Patents Assigned to Ethyl Petroleum Additives, Inc.
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Patent number: 5344951Abstract: This invention relates to an improved process for producing diesters of phosphorous acid. The process comprises (a) reacting phosphorous acid with monohydric alcohol in a petroleum distillate solvent while maintaining a reaction mass temperature within the range of from about 130.degree. to about 138.degree. C., and (b) refluxing the reaction mass during the reaction, wherein the phosphorous acid contains about 20 up to about 35 wt. % water, the molar ratio of alcohol to phosphorous acid used is within the range of from about 2.0:1 to about 4.0:1, and water is removed from the reaction mass essentially as it is formed during steps (b) and (c).Type: GrantFiled: March 16, 1993Date of Patent: September 6, 1994Assignee: Ethyl Petroleum Additives, Inc.Inventor: Abbas Kadkhodayan
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Patent number: 5328619Abstract: Haze formation in additive concentrates containing boron-containing ashless dispersants is inhibited, and improvements in performance capabilities can be realized, by suitably controlling the pH of the concentrate as produced. Not only does such pH control result in no sacrifice in wear and corrosion inhibition, but it has been found possible by suitable adjustment and control of pH to actually improve the effectiveness of the concentrate in its ability to inhibit wear and corrosion. Moreover, such pH control makes possible the provision of compositions having enhanced extreme pressure properties as seen in the standard L-42 test, and improved antirust performance as seen in the standard L-33 test.Type: GrantFiled: June 21, 1991Date of Patent: July 12, 1994Assignee: Ethyl Petroleum Additives, Inc.Inventor: Gregory S. Conary
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Patent number: 5326485Abstract: Lubricant and functional fluids, and additive concentrates, are composed of a) at least one overbased zinc dialkyldithiophosphate characterized in that (i) each of the alkyl groups is a primary alkyl group containing from 6 to 10 carbon atoms, (ii) the overbased to neutral ratio of the dithiophosphate is 0.96 or above as determined by .sup.31 P nmr, (iii) the integrated .sup.31 P nmr spectrum of the dithiophosphate shows less than about 0.25 area percent phosphorus at about 80 ppm, (iv) the integrated .sup.31 P nmr spectrum of the dithiophosphate shows essentially no phosphate species at about 5 to about 15 ppm, and (v) the dithiophosphate exhibits a copper weight loss in ASTM Test Method D2619 of 0.Type: GrantFiled: September 10, 1993Date of Patent: July 5, 1994Assignee: Ethyl Petroleum Additives, Inc.Inventors: Michelle M. Cervenka, Marsha J. Lester
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Patent number: 5312555Abstract: A product formed by reacting at least one acyclic hydrocarbyl substituted succinic acylating agent such as polyisobutenyl succinic anhydride with at least one N-(alkoxy-alkyl) alkanediamine such as N-(isodecyloxypropyl)-1,3-diaminopropane is effective as a detergent-dispersant for liquid fuels and oleaginous liquids.Type: GrantFiled: February 16, 1990Date of Patent: May 17, 1994Assignee: Ethyl Petroleum Additives, Inc.Inventor: Dennis J. Malfer
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Patent number: 5279626Abstract: This invention relates to a method for enhancing a fuel additive package so as to improve the shelf-life of the package comprising forming a fuel additive package containing (i) a major amount of detergent/dispersant and (ii) a minor amount of demulsifier; and admixing a solvent stabilizer composition with said additive package in an amount sufficient to improve the shelf-life of the fuel additive package.Type: GrantFiled: June 2, 1992Date of Patent: January 18, 1994Assignee: Ethyl Petroleum Additives Inc.Inventors: Lawrence J. Cunningham, Tim Brennan
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Patent number: 5256324Abstract: Preconditioned automatic transmission fluids are made by using a preblend formed by heating an alkenyl succinimide or succinamide dispersant with a phosphorus ester and water to partially hydrolyze the ester and then mixing the preblend and other additives with a base oil.Type: GrantFiled: September 27, 1991Date of Patent: October 26, 1993Assignee: Ethyl Petroleum Additives, Inc.Inventor: Andrew G. Papay
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Patent number: 5241003Abstract: Succinimides, succinic esters, and succinic ester-amides are formed by (A) reacting (i) at least one substantially aliphatic polymer of at least one lower olefin, and (ii) an acidic reactant or a mixture of two or more acidic reactants represented by the general formulaR--CO--CH.dbd.Type: GrantFiled: June 8, 1992Date of Patent: August 31, 1993Assignee: Ethyl Petroleum Additives, Inc.Inventors: David J. Degonia, Paul G. Griffin
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Patent number: 5225093Abstract: Gear oil additive concentrates and lubricant compositions containing a combination of additives which minimize noise and vibration that occasionally develop in limited slip axles. The additive combinations include (i) an oil-soluble succinimide of the formula ##STR1## wherein R.sub.1 is alkyl or alkenyl having 8 to 50 carbon atoms, and R.sub.2, R.sub.3 and R.sub.4 are hydrogen atoms or alkyl or alkenyl groups having up to about 4 carbon atoms; and (ii) a boronated or non-boronated carboxylic derivative composition produced by reacting a substituted succinic acylating agent with (a) amine having at least one primary or secondary amino group in the molecule, or (b) at least one alcohol, or (c) a combination of (a) and (b). The substituent of the succinic acylating agent is derived from polyalkene having a number average molecular weight of about 500 to about 100,000. The additive concentrates and lubricant compositions are devoid of any metal-containing component.Type: GrantFiled: December 3, 1992Date of Patent: July 6, 1993Assignee: Ethyl Petroleum Additives, Inc.Inventors: Donald G. Campbell, Stephen Norman, Gregory S. Conary
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Patent number: 5215547Abstract: This invention relates to novel hexahydrotriazine compounds, a process for their production and their use as additives for fuels and oleaginous fluids.Type: GrantFiled: September 9, 1991Date of Patent: June 1, 1993Assignee: Ethyl Petroleum Additives, Inc.Inventors: John G. Bostick, Lawrence J. Cunningham
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Patent number: 5208382Abstract: The copper corrosiveness of organic sulfides is reduced by treating them with an alkali metal-containing or alkaline earth metal-containing substance capable of dissolving elemental sulfur (e.g., sodium hydroxide, sodium sulfide, etc.). The process is conducted in the presence of a phase transfer catalyst in an aqueous liquid reaction medium. Experiments have shown that it is possible by use of this process to reduce the copper corrosiveness to a level below that exhibited by a product formed by treating the same initial organic sulfide in the same way but in the absence of a phase transfer catalyst.Type: GrantFiled: January 29, 1992Date of Patent: May 4, 1993Assignee: Ethyl Petroleum Additives, Inc.Inventors: Edmund F. Perozzi, John F. Sieberth
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Patent number: 5198133Abstract: Preconditioned automatic transmission fluids are made by using a preblend formed by heating an alkenyl succinimide or succinamide dispersant with a phosphorus ester and water to partially hydrolyze the ester and then mixing the preblend and other additives with a base oil.Type: GrantFiled: June 22, 1992Date of Patent: March 30, 1993Assignee: Ethyl Petroleum Additives, Inc.Inventor: Andrew G. Papay
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Patent number: 5180510Abstract: An additive for improving the antioxidation properties of lubricating oil is made by reacting a sulfur halide selected from sulfur monochloride or sulfur dichloride with an aliphatic monoolefin (e.g. isobutene) to form an adduct, reacting the adduct thus formed with an alkali metal salt of an organocarbamodithioic acid in an aqueous alkanol medium and recovering the reaction product.When added to lubricating oil, the additive products of the invention improve the antioxidation properties of the lubricating oil.Type: GrantFiled: March 31, 1988Date of Patent: January 19, 1993Assignee: Ethyl Petroleum Additives, Inc.Inventors: Edward F. Zaweski, Scott A. Culley
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Patent number: 5176840Abstract: Gear oil additive concentrates and lubricant compositions containing a combination of additives which minimize noise and vibration that occasionally develop in limited slip axles. The additive combinations include (i) an oil-soluble succinimide of the formula ##STR1## wherein R.sub.1 is alkyl or alkenyl having 8 to 50 carbon atoms, and R.sub.2, R.sub.3 and R.sub.4 are hydrogen atoms or alkyl or alkenyl groups having up to about 4 carbon atoms; and (ii) a boronated or non-boronated carboxylic derivative composition produced by reacting a substituted succinic acylating agent with (a) amine having at least one primary or secondary amino group in the molecule, or (b) at least one alcohol, or (c) a combination of (a) and (b). The substituent of the succinic acylating agent is derived from polyalkene having a number average molecular weight of about 500 to about 100,000. The additive concentrates and lubricant compositions are devoidd of any metal-containing component.Type: GrantFiled: February 16, 1990Date of Patent: January 5, 1993Assignee: Ethyl Petroleum Additives, Inc.Inventors: Donald G. Campbell, Stephen Norman, Gergory S. Conary
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Patent number: 5174915Abstract: There is provided a lubricating oil composition for use in medium speed diesel engines, such as railroad locomotive diesel engines. This lubricating oil composition comprises an oil of lubricating viscosity and a minor amount of a reaction product that is obtained by reacting an alkyl-substituted dicarboxylic acid compound selected from the group consisting of alkyl-substituted dicarboxyic acids, alkyl-substituted dicarboxylic acid anhydrides, and mixtures thereof with a basic salt of aminoguanidine under selected conditions that will provide a product rich in alkyl bis-3-amino-1,2,4-triazole.Type: GrantFiled: November 12, 1991Date of Patent: December 29, 1992Assignee: Ethyl Petroleum Additives, Inc.Inventors: David A. Hutchison, Richard D. Stauffer
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Patent number: 5174922Abstract: The invention provides a process of reducing the copper corrosiveness of dihydrocarbyl polysulfides by treating them with an alkali metal-containing or alkaline earth metal-containing substance capable of dissolving elemental sulfur (e.g., sodium hydroxide, sodium sulfide, etc.). The process is conducted in a liquid reaction medium composed of a mixture of water and at least one water-soluble alcohol. Experiments have shown that it is possible by use of this process to reduce the copper corrosiveness to a level below that exhibited by a product formed by treating the same initial dihydrocarbyl polysulfide in the same way but in a liquid medium composed solely of water.Type: GrantFiled: November 13, 1989Date of Patent: December 29, 1992Assignee: Ethyl Petroleum Additives, Inc.Inventors: Edmund F. Perozzi, Andrew G. Papay
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Patent number: 5166439Abstract: A sulfurized, phenolic antioxidant having a low chlorine content and good copper corrosion properties is prepared by reacting a partially sulfurized mixture of reactive, hindered phenols with formaldehyde or formaldehyde and an amine.Type: GrantFiled: November 24, 1989Date of Patent: November 24, 1992Assignee: Ethyl Petroleum Additives, Inc.Inventors: William Y. Lam, Christian S. Harstick
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Patent number: 5164103Abstract: Preconditioned automatic transmission fluids are made by using a preblend formed by heating an alkenyl succinimide or succinamide dispersant with a phosphorus ester and water to partially hydrolyze the ester and then mixing the preblend and other additives with a base oil.Type: GrantFiled: February 21, 1989Date of Patent: November 17, 1992Assignee: Ethyl Petroleum Additives, Inc.Inventor: Andrew G. Papay
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Patent number: 5164102Abstract: Engine wear and sludge are reduced by using in the engine crankcase a formulated motor oil containing a small amount of the combination of (i) an overbased alkaline earth metal sulfonate having a total base number of at least 100, (ii) a zinc dihydrocarbyl dithiophosphate, (iii) a sulfurized carboxylic acid ester, and (iv) a sulfurized fatty acid amide, ester or ester-amide of an oxyalkylated amine or mixtures thereof.Type: GrantFiled: August 3, 1990Date of Patent: November 17, 1992Assignee: Ethyl Petroleum Additives, Inc.Inventors: Armgard K. Everett, Edmund F. Perozzi
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Patent number: 5154844Abstract: A product formed by heating (A) a mixture of a carboxylic acid ester and a fatty acid oxyalkylated amine derivative selected from fatty acid amides, fatty acid esters, fatty acid ester-amides of such oxyalkylated amine, and mixtures thereof with (B) sulfur or a sulfur source at an elevated temperature at which sulfurization occurs. Such products are effective as oil additives in inhibiting excessive wear and sludge formation. And they possess excellent compatibility with oils of lubricating viscosity, such as mineral oils used as crankcase lubricating oil base stocks.Type: GrantFiled: September 26, 1990Date of Patent: October 13, 1992Assignee: Ethyl Petroleum Additives, Inc.Inventor: Edmund F. Perozzi
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Patent number: 5137978Abstract: Polybutenyl substituted succinic acylating agents are formed by reacting (a) an acidic reactant represented by the general formulaR--CO--CH.dbd.CH--CO--R'wherein R and R' are independently --OH, --O--lower alkyl, a halogen atom, or taken together are a single oxygen atom, with (b) a polymer composed mainly or entirely of polyisobutene, at least 50% of the polyisobutene content of the polymer having an end group represented by the formula ##STR1##The mole ratio o9f acidic reactant: polymer is at least 1:1; and the reaction mixture is maintained under superatmospheric pressure during at least a substantial portion of the reaction period. The reaction rate is high, the yields of desired product are high, and despite the fact that superatmospheric pressures and elevated temperatures are used, the process forms only small amounts of tars or resinous co-products, even when employing as much as a 20% or more molar excess of maleic anhydride.Type: GrantFiled: September 19, 1991Date of Patent: August 11, 1992Assignee: Ethyl Petroleum Additives, Inc.Inventors: David J. Degonia, Paul G. Griffin