Patents Assigned to Ensyn Renewables, Inc.
  • Patent number: 9951278
    Abstract: Processes for controlling afterburn in a reheater and loss of entrained solid particles in reheater flue gas are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium comprising combustible solid particles. The spent heat transfer medium is introduced into a fluidizing dense bed. The combustible solid particles of the spent heat transfer medium are combusted forming combustion product flue gas in a dilute phase above the fluidizing dense bed. The combustion product flue gas comprises flue gas and solid particles entrained therein. The solid particles are separated from the combustion product flue gas to form separated solid particles. At least a portion of the separated solid particles are returned to the fluidizing dense bed.
    Type: Grant
    Filed: February 24, 2016
    Date of Patent: April 24, 2018
    Assignee: Ensyn Renewables, Inc.
    Inventors: Paul A. Sechrist, Andrea G. Bozzano
  • Patent number: 9670413
    Abstract: Methods and apparatuses for thermally converting or pyrolyzing biomass are provided. In one embodiment, a method of thermally converting biomass includes introducing the biomass to a reactor feed chamber. The method provides for flowing a low oxygen gas into the reactor feed chamber to purge the reactor feed chamber and biomass of oxygen. The method also includes delivering the purged biomass to a thermal conversion reactor and thermally converting the biomass in the thermal conversion reactor.
    Type: Grant
    Filed: June 28, 2012
    Date of Patent: June 6, 2017
    Assignee: Ensyn Renewables, Inc.
    Inventors: Lance Awender Baird, Barry Freel, Doug Clarke, Gregory Joseph Morin
  • Patent number: 9631145
    Abstract: Processes are provided including quenching a hot vapor stream to improve rapid thermal conversion processes for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production.
    Type: Grant
    Filed: January 9, 2015
    Date of Patent: April 25, 2017
    Assignee: Ensyn Renewables, Inc.
    Inventor: Barry A. Freel
  • Patent number: 9441887
    Abstract: Pyrolysis methods and apparatuses that allow effective heat removal, for example when necessary to achieve a desired throughput or process a desired type of biomass, are disclosed. According to representative methods, the use of a quench medium (e.g., water), either as a primary or a secondary type of heat removal, allows greater control of process temperatures, particularly in the reheater where char, as a solid byproduct of pyrolysis, is combusted. Quench medium may be distributed to one or more locations within the reheater vessel, such as above and/or within a dense phase bed of fluidized particles of a solid heat carrier (e.g., sand) to better control heat removal.
    Type: Grant
    Filed: February 22, 2011
    Date of Patent: September 13, 2016
    Assignee: Ensyn Renewables, Inc.
    Inventors: Sathit Kulprathipanja, Paolo Palmas, Daniel N Myers
  • Patent number: 9422478
    Abstract: Char-handling processes for controlling overall heat balance, ash accumulation, and afterburn in a reheater are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium. The spent heat transfer medium is separated into segregated char and char-depleted spent heat transfer medium. The char-depleted spent heat transfer medium is introduced into a dense bed of heat transfer medium fluidized by a stream of oxygen-containing regeneration gas. All or a portion of the segregated char is combusted in the dense bed using the stream of oxygen-containing regeneration gas. A portion of the segregated char may be exported out of the pyrolysis system to control the overall heat balance and ash accumulation.
    Type: Grant
    Filed: July 8, 2011
    Date of Patent: August 23, 2016
    Assignee: Ensyn Renewables, Inc.
    Inventors: Paolo Palmas, Paul A. Sechrist, Sid Kulprathipanja, Stanley J. Frey, Barry Freel, Daniel N. Myers, Vincenza Myers
  • Patent number: 9422485
    Abstract: The present application generally relates to a method of trading cellulosic-renewable identification numbers by co-processing a renewable fuel oil with a petroleum fraction to form a renewable identification number-compliant fuel, obtaining one or more renewable identification numbers, and transferring the rights of renewable identification numbers.
    Type: Grant
    Filed: September 18, 2014
    Date of Patent: August 23, 2016
    Assignee: Ensyn Renewables, Inc.
    Inventors: Barry A. Freel, Robert G. Graham
  • Patent number: 9410091
    Abstract: The present application generally relates to methods to prepare a fuel from a liquid biomass by first producing the liquid biomass from a solid biomass by a thermal process, and then processing the liquid biomass with a petroleum fraction in the presence of a catalyst.
    Type: Grant
    Filed: September 16, 2014
    Date of Patent: August 9, 2016
    Assignee: Ensyn Renewables, Inc.
    Inventors: Barry A. Freel, Robert G. Graham
  • Patent number: 9347005
    Abstract: Embodiments of methods and apparatuses for rapid thermal processing of carbonaceous material are provided herein. The method comprises the step of contacting a carbonaceous feedstock with heated inorganic heat carrier particles at reaction conditions effective to rapidly pyrolyze the carbonaceous feedstock to form a product stream comprising pygas, pyrolysis oil, and solids. The solids comprise char and cooled inorganic heat carrier particles. The reaction conditions include a reactor pressure of about 70 kPa gauge or greater.
    Type: Grant
    Filed: September 13, 2011
    Date of Patent: May 24, 2016
    Assignee: Ensyn Renewables, Inc.
    Inventors: Sathit Kulprathipanja, Paolo Palmas
  • Patent number: 9127224
    Abstract: The present disclosure generally relates to methods to reduce the external steam supplied to a fluidized catalytic cracker by injecting a stream comprising a water-containing renewable fuel oil into a riser of a fluidized catalytic cracker.
    Type: Grant
    Filed: September 12, 2014
    Date of Patent: September 8, 2015
    Assignee: Ensyn Renewables, Inc.
    Inventors: Barry A. Freel, Robert G. Graham
  • Patent number: 9127223
    Abstract: The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.
    Type: Grant
    Filed: September 8, 2014
    Date of Patent: September 8, 2015
    Assignee: Ensyn Renewables, Inc.
    Inventors: Barry A. Freel, Robert G. Graham
  • Patent number: 9120988
    Abstract: The present application generally relates to methods to increase the gasoline and/or light cycle oil yield of a fluidized catalytic cracker processing a petroleum fraction by injecting a stream comprising a renewable fuel oil into a riser of a fluidized catalytic cracker, and the resulting fuels therefrom.
    Type: Grant
    Filed: September 16, 2014
    Date of Patent: September 1, 2015
    Assignee: Ensyn Renewables, Inc.
    Inventors: Barry A. Freel, Robert G. Graham
  • Patent number: 9120989
    Abstract: The present application generally relates to methods of generating cellulosic-renewable identification numbers by thermally processing a cellulosic biomass to form a renewable fuel oil, and then co-processing the renewable fuel oil with a petroleum fraction in a refinery to form a cellulosic-renewable identification number-compliant fuel.
    Type: Grant
    Filed: September 16, 2014
    Date of Patent: September 1, 2015
    Assignee: Ensyn Renewables, Inc.
    Inventors: Barry A. Freel, Robert G. Graham
  • Patent number: 9120990
    Abstract: The present application generally relates to a system to prepare a fuel from a biomass and a petroleum fraction wherein a renewable fuel oil is obtained via pyrolysis, delivered to the injection point of a refinery system, and then co-processed with a petroleum fraction in the presence of a catalyst.
    Type: Grant
    Filed: September 18, 2014
    Date of Patent: September 1, 2015
    Assignee: Ensyn Renewables, Inc.
    Inventors: Barry A. Freel, Robert G. Graham
  • Patent number: 9109177
    Abstract: The present application generally relates to the introduction of a renewable fuel oil as a feedstock into refinery systems or field upgrading equipment. For example, the present application is directed to methods of introducing a liquid thermally produced from biomass into a petroleum conversion unit; for example, a refinery fluid catalytic cracker (FCC), a coker, a field upgrader system, a hydrocracker, and/or hydrotreating unit; for co-processing with petroleum fractions, petroleum fraction reactants, and/or petroleum fraction feedstocks and the products, e.g., fuels, and uses and value of the products resulting therefrom.
    Type: Grant
    Filed: December 10, 2012
    Date of Patent: August 18, 2015
    Assignee: Ensyn Renewables, Inc.
    Inventors: Barry A. Freel, Robert G. Graham
  • Patent number: 9102890
    Abstract: The present application generally relates to a fluidized catalytic cracking apparatus having one or more ports for injecting a renewable fuel oil for co-processing the renewable fuel oil and a petroleum fraction.
    Type: Grant
    Filed: September 18, 2014
    Date of Patent: August 11, 2015
    Assignee: Ensyn Renewables, Inc.
    Inventors: Barry A. Freel, Robert G. Graham
  • Patent number: 9102888
    Abstract: The present application generally relates to the introduction of a reduced volatility renewable fuel oil as a feedstock and processing it with a petroleum stream in the presence of a catalyst to reduce the generation of waste streams in refinery systems or field upgrading equipment.
    Type: Grant
    Filed: September 12, 2014
    Date of Patent: August 11, 2015
    Assignee: Ensyn Renewables, Inc.
    Inventors: Barry A. Freel, Robert G. Graham
  • Patent number: 9102889
    Abstract: The present application generally relates to a riser quench system comprising a quench line and one or more quench injecting ports for injecting a renewable fuel oil into the riser of a fluidized catalytic cracker co-processing a renewable fuel oil and a petroleum fraction as reactants.
    Type: Grant
    Filed: September 12, 2014
    Date of Patent: August 11, 2015
    Assignee: Ensyn Renewables, Inc.
    Inventors: Barry A. Freel, Robert G. Graham
  • Patent number: 9044727
    Abstract: Embodiments of apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material are provided herein. The apparatus comprises a reheater for containing a fluidized bubbling bed comprising an oxygen-containing gas, inorganic heat carrier particles, and char and for burning the char into ash to form heated inorganic particles. An inorganic particle cooler is in fluid communication with the reheater to receive a first portion of the heated inorganic particles. The inorganic particle cooler is configured to receive a cooling medium for indirect heat exchange with the first portion of the heated inorganic particles to form first partially-cooled heated inorganic particles that are fluidly communicated to the reheater and combined with a second portion of the heated inorganic particles to form second partially-cooled heated inorganic particles. A reactor is in fluid communication with the reheater to receive the second partially-cooled heated inorganic particles.
    Type: Grant
    Filed: September 22, 2011
    Date of Patent: June 2, 2015
    Assignee: Ensyn Renewables, Inc.
    Inventors: Sathit Kulprathipanja, Paolo Palmas
  • Patent number: 8961743
    Abstract: An improved rapid thermal conversion process for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production, is disclosed. In the process, biomass material, e.g., wood, is fed to a conversion system where the biomass material is mixed with an upward stream of hot heat carriers, e.g., sand, that thermally convert the biomass into a hot vapor stream. The hot vapor stream is rapidly quenched with quench media in one or more condensing chambers located downstream of the conversion system. The rapid quenching condenses the vapor stream into liquid product, which is collected from the condensing chambers as a valuable liquid product.
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: February 24, 2015
    Assignee: Ensyn Renewables, Inc.
    Inventor: Barry Freel
  • Publication number: 20140363343
    Abstract: Embodiments of apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material are provided herein. The apparatus comprises a reheater for containing a fluidized bubbling bed comprising an oxygen-containing gas, inorganic heat carrier particles, and char and for burning the char into ash to form heated inorganic particles. An inorganic particle cooler is in fluid communication with the reheater to receive a first portion of the heated inorganic particles. The inorganic particle cooler is configured to receive a cooling medium for indirect heat exchange with the first portion of the heated inorganic particles to form first partially-cooled heated inorganic particles that are fluidly communicated to the reheater and combined with a second portion of the heated inorganic particles to form second partially-cooled heated inorganic particles. A reactor is in fluid communication with the reheater to receive the second partially-cooled heated inorganic particles.
    Type: Application
    Filed: September 14, 2012
    Publication date: December 11, 2014
    Applicant: ENSYN RENEWABLES, INC.
    Inventors: Sathit Kulprathipanja, Paolo Palmas