Patents Assigned to ENI
  • Patent number: 9289725
    Abstract: Process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction which comprises: feeding said aqueous stream containing the organic by products of the reaction to one or more pervaporation units, said one or more pervaporation units comprising at least one polymeric pervaporation membrane, obtaining two outgoing streams: —an aqueous stream (i) enriched in alcohols having from 1 to 8 carbon atoms, preferably from 2 to 4 carbon atoms; —an aqueous stream (ii) enriched in water.
    Type: Grant
    Filed: August 7, 2009
    Date of Patent: March 22, 2016
    Assignee: ENI S.p.A.
    Inventors: Roberta Miglio, Lino Carnelli, Gabriele Carlo Ettore Clerici, Roberto Zennaro
  • Patent number: 9290483
    Abstract: Monomers having formula (I) and process for their synthesis which comprises the etherification reaction of a halogen-derivative (Z?Cl, Br, I) having formula (III) with the hydroxyl group of the glycerol derivative (IV), according to the following scheme:(Formula III, IV & I) (III) (IV) (I)
    Type: Grant
    Filed: April 29, 2011
    Date of Patent: March 22, 2016
    Assignee: ENI S.p.A.
    Inventors: Giuliana Schimperna, Riccardo Po', Andrea Pellegrino, Maria Caldararo
  • Patent number: 9289700
    Abstract: The present invention relates to an apparatus (1) for the coalescence-separation of a mixture comprising two fluid phases mutually immiscible other and with a different specific density, characterized in that it comprises a tubular body (2) closed at opposite ends, of which, considering the apparatus in the configuration of use, one is higher than the other, at least one inlet mouth (5) of the mixture to be separated which is defined on the side surface of the tubular body (2), at least one outlet mouth (6) of the fluid phase with a lower specific density separated from the mixture which is defined close to the end of the tubular body at an upper height, at least one outlet mouth (7) of the fluid phase with a greater specific density separated from the mixture which is defined close to the end of the tubular body at a lower height and at least a set of coalescence plates (8) which is housed inside said tubular body (2), wherein each of the coalescence plates (8) has a flow plate (9) of the mixture which is ti
    Type: Grant
    Filed: December 28, 2011
    Date of Patent: March 22, 2016
    Assignee: ENI S.P.A.
    Inventors: Paolo Andreussi, Domenico Antonio Direnzo
  • Publication number: 20160068760
    Abstract: The process for treating a hydrocarbon-based heavy residue (1), in particular bituminous residues with a high asphaltene content, comprises the following operations: A) bringing the heavy residue to be treated to a temperature within the range of 325-500° C.; B) subjecting the heavy residue to be treated to a substantially adiabatic expansion in an environment at a pressure equal to or lower than about 0.1 bara, and at a temperature equal to or lower than 450° C., so as to separate, from the heavy residue to be treated, a first less volatile fraction (17) having a boiling point at atmospheric pressure equal to or higher than 540° C. and whose solid and/or anhydrous residue prevalently contains asphaltenes insoluble in pentane and/or other residues insoluble in tetrahydrofuran. It allows a more effective flushing, and also to actuate the process in an extremely simple plant and without centrifugations.
    Type: Application
    Filed: April 22, 2013
    Publication date: March 10, 2016
    Applicant: ENI S.p.A.
    Inventors: Giuseppe BELMONTE, Alberto Maria Antonio MALANDRINO, Vincenzo PICCOLO
  • Patent number: 9278339
    Abstract: New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.
    Type: Grant
    Filed: September 23, 2010
    Date of Patent: March 8, 2016
    Assignee: ENI S.p.A.
    Inventors: Giuseppe Bellussi, Angela Carati, Maria Federica Gagliardi, Stefano Zanardi, Marcello Marella, Roberto Scattolin, Michele Tomaselli
  • Patent number: 9273255
    Abstract: Production of middle distillates from a feedstock produced by Fischer-Tropsch synthesis and containing oxygenated compounds: a) catalytic hydrotreating; b) hydroisomerization/hydrocracking at least a part of liquid and gaseous effluent originating from a); c) gas/liquid separation of the stream from b) into a gaseous fraction comprising predominantly hydrogen, a hydroisomerized/hydrocracked organic liquid fraction and an aqueous fraction; d) fractionation of the organic liquid fraction in c) to obtain at least one fraction of middle distillates; and e) catalytic methanation of CO and CO2 on at least a part of said gaseous fraction in c) before hydrotreating a), and/or on at least a part of the liquid and gaseous effluent originating from a) in which the hydrogen in a) is obtained at least partly from the gaseous fraction separated in c).
    Type: Grant
    Filed: April 10, 2013
    Date of Patent: March 1, 2016
    Assignees: ENI S.P.A., IFP ENERGIES NOUVELLES
    Inventors: Jean-Philippe Heraud, Aline Grezaud, Hugues Dulot, Christophe Bouchy, Vincenzo Calemma
  • Patent number: 9267648
    Abstract: A system and method for continuous detection of impacts on pipelines for fluid transportation, particularly on pipelines placed on the seabed. The system includes at least two sensors each installed in correspondence with an end of a section subject to detection of a pipeline. A first sensor of the at least two sensors is configured to detect first acoustic waves, which propagate along a first transmission phase associated with the pipeline, and a second sensor of the at least two sensors is configured to detect second acoustic waves which propagate along a second transmission phase associated with the pipeline. The second acoustic waves have different elastic features with respect to the first acoustic waves.
    Type: Grant
    Filed: September 15, 2010
    Date of Patent: February 23, 2016
    Assignee: ENI S.p.A.
    Inventors: Mauro Gianni Dalmazzone, Gianpietro De Lorenzo, Giuseppe Giunta
  • Patent number: 9257236
    Abstract: Organic dye for a dye-sensitized solar cell (DSSC) comprising at least one electron-acceptor unit and at least one ?-conjugated unit. Said organic dye is particularly useful in a dye-sensitized photoelectric transformation element which, in its turn, can be used in a dye-sensitized solar cell (DSSC).
    Type: Grant
    Filed: April 19, 2013
    Date of Patent: February 9, 2016
    Assignees: Centre National de la Recherche Scientifique, ENI S.P.A.
    Inventors: Paolo Biagini, Dora Demeter, Philippe Leriche, Andrea Pellegrino, Jean Roncali, Giuliana Schimperna
  • Publication number: 20160031864
    Abstract: Monomers having formula (I) and process for their synthesis which comprises the etherification reaction of a halogen-derivative (Z?Cl, Br, I) having formula (III) with the hydroxyl group of the glycerol derivative (IV), according to the following scheme:
    Type: Application
    Filed: October 12, 2015
    Publication date: February 4, 2016
    Applicant: ENI S.p.A.
    Inventors: Giuliana SCHIMPERNA, Riccardo PO', Andrea Pellegrino, Maria Caldararo
  • Publication number: 20160012976
    Abstract: Organic dye for a dye sensitized solar cell (DSSC) comprising at least one substituted pyrrole group. Said organic dye is particularly useful in a dye sensitized photoelectric transformation element which, in its turn, can be used in a dye sensitized solar cell (DSSC).
    Type: Application
    Filed: February 13, 2014
    Publication date: January 14, 2016
    Applicant: ENI S.p.A.
    Inventors: Paolo BIAGINI, Alessandro ABBOTTO, Norberto MANFREDI
  • Publication number: 20160012207
    Abstract: Method for maximizing the reaction volume in a slurry phase reactor by determining the ratio (f) between the height of the foams (Hf) and the height of the reactor (HR) through an algorithm defining the gas hold-up in three zones, a first lower zone in which a bubble regime is established, a second intermediate zone where there can be the presence of foams, a third zone situated in the upper hemispherical part in which the multiphase mixture is accelerated until it reaches outlet conditions, the average gas hold-up being given by the weighted average of each of the three gas hold-ups of the three zones, characterized in that it uses nuclear densimeters positioned inside the reactor at different heights and comprises: measuring, for each nuclear densimeter used, gas density values, relating to different gas and/or slurry velocities, which correspond through said algorithm to calculated gas hold-up values, revealing, with a calculated gas hold-up of less than 40%, the absence of foams at least up to the height
    Type: Application
    Filed: January 22, 2014
    Publication date: January 14, 2016
    Applicant: ENI S.p.A.
    Inventors: Alberto Maria Antonio MALANDRINO, Vincenzo PICCOLO
  • Patent number: 9234221
    Abstract: Process for the production of lipids from biomass comprising polysaccharides. The biomass is subjected to acid hydrolysis to obtain a solid phase and an aqueous phase. The solid phase is subjected to acid or to enzymatic hydrolysis obtaining a further solid phase and a further aqueous phase. The aqueous phases obtained from both hydrolysis steps are subjected to fermentation with an oleaginous yeast. The obtained fermentation broth comprises oleaginous cellular biomass which is subjected to microfiltration for the isolation of lipids. Said lipids can be used in the production of biodiesel or green diesel.
    Type: Grant
    Filed: October 14, 2011
    Date of Patent: January 12, 2016
    Assignee: ENI S.P.A.
    Inventors: Giuliana Franzosi, Francesca Pizza, Daniela Cucchetti, Daniele Bianchi, Concetta Maria Compagno, Silvia Galafassi
  • Publication number: 20150376523
    Abstract: The invention relates to an integrated process for the production of fuel components starting from materials of a biological origin which comprises: (A) transformation of glycerine into an alkoxy-propanediol having formula RO—CH2—CHOH—CH2OH, wherein R is a linear or branched C1-C8 alkyl, (B) transformation of glycerine into 1,2-propanediol CH3—CHOH—CH2OH, (C) dehydration of the 1,2-propanediol obtained in (B) to propionic aldehyde, (D) reaction of part of the propionic aldehyde obtained in (C) with the alkoxy-propanediol having formula RO—CH2—CHOH—CH2OH obtained in (A) to give an acetal having formula (a) wherein R is a linear or branched C1-C8 alkyl, (E) transformation of part of the propionic aldehyde obtained in (C) to a propionate having formula CH3—CH2—COOR?, wherein R? is a linear or branched C1-C8 alkyl. Particular components for gasolines and/or diesel are also described.
    Type: Application
    Filed: February 11, 2014
    Publication date: December 31, 2015
    Applicant: ENI S.p. A.
    Inventors: Giuseppe BELLUSSI, Alberto Renato DE ANGELIS, Giulio ASSANELLI, Paolo POLLESEL
  • Publication number: 20150361790
    Abstract: A method for revealing anomalous discontinuity interfaces in pore pressures in non-drilled geological formations and an implementing system.
    Type: Application
    Filed: January 14, 2014
    Publication date: December 17, 2015
    Applicant: ENI S.p.A.
    Inventors: Paolo FERRARA, Axel TUROLLA, Massimo ZAMPATO
  • Publication number: 20150353841
    Abstract: The invention relates to a method for revamping a conventional refinery of mineral oils into a biorefinery, characterized by a production scheme which allows the treatment of raw materials of a biological origin (vegetable oils, animal fats, exhausted cooking oils) for the production of biofuels, prevalently high-quality biodiesel.
    Type: Application
    Filed: September 4, 2012
    Publication date: December 10, 2015
    Applicant: ENI S.p.A
    Inventors: Giacomo Fernando Rispoli, Claudia Prati, Andrea Amoroso, Paolo Pollesel
  • Publication number: 20150344470
    Abstract: Process for the preparation of a benzohetero-[1,3]diazole compound disubstituted with brominated heteroaryl groups which comprises reacting at least one dihalogenated benzohetero—[1,3]diazole compound with at least one brominated heteroaryl compound. Said benzohetero [1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of compounds useful in the construction of solar concentrators (LSCs—“Luminescent Solar Concentrators”). Furthermore, said benzohetero [1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of photoactive polymers useful in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid or flexible supports.
    Type: Application
    Filed: January 13, 2014
    Publication date: December 3, 2015
    Applicant: ENI S.p.A.
    Inventors: Gabriele BIANCHI, Riccardo PO'
  • Publication number: 20150331007
    Abstract: A method and system are described for the continuous remote monitoring of the position and advance speed of a pig device inside a pipeline suitable for transporting a pressurized fluid, wherein the pipeline consists of a plurality of pipe sections joined to each other by welding.
    Type: Application
    Filed: May 14, 2015
    Publication date: November 19, 2015
    Applicant: ENI S.p.A
    Inventors: Giuseppe GIUNTA, Giancarlo BERNASCONI, Silvio DEL GIUDICE
  • Patent number: 9187972
    Abstract: Method for stopping or at least reducing the uncontrolled release of hydrocarbons, blowout, from a well for the extraction of hydrocarbons, which comprises introducing high-density solids at the bottom of the well, through a suitable line, having a polyhedral, spheroidal, ellipsoidal or paraboloidal form, regular or irregular, possibly coated with swelling polymeric material in contact with the fluids leaving the well, the smallest dimension of said solids being greater than 1 mm and the largest dimension less than 100 mm, so that said solids introduced accumulate by random packing at the bottom of the well, forming a column which totally, or at least partially, blocks the uncontrolled release of said hydrocarbons.
    Type: Grant
    Filed: September 26, 2012
    Date of Patent: November 17, 2015
    Assignee: ENI S.P.A.
    Inventors: Alberto Giulio Di Lullo, Giambattista De Ghetto
  • Patent number: 9188270
    Abstract: Monitoring and analysis method of the conditions of a pipeline, comprising: providing an inspection device (1) in expanded polymeric or elastomeric material comprising at least one measurement instrument (2, 3), said measurement instrument including at least one casing and at least one sensor; introducing said inspection device into the pipeline (5); recovering said inspection device; wherein said casing is made of polymeric or elastomeric material, having a density, measured according to the regulation ASTM D3574, higher than or equal to 30 kg/m3, preferably ranging from 700 to 2,000 kg/m3. Said method allows the continuous registration and storage of useful parameters for revealing defects and/or anomalies inside the pipeline (5) that transports gas and/or liquids, as well as possible variations in the internal diameter of the same.
    Type: Grant
    Filed: July 13, 2011
    Date of Patent: November 17, 2015
    Assignee: ENI S.P.A.
    Inventors: Alberto Giulio Di Lullo, Alessia Poggio, Eliana De Marchi
  • Patent number: 9187584
    Abstract: The present invention relates to photoactive polymers and copolymers of acrylic monomers comprising cycloimide units functionalized with at least one luminescent chromophore group, preferably photoluminescent. The present invention also relates to spectrum converters comprising the above photoactive polymers and copolymers and solar devices comprising said converters.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: November 17, 2015
    Assignee: ENI S.p.A.
    Inventors: Antonio Alfonso Proto, Roberto Fusco, Mario Salvalaggio, Giacomo Ottimofiore