Abstract: In a method for cleaning an absorptive polyester, the polymer is dissolved in a first solvent (12) and subsequently the polymer solution is brought into tight contact with a second solvent (41) in a turbulent shear field under the influence of strong shear forces. Here, the second solvent (41) represents a non-solvent for the absorptive polyester and is mixable with the first solvent (12) to an unlimited extent. Subsequently, the polymer suspension resulting from the addition of the second solvent (41) is conveyed onto or into a rotating, cylindrical screen body (71) of a drum shear screen (70) and then the moist polymer mass is removed from the screen body (71) and subsequently dried. The method is suitable for the production of absorptive polyester with a high degree of quality and may be performed in a cost-effective fashion on an industrial scale as well.
Abstract: The invention relates to a controlled polymerization method for producing ABA-triblock copolymers on the basis of (meth)acrylate with A-blocks having a narrow, monomodal molecular weight distribution, and a B-block having a wide, monomodal molecular weight distribution. The invention further relates to the use thereof as binders in glues or sealing compounds.
Type:
Application
Filed:
October 6, 2009
Publication date:
November 17, 2011
Applicants:
Henkel AG & Co. KGaA, Evonik Roehm GMBH
Inventors:
Sven Balk, Holger Kautz, Stephan Fengler, Monika Maerz, Christine Troemer, Lars Zander, Jens Lueckert, Johann Klein, Thomas Moeller, Volker Erb
Abstract: The invention relates to a novel halogen-free and acid-free, readily soluble priming bonding agent for polyolefins, said agent containing (meth)acrylate-grafted, amorphous polyolefins.
Abstract: The invention relates to a controlled polymerization process for preparing (meth)acrylate-based AB diblock copolymers with a B block which has a narrow monomodal molecular weight distribution, and an A block which has a broad monomodal molecular weight distribution, and to the use thereof, for example, as a binder in adhesives or sealants.
Type:
Application
Filed:
October 6, 2009
Publication date:
November 17, 2011
Applicants:
Henkel AG & Co. KGaA, Evonik Roehm GmbH
Inventors:
Holger Kautz, Sven Balk, Stephan Fengler, Dorothea Staschik, Christine Miess, Lars Zander, Jens Lueckert, Johann Klein, Thomas Moeller, Volker Erb
Abstract: The invention relates to a controlled polymerization method for producing telechelics on the basis of (meth)acrylate, which have a wide, monomodal molecular weight distribution, and to the use thereof as binders in glues or sealing materials.
Type:
Application
Filed:
October 6, 2009
Publication date:
November 3, 2011
Applicants:
Henkel Ag & Co. KGAA, EVONIK ROEHM GMBH
Inventors:
Sven Balk, Holger Kautz, Gerd Loehden, Lars Zander, Jens Lueckert, Johann Klein, Thomas Moeller, Volker Erb
Abstract: Moulding composition, encompassing a) at least one polyalkyl (meth)acrylate, and b) at least one compound according to formula (I) in which the moieties R1 and R2 are independently an alkyl or cycloalkyl moiety having from 1 to 20 carbon atoms, where the moulding composition further comprises c) at least one infrared absorber, where the transmittance of the moulding composition at 500 nm is smaller than 89%, at 1000 nm is smaller than 80%, at 1150 nm is smaller than 70% and at 1600 nm is smaller than 77%, in each case measured by means of infrared spectroscopy at 25° C. on 3 mm plaques. The moulding composition is in particular used for the production of solar-cell modules.
Type:
Application
Filed:
October 15, 2009
Publication date:
November 3, 2011
Applicant:
Evonik Roehm GmbH
Inventors:
Peter Battenhausen, Ernst Becker, Klaus Schultes, Sven Strohkark
Abstract: The present invention relates to a process for preparing (meth)acrylates, which comprises the transesterification of an alcohol with a low-boiling ester of (meth)acrylic acid in the presence of catalysts, with the alcohol liberated from the low-boiling ester of (meth)acrylic acid being separated off by distillation, characterized in that the molar ratio of low-boiling ester of (meth)acrylic acid to starting alcohol present in the reaction mixture is increased during the reaction by addition of low-boiling ester of (meth)acrylic acid. The process of the invention makes a particularly inexpensive preparation of (meth)acrylates having a very high purity possible.
Type:
Grant
Filed:
May 8, 2008
Date of Patent:
November 1, 2011
Assignee:
Evonik Röhm GmbH
Inventors:
Guido Protzmann, Harald Trauthwein, Joachim Knebel, Thorben Schuetz, Gerhard Koelbl, Thomas Kehr, Guenther Lauster
Abstract: The invention relates to a copolymer for producing molded compounds or cast glass for the production of molded bodies having increased dimensional stability under heat, obtainable from the copolymerization of A) one or more ethylenically unsaturated ester compounds of the formula (I), where R1 is hydrogen or methyl and R2 a linear or branched alkyl group with 1 to 8 carbon atoms, B) one or more ethylenically unsaturated ester compounds of the formula (II), where R3 is hydrogen or methyl and R4 a cyclic group with 8 to 30 carbon atoms, C) one or more ethylenically unsaturated ester compounds of the formula (III), where R5 is hydrogen or methyl and R6 and R7, independently of each other, are hydrogen or a linear or branched group with 1 to 40 carbon atoms.
Type:
Application
Filed:
October 15, 2009
Publication date:
October 27, 2011
Applicant:
Evonik Roehm GmbH
Inventors:
Gerald Dietrich, Ruediger Carloff, Wilhelm Karnbrock, Joachim Knebel, Zhong Shen, Chiew-Chiang Haw
Abstract: The present invention discloses a process for preparing a photochromic polymeric composition, characterized in that the photochromic polymeric composition is prepared by comprising (meth) acrylamide compound in the reaction mixture useful for the preparation of the photochromic polymeric composition. The present invention also relates to the thus obtained polymeric composition, photochromic articles made from said polymeric composition, and use of said polymeric composition for preparing photochromic articles. The photochromic polymeric composition according to the present invention makes the absorption peak of the photochromic dye therein become longer, thus exhibiting a desired grey with a bit bluish green or grey with a bit blue.
Abstract: An impact resistant provided PMMA moulding material according to DE 195 44 563 is process into a surface-hardened film which is highly glossy, essentially free of gel bodies and can be processed in the “in-mould-film-decoration” method. The melted mass is generated by means of an extruder and fed to the inventive glazing rolls via a flexible lip nozzle, said rolls being configured in order to generate an especially high locking pressure in the roll slit. The smoothing rolls are cambered. The films are used for decorating surfaces of high-value thermoplastic moulded parts.
Type:
Grant
Filed:
June 17, 2002
Date of Patent:
October 25, 2011
Assignee:
Evonik Roehm GmbH
Inventors:
Uwe Numrich, Klaus Hofmann, Peter Kaube, Horst Schmidt, Heinz Vetter
Abstract: The present invention relates to the use of different-sized polymeric microparticles in hydraulically setting building material mixtures for the purpose of enhancing their frost resistance and cyclical freeze/thaw durability.
Type:
Grant
Filed:
March 24, 2006
Date of Patent:
October 18, 2011
Assignee:
Evonik Roehm GmbH
Inventors:
Jan Hendrik Schattka, Holger Kautz, Gerd Loehden
Abstract: The present invention relates to a process for preparing butanediol dimethacrylates, which comprises the transesterification of butanediol with an ester of methacrylic acid in the presence of catalysts, wherein a combination comprising at least one lithium compound and at least one calcium compound is used as catalyst, at least one of the compounds of lithium and/or of calcium is an oxide, a hydroxide, an alkoxide having from 1 to 4 carbon atoms or a carboxylate having from 1 to 4 carbon atoms and at least part of the reaction is carried out in the presence of an effective amount of water. The process of the invention makes a particularly inexpensive preparation of butanediol dimethacrylates having a very high purity possible.
Type:
Grant
Filed:
May 8, 2008
Date of Patent:
October 18, 2011
Assignee:
Evonik Roehm GmbH
Inventors:
Joachim Knebel, Thorben Schuetz, Harald Trauthwein, Thomas Kehr, Guenther Lauster, Guido Protzmann, Gerhard Koelbl, Guenter Westhaeuser
Abstract: The invention relates to a process for preparing CABAC or ACBCA pentablock copolymers based on (meth)acrylate with an OH functionalization of the A blocks.
Type:
Grant
Filed:
August 11, 2008
Date of Patent:
October 11, 2011
Assignees:
Evonik Roehm GmbH, Henkel AG&Co. HGAA
Inventors:
Sven Balk, Gerd Loehden, Holger Kautz, Volker Erb, Uwe Franken, Georg Kinzelmann, Thomas Moeller
Abstract: The invention relates to a pH-dependent controlled release pharmaceutical composition, comprising at least one pharmaceutical active ingredient, with the exception of opioids, wherein the core is coated at least by one coating layer, controlling the release of the pharmaceutical composition, wherein the coating layer comprises a polymer mixture of i) 40-95% by weight, based on dry weight of the polymer mixture, of at least one water insoluble essentially neutral vinyl polymer or copolymer, and ii) 5-60% by weight, based on dry weight of the polymer mixture, of at least one anionic polymer or copolymer, which is insoluble in a buffered medium below pH 4.0 and soluble at least in the range from pH 7.0 to pH 8.0, characterized in that the coating layer further comprises 110 to 250% by weight of a non-porous inert lubricant, 1 to 35% by weight of at least one neutral cellulosic compound and 1 to 25% by weight of at least one emulsifier, each calculated on dry weight of the polymer mixture.
Type:
Application
Filed:
September 24, 2008
Publication date:
September 22, 2011
Applicant:
Evonik Roehm GmbH
Inventors:
Hans Bär, Thomas Fürst, Gerhard Renner, Michael Gottschalk
Abstract: A novel process is described which allows N-isopropyl(meth)acrylamide to be obtained in high purity and yield in a simple manner, by reacting methacrylic anhydride with isopropylamine, optionally in a solvent.
Type:
Application
Filed:
November 19, 2009
Publication date:
September 8, 2011
Applicant:
EVONIK ROEHM GmbH
Inventors:
Joachim Knebel, Wilhelm Karnbrock, Volker Kerscher
Abstract: The present invention relates to a process for preparing aqueous dispersions. The invention also relates to the formation of core-shell particles in aqueous dispersions. The core-shell particles are useful as impact-modifiers for poly(meth)acrylate moulding compositions.
Type:
Application
Filed:
May 18, 2011
Publication date:
September 8, 2011
Applicant:
EVONIK ROEHM GMBH
Inventors:
Klaus SCHULTES, Thomas Suefke, Reiner Mueller, Hartmut Schikowsky, Werner Hoess
Abstract: The invention relates to a controlled polymerization method for producing telechelics on the basis of (meth)acrylate, which have a bimodal molecular weight distribution, and to the use thereof as binders in glues or sealing compounds.
Type:
Application
Filed:
October 6, 2009
Publication date:
September 1, 2011
Applicant:
Evonik Roehm Gmbh
Inventors:
Sven Balk, Stephan Fengler, Holger Kautz, Karola Dworak, Christine Troemer, Lars Zander, Jens Lueckert, Johann Klein, Thomas Moeller, Volker Erb
Abstract: The invention relates to a controlled polymerization method for producing ABA-triblock copolymers on the basis of (meth)acrylate with A-blocks which have a narrow, monomodal molecular weight distribution and a B-block which has a bimodal molecular weight distribution, and to the use thereof as binders in glues and sealing materials
Type:
Application
Filed:
October 6, 2009
Publication date:
August 25, 2011
Applicants:
EVONIK ROEHM GMBH, Henkel AG & Co. KGAA
Inventors:
Sven Balk, Holger Kautz, Stephan Fengler, Christine Troemer, Monika Maerz, Lars Zander, Jens Lueckert, Johann Klein, Thomas Moeller, Volker Erb