Abstract: The present invention relates to the stabilization of (meth)acrylic monomers against premature polymerization during synthesis, storage and transport. The term “(meth)acrylic monomers” is understood to mean derivatives both of methacrylic acid and of acrylic acid.
Type:
Application
Filed:
March 1, 2013
Publication date:
March 12, 2015
Applicant:
Evonik Roehm GmbH
Inventors:
Christine Maria Breiner, Klaus Dorn, Joachim Knebel, Thorben Schuetz
Abstract: The invention relates to a method for producing a carboxylic acid amide from a carbonyl compound and hydrocyanic acid, comprising the steps of A) reacting a carbonyl compound with hydrocyanic acid to produce a hydroxycarboxylic acid nitrile, B) hydrolysis of the hydroxycarboxylic acid nitrile obtained in step A) in the presence of a catalyst comprising manganese dioxide, wherein a molar excess of carbonyl compound is used in relation to the hydrocyanic acid to react the carbonyl compound with hydrocyanic acid according to step A), and the reaction mixture obtained in step A) is not purified by distillation before the hydrolysis according to step B) is carried out. The invention furthermore relates to a method for producing alkyl(meth)acrylates from polymers, moulding compounds and moulded bodies, wherein a method for producing a carboxylic acid amide from a carbonyl compound and hydrocyanic acid is carried out in accordance with the method described above.
Type:
Grant
Filed:
October 29, 2009
Date of Patent:
March 10, 2015
Assignee:
Evonik Roehm GmbH
Inventors:
Alexander May, Martin Koestner, Joerg Becker, Joerg Schallenberg, Hermann Siegert, Bernd Vogel
Abstract: A molding compound comprises a copolymer (I)a), produced by polymerization of 90-100% by weight methylmethacrylate, styrene and malic acid anhydride, and optionally 0-10% by weight additional monomers which can be copolymerized with methylmethacrylate, a (co)polymer (II)b), produced by polymerization of 80-100% by weight methylmethacrylate and optionally 0-20% by weight additional monomers which can be copolymerized with methylmethacrylate, and has a solution viscosity in chloroform at 25° C. (ISO 1628 Part 6) of 50 to 55 ml/g, as well as c) optional conventional additives, auxiliary agents and/or fillers. The molding compound is characterized in that the copolymer (I) has a solution viscosity in chloroform at 25° C. (ISO 1628 Part) of 55 ml/g or less. Also disclosed are moldings produced by thermoplastic processing of the molding compound and their uses.
Type:
Grant
Filed:
September 23, 2011
Date of Patent:
March 10, 2015
Assignee:
Evonik Röhm GmbH
Inventors:
Werner Hoess, Michael Wicker, Klaus Schultes, Klaus Albrecht, Martin Mohrmann
Abstract: The present invention relates to innovative materials which can be crosslinked by means of two different crosslinking mechanisms, the first crosslinking mechanism being an irreversible crosslinking. The second crosslinking mechanism is a thermoreversible mechanism. As a result of this thermoreversible change in the arc length, properties of the crosslinked material can be decisively changed and controlled, including flexibility, elasticity and other mechanical properties, but also chemical properties, the gas permeability and vapor permeability and storage capacity of the network. In this way it would be possible, for example, to store energy sources such as fuels.
Type:
Grant
Filed:
October 12, 2011
Date of Patent:
March 3, 2015
Assignee:
Evonik Roehm GmbH
Inventors:
Stefan Hilf, Friedrich Georg Schmidt, Christopher Barner-Kowollik, Jiawen Zhou
Abstract: The present invention relates to weathering-resistant, colored moldings made of poly(alkyl)(meth)acrylate with improved gloss and resistance to mechanical influences acting on the surface of the molding, in particular with improved wipe resistance and improved scratch resistance, and also to molding compositions for producing the same.
Type:
Grant
Filed:
August 22, 2011
Date of Patent:
February 24, 2015
Assignee:
Evonik Röhm GmbH
Inventors:
Victor Khrenov, Andreas Mischlich, Ursula Golchert, Stefan Nau, Anton Halblaender, Klaus Schultes, Marc Poth, Antonios Manis, Kathrin Lehmann, Zhen Zhu
Abstract: Stabilizer for a lower draft link of a three-point hitch of a tractor, the stabilizer comprising a first stabilizer member and a second stabilizer member which is movably connected to the first stabilizer member by a spring-loaded centering mechanism, wherein the second stabilizer member can be rotated with regard to the first stabilizer member to modify the overall length of the stabilizer. A locking bracket is pivotally connected to the first stabilizer member for blocking a rotation between the stabilizer members by engaging the locking bracket with a blocking groove formed in a circumference of the second stabilizer member. Furthermore, a locking cover is provided for disabling a movement between the stabilizer members in a closed position.
Abstract: The present invention relates to a process for hydrolysis of acetone cyanohydrin (ACH) by means of sulphuric acid within the ACH sulpho process for preparation of methacrylic acid (MAA) or methyl methacrylate (MMA).
Type:
Application
Filed:
March 6, 2013
Publication date:
February 12, 2015
Applicant:
Evonik Roehm GmbH
Inventors:
Arndt Selbach, Lorenza Sartorelli, Andreas Perl, Joachim Deinken, Stefanie Sohnemann, Norbert Mnich, Matthias Groemping, Udo Gropp, Thomas Mertz
Abstract: The invention relates to an aqueous medium containing an amino(meth)acrylate polymer or copolymer which is not soluble in dematerialised water, characterized in that the medium has a content of an aqueous phase of at least 60% by weight and a content of up to 40% by weight of solids comprising the amino(meth)acrylate polymer or copolymer, whereby the aqueous phase is charged by a sufficient amount of carbon dioxide that effects the amino(meth)acrylate polymer or copolymer to be present in solute form in the medium. The aqueous medium may be used beneficially as a coating or binding solution for the spray coating or binding of pharmaceutical compositions or nutraceutical compositions or cosmetical compositions.
Type:
Grant
Filed:
July 30, 2009
Date of Patent:
February 10, 2015
Assignee:
Evonik Röhm GmbH
Inventors:
Rosario Lizio, Michael Damm, Hans-Ulrich Petereit
Abstract: The subject matter of the invention is a detector system for detecting magnetic bodies in the human organism, which comprises at least two sensor assemblies, wherein each sensor assembly has one, two or three anisotropic magnetic resistance sensors, of which the axes of weak magnetisation point in different directions in pairs, and each sensor assembly has a spacing of 0.5 to 50 cm from the sensor assembly or the other sensor assemblies, and at least two sensor assemblies are tilted at an angle of 0 to 45° with respect to one another, and in addition a method for detecting the magnetic flux produced by a magnetic body in the human organism, and the use of the detector system according to the invention for detecting swallowed magnetic bodies and the disintegration of the same in the digestive system.
Type:
Application
Filed:
January 9, 2012
Publication date:
January 8, 2015
Applicant:
EVONIK ROEHM GMBH
Inventors:
Benedikt Hartwig, Peter Niepoth, Steffen Junginger, Hans-Joachim Stiller, Norbert Windhab, Gerhard Geipel
Abstract: An intumescent coating composition and a process for curing the coating to obtain an intumescent coating is provided. The intumescent coating composition contains a thermoplastic polymer which comprises as a copolymerized component, an acid (meth)acrylate or a copolymerizable polyfunctional carboxylic acid; at least one ethylenically unsaturated monomer; an azo or organic peroxide initiator; an acid source; a carbon source; and a gas source.
Type:
Grant
Filed:
March 7, 2012
Date of Patent:
December 30, 2014
Assignee:
Evonik Röhm GmbH
Inventors:
Günter Schmitt, Peter Neugebauer, Sybille Scholl, Heike Heeb, Peter Reinhard, Gilbert Kühl
Abstract: The present invention relates to a process for preparing (meth)acrylates, comprising the transesterification of a low-boiling ester of (meth)acrylic acid with a reactant alcohol in the presence of catalysts, which is characterized in that the transesterification is catalysed by a basic ion exchanger.
Abstract: The present invention relates to an innovative method for the reversible crosslinking of, for example, adhesives or coating materials. The reversible crosslinking method allows very rapid crosslinking even at room temperature and undoing of the crosslinks at higher temperatures, thereby regaining the capacity for thermoplastic processing and allowing the originally bonded substrates to be separated from one another again with ease. A particular aspect in this context is that a plurality of cycles of crosslinking and undoing of the crosslinks are possible with the present system.
Type:
Grant
Filed:
January 4, 2011
Date of Patent:
December 23, 2014
Assignee:
Evonik Roehm GmbH
Inventors:
Friedrich Georg Schmidt, Simon Krause, Andre Hennig, Stefan Hilf, Christopher Barner-Kowollik, Andrew John Inglis, Leena Nebhani, Ozcan Altintas
Abstract: The invention relates to a device for producing a reinforced foam material and for receiving a textile semifinished product in a hook. To this end, the device has a first subunit having a transport device and a second subunit having a receiving device. The transport device is designed to convey the textile semifinished product into the receiving device, and the first subunit and the second subunit are designed such that the textile semifinished product can be presented in defined length by a relative movement of the first subunit relative to the second subunit. Furthermore, the receiving device of the second subunit is set up such that the textile semifinished product can be placed in the hooks by a relative movement of the receiving device relative to the hook.
Type:
Grant
Filed:
November 20, 2008
Date of Patent:
December 23, 2014
Assignees:
Airbus Operations GmbH, Evonik Roehm GmbH
Inventors:
Jörg Rippert, Uwe Lang, Matthias Alexander Roth, Hans-Jürgen Weber, Gregor Christian Endres
Abstract: The invention relates to a controlled polymerization method for producing ABA-triblock copolymers on the basis of (meth)acrylate with A-blocks which have a narrow, monomodal molecular weight distribution and a B-block which has a bimodal molecular weight distribution, and to the use thereof as binders in glues and sealing materials.
Type:
Grant
Filed:
October 6, 2009
Date of Patent:
November 25, 2014
Assignees:
Evonik Roehm GmbH, Henkel AG & Co. KGaA
Inventors:
Sven Balk, Holger Kautz, Stephan Fengler, Christine Troemer, Monika Maerz, Lars Zander, Jens Lueckert, Johann Klein, Thomas Moeller, Volker Erb
Abstract: The present invention relates to processes for transesterification, comprising the steps of A) mixing an organic acid a) with an ester b) and B) transferring the alcohol radical of the ester b) to the acid a) to obtain the ester of the acid a) and the acid of the ester b), step B) being carried out in a still.
Type:
Grant
Filed:
May 12, 2006
Date of Patent:
November 18, 2014
Assignee:
Evonik Roehm GmbH
Inventors:
Jochen Ackermann, Alexander May, Udo Gropp, Hermann Siegert, Bernd Vogel, Soenke Broecker
Abstract: The invention describes a method for producing a foam moulding from poly(meth)acrylimide, an adhesion promoter or an adhesion promoter mixture and optional auxiliaries, comprising the following steps: grinding a polymeric moulding made of poly(meth)acrylamide, coating the grindings obtained in the preceding step with an adhesion promoter, introducing the coated grindings into a mould, optionally adding the auxiliaries, heating the mould, cooling the mould below the foaming temperature, and demoulding the foam moulding. The resulting foam moulding has outstanding mechanical properties and is suitable for applications including as a component in the production of space, air, water and land vehicles.
Type:
Application
Filed:
September 25, 2012
Publication date:
October 16, 2014
Applicant:
EVONIK ROEHM GMBH
Inventors:
Sebastian Buehler, Arnim Kraatz, Ina Piotrowski, Kay Bernhard
Abstract: The invention relates to a process for preparing a (meth)acrylate copolymer containing tertiary amino groups by free-radical polymerization in solution from a monomer mixture selected from a) 30 to 70% by weight of a C1-C4-alkyl ester of acrylic acid or methacrylic acid and b) 70 to 30% by weight of an alkyl ester of acrylic acid or methacrylic acid with a tertiary amino group in the alkyl radical and c) 0 to 10% of further copolymerizable vinyl monomers, whereby one or more polymerization initiators, optionally one or more molecular weight regulators and one or more solvents or of a solvent mixture are added to the monomer mixture to give a polymerization mixture, which is polymerized at temperatures from 30 to 120° C.
Type:
Grant
Filed:
October 13, 2010
Date of Patent:
October 14, 2014
Assignee:
Evonik Röhm GmbH
Inventors:
Christian Meier, Andreas Weber, Johannes Vorholz, Alpertunga Kueksal, Andreas Klosendorf, Pamela Boehmann, Marcus Denger, Norbert Hoffmann, Nikolaos Papadopoulos
Abstract: A method of producing a trafficway marking, the method including applying a cold plastic to a trafficway surface, to obtain the trafficway marking, where, in less than 5 minutes after the applying, the trafficway marking can withstand the passage of traffic, and where the cold plastic includes from 15% to 45% by weight of a reactive resin; from 1% to 5% by weight of a mixture comprising an initiator; from 7% to 15% by weight of an inorganic pigment; and from 50% to 60% by weight of a mineral filler.
Type:
Application
Filed:
June 10, 2014
Publication date:
October 2, 2014
Applicant:
Evonik Roehm GmbH
Inventors:
Peter NEUGEBAUER, Heike Heeb, Ingrid Kizewski
Abstract: The invention relates to a process for preparing N-alkyl(meth)acrylamides by reacting (meth)acrylic anhydride with corresponding alkylamines.
Type:
Application
Filed:
November 20, 2012
Publication date:
September 25, 2014
Applicant:
Evonik Roehm GmbH
Inventors:
Dirk Broell, Benedikt Laux, Christian Maul, Patrick Peter, Claus Zimmer
Abstract: The invention relates to a controlled polymerization method for producing ABA-triblock copolymers on the basis of (meth)acrylate with A-blocks having a narrow, monomodal molecular weight distribution, and a B-block having a wide, monomodal molecular weight distribution. The invention further relates to the use thereof as binders in glues or sealing compounds.
Type:
Grant
Filed:
October 6, 2009
Date of Patent:
September 9, 2014
Assignees:
Evonik Roehm GmbH, Henkel AG & Co. KGaA
Inventors:
Sven Balk, Holger Kautz, Stephan Fengler, Monika Maerz, Christine Troemer, Lars Zander, Jens Lueckert, Johann Klein, Thomas Moeller, Volker Erb