Patents Assigned to Eni S.p.A.it
  • Publication number: 20210351355
    Abstract: There is a conjugated polymer having a derivative of indacen-4-one having general formula (I): wherein: R1 and R2, same or different, are selected from C1-C30 alkyl groups, linear or branched; optionally substituted cycloalkyl groups; optionally substituted aryl groups; optionally substituted heteroaryl groups; C1-C30 alkoxyl groups, linear or branched; R4—O—[CH2—CH2—O]m— polyoxyethylene groups, wherein R4 is selected from C1-C30 alkyl groups, linear or branched, and m is an integer ranging from 1 to 4; —R5—OR6 groups, wherein R5 is selected from C1-C30 alkylene groups, linear or branched, and R6 represents a hydrogen atom or is selected from C1-C30 alkyl groups, linear or branched, or is selected from R4—[—OCH2—CH2—]p— polyoxyethylene groups, wherein R4 has the same meanings as reported above and p is an integer ranging from 1 to 4; —COR7 groups, wherein R7 is selected from C1-C30 alkyl groups, linear or branched; —COOR8 groups, wherein R8 is selected from C1-C30 alkyl groups, linear or branched; or t
    Type: Application
    Filed: September 18, 2019
    Publication date: November 11, 2021
    Applicant: ENI S.P.A.
    Inventor: Gabriele Bianchi
  • Patent number: 11162118
    Abstract: Process for the production of lipids from biomass including at least one polysaccharide comprising: —subjecting said biomass to hydrolysis to obtain a mixture comprising a first solid phase and a first aqueous phase; —preparing an inoculum comprising at least one oleaginous microorganism in a first fermentation device to obtain a first fermentation broth; —feeding said first aqueous phase and said first fermentation broth to a second fermentation device to obtain a second fermentation broth; —subjecting at least a portion of said second fermentation broth to microfiltration to obtain a first retentate and a first permeate; —feeding said first retentate to said second fermentation device; —subjecting said first permeate to a purification treatment to obtain a second permeate and a second retentate; —feeding said second retentate to said second fermentation device; —at the end of said fermentation, subjecting said second fermentation broth to separation to obtain an aqueous suspension of oleaginous cellular bio
    Type: Grant
    Filed: April 22, 2015
    Date of Patent: November 2, 2021
    Assignee: Eni S.P.A.
    Inventors: Roberta Miglio, Daniela Cucchetti, Valentina Rodighiero
  • Patent number: 11158753
    Abstract: Photovoltaic panel (or solar panel) comprising: at least one luminescent solar concentrator (LSC) having an upper surface, a lower surface and one or more outer sides; at least one photovoltaic cell (or solar cell) placed on the outside of at least one of the outer sides or on the outside of at least one part of the lower surface of said luminescent solar concentrator (LSC); at least one rigid or semi-rigid support placed on the outside of said at least one photovoltaic cell (or solar cell), said at least one rigid or semi-rigid support being placed in direct contact with said at least one photovoltaic cell (or solar cell); at least one transparent frame placed outside said at least one rigid or semi-rigid support, said at least one transparent frame being placed in direct contact with said at least one rigid or semi-rigid support; optionally, at least one transparent protective shell placed between said at least one transparent frame and said at least one rigid or semi-rigid support, said at least one tra
    Type: Grant
    Filed: May 2, 2018
    Date of Patent: October 26, 2021
    Assignee: ENI S.P.A.
    Inventors: Daniele Testa, Lino Carnelli, Luca Panzeri
  • Patent number: 11149210
    Abstract: The present invention relates to a method for the physical separation of solids and asphaltenes with a conversion degree higher than or equal to 90%, present in refinery purge streams. Said method provides for heating a refinery purge stream to a temperature higher than or equal to 185° C. and not exceeding 220° C. and, subsequently, subjecting said heated purge to sedimentation by progressively lowering the temperature in a controlled manner to a minimum temperature of 100° C., without stirring the purge, so as to form a light phase and a heavy phase defined in relation to the density.
    Type: Grant
    Filed: March 29, 2018
    Date of Patent: October 19, 2021
    Assignee: ENI S.P.A.
    Inventors: Alberto Landoni, Stefania Guidetti, Giuseppe Belmonte
  • Publication number: 20210320262
    Abstract: Luminescent solar concentrator (LSC) having at least one dithienylpyridinethiadiazole compound having general formula (I) or (II): Said luminescent solar concentrator (LSC) can be advantageously used in the construction of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), both on rigid support, and on flexible support.
    Type: Application
    Filed: December 20, 2019
    Publication date: October 14, 2021
    Applicant: ENI S.P.A.
    Inventors: Luigi Abbondanza, Antonio Alfonso Proto, Giuliana Schimperna
  • Patent number: 11130846
    Abstract: The present invention relates to an aqueous emulsion comprising: a) from 50% to 60% of an organic phase dispersed in an aqueous phase, said organic phase containing a mixture including from 24% to 30%, calculated with respect to the final emulsion, of ethylene-vinyl acetate copolymers and/or polyalkyl(meth)acrylates, indicated in the present description as polymeric component, and a high-boiling organic solvent, or a mixture of said solvents; b) a primary emulsifier at a concentration higher or equal to 0.1% and lower than or equal to 3% by weight, calculated with respect to the final emulsion; c) from 37% to 47% of an aqueous phase; wherein the ratio between said polymer component and said organic solvent in the final aqueous emulsion is at least 1/1 and where the organic solvent and any polymer of the polymeric component have a Hildebrand solubility parameter ? such that, the difference (?solvent_?polymer) is lower than 2 in absolute value for any polymer of the polymeric component.
    Type: Grant
    Filed: December 2, 2016
    Date of Patent: September 28, 2021
    Assignees: versalis S.p.A., ENI S.p.A.
    Inventors: Alessandro Casalini, Michela Agnoli, Paolo Mariani, Romano Lima, Massimo Merlini
  • Patent number: 11133474
    Abstract: Disubstituted diaryloxybenzoheterodiazole compound of general formula (1): in which:—Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR5 group in which R5 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups;—R1, R2 and R3 are as defined in the claims. The said disubstituted diaryloxybenzoheterodiazole compound of general formula (I) can advantageously be used as a spectrum converter in luminescent solar concentrators (LSCs) which are in turn capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules) on either a rigid substrate or a flexible substrate.
    Type: Grant
    Filed: September 24, 2015
    Date of Patent: September 28, 2021
    Assignee: Eni S.P.A.
    Inventors: Luigi Abbondanza, Andrea Alessi, Antonio Alfonso Proto, Giuliana Schimperna, Liliana Gila
  • Patent number: 11131171
    Abstract: The present invention relates to a system for facilitating the extraction of hydrocarbons. Tubular protection for an extraction system is provided using the RF heating of highly viscous hydrocarbons in situ by means of an antenna having a coaxial array of mode converters.
    Type: Grant
    Filed: December 1, 2017
    Date of Patent: September 28, 2021
    Assignee: ENI S.P.A.
    Inventors: Sebastiano Burrafato, Alberto Maliardi, Domenico Di Renzo
  • Publication number: 20210292673
    Abstract: There is a process for the production of a liquid fuel and of a gaseous fuel from biomass. The biomass is sent to a pre-treatment section to form a homogeneous phase that can be moved and/or pumped, wherein inert parts are separated from the biomass and the biomass shredded and/or ground to reduce its size. The homogeneous phase obtained is then subjected to subcritical hydrothermal liquefaction at a temperature between 240° C. and 310° C. to form a liquefied phase. The liquefied phase is separated. After separation, the process continues in two alternative and mutually exclusive modes. In the first mode, the first aqueous phase is subjected to an anaerobic reaction with multiple stages producing biogas; the oily phase is separated into a bio-oil and a solid residue. In the second mode, the separate mixed phase is separated by density or dynamics forming a first aqueous phase, bio-oil and a gaseous phase.
    Type: Application
    Filed: July 31, 2019
    Publication date: September 23, 2021
    Applicant: ENI S.P.A.
    Inventors: Roberta Miglio, Roberto Paglino, Christian Torri, Alisar Kiwan, Daniele Fabbri
  • Patent number: 11118448
    Abstract: A pipe for cableless bidirectional data transmission and continuous circulation of a stabilizing fluid in a well for the extraction of formation fluids includes a hollow tubular body which couples with respective drill or completion pipes; a radial valve associated with the tubular body, the radial valve connectable to a pumping system outside the tubular body; an axial valve associated with the tubular body; a communication module associated with the tubular body that includes at least one metal plate selected from a transmitting metal plate, a receiving metal plate, and a transceiver metal plate; an electronic processing and control unit that processes signals to be transmitted by means of the at least one metal plate or signals received by means of the at least one metal plate; and one or more supply batteries for feeding the metal plates and the electronic processing and control unit.
    Type: Grant
    Filed: October 20, 2017
    Date of Patent: September 14, 2021
    Assignee: ENI S.p.A.
    Inventors: Sebastiano Burrafato, Alberto Maliardi, Axel Turolla
  • Patent number: 11098264
    Abstract: Process for producing lipids and other organic compounds from biomass comprising the following steps: (a) subjecting said biomass to extraction, at room temperature, in the presence of at least one low-boiling point solvent, thereby obtaining a first organic phase comprising lipids and solvent, and a first slurry phase comprising carbohydrates and proteins; (b) subjecting the first organic phase obtained in said step (a) to evaporation of the solvent, obtaining a second organic phase comprising lipids and a third organic phase comprising solvent, which is recycled to said step (a); (c) subjecting the first slurry phase obtained in said step (a) to liquefaction operating at a temperature ranging from 100° C. to 200° C., preferably ranging from 110° C. to 180° C.
    Type: Grant
    Filed: December 1, 2017
    Date of Patent: August 24, 2021
    Assignee: ENI S.P.A.
    Inventor: Mauro Burattini
  • Publication number: 20210253935
    Abstract: The present invention relates to a composition for inhibiting water permeation in an extraction well of a hydrocarbon oil from an underground reservoir which comprises injecting into said reservoir at least one polymerizable composition comprising: at least one hydrophilic monomer, at least one hydrophilic initiator of radical polymerization with thermal activation (hydrophilic initiator), at least one lipophilic initiator of radical polymerization with thermal activation (lipophilic initiator). The present invention also relates to the polymerizable compositions that can be used in said method.
    Type: Application
    Filed: May 3, 2021
    Publication date: August 19, 2021
    Applicant: ENI S.P.A.
    Inventors: Lucilla DEL GAUDIO, Davide MOSCATELLI, Paola ALBONICO
  • Publication number: 20210245210
    Abstract: An apparatus and related process for the internal cleaning of a pipeline includes an interchangeable rotary cleaning head, a motor device coupled to the rotary head, a movement device configured to move the apparatus inside the pipeline, and a remote control system. The combined movement of the rotary head rotation and of the advancing motion of the apparatus inside the pipeline allows the disintegration of the deposits present internally of the pipeline by mechanical action.
    Type: Application
    Filed: June 28, 2019
    Publication date: August 12, 2021
    Applicant: ENI S.P.A.
    Inventors: Riccardo Schiavon, Nicola Buongiorno
  • Patent number: 11078437
    Abstract: Hydrogenated polymers with a radial structure having a core made up of calixarenes of the general formula (I), to the core of which is linked a number P of hydrogenated linear polymer segments selected from: —hydrogenated homopolymers or co-polymers of conjugated dienes; or—hydrogenated co-polymers of said conjugated dienes and monoalkenyl arenes, and—mixtures thereof said formula (I) in which: —R1, R2, R3 and R4 are independently selected from hydrogen; a group containing carbon and hydrogen; a group also containing heteroatoms in addition to carbon and hydrogen; a group also containing silicon in addition to carbon, hydrogen and heteroatoms; —one of the two substituents R5 and R6 is hydrogen, while the other may be hydrogen or alkyl, with a number of carbon atoms between 1 and 6, preferably methyl and ethyl; —n is an integer in the range between 4 and 16.
    Type: Grant
    Filed: January 27, 2020
    Date of Patent: August 3, 2021
    Assignees: Eni S.P.A., Versalis S.P.A.
    Inventors: Marcello Notari, Claudio Cavallo, Alberto Roselli, Alessandro Casnati, Francesco Sansone, Alessandro Burlini
  • Publication number: 20210230358
    Abstract: Thermoplastic copolymer with a high sulphur content comprising sulphur in a quantity higher than or equal to 40% by weight, preferably ranging from 45% by weight to 90% by weight, with respect to the total weight of said thermoplastic copolymer, and at least one monomer having general formula (I) wherein: R1 and R2, equal to or different from each other, represent a hydrogen atom; or they are selected from C1-C20, preferably C1-C15, linear or branched alkyl groups, C2-C20, preferably C2-Ci5, linear or branched alkenyl groups, C2-C20, preferably C2-C15, linear or branched alkylidene groups; or R1 and R2, may optionally be bound to one another so as to form, together with the other atoms to which they are bound, a cycloalkene containing from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally substituted with C1-C20, preferably C1-C15, linear or branched alkyl groups, said cycle optionally containing heteroatoms such as, for example, oxygen, sulphur, nitrogen, silicon, phosphorus, selenium; sai
    Type: Application
    Filed: May 10, 2019
    Publication date: July 29, 2021
    Applicant: ENI S.P.A.
    Inventors: Alberto Renato De Angelis, Marco Guidolin
  • Patent number: 11034882
    Abstract: The present invention relates to a method for inhibiting water permeation in an extraction well of a hydrocarbon oil from an underground reservoir which comprises injecting into said reservoir at least one polymerizable composition comprising: at least one hydrophilic monomer, -at least one hydrophilic initiator of radical polymerization with thermal activation (hydrophilic initiator), at least one lipophilic initiator of radical polymerization with thermal activation (lipophilic initiator). The present invention also relates to the polymerizable compositions that can be used in said method.
    Type: Grant
    Filed: August 22, 2017
    Date of Patent: June 15, 2021
    Assignee: ENI S.P.A.
    Inventors: Lucilla Del Gaudio, Davide Moscatelli, Paola Albonico
  • Patent number: 11028415
    Abstract: A process for the production of lipids from biomass derived from guayule plants comprising: obtaining a hydrolysate comprising 5 carbon atom (C5) sugars from biomass derived from guayule plants, said 5 carbon atom (C5) sugars being present in said hydrolysate in a quantity greater than or equal to 80% by weight, preferably ranging from 85% by weight to 99% by weight, with respect to the total weight of said hydrolysate; feeding said hydrolysate to a fermentation device in the presence of at least one oleaginous yeast to obtain a fermentation broth; at the end of fermentation, subjecting said fermentation broth to separation obtaining an aqueous suspension of oleaginous cellular biomass comprising lipids and an aqueous phase. The lipids thus obtained can be advantageously used in the production of biofuel such as, for example, biodiesel or green diesel that can be used as such, or in mixtures with other fuels, for automotive transport.
    Type: Grant
    Filed: June 26, 2018
    Date of Patent: June 8, 2021
    Assignees: Versalis S.P.A., Eni S.P.A.
    Inventors: Daniela Cucchetti, Ezio Battistel, Chiara Gambaro, Alessandra D'Arminio Monforte
  • Publication number: 20210102731
    Abstract: The present invention relates to a system for a parabolic solar concentrator (SCA) having a substantially continuous reflective surface aiming to maximize the efficiency of the parabolic solar concentrator and of its fabrication method. The system of the present invention allows the fabrication of a low cost parabolic solar concentrator, based on a torsion bar, ribs and a plurality of reflective pieces of sheet metal preferably covered with a reflective film. The parabolic solar concentrator according to a preferred embodiment allows the reduction of surfaces shading the reflective surface. Another advantage is the lack of presence of supporting or movement elements protruding in the concave side of the parabola, not including receiver tube components and supports, thereby increasing the reflection efficiency and solar collection.
    Type: Application
    Filed: April 12, 2019
    Publication date: April 8, 2021
    Applicant: ENI S.P.A.
    Inventors: Claudio Boris Volpato, Lino Carnelli, Giulio Lanza, Marco Morone, Stefano Re Fiorentin
  • Patent number: 10968406
    Abstract: The present invention relates to an apparatus for the hydroconversion of heavy oil products (the fresh load). Said apparatus comprises: a slurry bubble column hydroconversion reactor, which comprises a feed line in which the fresh load and the recirculated slurry phase are conveyed, an inlet line for a hydrogenating stream and an outlet for a reaction effluent through an outlet nozzle; a stripping column at high pressure and high temperature placed downstream of the reactor and directly connected to the reactor head through a pipeline in which the reaction effluent flows; said column having an inlet line for a stripping gas, an inlet for the reactor effluent, a head outlet for steam and an outlet for the slurry phase; lines and means for recirculating the slurry leaving the stripping column; lines and means for taking a drain stream, which has the function of preventing the accumulation of solids in the reactor.
    Type: Grant
    Filed: October 26, 2017
    Date of Patent: April 6, 2021
    Assignee: ENI S.P.A.
    Inventors: Mario Molinari, Susi Bonomi
  • Patent number: 10961497
    Abstract: A method for concentrating, in order to favour the subsequent extraction process of intracellular lipids, a cell suspension containing a biomass of oleaginous yeasts fermented in fermentation broth under conditions that allow the intracellular accumulation of lipids, where the biomass contains significant quantities of mucilaginous material. The method includes: a) cultivating the oleaginous yeasts in a fermentation broth to obtain a cell suspension containing the mucilaginous biomass; b) subjecting the cell suspension obtained from a) to heat treatment, at a temperature between 95° C. and 120° C. and to acid treatment, to obtain a treated cell suspension containing the mucilaginous biomass containing intact oleaginous yeast cells; and c) concentrating the treated cell suspension obtained from b), by removing at least part of the fermentation broth to obtain a concentrated cell suspension.
    Type: Grant
    Filed: August 5, 2016
    Date of Patent: March 30, 2021
    Assignee: ENI S.p.A.
    Inventors: Rossella Bortolo, Daniele Bianchi, Mario Baldassarre