Patents Assigned to Eniricerche S.p.A.
  • Patent number: 5672799
    Abstract: Process for the preparation of cumene by the alkylation of benzene with propylene, catalyzed by zeolite Beta into which certain quantities of suitable alkaline, alkaline-earth or metallic cations have been introduced by ion exchange.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: September 30, 1997
    Assignees: Eniricerche S.p.A., Enichem Synthesis S.p.A.
    Inventors: Carlo Perego, Giannino Pazzuconi, Gianni Girotti, Giuseppe Terzoni
  • Patent number: 5670442
    Abstract: Methane is converted into higher hydrocarbon products by oxidative coupling, by bringing a gaseous mixture containing methane and oxygen into contact with a solid catalyst formed from calcium oxide, magnesium oxide, a lanthanide oxide plus possibly lithium oxide, wherein:the lithium content is between 0 and 0.20 wt %,the calcium/magnesium atomic ratio is between 0.08 and 0.7, andthe (calcium+magnesium)/lanthanide atomic ratio is between 0.8/1 and 8/1, and preferably between 2/1 and 4/1.
    Type: Grant
    Filed: March 8, 1996
    Date of Patent: September 23, 1997
    Assignee: Eniricerche S.p.A.
    Inventors: Giuseppe Fornasari, Giuseppe Bellussi
  • Patent number: 5660730
    Abstract: Process for the inertization of liquid waste, mud and solid waste, containing sulphates and heavy metals, which comprises a neutralization step of the compounds to be treated and an anaerobic reduction step of the sulphate ion to allow the formation of sulphide ions necessary for the process. A consortium of sulphate-reducing bacteria and lactobacilli is used, with whey as a carbon and nitrogen source.
    Type: Grant
    Filed: July 7, 1995
    Date of Patent: August 26, 1997
    Assignee: Eniricerche S.p.A.
    Inventors: Giuseppe Lucchese, Andrea Robertiello, Giuseppe Scolla
  • Patent number: 5659101
    Abstract: A catalytic system to polymerize diolefinic monomers consists of a lanthanide salt, an organometallic compound of a metal belonging to groups I, II and III of the periodic table of elements and an organometallic compound of boron. The polymers obtained are characterized in that they have a high degree of 1,4 chain units and ratio between 1.4-cis/1,4-trans units which can vary as desired, and also a narrow molecular weight distribution.
    Type: Grant
    Filed: August 17, 1995
    Date of Patent: August 19, 1997
    Assignees: Enichem Elastomeri S.r.l., Eniricerche S.p.A.
    Inventors: Paolo Biagini, Gabriele Lugli, Fabio Garbassi, Piero Andreussi
  • Patent number: 5659105
    Abstract: A process for the alkylation of aliphatic hydrocarbons with olefins catalyzed by a silica-based material, characterised in that the surface Si--OH groups of said silica are esterified with a fluoroalkylsulphonic acid of formula CF.sub.3 (CF.sub.2).sub.n SO.sub.3 H, where n is a whole number between 0 and 11, said material having a Hammett acidity Ho.ltoreq.-11.4.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: August 19, 1997
    Assignees: Eniricerche S.p.A., Agip Petroli S.p.A.
    Inventors: Mario Gabriele Clerici, Carlo Perego, Alberto de Angelis, Luciano Montanari
  • Patent number: 5652116
    Abstract: Disclosed is a novel method for the in vivo and in vitro synthesis of modified peptides, using either engineered microorganisms capable of expressing peptide synthetases with modified substrate specificity, or peptide synthetases extracted from said microorganisms.
    Type: Grant
    Filed: July 6, 1994
    Date of Patent: July 29, 1997
    Assignee: Eniricerche S.p.A.
    Inventors: Guido Grandi, Francesca De Ferra, Giuliano Galli, Paola Cosmina
  • Patent number: 5646092
    Abstract: Disclosed is a process for preparing aqueous, clay-based muds, not aggressive to layer clays, which process comprises a first step in which clay is treated with an aqueous solution containing the necessary amount of dispersant to fluidify the mud; a second step, of separation of so treated clay from the aqueous solution containing any not adsorbed dispersant, and finally, a step of re-dispersion of so treated clay in water, in order to formulate the mud.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: July 8, 1997
    Assignees: Agip S.p.A., Eniricerche S.p.A.
    Inventors: Stefano Carminati, Giovanni Burrafato
  • Patent number: 5633421
    Abstract: A process for dehydrogenating light paraffins, in particular C.sub.2 -C.sub.5, to obtain the corresponding light olefins, comprising reacting said paraffins with a catalytic system containing platinum, tin and an alumina support and possibly an element of the lanthanide group in a fluidized bed reactor, where the heat required for the reaction is provided by said catalytic system as sensible heat, operating at a temperature of between 500.degree. and 700.degree. C. and at a pressure of between 1 and 2 kg/cm.sup.2, and regenerating said catalytic system by burning the coke which has deposited on the surface of the catalytic system, said regeneration being conducted in air and/or oxygen, if necessary by increasing the temperature of the catalytic system to a suitable level, followed by reduction of said catalytic system with a reducing agent.
    Type: Grant
    Filed: February 22, 1995
    Date of Patent: May 27, 1997
    Assignees: Eniricerche S.p.A., Snamprogetti S.p.A.
    Inventors: Rodolfo Iezzi, Andrea Bartolini
  • Patent number: 5627119
    Abstract: A catalytic system to polymerize diolefinic monomers consists of a lanthanide salt, an organometallic compound of a metal belonging to groups I, II and III of the periodic table of elements and an organometallic compound of boron. The polymers obtained are characterized in that they have a high degree of 1,4 chain units and ratio between 1.4-cis/1,4-trans units which can vary as desired, and also a narrow molecular weight distribution.
    Type: Grant
    Filed: February 3, 1995
    Date of Patent: May 6, 1997
    Assignees: Encichem Elastomeri S.r.l., Eniricerche S.p.A.
    Inventors: Paolo Biagini, Gabriele Lugli, Fabio Garbassi, Piero Andreussi
  • Patent number: 5625108
    Abstract: An amorphous, micro/mesoporous silica-alumina gel with controlled pore size, having a surface area of at least 500 m.sup.2 /g and with a molar ratio of SiO.sub.2 :Al.sub.2 O.sub.3 of at least 30:1, is prepared by hydrolysing and causing a tetra-alkyl ammonium hydroxide, an aluminum trialkoxide, and a tetra-alkyl orthosilicate to gelate, by operating at a temperature equal to, or higher than, the boiling temperature, under atmospheric pressure, of any alcohols which are developed as a by-product from said hydrolysis reaction, without said alcohols being removed, or being substantially removed, from the reaction media; and the so produced gel being dried and fired. So obtained gel is an active catalyst in hydrocarbon conversion reactions, in particular in light olefin isomerization and oligomerization processes, e.g., in propylene oligomerization processes to yield useful liquid hydrocarbons for gasoline and jet fuel formulation.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: April 29, 1997
    Assignees: Eniricerche S.p.A., AGIP Petroli S.p.A., Enichem Synthesis S.p.A.
    Inventors: Carlo Perego, Stefano Peratello, Roberto Millini
  • Patent number: 5625115
    Abstract: A difunctional catalyst is disclosed which is constituted by:(a) silica particles partially coated with zirconia, acidified by means of the introduction of sulfate moieties,(b) one or more metal(s) from Group VIIIA.The preparation of said catalyst and its use in wax hydroisomerization are disclosed as well.
    Type: Grant
    Filed: January 4, 1996
    Date of Patent: April 29, 1997
    Assignees: Eniricerche S.p.A., AGIP Petroli S.p.A.
    Inventors: Cristina Flego, Laura Zanibelli
  • Patent number: 5622706
    Abstract: The cloning and sequencing of the gene which codes for a new pilinic subunit of Bordetella pertussis are described. The aminoacid sequence of the mature subunit, deduced from its necleotide sequence, is similar but not identical to that of the known pilins 2, 3 and 6. Polypeptides having the aminoacid sequence of the mature pilinic subunit or of regions thereof are particularly useful for the development of synthetic acellular vaccines against pertussis.
    Type: Grant
    Filed: November 4, 1994
    Date of Patent: April 22, 1997
    Assignees: Sclavo S.p.A., Eniricerche S.p.A.
    Inventors: Paola Pedroni, Barbara Riboli, Francesca De Ferra, Guido Grandi, Salvatore Toma, Beatrice Arico, Rino Rappuoli
  • Patent number: 5614139
    Abstract: A process for preparing a composite, continuous-fiber-containing filament which entails:a) unwinding a continuous fiber bundle from a bobbin,b) loosening the fiber bundle, in order to separate the bundle substantially into individual fibers,c) impregnating the individual fibers with a thermoplastic polymer powder, andd) recompacting the fiber bundle and providing a flexible sheltering sheath around the bundle, whereby the fiber bundle is caused to have a substantially elliptical cross-section.
    Type: Grant
    Filed: April 7, 1995
    Date of Patent: March 25, 1997
    Assignees: Eniricerche S.p.A., Enichem S.p.A.
    Inventors: Domingo Cutolo, Erminio Zoppi
  • Patent number: 5610202
    Abstract: A catalyst system for the liquid-phase production of methanol from synthesis gas is described, consisting of:one or more copper compounds;one or more alkoxides of the lanthanum group of formula (R.sub.1 O).sub.x Ln and/or one or more inorganic oxides of the lanthanum and/or aluminium group;one or more alkaline and/or alkaline-earth alkoxides of formula (R.sub.a O).sub.x M,if at least one alkoxide of the lanthanum group is present, then one or more alkoxides of the titanium group of formula (R.sub.t O).sub.x T is present,where R.sub.1, R.sub.a and R.sub.t, which can be the same or different, are C.sub.1 -C.sub.10 alkyl groups,M is the alkaline or alkaline-earth metal,Ln is an element or the lanthanum group,T is an element of the titanium group,x is equal to the valency of the metal or element.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: March 11, 1997
    Assignees: Eniricerche S.p.A., Snamprogetti S.p.A.
    Inventors: Mario Marchionna, Massimo Lami
  • Patent number: 5608134
    Abstract: An improved process for preparing a difunctional catalyst active in the hydroisomerization of long-chain normal paraffins is disclosed, which is constituted by an amorphous silica-alumina gel and one or more metals belonging to Group VIIIA,
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: March 4, 1997
    Assignee: Eniricerche S.p.A.
    Inventors: Carlo Perego, Giuseppe Bellussi, Vincenzo Calemma
  • Patent number: 5602292
    Abstract: Disclosed is an active catalyst in the hydroisomerization of waxes (paraffins), which catalyst is constituted by a carrier of acidic nature, of silica-alumina gel, and one or more metals belonging to Group VIIIA.Also a process for preparing said catalyst is disclosed.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: February 11, 1997
    Assignee: Eniricerche S.p.A.
    Inventors: Carlo Perego, Laura Zanibelli, Cristina Flego, Alberto Del Bianco, Giuseppe Bellussi
  • Patent number: 5597855
    Abstract: Poly(Pentaerythrityl diphosphonate) of formula (I): ##STR1## wherein n is an integer having a value comprised within the range of from 3 to 100.The poly(pentaerythrityl diphosphonate) of formula (I) is useful as a flame retardant additive for thermoplastic polymers.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: January 28, 1997
    Assignee: Eniricerche S.p.A.
    Inventors: William Giroldini, Antonio Rinaldi, Gianluigi Landoni, Neri Carlo
  • Patent number: 5595596
    Abstract: The present invention relates to a cement composition containing water, hydraulic cement, inert products and a foaming agent obtained by reacting ethylene oxide with a substrate deriving from the production of synthetic alcohols by the oxosynthesis of normal-olefins, sulfating the ethoxylate compound thus obtained with sulfuric anhydride and neutralizing the sulfated acid product with a base of an alkaline, earth-alkaline metal or ammonia.The cement composition can optionally contain conventional additives such as stabilizers, set retarders or accelerators and disperding agents suitable for lowering the viscosity of the composition.This cement composition has improved processability characteristics and enables the production of lightweight concretes having greater mechanical resistance and durability and lower thermal conductivity particularly appropriate for the building industry.
    Type: Grant
    Filed: December 29, 1995
    Date of Patent: January 21, 1997
    Assignee: Eniricerche S.p.A.
    Inventors: Armando Marcotullio, Massimo Santori
  • Patent number: 5585002
    Abstract: The present invention relates to a process for treatment of soils polluted by high-boiling organic substances, such as petroleum, polynuclear aromatics and chloro-organic substances, which process uses an extractant with high dissolving power for the pollutant, and which improves the soil-extractant contact thanks to the addition of a minimal amount of a hydrophilic co-solvent.
    Type: Grant
    Filed: November 1, 1995
    Date of Patent: December 17, 1996
    Assignee: Eniricerche S.p.A.
    Inventors: Alessandro Nardella, Raffaello Sisto
  • Patent number: 5578744
    Abstract: A catalytically active gel is described consisting of a silica matrix with uniform porosity, monomodal pore distribution and high surface area, within which one or metal oxides possessing catalytic activity are dispersed. A process for preparing this catalytic gel is also described.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: November 26, 1996
    Assignees: Eniricerche S.p.A., Snamprogetti S.p.A.
    Inventors: Angela Carati, Enrico Davini, Mario G. Clerici, Giuseppe Bellussi