Abstract: A novel process is described which allows N-isopropyl(meth)acrylamide to be obtained in high purity and yield in a simple manner, by reacting methacrylic anhydride with isopropylamine, optionally in a solvent.
Type:
Grant
Filed:
November 19, 2009
Date of Patent:
December 6, 2016
Assignee:
EVONIK ROEHM GmbH
Inventors:
Joachim Knebel, Wilhelm Karnbrock, Volker Kerscher
Abstract: The invention relates to a process for the production of prefoamed poly(meth)acrylimide (P(M)I) particles which can be further processed to give foam mouldings or composites. A feature of this process is that a polymer granulate is first heated and thus prefoamed in an apparatus by means of IR radiation of a wavelength suitable for this purpose. Said granulate can be further processed in subsequent steps, e.g. in a press mould with foaming to give a moulding or a composite workpiece with foam core.
Type:
Application
Filed:
December 3, 2014
Publication date:
November 17, 2016
Applicant:
EVONIK ROEHM GMBH
Inventors:
Kay BERNHARD, Ina LIEBL, Denis HOLLEYN, Christoph SEIPEL
Abstract: The invention relates to a gastric resistant pharmaceutical or nutraceutical composition, comprising a core, comprising a pharmaceutical or nutraceutical active ingredient and a gastric resistant coating layer onto the core, wherein the release of the pharmaceutical or nutraceutical active ingredient is not more than 15% under in-vitro conditions at pH 1.2 for 2 hours in medium according to USP with and without the addition of 40% (v/v) ethanol, wherein the gastric resistant coating layer comprises 10 to 100% by weight of one or more salts of alginic acid with a viscosity of 30 to 720 cP of a 1% aqueous solution.
Abstract: The invention relates to novel particulate drug-delivery systems based on a polymer support containing at least one linear, branched or cross-linked polymer in a fraction of over 50 percent by weight in relation to the total weight of the support. The system is characterized in that at least one signal substance for transport through a biological barrier and at least one active ingredient are stored, the support, signal substance and active ingredient having no covalent links and no active-ingredient specific and signal substance specific coordinative links between one another.
Abstract: The invention relates to a process for preparing methacrylic esters of hydroxyl-functional benzophenones and to their use. Methacrylated benzophenones (benzophenone (meth)acrylates) can be prepared in high purity by the process of the invention, in a simple way and in a high yield.
Type:
Application
Filed:
September 29, 2014
Publication date:
October 13, 2016
Applicant:
EVONIK ROEHM GmbH
Inventors:
Wolfgang KLESSE, Joachim KNEBEL, Doris SAAL
Abstract: The present invention relates to a novel process for the production of novel fibre-reinforced profile materials comprising a rigid foam core, in particular a PMI foam core. In particular, the present invention relates to a novel process which can be carried out in two variants, a short Pul-press process and a Pul-shape process. One step here produces a fibre-reinforced profile material and simultaneously inserts the rigid foam core into same. The same step moreover ensures very good binding of the rigid foam core to the fibre-reinforced profile material.
Type:
Application
Filed:
October 22, 2014
Publication date:
October 6, 2016
Applicant:
EVONIK ROEHM GMBH
Inventors:
Sebastian BÜHLER, Karl-Heinz SEMLITSCH, Sivakumara K. KRISHNAMOORTHY
Abstract: The present invention relates to a process for hydrolysis of acetone cyanohydrin (ACH) by means of sulphuric acid within the ACH sulpho process for preparation of methacrylic acid (MAA) or methyl methacrylate (MMA).
Type:
Grant
Filed:
March 6, 2013
Date of Patent:
October 4, 2016
Assignee:
EVONIK ROEHM GmbH
Inventors:
Arndt Selbach, Lorenza Sartorelli, Andreas Perl, Joachim Deinken, Stefanie Sohnemann, Norbert Mnich, Matthias Groemping, Udo Gropp, Thomas Mertz
Abstract: The present invention relates to a catalytic continuous process for producing methyl methacrylate, said process comprising the step of reacting methacrolein with oxygen and methanol in the presence of a heterogeneous noble-metal-containing catalyst in an oxidative esterification reaction to give methyl methacrylate, characterized in that the stationary concentration of the starting material methacrolein is equal to or less than 12% by weight based on the total weight of the reaction mixture in the reactor, and the ratio F between the total liquid volume within the reactor expressed in litres divided by the total weight of catalyst in the reactor expressed in kilograms is equal to or less than 4.
Type:
Application
Filed:
December 11, 2014
Publication date:
September 29, 2016
Applicant:
Evonik Roehm GmbH
Inventors:
Steffen KRILL, Alexander LYGIN, Matthias GRÖMPING, Torsten BALDUF, Rudolf BURGHARDT
Abstract: The present invention relates to a process for producing methacrolein from propionaldehyde and formalin. This novel process is notable in that the catalyst system used for this reaction is modified by the simultaneous presence of secondary and tertiary amines such that the synthesis can be carried out more efficiently and with less purification being required.
Type:
Application
Filed:
December 3, 2014
Publication date:
September 29, 2016
Applicant:
EVONIK ROEHM GMBH
Inventors:
Rudolf BURGHARDT, Steffen KRILL, Torsten BALDUF, Eduard RUNDAL
Abstract: The present invention relates to a continuous or semi-continuous freeze coagulation process for aqueous polymer dispersions, wherein said process comprises a freezing step and a solid-liquid separation step and is further characterized in that it comprises the further step of admixing water and/or water vapor between the freezing step and the solid-liquid separation step.
Type:
Application
Filed:
November 6, 2014
Publication date:
September 29, 2016
Applicant:
Evonik Roehm GmbH
Inventors:
Dominic STOERKLE, Andreas WEBER, Johannes VORHOLZ, Melanie JUNGKAMP, Marcus DENGER, Norbert HOFFMANN, Mona RUEPPEL, Reiner MUELLER, Klaus ALBRECHT
Abstract: The present invention relates to a method for producing light guide bodies and to their use in lighting units, for example for liquid crystal displays or for monitors. In particular, the present invention relates to a method for producing light guide bodies which have a thickness of at most 1 mm and contain at least 80 wt % of polymethyl methacrylate and no light-scattering constituents.
Type:
Grant
Filed:
November 11, 2011
Date of Patent:
September 13, 2016
Assignee:
Evonik Roehm GmbH
Inventors:
Markus Parusel, Guenther Dickhaut, Thomas Pfaff, Helmut Haering, Michael Enders
Abstract: A 3D extrusion print process for producing multicolored three-dimensional objects is provided. The process produces mechanically stable, multicolored 3D objects with good color definition. The process according to the invention is based on coating, upstream of the printing head, of the polymer strand used for producing the actual object, and on fixing of the coating upstream of entry of the polymer strand into the printing head. Downstream of the extrusion process in the printing head, the coating remains predominantly at the surface of the extruded strand.
Type:
Grant
Filed:
October 31, 2013
Date of Patent:
September 6, 2016
Assignee:
EVONIK RÖHM GmbH
Inventors:
Markus Pridoehl, Guenter Schmitt, Dirk Poppe, Stephan Kohlstruk, Benjamin Hammann, Sonja Cremer, Kris Beks, Ludo Dewaelheyns
Abstract: The present invention relates to a process for preparing methyl methacrylate by a direct oxidative esterification of methacrolein with oxygen and methanol, which is conducted in the liquid phase at a pressure of 2 to 100 bar with a gold catalyst. According to the invention, the liquid phase is withdrawn continuously from the reactor and optionally enriched with oxygenous gas, the pH, after the withdrawal, is adjusted to a pH between 5 and 9 by means of addition of a basic solution and this liquid phase is conducted back into the reactor again to an extent of at least 50%.
Type:
Application
Filed:
December 5, 2014
Publication date:
September 1, 2016
Applicant:
EVONIK ROEHM GMBH
Inventors:
Alexander LYGIN, Steffen KRILL, Torsten BALDUF, Rudolf BURGHARDT, Andreas TEPPERIS, Matthias GRÖMPING
Abstract: The present invention relates to a process for producing colored plastics molding compositions with aqueous liquid colors, where an aqueous liquid color is added to a molten plastics molding composition. The present invention also describes a system for conducting the said process.
Type:
Grant
Filed:
August 20, 2010
Date of Patent:
August 30, 2016
Assignee:
Evonik Roehm GmbH
Inventors:
Andreas Kluge, Simon Becht, Thorsten Goldacker, Thomas Wick, Michael Jucys, Ursula Golchert, Klaus Schultes
Abstract: The present invention describes a process for preparing alpha-beta-unsaturated carboxylic acids by dehydration of hydroxycarboxylic or alkoxycarboxylic acids which are substituted in the alpha position, in particular 2-hydroxyisobutyric acid, while avoiding accumulation of by-products and additives.
Type:
Grant
Filed:
April 28, 2014
Date of Patent:
August 30, 2016
Assignee:
EVONIK ROEHM GmbH
Inventors:
Alexander May, Steffen Krill, Joerg Becker, Willi Ploesser, Marcel Treskow, Martin Koestner
Abstract: A reactive mixture for coating mouldings by means of reaction injection moulding, containing at least 40% by weight of (meth)acrylates having at least two double bonds. The reactive mixture contains at least one photoinitiator and at least one thermal initiator. The present invention furthermore describes a coated moulding including a moulding which is obtainable by injection moulding processes and includes at least one polymer selected from polymethyl methacrylate, polymethylmethacrylimide, styrene-acrylonitrile copolymer, styrene-maleic acid copolymer and polymethyl methacrylate copolymers, and a coating which is obtainable by polymerization of (meth)acrylates having at least two double bonds. The coating has an adhesive strength rating of not more than 1 according to the cross hatch test and a decrease in gloss at 20° after a scratch resistance test according to ASTM 1044 (12/05) (applied weight 500 g, number of cycles=100) of not more than 10%.
Type:
Grant
Filed:
July 11, 2012
Date of Patent:
August 9, 2016
Assignee:
Evonik Roehm GmbH
Inventors:
Klaus Schultes, Thorsten Goldacker, Klaus Koralewski, Werner Höβ, Ghirmay Seyoum, Elevtherios Gross, Erwin Felger
Abstract: A peptide having an amino acid sequence containing at least eight consecutive amino acids of the human lactoferrin protein or of the bovine lactoferrin protein. The peptide is suitable as a cell-penetrating peptide. A complex of the peptide and a cargo molecule non-covalently bound to the peptide. The cargo molecule may be a nucleic acid, an amino acid, a peptide, a protein, a carbohydrate, a lipid, or a small molecule. A method of penetrating or transfecting a cell using the complex.
Abstract: Provided is an adhesive composition suitable for producing a laminate. The composition contains specified amounts of (a) polyisobutyl methacrylate, isobutyl methacrylate or a mixture thereof, (b) butyl acrylate, (c) polybutyl acrylate, (d) a (meth)acrylate compound and (e) a silicon compound. These components may be in polymerizable form, in polymerized form or in a combination of polymerizable form and polymerized form. The amounts of components (a) to (e) total 100 wt. % and the amount of (b) and (c) represents 30 to 90 wt. %, based on the sum total of components (a) to (e). The composition may optionally further contain from 0.1 to 6 wt. %, based on the total weight of the adhesive composition, of additives different from components (a) to (e) described above.
Type:
Grant
Filed:
February 14, 2013
Date of Patent:
July 26, 2016
Assignee:
EVONIK RÖHM GmbH
Inventors:
Thomas Hasskerl, Klaus Koralewski, Sabine Schwarz-Barac, Roger Recktenwald, Werner Hoess, Florian Band
Abstract: The invention refers to a Process for preparing a bio-resorbable polyester the form of a powder with a bulk density of 0.3 g/ml or more, a tapped density of 0.4 g/ml or more and a specific surface area of 2.0 m2/g or less comprising the steps a. dissolving a bio-resorbable polyester in a first solvent to form a polymer solution, b. contacting the polymer solution with a second solvent which is a non-solvent for the bioresorbable polyester and which is mainly water to result the precipitation of the bio-resorbable polyester in the form of a wet polymer mass, c. pre-drying the wet polymer mass at a temperature below the TgO of the bio-resorbable polyester, d. comminuting the pre-dried polymer mass to polymer particles with a size below 10 mm, e. drying the comminuted polymer particles below the TgO of the bio-resorbable polyester to a residual water content of 1% or less by weight/weight, f.
Type:
Application
Filed:
August 29, 2013
Publication date:
July 21, 2016
Applicant:
EVONIK RÖHM GMBH
Inventors:
Hans BÄER, Julian BLAESY, Felix HOFMANN, Silke SCHMINKE, Isabel WAHL
Abstract: The present invention relates to a process for preparing methyl methacrylate by direct oxidative esterification of methacrolein and the preparation of methacrolein. It is a feature of this novel process that it was possible to distinctly increase the yield and the efficiency of the process compared to the prior art through a sequence of different distillation steps.
Type:
Application
Filed:
August 27, 2014
Publication date:
July 14, 2016
Applicant:
EVONIK ROEHM GMBH
Inventors:
Steffen KRILL, Matthias GROEMPING, Alexander LYGIN, Torsten BALDUF, Rudolf BURGHARDT