Abstract: An electrochemical system includes first and second endplates and a plurality of electrochemical units disposed between the first and second endplates. Each of the plurality of electrochemical units includes a porous anode disposed in an anode compartment, a porous cathode disposed in a cathode compartment, and a center compartment disposed between and separated from the anode compartment and the cathode compartment by cation exchange membranes.

Abstract: A method and system of providing ultrapure water for semiconductor fabrication operations is provided. The water is treated by utilizing a free radical scavenging system. The free radical scavenging system can utilize actinic radiation with a free radical precursor compound, such as ammonium persulfate. The ultrapure water may be further treated by utilizing ion exchange media and degasification apparatus. A control system can be utilized to regulate a continuously variable intensity of the actinic radiation.

Abstract: Systems for treating water are disclosed. The system includes an ozonation subsystem including a source of ozone configured to dissolve ozone into water from a source of water to produce ozonated water. The system further includes an electrochemical cell co-located with the ozonation subsystem having an inlet connectable to a source of electrolyte and an outlet. The electrochemical cell is configured to produce hydrogen peroxide from electrolyte from the source of electrolyte. The system additionally includes a mixing zone configured to receive the ozonated water, to receive the hydrogen peroxide from the outlet of the electrochemical cell, and to mix the ozonated water and hydrogen peroxide to form peroxone. Systems and methods of treating water, such as by selectively removing one or more emergent compounds from contaminated water, using the system are also disclosed.

Abstract: Methods of stabilizing virgin ion exchange resin material are provided. The methods include cleansing the virgin ion exchange resin material with a preparation comprising a non-ionic detergent. The methods include cleansing the virgin ion exchange resin material with a preparation comprising an alcohol solvent. The methods include rinsing virgin ion exchange resin material with deoxygenated water, the methods include introducing the cleansed/rinsed virgin ion exchange resin material into a gas impermeable vessel and hermetically sealing the vessel. The methods include introducing an oxygen scavenging material into the gas impermeable vessel, and hermetically sealing the vessel. A method of facilitating water treatment in a site in need thereof by providing a cleansed virgin ion exchange resin material in deoxygenated water is also disclosed.

Abstract: Water treatment systems including electrically-driven and pressure-driven separation apparatus configured to produce a first treated water suitable for use as irrigation water and a second treated water suitable for use as potable water from one of brackish water and saline water and methods of operation of same.

Abstract: A method of treating wastewater comprises performing biological treatment of the wastewater to generate a sludge, adding a ballasting agent to the sludge to form a ballasted sludge, and performing solid-liquid separation of a first portion of the ballasted sludge using a dissolved air flotation process to form a solids-rich concentrated sludge and a solids-lean effluent.

Abstract: A reverse osmosis (RO) system is described that is connected to a dialysis machine and is capable of using heated purified water to clean and disinfect an external connection section or portion disposed between the RO systems and the dialysis unit (or any other external heat tolerant device) without forming a closed loop system between both systems before and during a heat forward process. This can be accomplished without the need for direct/indirect or wired/wireless communication with the dialysis unit or the need to introduce a chemical cleaner or process that would require further rinsing after chemical disinfection.

Abstract: A method of operating an electrochemical device includes periodically discharging a volume of concentrate reject in a timed batch cycle and replacing the concentrate reject with feed water. An electrochemical water treatment system includes a recycle line having a valve controlled by a control module. The control module periodically opens the valve to discharge concentrate reject from the recycle line in a batch timed cycle. The recycle line is fed with feed water to replace the discharged concentrate reject.

Abstract: A water treatment system for producing potable water and water for irrigation from saline water, the system includes an electrodialysis apparatus including one or more monovalent selective membranes and having an inlet fluidly connectable to a source of water to be treated, a diluate outlet, and a concentrate outlet, a nanofiltration apparatus positioned downstream of the electrodialysis apparatus and having an inlet fluidly connectable to the diluate outlet of the electrodialysis apparatus, a permeate outlet, and a retentate outlet, and an electrolyzer in fluid communication with one of the concentrate outlet and the retentate outlet, and configured to generate a product stream including one or more of chlorine gas, hypochlorite ion, sodium hydroxide, sulfuric acid, hydrochloric acid, or sodium hypochlorite.

Abstract: A wastewater treatment system including a contact tank, a dissolved air flotation unit, a fermentation unit, and a biological treatment unit is disclosed. A method of retrofitting a wastewater treatment system by arranging the wastewater treatment system such that floated biosolids are fermented in an anerobic environment and fluidly connecting the biological treatment unit to receive at least a portion of the fermented solids is also disclosed. The method optionally includes providing a fermentation unit and fluidly connecting the fermentation unit to a biological treatment unit. A method of treating wastewater including combining the wastewater with activated sludge, floating biosolids from the activated wastewater, fermenting the floated biosolids, and biologically treating the effluent with the fermented solids is also disclosed. A method of facilitating delivery of soluble organic carbon to a biological treatment unit is also disclosed.

Abstract: A method of recovering phosphoric acid from process water includes directing a process water stream having a pH and a first concentration of phosphoric acid and at least one salt into a vessel, contacting the process water stream with a sorption agent in the vessel, the sorption agent adsorbing phosphoric acid from the process water, withdrawing a first effluent including a first concentration of the at least one salt and a second concentration of phosphoric acid from the vessel, and contacting the sorption agent including the phosphoric acid with water, at least a portion of the phosphoric acid desorbing from the ion exchange media into the water to form a second effluent having a third concentration of phosphoric acid.

Abstract: Methods of producing an ion exchange membrane support are disclosed. The methods include saturating a polymeric microporous substrate with a charged monomer solution comprising at least one functional monomer, a cross-linking agent, and an effective amount of at least one photopolymerization initiator and polymerizing the at least one functional monomer by exposing the saturated polymeric microporous substrate to ultraviolet light under conditions effective to cross-link the at least one functional monomer and produce the ion exchange membrane support. Methods of producing a monovalent selective ion exchange membrane are also disclosed. The methods include functionalizing an exterior surface of the ion exchange membrane support with a charged compound layer, drying the ion exchange membrane support and soaking the ion exchange membrane support in a solution comprising an acid or a base for an amount of time effective to produce the monovalent selective ion exchange membrane.

Abstract: A conditioning system for a filter module is disclosed. The conditioning system may generally include an inlet, a heat exchanger, a magnetically levitated pump, a channel provided to bypass the heat exchanger, a controller, an outlet, and a base. The system may have components lined with corrosion-resistant materials. A method of conditioning a filter module is also disclosed. The method may generally include measuring TOC in a source of ultrapure water, heating the ultrapure water, rinsing a filter module with the heated water, flushing the filter module with ambient temperature water, and repeating the rinsing with heated water and flushing with ambient temperature water. A method of facilitating conditioning of the filter module is also disclosed. The method may generally include providing a portable filter module conditioning system and providing instructions for installation or use.

Abstract: A method of treating water in a water treatment system after a replacement of an ion exchange bed includes introducing water to be treated into the ion exchange bed of the water treatment system to produce treated water, calculating a current exchange daily average flow rate of water through the water treatment system, calculating a cumulative daily average flow rate of water through the water treatment system, and determining an estimated number of days remaining to exhaustion of the ion exchange bed based on the current exchange daily average flow rate and the cumulative daily average flow rate.

Abstract: Modified activated carbon is disclosed for use in water treatment. In at least some embodiments, activated carbon may be treated with a positively-charged surfactant, i.e. a quaternary ammonium-based surfactant, to promote the removal of poly- and perfluoroalkyl substances from water.

Abstract: A system for the treatment of phosphate-containing wastewater comprises a pretreatment subsystem including a mixing chamber configured to mix a potassium-based salt with the wastewater to precipitate K2SiF6 from the wastewater, a solids-liquid separator to separate the precipitated K2SiF6 from the wastewater and form a pretreated wastewater, and a mixing chamber to dilute the pretreated wastewater with raw wastewater, and a filtration subsystem including a first filtration configured to receive the pretreated wastewater and remove particles to form a first effluent, a second filtration unit remove divalent ions from the first effluent and form a second effluent, and a third filtration unit configured to remove additional dissolved solids from the second effluent and form a third effluent suitable for discharge to the environment.

Abstract: A gas analyzer uses continuous sonic signals through a conduit to determine the composition of a gas in the conduit. A transmitting transducer drives sonic signals at a fixed frequency and a second transducer receives the sonic signals. The phase shift between two signals corresponds to the speed of sound through the gas and is related to the composition of the gas. The electronic versions of these signals are processed by lowering, or dividing, the fixed frequency which expands the range of phase shift measurement and allows the determination of an expanded range for the gas composition. In an ozone generation system, the gas analyzer is highly suitable for determining the composition of gases derived from air as a gas of known composition and a calibration point.

Abstract: In a system for decomposing organic compounds in water for use in semiconductor manufacturing, a chemical reactor vessel having a fluid inlet and a fluid outlet, a persulfate anion addition system upstream of the reactor vessel, and a light emitting device contained within the reactor vessel. The light emitting device provides light capable of decomposing persulfate anions.

Abstract: The present invention is directed to asymmetric membranes and methods for making such membranes, wherein the membranes have a void volume and nanoparticles located in the void volume. The membranes have a variety of applications, including blood purification, water purification, water decontamination and bioprocessing.

Abstract: An electrochlorination system comprises a source of feed fluid, a product fluid outlet, and a plurality of electrochemical cells connected fluidically between the source of feed fluid and the product fluid outlet. The system is configured to operate at least one of the plurality of electrochemical cells at one of a first current density or a first flow rate, and to operate another of the plurality of electrochemical cells at a second current density or second flow rate different from the respective first current density or first flow rate.