Patents Assigned to Exxon Chemical Patents Inc
  • Patent number: 5993054
    Abstract: Additives are blended with a stream of liquid, for example of diesel fuel, by injecting at least two different additive compositions into the stream, and adjusting the rates of injection and the relative proportions of the injected additive compositions. This enables the consumption of additives to be minimized while enabling desired fuel characteristics to be maintained despite variations in the characteristics of the untreated liquid. The rates of injection may be adjusted by an automatic controller (32) in response to signals from sensors (28, 30) representing characteristics of the liquid before and after treatment.
    Type: Grant
    Filed: September 10, 1997
    Date of Patent: November 30, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Gerard BH Tan, Brian William Davies, Francesco L Baracchini
  • Patent number: 5994603
    Abstract: A process is provided for the production of paraxylene by the methylation of toluene in the presence of a zeolite bound zeolite catalyst. The catalyst comprises first zeolite crystals which are bound together by second zeolite crystals. When used to methylate toluene to para-xylene, the zeolite bound zeolite catalyst has a para-xylene selectivity greater than thermodynamic equilibrium. This selectivity can be enhanced by selectivating the catalyst.
    Type: Grant
    Filed: May 29, 1997
    Date of Patent: November 30, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Gary D. Mohr, Robert Scott Smith
  • Patent number: 5994482
    Abstract: The present invention relates to polypropylene alloys which are especially suited for soft fiber and fabric applications. An embodiment of these alloys comprise an ethylene-propylene random copolymer having an ethylene content of from about 1.0 to 5.0% by weight, in an amount of from about 40 to 90% by weight of the alloy; and an ethylene-propylene bipolymer having an ethylene content of from about 10 to 30% by weight, in an amount of from about 10 to 60% by weight of the alloy. The present invention further relates to a hybrid process for making these alloys.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: November 30, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: George Byron Georgellis, Chia Yung Cheng, William Moa-Tseng Chien
  • Patent number: 5993642
    Abstract: There is provided a process for converting hydrocarbons which utilizes a zeolite bound zeolite catalyst that has enhanced performance when utilized in hydrocarbon conversion processes, e.g., catalytic cracking, alkylation, disproportionation of toluene, isomerization, and transalkylation reactions. The catalyst comprises a first zeolite having particles of greater than about 0.1 micron average particle size and a binder comprising second zeolite particles having an average particle size less than said first particles.
    Type: Grant
    Filed: November 22, 1995
    Date of Patent: November 30, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Gary David Mohr, Tan Jen Chen, Kenneth Ray Clem, Mechilium Johannes Geradus Janssen, Phillip Andrew Ruziska, Johannes Petrus Verduijn, Jannetje Maatje van den Berge
  • Patent number: 5994277
    Abstract: Crankcase lubricant compositions for use in automobile or truck engines comprise a major amount of a lubricating oil, added copper present in oil-soluble form, at least 2 ppm of molybdenum present in oil-soluble form, and a total of from 0.05 to 2 mass % of one or more oil-soluble aromatic amines. The specified additives provide a highly effective antioxidant system.
    Type: Grant
    Filed: April 3, 1996
    Date of Patent: November 30, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Andrew J. D. Ritchie, Harold Shaub, Ian P. Field
  • Patent number: 5994278
    Abstract: A lubricating oil comprising an add mixture of the following components: (A) a complex alcohol ester basestock which comprises the reaction product of an add mixture of the following: (1) a polyhydroxyl compound represented by the general formula:R(OH).sub.nwherein R is any aliphatic or cyclo-aliphatic hydrocarbyl group and n is at least 2, provided that the hydrocarbyl group contains from about 2 to 20 carbon atoms; (2) a polybasic acid or an anhydride of a polybasic acid, provided that the ratio of equivalents of the polybasic acid to equivalents of alcohol from the polyhydroxyl compound is in the range between about 1.6:1 to 2:1; and (3) a monohydric alcohol, provided that the ratio of equivalents of the monohydric alcohol to equivalents of the polybasic acid is in the range between about 0.84:1 to 1.2:1; wherein the complex alcohol ester exhibits a viscosity in the range between about 100-700 cSt at 40.degree. C. and having a polybasic acid ester concentration of less than or equal to 70 wt.
    Type: Grant
    Filed: February 7, 1997
    Date of Patent: November 30, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Carolyn Boggus Duncan, David Wayne Turner
  • Patent number: 5981817
    Abstract: A process for isomerizing a nonequilibrium xylene feed mixture is disclosed. The isomerization is conducted in the presence of hydrogen and at pressures in excess of 75 psig over a ZSM-5 type catalyst containing about 0.1 to 5 wt % of at least one metal selected from the group consisting of zinc, copper, silver and gallium. In another embodiment, the catalyst may further contain an oxide of at least one element selected from silicon, germanium and tin. The process produces a product containing about or above equilibrium quantities of para-xylene with low xylene loss.
    Type: Grant
    Filed: April 10, 1997
    Date of Patent: November 9, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Jar-Lin Kao, Greg J. De Martin, Stuart Leon Soled
  • Patent number: 5981820
    Abstract: A process and catalyst for isomerizing olefins are disclosed. The process and catalyst are particularly useful for isomerizing alkenyl bridged ring compounds to the corresponding alkyladiene bridged ring compounds. In one embodiment, the isomerization catalyst comprises an oxygen treated mixture of an alkali metal on a dried support having a surface area of 125 to 195 m.sup.2 /g when the support consists essentially of alumina wherein the alumina precursor is a large crystallite pseudoboehmite. The catalyst is particularly useful for isomerizing 5-vinyl-2-norbornene to 5-ethylidiene-2-norbornene. The catalyst is very active and highly selective and resistant to catalyst poisons. The process contacts the catalyst with an alkenyl bridged ring compound and yields the corresponding alkyladiene bridged ring compound.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: November 9, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Robert Scott Smith, Christopher Lynn Becker
  • Patent number: 5980731
    Abstract: The invention provides a crystalline type L zeolite reforming catalyst comprising cylindrically shaped crystals having a length of 0.6 microns or less and an average length: diameter ratio of less than about 0.5, the catalyst containing at least one Group VIII metal and from about 0.1 to 2 wt % halogen e.g., chlorine. Also provided is a method for activating or regenerating the catalyst wherein a fresh or de-coked catalyst is oxychlorinated, purged to remove excess chlorine and reduced. The catalysts are particularly useful for the reforming of C.sub.6 to C.sub.11 naphthas to produce reformates having a high content of C.sub.6 to C.sub.8 light aromatics and a reduced content of heavier C.sub.9 and C.sub.10 aromatics.
    Type: Grant
    Filed: November 7, 1997
    Date of Patent: November 9, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Jar-Lin Kao, Scott A. Ramsey
  • Patent number: 5981643
    Abstract: Copolymers of ethylene and a cyclic olefin, preferably a fused ring cyclic olefin (FRCO), optionally containing an alpha-olefin and/or a non-conjugated diene, display increasing glass transition temperatures (T.sub.g) as the amount of FRCO in the copolymer increases. This increase brings these polymers quickly above a T.sub.g acceptable as elastomers. Addition of specially selected process oils, based on cohesive energy densities of both the copolymer and the process oil, is shown to lower T.sub.g to a range acceptable for elastomers e.g. below about -30.degree. C. The copolymer/process oil combination can then be used in elastomer compounding operations and behave in typical elastomer fashion.
    Type: Grant
    Filed: October 9, 1997
    Date of Patent: November 9, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Sudhin Datta, Bruce A. Harrington
  • Patent number: 5976706
    Abstract: Polyesterdiols having low viscosities of less than 3500 cps, high content of non-volatile matter in excess of 96 wt %, and narrow molecular weight distribution of less than about 1.4 are prepared by esterification of one or more aliphatic dicarboxylic acids or ester derivatives thereof using at least a 1.5 molar excess of one or more aliphatic diols until an acid number of less than 20 is achieved, and stripping excess diol from the polyesterdiol reaction product. Where esterification catalyst is used, catalyst is substantially removed prior to stripping excess unreacted diol from polyesterdiol reaction product. The polyesterdiols so produced are useful as (i) curable components in thermosettable resin compositions, particularly compositions essentially free of volatile organic solvent and also containing a crosslinking agent and a reactive hardening agent: and/or (ii) useful as coatings, paints and adhesives, providing coatings with very low content of volatile organic compounds.
    Type: Grant
    Filed: July 27, 1998
    Date of Patent: November 2, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Albert Ilya Yezrielev, Konstantinos R. Rigopoulos, Richard William Ryan, Karen K. Kuo, George Andrew Knudsen
  • Patent number: 5972853
    Abstract: A lubricating oil composition comprising oil, and an additive combination comprising a poly alpha-olefin polymer dispersant with a number average molecular weight above 2500, and a metal dihydrocarbyl dithiophosphate sufficient to yield a phosphorous content of up to 0.1 percent weight based on the total weight of the oil. The poly alpha-olefin polymer can be ethylene alpha-olefin copolymer such as ethylene-1-butene or ethylene-1-butene-hydrocarbyl polyamine. Preferably, the ethylene-1-butene-hydrocarbyl polyamine has a number average molecular weight of about 3300.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: October 26, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Alexander B. Boffa, Thomas R. Bidwell
  • Patent number: 5972203
    Abstract: There is provided catalysts and conversion processes for converting hydrocarbons using the catalysts. The catalysts comprises a first alumino-phosphospho-molecular sieves and a binder comprising a second alumino-phopho-molecular sieves. Exemplary conversion processes include the conversion of oxygenates to olefins, dewaxing, reforming, dealkylation, dehydrogenation, transalkylation, alkylation, and isomerization.
    Type: Grant
    Filed: May 29, 1997
    Date of Patent: October 26, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Robert Scott Smith, Gary D. Mohr
  • Patent number: 5973072
    Abstract: The present invention is directed to a polymeric vehicle, the formulated coating composition and a coating binder made from the polymeric vehicle and a method for making the polymeric vehicle where the polymeric vehicle includes a phenolic urethane reactive diluent. The phenolic urethane reactive diluent may be made from a phenolic ester alcohol having at least one aliphatic hydroxyl group.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: October 26, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Frank N. Jones, Vijay Swarup, Ramachandran P. Subrayan, Suru Zhang
  • Patent number: 5972823
    Abstract: The invention is directed to a catalyst composition suitable for addition reactions of ethylenically and acetylenically unsaturated monomers comprising a metal oxide support having covalently bound to the surface thereof directly through the oxygen atom of the metal oxide an activator anion that is also ionically bound to a catalytically active transition metal cation compound. The invention includes a preparation process for the invention catalyst composition exemplified by reacting a Lewis acid, such as trisperfluorophenyl boron with residual silanol groups of a silica support, preferably then reacting with a Lewis base such as diethylaniline, so as to prepare a silica bound anionic activator that when combined with a suitable transition metal compound will protonate it so as to form the ionic catalyst system. Use of the invention catalyst to polymerize alpha-olefins is exemplified.
    Type: Grant
    Filed: July 14, 1997
    Date of Patent: October 26, 1999
    Assignee: Exxon Chemical Patents Inc
    Inventor: John Flexer Walzer, Jr.
  • Patent number: 5972852
    Abstract: Synthetic lubricating oils for use in lubricating internal combustion engines, having good compatibility with elastomeric seals and good stability, but without making use of organic acid ester basestocks, comprise a synthetic basestock such as polyalphaolefin oligomers, an additive package comprising a hydrocarbyl substituted dicarboxylic acid or anhydride in which the hydrocarbyl group has a number average molecular weight (M.sub.n) of from 700 to 5000 and a viscosity modifier.
    Type: Grant
    Filed: March 26, 1997
    Date of Patent: October 26, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventor: Robert Robson
  • Patent number: 5969085
    Abstract: This invention relates to a polymeric vehicle which is effective for providing a high solids formulated coating composition. The polymeric vehicle comprises a blend of at least one nonmesogenic substantially linear oligoester diol and at least one hardener which is a mesogenic polyol, phenolic ester alcohol or crystalline polyol, which blend is effective for reaction with a crosslinker which is reactive with the nonmesogenic oligoester and hardener.
    Type: Grant
    Filed: November 10, 1997
    Date of Patent: October 19, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Frank N. Jones, Shou-Kuan Fu, Xiaoying Yuan, Jun Hua, Vijay Swarup
  • Patent number: 5965805
    Abstract: Described is an apparatus and a method to accurately determine the gas entrainment characteristics of liquids, such as automatic transmission fluids. The apparatus comprises a liquid reservoir, a conduit having an inlet and an outlet connected to the liquid reservoir so as to form a pressurized recirculating loop for the liquid in the liquid reservoir, a pump for moving the liquid through the conduit, and a means for admitting gas (such as air) into the conduit to aerate the liquid.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: October 12, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Raymond F. Watts, Manoj Tandon, Patrick J. Colby
  • Patent number: 5965497
    Abstract: This invention relates to shear stable multigrade oils for crankcase lubrication of gasoline and diesel engines which oils are substantially free of viscosity modifier additives and comprise a detergent inhibitor package of lubricating oil additives, which package includes an ashless dispersant comprising an oil soluble polymeric hydrocarbon backbone having functional groups in which the hydrocarbon backbone is derived from an ethylene alpha-olefin (EAO) copolymer or alpha-olefin homo- or copolymer an M.sub.n of from 500 to 7000. Such multigrade crankcase oils without viscosity modifiers are more economical and may provide better diesel performance and seal comparability. The oils are also substantially shear stable and may be used in turbocharged engines and racing engines, with reduced mechanical breakdown of the oil.
    Type: Grant
    Filed: December 9, 1996
    Date of Patent: October 12, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: David Robert Adams, Paul Brice
  • Patent number: 5965498
    Abstract: A two-cycle oil composition comprising: (a) 10-20% of a first synthetic ester base stock oil (a copolymer of an alpha-olefin with an ester of a dicarboxylic acid, viscosity 20 to 50 cSt at 100.degree. C.); (b) 18-30% of a second synthetic ester base stock oil (an oxo alcohol of a dicarboxylic acid, viscosity 3 to 10 cSt at 100.degree. C.; (c) 30-40% of a polybutene polymer (Mn 300-1500); (d) 15-25% of a nor liquid solvent (boiling point up to 300.degree. C., flash point of 60 .degree.-120.degree. C.); (e) 0.2 to 2.0% of an oil soluble copper compound, and (f) 0 to 5% of other lubricating oil additives.
    Type: Grant
    Filed: May 14, 1998
    Date of Patent: October 12, 1999
    Assignee: Exxon Chemical Patents Inc
    Inventor: John Henry Smythe