Patents Assigned to ENI
  • Publication number: 20160240713
    Abstract: A luminescent solar concentrator (LSC) comprising at least one tetra-substituted benzoheterodiazole compound having general formula (I): wherein: R1 and R2, equal to or different from each other, are selected from: C6-C40, preferably C6-C20 aryl groups, optionally substituted; C4-C40, preferably C5-C20, heteroaryl groups, optionally substituted; R3 and R4, equal to or different from each other, are selected from: halogen atoms such as, for example, fluorine, chlorine, bromine, iodine, preferably fluorine; linear or branched C1-C30, preferably C1-C20, trihalogenated alkyl groups; C6-C40, preferably C6-C20, aryloxyl groups optionally substituted; linear or branched C1-C30, preferably C1-C20, alkoxyl groups optionally substituted; C4-C40, preferably C5-C20, heteroaryloxyl groups optionally substituted; Z represents a sulfur atom, an oxygen atom or a selenium atom; a NR5 group wherein R5 represents a hydrogen atom, or it is selected from linear or branched C1-C24, preferably C6-C24, alkyl groups, optionally conta
    Type: Application
    Filed: September 30, 2014
    Publication date: August 18, 2016
    Applicant: ENI S.p.A
    Inventors: Samuele SANTARELLI, Antonio Alfonso PROTO
  • Patent number: 9403693
    Abstract: A process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction using distillation and/or stripping treatment, a treatment with at least one inorganic base and a treatment with at least one organic base. This process allows at least a part of the aqueous stream coming from the Fischer-Tropsch reaction to be used as process water in the synthesis gas production plant, subsequently sent to the Fischer-Tropsch plant for the production of hydrocarbons.
    Type: Grant
    Filed: December 16, 2009
    Date of Patent: August 2, 2016
    Assignee: ENI S.p.A.
    Inventors: Lino Carnelli, Roberta Miglio, Roberto Zennaro
  • Publication number: 20160208175
    Abstract: A reactor for Fischer-Tropsch reaction effected in a three-phase system essentially consisting of a gaseous reagent phase, a liquid reacted phase and a solid catalytic phase, wherein the solid catalytic phase is composed of packed bodies encaged in at least one open-cell foam structure with a high thermal conductivity.
    Type: Application
    Filed: September 2, 2014
    Publication date: July 21, 2016
    Applicant: ENI S.p.A
    Inventors: Gianpiero GROPPI, Enrico TRONCONI, Carlo Giorgio VISCONTI, Andrea TASSO, Roberto ZENNARO
  • Patent number: 9387456
    Abstract: Reactor for Fischer-Tropsch reaction which is carried out in a three-phase system essentially consisting of a reacting gaseous phase, a reacted liquid phase and a solid catalytic phase, wherein the solid catalytic phase consists of packed or structured bodies of catalytic material encaged within at least one honeycomb monolithic structure with a high thermal conductivity.
    Type: Grant
    Filed: May 10, 2010
    Date of Patent: July 12, 2016
    Assignee: ENI S.p.A.
    Inventors: Massimo Iovane, Roberto Zennaro, Pio Forzatti, Gianpiero Groppi, Luca Lietti, Enrico Tronconi, Carlo Giorgio Visconti, Stefano Rossini, Elsa Mignone
  • Patent number: 9377336
    Abstract: The present invention relates to an apparatus and method for measuring the flow-rate of different fluids present in a plurality of distinct multiphase streams (C), in transit, each through a respective main flow pipe (2). The apparatus (1) comprises a measuring unit (3) for each pipe (2). Each measuring unit (3) comprises a sampling device (4). Each measuring unit (3) comprises first and second measuring means (5) of the differential pressure type situated downstream of the respective sampling device (4). The apparatus (1) comprises a phase separator (8) associated with the measuring unit (3). The apparatus (1) comprises selection means (18) interposed between the measuring unit (3) and the separator (8) for putting the latter in communication with one of the sampling devices (4) envisaged.
    Type: Grant
    Filed: April 18, 2012
    Date of Patent: June 28, 2016
    Assignee: ENI S.P.A.
    Inventors: Stefano Boschi, Paolo Andreussi
  • Publication number: 20160168530
    Abstract: An integrated system for the cultivation of algae or plants and the production of electric energy, comprising:—at least one luminescent solar concentrator (LSC) in which at least one photovoltaic cell (or solar cell) is positioned on at least one of its outer sides;—at least one cultivation area.
    Type: Application
    Filed: July 24, 2014
    Publication date: June 16, 2016
    Applicant: ENI S.p.A.
    Inventors: Roberta MIGLIO, Stefano PALMERY
  • Patent number: 9367796
    Abstract: A method for predicting the properties of crude oils by the application of neural networks articulated in phases and characterized by determining the T2 NMR relaxation curve of an unknown crude oil and converting it to a logarithmic relaxation curve; selecting the values of the logarithmic relaxation curve lying on a characterization grid; entering the selected values as input data for a multilayer neural network of the back propagation type, trained and optimized by means of genetic algorithms; predicting, by means of the trained and optimized neural network, the physico-chemical factors of the unknown crude oil. The method comprises a training and optimization process of the multilayer neural network of the back propagation type. The method thus defined allows the most representative physico-chemical factors of crude oils to be predicted rapidly and without onerous laboratory structures, or alternatively the distillation curve of crude oils with an acceptable approximation degree.
    Type: Grant
    Filed: October 18, 2012
    Date of Patent: June 14, 2016
    Assignee: ENI S.P.A.
    Inventors: Giuseppe Maddinelli, Silvia Pavoni
  • Patent number: 9353125
    Abstract: Process for the preparation of a benzohetero[1,3]diazole compound disubstituted with heteroaryl groups which comprises reacting at least one benzohetero[1,3]diazole compound disubstituted with at least one heteroaryl compound. Said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can be advantageously used in the construction of luminescent solar concentrators (LSC). Furthermore, said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can be advantageously used in the construction of photovoltaic devices such as, for example, photovoltaic cells, photovoltaic modules, solar cells, solar modules, on both a rigid and flexible support. Said benzohetero[1,3]diazole compound disubstituted with heteroaryl groups can also be advantageously used as a precursor of monomeric units in the preparation of semiconductor polymers.
    Type: Grant
    Filed: August 1, 2012
    Date of Patent: May 31, 2016
    Assignee: ENI S.P.A.
    Inventors: Giuliana Schimperna, Gabriele Bianchi
  • Patent number: 9353128
    Abstract: Disubstituted naphthoheterodiazole compound having general formula (I): wherein: Z represents a heteroatom selected from oxygen (O), sulfur (S), selenium (Se), tellurium (Te), preferably sulfur (S); R1, R2, R3, R4, R5, R6 and R7, equal to or different from each other, represent a hydrogen atom; or they are selected from n-butyl, iso-butyl, sec-butyl, t-butyl. Said disubstituted naphthoheterodiazole compound having general formula (I) can be advantageously used as spectrum converter in luminescent solar concentrators (LSCs), in its turn capable of improving the performances of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid and flexible supports.
    Type: Grant
    Filed: April 11, 2014
    Date of Patent: May 31, 2016
    Assignee: ENI S.p.A.
    Inventors: Andrea Alessi, Samuele Santarelli
  • Patent number: 9353320
    Abstract: A method for producing middle distillates from a feedstock produced by Fischer-Tropsch synthesis and containing oxygenated compounds, including: a) a step of bringing the feedstock into contact with a hydrotreating catalyst allowing the methanation of the CO and CO2 contained in the feedstock or originating from the decomposition of the oxygenated compounds present in the feedstock, b) a step of hydroisomerization/hydrocracking of at least a part of the liquid and gaseous effluent originating from step a), in the presence of a hydroisomerization/hydrocracking catalyst, c) a step of gas/liquid separation of the effluent originating from step b) into a gaseous fraction comprising predominantly hydrogen and a hydroisomerized/hydrocracked liquid fraction, d) a step of fractionation of the liquid fraction separated in step c) to obtain at least one fraction of middle distillate, in which the hydrogen in step a) is obtained from the gaseous fraction separated in step c).
    Type: Grant
    Filed: April 11, 2013
    Date of Patent: May 31, 2016
    Assignees: IFP Energies Nouvelles, ENI S.p.A.
    Inventors: Aline Grezaud, Jean Philippe Heraud, Hugues Dulot, Christophe Bouchy, Vincenzo Calemma
  • Patent number: 9334450
    Abstract: A process for the conversion of lignin to liquid hydrocarbons comprising: (1) hydrogenolyzing a lignin in the presence of at least one hydrogenolysis catalyst, at a temperature ranging from 250° C. to 350° C., preferably ranging from 290° C. to 320° C., to obtain depolymerized lignin; and (2) hydrodeoxygenating said depolymerized lignin in the presence of a hydrodeoxygenating catalyst to obtain a mixture of liquid hydrocarbons. The resultant liquid hydrocarbons can be used as such (biofuels) for the production of reformulated gasolines, or they can be used for the production of gasolines or oils by conventional refining processes.
    Type: Grant
    Filed: March 17, 2011
    Date of Patent: May 10, 2016
    Assignee: ENI S.p.A.
    Inventors: Daniele Delledonne, Roberto Buzzoni, Daniele Bianchi
  • Patent number: 9329299
    Abstract: A detection system of geological formations, particularly but not exclusively used for oil exploration, and for characterization and monitoring of hydrocarbon reservoirs. The detection system includes an electromagnetic transmission device positioned on a surface of a geological formation close to a first well having a vertical development direction, the first well being covered by a metal casing, and an electromagnetic reception device positioned deep inside the first well, the electromagnetic reception device including an electromagnetic detector. The electromagnetic transmission device includes a primary electromagnetic field generator configured to generate a primary electromagnetic field focalized in a direction of the metal casing, the metal casing irradiating the primary electromagnetic field into the geological formation.
    Type: Grant
    Filed: February 15, 2012
    Date of Patent: May 3, 2016
    Assignee: ENI S.p.A.
    Inventors: Paolo Dell'Aversana, Massimo Zampato
  • Patent number: 9328109
    Abstract: Process for the preparation of a benzohetero-[1,3]diazole compound disubstituted with brominated heteroaryl groups which comprises reacting at least one dihalogenated benzohetero[1,3]diazole compound with at least one brominated heteroaryl compound. Said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of compounds useful in the construction of solar concentrators (LSCs—“Luminescent Solar Concentrators”). Furthermore, said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of photoactive polymers useful in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid or flexible supports.
    Type: Grant
    Filed: January 13, 2014
    Date of Patent: May 3, 2016
    Assignee: ENI S.p.A.
    Inventors: Gabriele Bianchi, Riccardo Po'
  • Patent number: 9315516
    Abstract: Compound comprising a benzoetherodiazole group of formula (I) and at least one benzodithiophene group or a mixture of compounds comprising a benzoetherodiazole group and at least one benzodithiophene group of formulae (II) and (III). Both said compound and said mixture of compounds can be advantageously used as spectrum converters in luminescent solar concentrators (LSCs), capable, in their turn, of enhancing the performances of solar devices (i.e. devices for exploiting solar energy) such as, for example, photovoltaic cells, photoelectrolytic cells.
    Type: Grant
    Filed: December 20, 2012
    Date of Patent: April 19, 2016
    Assignee: ENI S.P.A.
    Inventors: Roberto Fusco, Paolo Biagini, Stefano Maiorana, Emanuela Licandro
  • Publication number: 20160101410
    Abstract: New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) Xa Yb Zc Od.
    Type: Application
    Filed: December 15, 2015
    Publication date: April 14, 2016
    Applicant: ENI S.p.A.
    Inventors: Giuseppe BELLUSSI, Angela CARATI, Maria Federica GAGLIARDI, Stefano ZANARDI, Marcello MARELLA, Roberto SCATTOLIN, Michele TOMASELLE
  • Publication number: 20160102519
    Abstract: The emergency valve assembly (5) for extraction wells according to the invention comprises A) an external housing (50) and B) a rotating stopper (54). The pass-through duct (52) is arranged for the passage of a production and/or drilling line arranged for containing and carrying, through at least one relative pipe (9), extraction fluids such as, for example, petroleum, oil, water, sludge, rock debris and/or earth, natural gas, or other fluids extracted from an underground reservoir. The valve (5) also comprises a stopper drive (56), arranged for actuating the rotating stopper (54) making it rotate so as to shear the production or perforation line passing through it, in particular shearing the pipe (9) and closing the pass-through duct (52). The pass-through duct (52, 520) has a minimum passage section having a diameter equal to or greater than seven inches. It provides an effective additional safety measure in the case of emergencies.
    Type: Application
    Filed: May 23, 2014
    Publication date: April 14, 2016
    Applicant: ENI S.P.A.
    Inventor: Claudio MOLASCHI
  • Publication number: 20160090371
    Abstract: Compound containing a pentalene unit having general formula (I) wherein R1 and R2, equal to or different from each other, are selected from: linear or branched C1-C20, preferably C2-C12, alkyl groups, saturated or unsaturated, optionally containing heteroatoms, cycloalkyl groups optionally substituted, linear or branched C1-C20, preferably C2-C12, alkoxyl groups, saturated or unsaturated, optionally substituted; or the groups R1 and R2 can be optionally bound to each other so as to form, together with the carbon atoms to which they are bound, a cycle or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; R3 is selected from aryl groups optionally substituted, heteroaryl groups optionally substituted; n is 0 or 1; with the proviso that: when n is 0, X represents a covalent bond and Y represents a sulfur atom
    Type: Application
    Filed: July 22, 2014
    Publication date: March 31, 2016
    Applicant: ENI S.P.A.
    Inventors: Gabriele BIANCHI, Giuliana SCHIMPERNA
  • Patent number: 9296628
    Abstract: Process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction which comprises feeding said aqueous stream to one or more pervaporation units obtaining an aqueous stream enriched in oxygenated organic compounds (retentate side) and an aqueous stream enriched in water (permeate side), feeding said aqueous stream enriched in oxygenated organic compounds to a saturator obtaining a gaseous stream leaving the saturator, feeding said gaseous stream to a synthesis gas production plant. Said process allows at least a part of the aqueous stream coming from the Fischer-Tropsch reaction to be used as process water in a synthesis gas production plant, subsequently sent to a Fischer-Tropsch plant for the production of hydrocarbons.
    Type: Grant
    Filed: April 22, 2010
    Date of Patent: March 29, 2016
    Assignee: ENI S.p.A.
    Inventors: Roberta Miglio, Palma Pizzocchi, Oliviero Perotti, Ines Perotti, Serafino Tonani
  • Publication number: 20160087133
    Abstract: Light concentration device comprising: —a primary luminescent solar concentrator (LSC) having a polygonal, circular or elliptic form, comprising at least one photoluminescent compound having a first absorption range and a first emission range; —at least a secondary luminescent solar concentrator (LSC) positioned outside said primary luminescent solar concentrator (LSC), said secondary luminescent solar concentrator (LSC) comprising at least one photoluminescent compound having a second absorption range superimposable to said first emission range and a second emission range. Said light concentration device can be advantageously used in photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photoelectrolytic cells. Said light concentration device can also be advantageously used in photovoltaic windows.
    Type: Application
    Filed: June 25, 2014
    Publication date: March 24, 2016
    Applicant: ENI S.P.A.
    Inventors: Roberto FUSCO, Marco LISCIDINI, Sthy Warren FLORES DAORTA, Lucio ANDREANI
  • Patent number: 9290699
    Abstract: The present invention concerns a process for the synthesis of hydrocarbons from a feed comprising synthesis gas, in which a solid catalyst comprising cobalt is used in a three-phase reaction section operated such that said catalyst is maintained in suspension in a liquid phase by movement of a gas phase from the bottom to the top of said reaction section, said process comprising an external loop for separating waxes, characterized in that: 1) the theoretical ratio PH2O:PH2 in the external loop for separating waxes is determined using the following calculation: PH2O:PH2 theoretical=Cv/(R1?Rft×Cv) where Cv=(COinlet?COdegas)/COinlet R1=H2 inlet/COinlet Rft=(H2 inlet?H2 degas)/(COinlet?COdegas) 2) if the theoretical ratio PH2O:PH2 determined in step 1) has a value of Rthreshold or higher, the temperature in the degassing means for the external loop for separating waxes is reduced, 3) steps 1) to 2) are repeated until the theoretical ratio PH2O:PH2 has a value strictly less than Rthreshold, where Rthreshold
    Type: Grant
    Filed: April 10, 2013
    Date of Patent: March 22, 2016
    Assignees: ENI S.P.A., IFP ENERGIES NOUVELLES
    Inventors: Jean Philippe Heraud, Jean Christophe Viguie, Sebastien Boucher, Chiara Della Torre, Elsa Mignone