Abstract: A process for cracking a heavy hydrocarbon feed comprising a vaporization step, a hydroprocessing step, and a steam cracking step is disclosed. The heavy hydrocarbon feed is passed to a first zone of a vaporization unit to separate a first vapor stream and a first liquid stream. The first liquid stream is passed to a second zone of the vaporization unit and contacted intimately with a counter-current steam to produce a second vapor stream and a second liquid stream. The first vapor stream and the second vapor stream are cracked in the radiant section of the steam cracker to produce a cracked effluent. The second liquid stream is reacted with hydrogen in the presence of a catalyst to produce a hydroprocessed product. A liquid hydroprocessed product is fed to the vaporization unit.
Type:
Grant
Filed:
November 23, 2010
Date of Patent:
February 25, 2014
Assignee:
Equistar Chemicals, LP
Inventors:
Robert S. Bridges, Sellamuthu G. Chellappan
Abstract: A hydrocarbon feed is passed to a first zone of a vaporization unit to separate a first vapor stream and a first liquid stream. The first liquid stream is passed to a second zone of the vaporization unit and contacted with a counter-current steam to produce a second vapor stream and a second liquid stream. The first vapor stream and the second vapor stream are cracked in the radiant section of the steam cracker to produce a cracked effluent. The second liquid stream is catalytically cracked to produce a cracked product. The cracked product is distilled to produce an overhead stream, a light cycle oil, and a heavy cycle oil. The light cycle oil is reacted with hydrogen in the presence of a catalyst to produce a hydrotreated light cycle oil. The hydrotreated light cycle oil and the overhead stream are fed to the vaporization unit.
Abstract: A process for cracking a heavy hydrocarbon feed comprising a vaporization step, a coking step, a hydroprocessing step, and a steam cracking step is disclosed.
Type:
Grant
Filed:
November 23, 2010
Date of Patent:
February 25, 2014
Assignee:
Equistar Chemicals, LP
Inventors:
Robert S. Bridges, Sellamuthu G. Chellappan
Abstract: The present invention is a polyolefin composition, which comprises a thermoplastic olefin polymer and a polyethylene. The thermoplastic olefin polymer (TPO) comprises a polypropylene and an olefin copolymer and is present in an amount of about 10 weight percent to about 50 weight percent; the TPO has a density in the range of about 0.85 g/cm3 to about 0.92 g/cm3 and a flexural modulus of less than about 700 MPa as measured by ISO 178. The polyethylene is either a medium density polyethylene or a high density polyethylene and present in an amount of about 50 weight percent to about 90 weight percent. The polyolefin composition is useful for preparing articles of manufacture such as sheets, roofing membranes, geomembranes, soft skins, drawn tapes, drawn fibers, and drawn filaments.
Abstract: A process of extruding a blend of an irradiated first propylene polymer and a non-irradiated second propylene polymer, where the first propylene polymer comprises a non-phenolic stabilizer. The irradiation of the first propylene polymer extrudate is conducted in a reduced oxygen environment, and the irradiated first propylene polymer and the non-irradiated second propylene polymer are blended at a temperature below their respective melting points. The blend has a viscosity retention of 20 to 35%.
Type:
Application
Filed:
October 2, 2013
Publication date:
January 30, 2014
Applicant:
Equistar Chemicals, LP
Inventors:
Chun Lee, Dinshong Dong, Charles S. Holland, James R. Beren
Abstract: Graft compositions, useful for tie-layer adhesives, are disclosed. The graft compositions comprise the reaction product of a live, grafted polyolefin and an olefin elastomer. The grafted polyolefin is first made by heating a polyolefin and an unsaturated monomer. Further reaction of the live, grafted polyolefin with an olefin elastomer provides the graft composition. Grafting efficiency is boosted dramatically by the presence of the olefin elastomer and use of the additional reaction step. The graft composition, when formulated into a tie-layer adhesive at low concentration, affords multilayer structures with good adhesion and high clarity.
Abstract: Disclosed are polyethylene blends and films. The blend comprises from 1 to 99%, based on the weight of the blend, of a medium density polyethylene (MDPE) and from 1 to 99% a polyolefin selected from the group consisting of high density polyethylene (HDPE), linear low density polyethylene (LLDPE), low density polyethylene (LDPE), polypropylene, polybutene, and mixtures thereof. The MDPE is made by high pressure, free radical polymerization and has a density within the range of greater than 0.928 to 0.940 g/cm3 and an MI2 within the range of 0.1 to 1 dg/min. The shrink films made from the blend have strong contraction force and low creep.
Abstract: Adhesive compositions suitable for use as tie-layer adhesives in multi-layer films and sheets are provided. The adhesive compositions contain an olefin polymer base resin, a modified polyolefin and a paraffinic liquid hydrocarbon.
Abstract: A process of extruding a blend of an irradiated first propylene polymer and a non-irradiated second propylene polymer, where the first propylene polymer comprises a non-phenolic stabilizer. The irradiation of the first propylene polymer extrudate is conducted in a reduced oxygen environment, and the irradiated first propylene polymer and the non-irradiated second propylene polymer are blended at a temperature below their respective melting points. The blend has a viscosity retention of 20 to 35%.
Type:
Grant
Filed:
February 9, 2011
Date of Patent:
November 5, 2013
Assignee:
Equistar Chemicals, LP
Inventors:
Chun Lee, Dinshong Dong, Charles S. Holland, James R. Beren, Anthony J. De Nicola, Jr.
Abstract: Tie-layer adhesives having graft compositions for bonding to metal substrates is disclosed. The graft compositions are made up of the reaction product of a live, grafted polyolefin and an olefin elastomer. The grafted polyolefin is first made by heating a polyolefin and an unsaturated monomer. Further reaction of the live, grafted polyolefin with an olefin elastomer provides the graft composition. Grafting efficiency is boosted dramatically by the presence of the olefin elastomer and use of the additional reaction step. The graft composition, when formulated into a tie-layer adhesive provides improved bonding to metal substrates.
Abstract: The present invention relates to a process comprising extruding a blend of an first propylene polymer comprising a non-phenolic stabilizer and a non-irradiated second propylene polymer, wherein the irradiation of the first propylene polymer was conducted in a reduced oxygen environment, and the irradiated first propylene polymer and the non-irradiated second propylene polymer were blended at a temperature below the melting point of the first and second propylene polymers.
Type:
Grant
Filed:
February 9, 2011
Date of Patent:
October 1, 2013
Assignee:
Equistar Chemicals, LP
Inventors:
Chun Lee, Dinshong Dong, Charles S. Holland, James R. Beren, Anthony J. De Nicola, Jr., Sameer D. Mehta, Vu A. Dang, Richard J. Fezza
Abstract: Disclosed is a method for improving the barrier properties of polyethylene films The method comprises mixing a substantially linear, high density polyethylene with a nucleating agent and converting the mixture into a film The film made by the method of the invention has at least a 15% improvement on the water vapor barrier property and/or in the oxygen barrier property compared with the control film made from the same substantially linear, high density polyethylene but does not contain the nucleating agent.
Type:
Application
Filed:
April 3, 2013
Publication date:
August 29, 2013
Applicant:
Equistar Chemicals, LP
Inventors:
JEFFREY S. BORKE, Douglas C. McFaddin, Stephen M. Imfeld
Abstract: Processes and systems for forming propylene are described herein. The processes generally include reacting a metathesis feed stream including at least 95 wt. % 2-butene with ethylene in the presence of a metathesis catalyst to form a metathesis product stream including propylene, and recovering propylene from the process.
Type:
Application
Filed:
February 22, 2013
Publication date:
July 4, 2013
Applicants:
Equistar Chemicals, LP, Lyondell Chemical Technology, L.P.
Inventors:
Steven T. Coleman, Gary A. Sawyer, Robert S. Bridges, Shaotian Wang, Lawrence M. Candela
Abstract: Resin blends useful for pipe and blow-molded articles are disclosed. The blends comprise a low-molecular-weight, high-density polyethylene and a high-molecular-weight, low-density ethylene copolymer. The high-molecular-weight component is made with a bridged indenoindolyl Group 4 metal complex having open architecture. Blends of the invention uniquely have high molecular weight (Mw>200,000) and low levels of long-chain branching. A quick, convenient approach for estimating levels of long-chain branching in polyethylenes from gel permeation chromatography and dynamic oscillatory rheometry (“viscosity enhancement factor”) is disclosed.
Type:
Grant
Filed:
August 29, 2007
Date of Patent:
July 2, 2013
Assignee:
Equistar Chemicals, LP
Inventors:
Shaotian Wang, Gregory G. Hlatky, Sebastian Joseph, Jean A. Merrick-Mack, Kenneth J. Klug, Wallace W. Yau
Abstract: A process for preparing a polyethylene in a multi-stage process is described. The process comprises pre-treating a Ziegler catalyst in a first stage in the presence of a 1-olefin/ethylene mixture or a 1-olefin to produce a LLDPE or VLDPE, which have the characteristics of a polymer prepared with a single-site catalyst, e.g. high levels of short-chain branching that are uniformly distributed. The contents of the first stage are then transferred to a second stage where an ethylene or an ethylene/1-olefin mixture is polymerized in the presence of the pre-treated catalyst to form a polyethylene with good processability.
Abstract: Disclosed is a method for producing polyethylene films which have high resistance to deformation or elongation under loading in tension. The method comprises orienting in the machine direction (MD) a high density polyethylene film at a draw-down ratio effective to give the film an MD tensile strength at yield greater than or equal to 50,000 psi, wherein the HDPE has a density greater than 0.940 g/cm3.
Abstract: Disclosed is a method for improving the barrier properties of polyethylene films. The method comprises mixing a substantially linear, high density polyethylene with a nucleating agent and converting the mixture into a film. The film made by the method of the invention has at least a 15% improvement on the water vapor barrier property and/or in the oxygen barrier property compared with the control film made from the same substantially linear, high density polyethylene but does not contain the nucleating agent.
Type:
Grant
Filed:
March 14, 2007
Date of Patent:
May 7, 2013
Assignee:
Equistar Chemicals, LP
Inventors:
Jeffrey S. Borke, Douglas C. McFaddin, Stephen M. Imfeld
Abstract: Disclosed is a method for controlling the decanter phase separation of an acetic acid production by methanol carbonylation. The method comprises measuring the methyl acetate concentration of the reactor mixture, calculating the density of the decanter heavy, organic phase according to the measured methyl acetate concentration, and adjusting the conditions in the reactor or in the decanter to ensure phase separation of the decanter.
Type:
Grant
Filed:
July 21, 2010
Date of Patent:
April 30, 2013
Assignee:
Equistar Chemicals, LP
Inventors:
Noel Hallinan, Michael E. Fitzpatrick, John D. Hearn, Miraj S. Patel
Abstract: Compositions suitable for use as adhesives in multi-layer structures. The compositions comprise a blend of an ethylene copolymer of butene and a propylene-based polymer; a polyolefin grafted with an ethylenically unsaturated carboxylic acid or acid derivative; and an olefin polymer resin different than the ethylene copolymer of butene, the propylene-based polymer and the grafted polyolefin.