Abstract: A process for preparing poly(lactide-co-glycolide) copolymer particles with an average particle size in the range of 50-800 nm includes transferring a mixture of poly(lactide-co-glycolide) copolymer, ethanol and carbon dioxide from a first reactor into a second reactor under rapid reduction of the pressure and expansion with phase separation into a gas phase, an ethanol aerosol and an ethanolic suspension containing poly(lactide-co-glycolide) copolymer particles, removing the carbon dioxide gas and the ethanol aerosol from the second reactor, and obtaining the poly(glycolide-co-lactide) copolymer particles in the form of an ethanolic suspension or in dry form from the second reactor.
Type:
Grant
Filed:
June 21, 2016
Date of Patent:
May 21, 2019
Assignee:
Evonik Röhm GmbH
Inventors:
Andreas Kirchner, Rosario Lizio, Markus Rolf Rossmeissl, Wolfgang Luley, Johannes Vorholz, Silko Grimm, Marc Schneider
Abstract: A disclosed process includes steps of heating a foamed material by irradiation with near infrared radiation having a wavelength between 0.78 and 1.40 ?m to form a heated material, forming the heated material with a forming tool to obtain a formed material, and cooling the formed material and demolding to obtain a final workpiece. The foamed material may be constructed as a composite ply construction including an outer material and a foamed core between the outer material. The foamed material may contain a poly(meth)acrylimde, a polypropylene or a highly-crosslinked polyurethane.
Type:
Grant
Filed:
June 24, 2013
Date of Patent:
May 7, 2019
Assignee:
Evonik Roehm GmbH
Inventors:
Jorge Pinto, Matthias Alexander Roth, Joern Daniel Suendermann, Arnim Kraatz, Dieter Schlager, Rainer Zimmermann
Abstract: The present invention relates to the technical field of 3D printing, especially in the form of the binder jetting method, in which particles in a powder bed are bonded by means of a printed adhesive to form a three-dimensional object. The particles may be inorganic particles, for example sand or a metal powder, or polymeric particulate, for example polymethacrylates or polyamides. For this purpose, polymethacrylates may take the form, for example, of suspension polymers, called bead polymers.
Type:
Application
Filed:
April 4, 2017
Publication date:
May 2, 2019
Applicant:
Evonik Röhm GmbH
Inventors:
Dirk POPPE, Andrea FRUTH, Stefan BERNHARDT, Stephan WIEBER
Abstract: The present invention relates to the technical field of 3D printing, in particular in the form of the binder jetting process in which particles in a powder bed are adhesive-bonded by means of a printed adhesive to give a three-dimensional object. The particles here can be inorganic materials, e.g. sand or a metal powder, or polymeric particles, such as polymethacrylates or polyamides. To this end, polymethacrylates can by way of example take the form of suspension polymers known as bead polymers. In this context the present invention in particular relates to, as powders for 3D printing, suspension polymers which differ from the prior art in that they comprise a hard phase and an uncrosslinked soft phase.
Type:
Application
Filed:
April 12, 2017
Publication date:
May 2, 2019
Applicant:
Evonik Röhm GmbH
Inventors:
Stefan Bernhardt, Thomas HASSKERL, Dirk POPPE, Stephan WIEBER
Abstract: The present invention relates to a process for producing methyl methacrylate, comprising the following steps: A) producing methacrolein and B) reacting the methacrolein obtained in step A) in an oxidative esterification reaction to give methyl methacrylate, characterized in that the two steps A) and B) take place in a liquid phase at a pressure of from 2 to 100 bar, and step B) is carried out in the presence of a heterogeneous noble-metal-containing catalyst comprising metals and/or comprising metal oxides.
Type:
Grant
Filed:
October 27, 2017
Date of Patent:
April 30, 2019
Assignee:
EVONIK RÖHM GmbH
Inventors:
Steffen Krill, Torsten Balduf, Martin Koestner, Matthias Groemping, Alexander Lygin, Rudolf Burghardt
Abstract: The present invention relates to a process for producing methyl methacrylate, comprising the following steps: A) producing methacrolein and B) reacting the methacrolein obtained in step A) in an oxidative esterification reaction to give methyl methacrylate, characterized in that the two steps A) and B) take place in a liquid phase at a pressure of from 2 to 100 bar, and step B) is carried out in the presence of a heterogeneous noble-metal-containing catalyst comprising metals and/or comprising metal oxides.
Type:
Application
Filed:
October 16, 2018
Publication date:
April 18, 2019
Applicant:
Evonik Roehm GmbH
Inventors:
Steffen KRILL, Torsten BALDUF, Martin KOESTNER, Matthias GROEMPING, Alexander LYGIN, Rudolf BURGHARDT
Abstract: A process for performing a heterogeneously catalysed reaction in a three-phase reactor, where there is at least one liquid phase, at least one gaseous phase and at least one solid phase in the reactor and the reactor has at least two zones, with the reaction mixture being conveyed downward in zone 1, the reaction mixture being conveyed upward in zone 2, zones 1 and 2 being separated from one another by a dividing wall, and in that the ratio between the average catalyst concentrations in zone 2 and in zone 1 is greater than 2.
Type:
Application
Filed:
April 13, 2017
Publication date:
April 4, 2019
Applicant:
Evonik Roehm GmbH
Inventors:
Alexander LYGIN, Matthias GROEMPING, Steffen KRILL
Abstract: The present invention relates to a novel process for oxidative esterification, generally for reaction of aldehydes with alcohols in the presence of oxygenous gases directly to give the corresponding ester in the presence of a heterogeneous catalyst, by means of which, for example, (meth)acrolein can be converted to methyl (meth)acrylate. The new catalyst has titanium dioxide as the main component of the support material. The catalysts are especially notable for high mechanical and chemical stability and for good catalytic performance even over very long periods. The process is an improvement in the catalyst service life, activity and selectivity over prior art catalysts which lose activity and/or selectivity relatively quickly in continuous operation in media having even a small water content.
Abstract: The present invention is in the field of medical diagnostics and microfluidics and primarily relates to a microfluidic device for the analysis of biological samples. The microfluidic device of the present invention comprises at least one microchannel, the inner surface of which is at least partially coated with a hydrophilic coating. This hydrophilic coating is located on top of the intermediate layer which, in turn, is located between the material of the inner surface of the microchannel and the hydrophilic coating.
Type:
Application
Filed:
March 9, 2017
Publication date:
March 21, 2019
Applicant:
Evonik Roehm GmbH
Inventors:
Ghirmay SEYOUM, Anderea FRUTH, Michael ENDERS
Abstract: Catalysts for oxidative esterification can be used, for example, for converting (meth)acrolein to methyl (meth)acrylate. The catalysts are especially notable for high mechanical and chemical stability even over very long time periods, including activity and/or selectivity relatively in continuous operation in media having even a small water content.
Type:
Grant
Filed:
December 29, 2015
Date of Patent:
March 19, 2019
Assignee:
Evonik Röhm GmbH
Inventors:
Alexander Lygin, Steffen Krill, Matthias Groemping, Andreas Tepperis
Abstract: The present invention relates to a process for producing methyl methacrylate, comprising the following steps: A) producing methacrolein and B) reacting the methacrolein obtained in step A) in an oxidative esterification reaction to give methyl methacrylate, characterized in that the two steps A) and B) take place in a liquid phase at a pressure of from 2 to 100 bar, and step B) is carried out in the presence of a heterogeneous noble-metal-containing catalyst comprising metals and/or comprising metal oxides.
Type:
Application
Filed:
October 16, 2018
Publication date:
March 14, 2019
Applicant:
Evonik Roehm GmbH
Inventors:
Steffen KRILL, Torsten BALDUF, Martin KOESTNER, Matthias GROEMPING, Alexander LYGIN, Rudolf BURGHARDT
Abstract: The present invention relates to a process for preparing alpha-hydroxycarboxylic esters proceeding from hydrogen cyanide, wherein the ammonia formed in the step of alcoholysis of the corresponding alpha-hydroxycarboxamide is recycled into a hydrogen cyanide preparation process after a purification step.
Type:
Grant
Filed:
September 4, 2015
Date of Patent:
March 12, 2019
Assignee:
Evonik Roehm GmbH
Inventors:
Steffen Krill, Belaid Ait Aissa, Alexander May, Marcel Treskow
Abstract: The invention relates to a process for the production of mold-foamed poly(meth)acrylimide (P(M)I) cores, in particular of polymethacrylimide (PMI) cores, which can be used by way of example in automobile construction or aircraft construction. A feature of this process is that polymer granules or polymer powder preheated under pressure are moreover charged under pressure to a compression mold where they are foamed with depressurization. In particular, a feature of the process is that it optionally uses a preferably two-shell compression mold for the heating and also for the cooling of the granules and, respectively, the rigid foam core formed therefrom.
Type:
Grant
Filed:
June 25, 2015
Date of Patent:
February 19, 2019
Assignee:
Evonik Roehm GmbH
Inventors:
Kay Bernhard, Ina Liebl, Tim Denk, Florian Becker, Thomas Richter
Abstract: A transparent, heat-sealable coating for transparent PET packaging foils can be provided by using a heat-sealable lacquer based on styrene-containing copolymers, on poly(meth)acrylates, on at least one polyester and optionally on a tackifier, and also the process for the sealing of a foil coated with this lacquer. It is surprising here that, despite the use of a rubber based on styrene-containing polymers that is not optically compatible with polyesters and polymethacrylate, the transparency of the heat-sealable coatings is still very high.
Type:
Grant
Filed:
May 17, 2017
Date of Patent:
February 5, 2019
Assignee:
Evonik Roehm GmbH
Inventors:
André Hennig, Bruno Keller, Juergen Hartmann, Thomas Arnold, Michael Waldhaus, Monika Maerz
Abstract: A process produces a (meth)acrylate ester mixture. The process includes reacting a glycerol formal isomer mixture with an alkyl (meth)acrylate in the presence of a catalyst.
Abstract: The invention refers to a nanoparticle with a diameter which is the maximum in the nanoparticle size distribution, in the range of 10-300 nm, comprising a) a calcium phosphate nanoparticle core a), b) an active ingredient coating b) on the calcium phosphate nanoparticle core a), c) a lactic acid polymer coating c) on the active ingredient coating b), d) a cationic polymer coating d) on the lactic acid polymer coating c) selected from the group of polyethylene-imines, chitosan and human lactoferrin-derived peptides with a length of 14 to 30 amino acids.
Abstract: The invention relates to a cell which has been genetically modified so as to be capable of producing more 2-hydroxyisobutyric acid or more polyhydroxyalkanoates containing 2-hydroxyisobutyric acid monomer units than its wild type, characterized in that 2-hydroxyisobutyric acid or polyhydroxyalkanoates containing 2-hydroxyisobutyric acid monomer units are produced via acetoacetyl-coenzyme A as intermediate and 3-hydroxybutyryl-coenzyme A as precursor.
Type:
Grant
Filed:
April 28, 2009
Date of Patent:
January 8, 2019
Assignee:
EVONIK ROEHM GmbH
Inventors:
Liv Reinecke, Steffen Schaffer, Achim Marx, Markus Poetter, Thomas Haas
Abstract: The invention relates to a device with a sensor arrangement, which is able to detect magnetic or magnetized oral administration forms after oral take-up, moreover tracks the dissolution thereof via the reduction or disappearance of the magnetic field of the oral administration form, and with a log function, which records a subjective evaluation on the part of the human wearer of the sensor arrangement during or after the oral take-up.
Type:
Grant
Filed:
June 6, 2014
Date of Patent:
January 1, 2019
Assignee:
EVONIK ROEHM GmbH
Inventors:
Benedikt Hartwig, Peter Niepoth, Hans-Joachim Stiller, Steffen Junginger
Abstract: The present invention relates to aqueous binders and to heat-sealing lacquers produced therefrom for heat-sealable coatings which adhere on aluminium without use of any primer, permit good sealability of the coated aluminium foil with respect to PS and/or PVC, and moreover feature good blocking resistance even at temperatures above 40° C.
Type:
Application
Filed:
August 29, 2018
Publication date:
December 27, 2018
Applicant:
Evonik Roehm GmbH
Inventors:
Florian HERMES, Dominik STURM, Christian GOLDITZ, Michael WICKE, Herbert JUNG, Juergen HARTMANN, Bruno KELLER
Abstract: The present invention describes a process for dehydrating alpha-substituted carboxylic acids in the presence of water at high pressures while avoiding by-products.
Type:
Grant
Filed:
June 24, 2015
Date of Patent:
December 25, 2018
Assignee:
Evonik Roehm GmbH
Inventors:
Belaid Ait Aissa, Steffen Krill, Matthias Groemping