Abstract: The present disclosure relates to pipes comprising bimodal high molecular weight high density polyethylene which has been extruded in the presence of one or more organic peroxides that are present in an amount ranging from 30 ppm to 200 ppm. The pipe has an improved long-term hydrostatic strength. Also provided are methods for preparing pipes having these characteristics.

Abstract: The present disclosure generally relates to low density compositions useful for making automotive components, such as molded parts, as well as other articles of manufacture; such compositions comprise (a) a polyolefin comprising polypropylene, a propylene-ethylene block copolymer, or combinations thereof, wherein the polyolefin blend is present in an amount ranging from about 53 wt. % to about 65 wt. %, based on a total weight of the composition; (b) a first elastomer, a second elastomer, and an impact-modifying compatibilizer, wherein the combined weight percent of components (b) ranges from about 27 wt. % to about 32 wt. %, based on the total weight of the composition; (c) a filler present in an amount ranging from about 5 wt. % to about 12 wt. %, based on the total weight of the composition; and (d) an additive package present in an amount ranging from about 0.5 wt. % to about 5 wt. %.

Abstract: This disclosure provides for compatibilizer compositions that are useful in compounding polypropylenes and ethylene elastomeric copolymers for injection molding applications. The compatibilizer includes a combination of: Component A of polypropylene homopolymers or polypropylene copolymers containing small amounts of ethylene; and Component B of propylene bipolymers with ethylene and/or other ?-olefin comonomers, the bipolymer having a relatively high proportion of propylene moieties, for example, 50-75% propylene. Compared to known or conventional compatibilizer formulations, the bipolymer Component B is relatively propylene rich and generally can be used in the injection molding composition in lower concentrations.

Abstract: The present disclosure relates to polyolefin-based compositions made from or containing (A) a butene-1 polymer grafted with an unsaturated monomer, (B) a second polyolefin polymer, and (C) an ethylene-propylene elastomer. In some embodiments, the polyolefin-based composition is further made from or contains an additives composition. In additional embodiments, the polyolefin-based composition is made from or contains a heterophasic polypropylene copolymer.

Abstract: The present disclosure relates to adhesive compositions, processes of forming adhesive compositions, and multi-layer films. The processes generally include contacting an olefin monomer with a catalyst system within a polymerization zone to form an olefin based polymer under polymerization conditions sufficient to form the olefin based polymer, the catalyst system including a metal component generally represented by the formula: MRx; wherein M is a transition metal, R is a halogen, an alkoxy, or a hydrocarboxyl group and x is the valence of the transition metal, wherein the catalyst system further includes an internal donor (ID) comprising a C3-C6 cyclic ether; and withdrawing the olefin based polymer from the polymerization zone; and melt blending the olefin based polymer with a graft (polyolefin/elastomer) copolymer to form a polyolefin based adhesive composition, wherein the process is an in-line process.

Abstract: Adhesive compositions, processes of forming adhesive compositions, and multi-layer films are discussed herein. The processes generally include contacting an olefin monomer with a catalyst system within a polymerization zone to form an olefin based polymer under polymerization conditions sufficient to form the olefin based polymer, the catalyst system including a metal component generally represented by the formula: MRx; wherein M is a transition metal, R is a halogen, an alkoxy, or a hydrocarboxyl group and x is the valence of the transition metal, wherein the catalyst system further includes an internal donor (ID) comprising a C3-C6 cyclic ether; and withdrawing the olefin based polymer from the polymerization zone; and melt blending the olefin based polymer with a functionalized polyolefin to form a polyolefin based adhesive composition, wherein the process is an in-line process.

Abstract: The present disclosure provides a polyolefin-based composition suitable for use as adhesives and/or tie-layer adhesive compositions as well as a multi-layered structure made from and/or containing the polyolefin-based composition. The polyolefin-based composition is made from and/or contains (a) a grafted polyolefin composition, (b) a first polymer composition, (c) a polypropylene-containing blend composition, and (d) optionally, an additives composition having one or more additives.

Abstract: The present disclosure provides a filled composition made from and/or containing (A) a first polymer composition made from and/or containing (i) a heterophasic polypropylene copolymer and (ii) a polypropylene blend, and (B) a biofiller composition made from and/or containing a cellulose-based biofiller. The filled composition can additionally be made with and/or contain an elastomeric ethylene copolymer composition. Optionally, the filled composition can further be made with and/or contains a grafted polyolefin composition. The filled composition is useful in making automotive components.

Abstract: Adhesive compositions for styrene polymers are provided. The adhesives are suitable for use as tie-layers in multi-layer films and sheets and comprise a polyolefin base resin, a functionalized polyolefin and a combination of styrene triblock copolymers.

Abstract: The present disclosure provides a filled composition made from and/or containing (A) a first polymer composition made from and/or containing (i) a heterophasic polypropylene copolymer and (ii) a polypropylene blend, and (B) a biofiller composition made from and/or containing a cellulose-based biofiller. The filled composition can additionally be made with and/or contain an elastomeric ethylene copolymer composition. Optionally, the filled composition can further be made with and/or contains a grafted polyolefin composition. The filled composition is useful in making automotive components.

Abstract: The present disclosure provides for a polyolefin-based composition made from or comprising (A) a first polymer composition made from or containing an ethylene polymer grafted with an unsaturated monomer, and (B) a second polymer composition comprising a propylene polymer, wherein the ethylene polymer grafted with an unsaturated monomer is covalently bonded to the propylene polymer. The polymeric composition may be used as a tie-layer adhesive composition.

Abstract: Ethylene separation processes are described herein. The ethylene separation processes generally include introducing a feed stream including ethylene and butene into a de-ethenizer; and separating the ethylene from the butene via fractional distillation within the de-ethenizer to form an overhead stream including separated ethylene and a bottoms stream including separated butene, wherein the de-ethenizer operates at a pressure of less than 350 psig.

Abstract: A tie layer adhesive composition for multilayer structures, wherein the tie layer is composed of a graft polyolefin and a hybrid polyolefin.

Abstract: A polyolefin-based composition made from or containing (A) a first polymer composition made from or containing a polyolefin grafted with an unsaturated monomer, (B) a second polymer composition made from or containing a polyethylene, and (C) a third polymer composition made from or containing (i) a first polyisobutylene and (ii) a second polyisobutylene. The first polyisobutylene has a Viscosity Average Molecular Weight (VAMW1), and the second polyisobutylene has a Viscosity Average Molecular Weight (VAMW2), wherein VAMW1?VAMW2. The polyolefin-based composition is useful as an adhesives or a tie-layer adhesive composition for multi-layered structures. In particular, the composition is useful as an adhesive to bind a metal layer to a dissimilar substrate.

Abstract: A multilayer structure and a method for forming a multilayer structure, the multilayer structure includes: (A) a first polyolefin layer; (B) a styrene polymer layer; (C) a second polyolefin layer; and (D) at least one tie-layer comprising a tie-layer composition. The tie-layer composition includes: (1) 25 to 75 wt. %, based upon the total weight of the tie-layer composition, of a first copolymer, wherein the first copolymer comprises ethylene derived units and units derived from a C4-8 ?-olefin; (2) 5 to 25 wt. %, based upon the total weight of the tie-layer composition, of a polyethylene resin grafted with an ethylenically unsaturated carboxylic acid or acid derivative; (3) 20 to 50 wt. %, based upon the total weight of the tie-layer composition, of a triblock copolymer composition; and (4) optionally, 0.001 to 20 wt. %, based upon the total weight of the tie-layer composition, of a low density polyethylene.

Abstract: The present disclosure provides a polyolefin-based composition made from or containing (A) a first grafted polyolefin composition, (B) a second grafted polyolefin composition made from or containing a first metallocene-catalyzed linear low density polyethylene grafted with an unsaturated monomer, (C) a second metallocene-catalyzed linear low density polyethylene composition, (D) a Ziegler-Natta-catalyzed linear low density polyethylene composition, (E) an elastomeric composition made from or containing (i) an elastomeric ethylene copolymer and (ii) an ethylene-propylene elastomer, and (F) a tackifier composition. Optionally, the polyolefin-based composition may be further made from or contain an additives composition. The polymeric composition is suitable for use as a tie-layer adhesive composition.

Abstract: A polyolefin-based composition made from or containing (A) a first polymer composition made from or containing a polyolefin grafted with an unsaturated monomer, (B) a second polymer composition made from or containing a polyethylene, and (C) a third polymer composition made from or containing (i) a first polyisobutylene and (ii) a second polyisobutylene. The first polyisobutylene has a Viscosity Average Molecular Weight (VAMW1), and the second polyisobutylene has a Viscosity Average Molecular Weight (VAMW2), wherein VAMW1?VAMW2. The polyolefin-based composition is useful as an adhesives or a tie-layer adhesive composition for multi-layered structures. In particular, the composition is useful as an adhesive to bind a metal layer to a dissimilar substrate.

Abstract: The present disclosure provides a polyolefin-based composition suitable for use as adhesives and/or tie-layer adhesive compositions as well as multi-layered structures made from and/or containing the polyolefin-based composition. The polyolefin-based composition is made from and/or contains (a) a grafted polyolefin composition, (b) a linear low density polyethylene composition made from and/or containing metallocene-catalyzed linear low density polyethylene having a melt index from about 2 to about 10 grams per 10 minutes, (c) an elastomer composition made from and/or containing an polyethylene elastomer, (d) a hydrocarbon-based tackifier, and (e) optionally, an additives composition having one or more additives.

Abstract: Embodiments of the present disclosure include methods for producing aromatic products, the methods including separating a crude oil and condensate feed into at least a light naphtha stream, a heavy naphtha stream, and a bottoms stream, reforming at least a portion of the heavy naphtha stream to produce a reformate stream, feeding a cracker feed stream, comprising the light naphtha stream, the bottoms stream, and a reformate extraction raffinate, to an olefins cracker to produce cracker products comprising pyrolysis gasoline, and introducing an extractor feed stream comprising the pyrolysis gasoline and the reformate to an aromatic extraction unit to produce an aromatic product and the reformate extraction raffinate.

Abstract: Embodiments of the present disclosure include methods for producing aromatic products, the methods including separating a crude oil and condensate feed into at least a light naphtha stream, a heavy naphtha stream, and a bottoms stream, reforming at least a portion of the heavy naphtha stream to produce a reformate stream, feeding a cracker feed stream, comprising the light naphtha stream, the bottoms stream, and a reformate extraction raffinate, to an olefins cracker to produce cracker products comprising pyrolysis gasoline, and introducing an extractor feed stream comprising the pyrolysis gasoline and the reformate to an aromatic extraction unit to produce an aromatic product and the reformate extraction raffinate.