Patents Assigned to Elf Atochem S.A.
  • Patent number: 5869414
    Abstract: The invention relates to a breathing film constituting a mixture including:(a) at least one thermoplastic elastomer which has polyether blocks;(b) at least one copolymer including ethylene and at least one alkyl (meth)acrylate.They can be used in combination with fabrics or with nonwovens.
    Type: Grant
    Filed: May 27, 1998
    Date of Patent: February 9, 1999
    Assignee: Elf Atochem S.A.
    Inventors: Laurent Fischer, Michel Degrand, Alain Bouilloux, Jean-Claude Jammet, Yves Germain
  • Patent number: 5856598
    Abstract: The invention relates to a dielectric composition including at least one polyarylalkane oligomer of formula: ##STR1## in which n.sub.1 and n.sub.2 =0, 1 or 2, with the proviso that n.sub.1 +n.sub.2 =1 or 2, x=0, 1, 2, 3, 4, 5 or 6 and that the said composition has, in particular, a breakdown voltage increasing with the temperature.
    Type: Grant
    Filed: October 2, 1995
    Date of Patent: January 5, 1999
    Assignee: Elf Atochem S.A.
    Inventors: Noelle Berger, Raymond Commandeur
  • Patent number: 5856019
    Abstract: The process according to the invention consists in bringing the substrate to be coated into contact with a solution of a catalyst of olefin polymerization and in then polymerizing at least one olefin in gaseous phase in the presence of the said substrate. The invention also relates to the use of an item including a coating made of polymer for coming into contact with polyolefin particles, the polymer forming the coating including chain sequences of formula --CH.sub.2 --CHR--.
    Type: Grant
    Filed: December 29, 1995
    Date of Patent: January 5, 1999
    Assignee: Elf Atochem S.A.
    Inventor: Claude Brun
  • Patent number: 5854364
    Abstract: At least one of the monomers is polymerized or copolymerized in bulk, solution, emulsion or suspension, at a temperature which may be as low as 0.degree. C., in the presence of at least one radical-generator compound and at least one metal complex catalyst of formula Ma.sub.a (L).sub.n (M=Cu, Ag or Au; A=Hal, pseudohalogen or carboxylate; L=ligands of M chosen from those of formula ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 =H, C.sub.1 -C.sub.10 alkyl, aromatic or heteroaromatic; Z.sup.1, Z.sup.2 and Z.sup.3 =one of the following: ##STR2## (R.sup.7 to R.sup.18 =H, C.sub.1 -C.sub.10 alkyl, aromatic or heteroaromatic; R.sup.19 and R.sup.20 =H, Hal, C.sub.1 -C.sub.10 alkyl, C.sub.1 -C.sub.10 alkoxy or --(CR.sup.21 R.sup.22)rNR.sup.23 R.sup.24, where R.sup.21, R.sup.22, R.sup.23 and R.sup.24 =H,C.sub.1 -C.sub.10 alkyl, aromatic or heteroaromatic, and r=integer from 1 to 10; it being possible also for not more than two from among Z.sup.1, Z.sup.2 and Z.sup.
    Type: Grant
    Filed: June 27, 1997
    Date of Patent: December 29, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Thierry Senninger, Laurent Sanchez, Vincent Darcos, Dominique Lastecoueres, Jean-Baptiste Verlhac
  • Patent number: 5852141
    Abstract: The present invention relates to a prepolymer for the polymerization of olefins, the said prepolymer achieving a combination of a number of solid catalytic components for the polymerization of olefins. The combination of catalytic components makes it possible to combine two properties within the same polymer, one of the properties being contributed by one of the catalytic components and the other property being contributed by the other catalytic component.
    Type: Grant
    Filed: September 17, 1996
    Date of Patent: December 22, 1998
    Assignee: Elf Atochem S.A.
    Inventor: Jean Malinge
  • Patent number: 5849957
    Abstract: The present invention relates to a process for obtaining isophorone from acetone, characterized in that the operation is carried out (i) in liquid phase in the presence of a magnesium aluminum double oxide of formula Mg.sub.1-x Al.sub.x O.sub.1+x or (ii) either in gaseous or liquid phase in the presence of a catalyst of general formula (I):?(Mg.sup.2+).sub.1-x (Al.sup.3+).sub.x (OH.sup.-).sub.2 !.sup.x+ ?(OH.sup.-).sub.x !.sup.x- (H.sub.2 O).sub.n (I)with 0.20.ltoreq.x.ltoreq.0.33 and n<1.
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: December 15, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Remy Teissier, Jacques Kervennal
  • Patent number: 5846661
    Abstract: The present invention relates to a film (A) consisting of a mixture comprising at least one polyamide and at least one polyolefin, the said film being placed on agricultural land into which a fumigant is injected. According to a first variant, the invention also relates to a film comprising the above layer (A) and a layer (B) consisting essentially of a polyolefin. According to a second variant, the invention also relates to a film comprising the above layer (A) placed between two layers (B). A coextrusion binder may optionally be placed between the layers (A) and (B) in the two variants. The invention also relates to a process for the treatment of soils by fumigation.
    Type: Grant
    Filed: October 7, 1996
    Date of Patent: December 8, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Dominique Basset, Marie-Pierre Corbic-Bellinger, Bruno Echalier
  • Patent number: 5840819
    Abstract: The process for the manufacture of (co)polymer powders by aqueous suspension polymerization of at least one monomer which is polymerizable in suspension is conducted in the presence of at least one free-radical generator as catalyst, of at least one dispersing agent and, in addition, of at least one inhibitor scavenging free radicals of at least one complexing agent.
    Type: Grant
    Filed: April 17, 1997
    Date of Patent: November 24, 1998
    Assignee: Elf Atochem S.A.
    Inventor: Michel Biensan
  • Patent number: 5840807
    Abstract: The invention relates to a packaging comprising a thermoplastic film based on a polymer containing polyamide blocks and polyether blocks, said polymer being permeable to water vapor, to ethylene, to CO.sub.2 and to oxygen, such that the permeability to CO.sub.2 is very much greater than the permeability to oxygen. The invention is particularly useful for making sachets in order to conserve fresh fruit, vegetables or meat.
    Type: Grant
    Filed: December 13, 1996
    Date of Patent: November 24, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Alain Frey, Roland Leroux, Laurent Fischer
  • Patent number: 5837778
    Abstract: A multifunctional anionic polymerization initiator which is in the form of a star-shaped polymer, and which is soluble in a nonpolar medium and is substantially free of residual double bonds. The initiator is denoted by the general formula (PA).sub.a N.sup.n- nLi.sup.+. PA is a polymer block of a vinylaromatic or diene monomer A. The variable "a" is the number of branches in the block PA. N is a crosslinked core comprising no or practically no residual double bonds and has the formula (PMc)(RLi).sub.p. Mc is a monomer containing at least two polymerizable double bonds per molecule. PMc is a crosslinked core of at least one polymerized monomer Mc, containing 3 to 30% of residual double bonds in relation to the initial double bonds originating from the monomer Mc. R is an alkyl, aryl, arylalkyl, alkylaryl, cycloalkyl, or alkenyl. The variable "p" is the number of residual double bonds in PMc which are neutralized by RLi. The variable "n" is the number of anionic sites present in the crosslinked core N.
    Type: Grant
    Filed: September 29, 1997
    Date of Patent: November 17, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Pierre Lutz, Paul Rempp, David Rein, Philippe Heim, Pascal Nicol, Bruno Vuillemin
  • Patent number: 5830975
    Abstract: The invention relates to a mixture in powder form and comprising (i) at least one polyamide and (ii) at least one polymer (A) containing hydroxyl functional groups and compatible with the polyamide. The polymer (A) may be an ethylene/vinyl alcohol copolymer. The mixture may be used to coat metal substrates.
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: November 3, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Eric Perraud, Arnaud Tedoldi, Jean Marc Sage
  • Patent number: 5830983
    Abstract: The invention relates to belts made of thermoplastic polymer (A) and comprising a sufficient amount of a polymer (B) to render them antistatic, the said polymer (B) comprising polyethylene glycol blocks. Use is advantageously made of polymers (A) containing polyamide-6 (PA-6) or polyamide-12 (PA-12) blocks and polytetramethylene glycol blocks and polymers (B) containing PA-6 or PA-12 blocks and polyethylene glycol blocks.
    Type: Grant
    Filed: December 23, 1996
    Date of Patent: November 3, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Patrick Alex, Jun Yamamoto
  • Patent number: 5824238
    Abstract: The present invention relates to firefighting foam concentrates including a protein hydrolysate in association with:(a) at least one fluorinated cotelomer which has a perfluoroalkyl radical and a polymerized chain consisting of units of an anionic hydrophilic monomer and of a nonionic hydrophilic monomer, and(b) at least one fluorinated surface-active agent whose aqueous solution at a concentration 1 g/l has at 20.degree. C. a surface tension lower than 25 mN/m.These film-forming emulsifiers are effective both against hydrocarbon fires and against polar-liquid fires.
    Type: Grant
    Filed: July 26, 1996
    Date of Patent: October 20, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Gilbert Garcia, Pierre Durual
  • Patent number: 5824716
    Abstract: This invention relates to dicyclopentyl-oxyethyl methacrylate acrylic copolymer latices forming photocurable coalesced films and prepared by adding a photoinitiator to the latex, and which are useful for preparing lacquers and paints, particularly for building facades.
    Type: Grant
    Filed: July 19, 1996
    Date of Patent: October 20, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Xavier Coqueret, Pierre Rousseau, Christophe Verge
  • Patent number: 5811500
    Abstract: This process is characterized in that at least one of the said monomers is polymerized or copolymerized in bulk, solution, emulsion or suspension, at a temperature which may be as low as 0.degree. C., in the presence of an initiator system comprising at least one non-peroxy radical-generator compound and at least one catalyst consisting of a metal complex represented by formula Ma.sub.a (L).sub.n in which M represents Rh, Co or Ir; A represents, a halogen or a pseudohalogen; the groups L, which may be identical or different, each represent a ligand which may be a chiral ligand, which is chosen from cyclooctadiene, PRR'R", P(OR) (OR') (OR"), NRR'R", ORR', SRR', SeRR', AsRR'R", SbRR'R", each radical R, R' and R" independently representing an optionally substituted C.sub.1 -C.sub.14 alkyl group or an optionally substituted aromatic group, it being possible for at least two of these ligands to be joined together by one or more divalent radicals; a is an integer such that 1.ltoreq.a.ltoreq.
    Type: Grant
    Filed: June 27, 1997
    Date of Patent: September 22, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Philippe Dubois, Georges Moineau, Philippe Teyssie, Robert Jerome, Thierry Senninger
  • Patent number: 5807916
    Abstract: The process consists in the agglomeration of fine particles of superabsorbent polymer, carried out by introducing an aqueous solution of monomer into a slurry of aqueous polymer dispersed within a hydrocarbon liquid, this introduction being performed directly at the temperature and in conditions of polymerization of the monomer. A superabsorbent product is thus obtained in a very good yield, in the form of aggregates of particles such that the fraction passing through a 100-micron screen is less than 1%.
    Type: Grant
    Filed: April 10, 1996
    Date of Patent: September 15, 1998
    Assignee: Elf Atochem S. A.
    Inventors: Christian Collette, Manuel Hidalgo, Andre Kowalik, Emmanuel Puchois, Shu-Rong Rebre
  • Patent number: 5807796
    Abstract: A laminate is provided comprising a) a non-woven based on fibers obtained from a mixture of a polyolefin and an ethylene copolymer; and (b) a thermoplastic film comprising a thermoplastic polymer and an ethylene copolymer.
    Type: Grant
    Filed: October 17, 1996
    Date of Patent: September 15, 1998
    Assignee: Elf Atochem, S.A.
    Inventors: Michel Degrand, Marie-Noelle Chausset
  • Patent number: 5804681
    Abstract: The present invention relates to thermoplastic polyamides and to thermoplastic elastomers based on polyamide with improved thermomechanical performance. They are obtained by grafting along the polymer chain with alkoxysilanes having at least one unsaturation, and especially vinyltrialkoxysilanes of formula CH.sub.2 .dbd.CH--Si--(OR).sub.3 where R represents an alkyl or an alkoxy-substituted alkyl group. The weight ratio of the silane to polyamide in the grafted polymer is generally between 0.1 and 5%. These grafted polyamides may be crosslinked by hydrolysis in steam at 100.degree. C. or by contact with water. The grafted and optionally crosslinked polyamides may be used for producing molded or extruded articles, such as tubes, jackets, single-layer and multilayer films and complex parts, and powder for coating substrates.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 8, 1998
    Assignee: Elf Atochem S. A.
    Inventor: Patrice Breant
  • Patent number: 5804687
    Abstract: A compound (Ia) or (Ib) is prepared by reacting, in a polar aprotic solvent, a compound (III) with a salt of a carboxylic or dicarboxylic acid (IIa) or (IIb). The reaction may be carried out under pressure, but also at normal atmospheric pressure or in the region of normal atmospheric pressure (especially between 0.10 bar and 2 bars). The product (Ia) or (Ib) formed is, in this latter case, recovered continuously as it is formed. ##STR1## R.sup.1, R.sup.2 =optionally substituted saturated or unsaturated acyclic or cyclic hydrocarbon radicals; R.sup.3 =C.sub.1 -C.sub.10 perhaloalkyl; 0<n.ltoreq.4; X=halogen.The applications of the fluoroalkyl (meth)acrylates obtained are especially: anti-dust or anti-soiling paints for various supports such as exterior coatings and metal furniture; optical fibers; contact lenses; lithography; electrophotography; heat-resistant materials; dental resins.
    Type: Grant
    Filed: January 22, 1996
    Date of Patent: September 8, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Gilles Drivon, Jean-Philippe Gillet, Sophie Suc
  • Patent number: 5801283
    Abstract: The process for the purification of an alkanesulphonyl chloride (ASC) in order to reduce the sulphate content thereof consists in washing the alkanesulphonyl chloride with water or with an aqueous solution of an acid having a pH of between -0.57 and 7 and then in separating the alkanesulphonyl chloride thus purified from the aqueous phase.This purified ASC leads, by total hydrolysis, to alkanesulphonic acid with a low content of sulphuric acid.
    Type: Grant
    Filed: April 24, 1997
    Date of Patent: September 1, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Jean Ollivier, Annie Commarieu