type: GrantFiled: March 2, 2017Date of Patent: March 5, 2019Assignee: Ecolab USA Inc.Inventors: Charles Allen Hodge, Christopher Michael McGuirk, Amanda Ruth Blattner, Claire Lucille Notermann
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Publication number: 20190062184Abstract: A composition and method for dispersing sulfur, cleaning sulfur deposits, and minimizing foaming in an aqueous system is disclosed. The method may include adding a first sulfur dispersant to process water containing sulfur and dispersing the sulfur. The first sulfur dispersant may include a C5-C25 alkyl polyglycoside. A second sulfur dispersant may also be added to the process water. The second sulfur dispersant may include a polymer of acrylic acid and 2-acrylamido-2-methylpropane sulfonic acid.Type: ApplicationFiled: August 21, 2018Publication date: February 28, 2019Applicant: ECOLAB USA, Inc.Inventors: Dinesh Mantri, David Rodman, Jasbir S. Gill
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Patent number: 10214679Abstract: A composition including crosslinked expandable polymeric microparticles capable of hydrolysis at or below neutral pH and a method of modifying the permeability to water of a subterranean formation by introducing such compositions into the subterranean formation. This disclosure further relates to compositions and methods for the recovery of hydrocarbon fluids from a subterranean reservoir or formation subjected to CO2 or CO2 Water Alternating Gas flooding at low pH and increases the mobilization and/or recovery rate of hydrocarbon fluids present in the subterranean formations.Type: GrantFiled: July 21, 2015Date of Patent: February 26, 2019Assignee: Ecolab USA Inc.Inventors: Pious V. Kurian, Mingli Wei, Kin-Tai Chang
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Publication number: 20190055502Abstract: A method of cleaning a cooling water system is disclosed. The method may include contacting a cooling tower fill with a composition that may include a surfactant and an additive selected from an oxidizing agent, an acid, and any combination thereof when the cooling water system is off-line. The method may include contacting a deposit in the cooling tower fill with the composition. The oxidizing agent may be hydrogen peroxide, sodium hypochlorite, chlorine dioxide, ozone, sodium hypobromite, sodium or potassium permanganate, or any combination thereof. The surfactant may include a C8-C10 alkyl polyglycoside and a C10-C18 alkyl polyglycoside.Type: ApplicationFiled: August 14, 2018Publication date: February 21, 2019Applicant: ECOLAB USA, Inc.Inventors: Lanhua Hu, Amit Gupta