Abstract: The invention relates to a process for converting oxygenated organic material, to olefins using small pore molecular sieve catalysts. More particularly, the invention relates to a method for converting oxygenated organic material to olefins with improved the olefin yields and decreased yields of methane and other light saturate byproducts. The improved yield slate is achieved by treating the small pore molecular sieve catalyst with a modifier selected from the group consisting of polynuclear aromatic heterocyclic compounds with at least three interconnected ring structures having at least one nitrogen atom as a ring substituent, each ring structure having at least five ring members, decomposed derivatives of said polynuclear aromatic heterocyclic compound, and mixtures thereof.
Type:
Grant
Filed:
October 29, 1997
Date of Patent:
April 18, 2000
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Hsiang-ning Sun, Stephen Neil Vaughn, Robert Scott Smith
Abstract: A dilute ethylene stream, e.g., one produced by steam cracking, is oxonated to yield propanal, without the need to separate other lower hydrocarbons.
Type:
Grant
Filed:
October 15, 1997
Date of Patent:
April 11, 2000
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Gabor Kiss, Michael G Matturro, Harry William Deckman, Frank Hershkowitz, David R. Lumgair, Jr., Gary F Janda, Daniel N King
Abstract: A method for preparing a catalyst and the use of such catalyst for converting an oxygenate feed to olefins wherein the catalyst is modified or treated with the aid of electromagnetic energy.
Abstract: The compatibility with nitrile ester seals of lubricating compositions containing active sulphur-containing additives may be enhanced bt treating the additives, or concentrates containing them, or the composition themselves, with one or more olefinically unsaturated compounds selected from:(a) acyclic compounds having at least two double bonds with adjacent double bonds separated by two saturated carbon atoms;(b) compounds containing an acyclic ring, which ring contains at least, eight carbon atoms and at least two double bonds, each double bond being separated from the closest adjacent double bond(s) by two saturated carbon atoms; and(c) compounds containing a saturated alicyclic ring and at least one exocyclic double bond.
Type:
Grant
Filed:
July 13, 1998
Date of Patent:
March 28, 2000
Assignee:
Exxon Chemical Patents, Inc.
Inventors:
Dale Robert Carroll, Brid Dilworth, Michele Anne Thornhill
Abstract: Low temperature hydrothermal treatment of an LTL zeolite-producing mixture produces a colloidal suspension of the zeolite; the suspension may be used as seeds in Al-- and Ga--LTL zeolite manufacture.
Type:
Grant
Filed:
June 20, 1997
Date of Patent:
March 28, 2000
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Johannes Petrus Verduijn, Machteld M Mertens, Marc H Anthonis
Abstract: There is provided a zeolite bound zeolite catalyst which does not contain significant amounts of non-zeolitic binder and a process for converting hydrocarbons utilizing the zeolite bound zeolite catalyst. The catalyst comprises first zeolite, crystals, a binder comprising second zeolite crystals and a hydrogenation/dehydrogenation metal. The zeolite bound zeolite catalyst is prepared by converting the silica binder of a silica bound aggregate containing the first crystals of said first zeolite and at least a portion of the hydrogenation/dehydrogenation metal to said second zeolite. The zeolite bound zeolite catalyst has excellent performance when used in hydrocarbon conversion processes such as naphtha reforming and xylenes isomerization/ethylbenzene conversion.
Type:
Grant
Filed:
May 29, 1997
Date of Patent:
March 21, 2000
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Gary David Mohr, Johannes Petrus Verduijn
Abstract: A method for converting starting material to olefins comprising contacting the starting material with a small pore non-zeolitic molecular sieve catalyst under effective conditions to produce olefins, wherein the non-zeolitic molecular sieve has been prepared in-situ or modified after synthesis by incorporation using an alkaline earth metal compound, wherein the alkaline earth metal ion is selected from the group consisting of strontium, calcium, barium, and mixtures thereof.
Abstract: There is provided a process for converting hydrocarbons which utilizes a zeolite bound zeolite catalyst that has enhanced performance when utilized in hydrocarbon conversion processes, e.g., catalytic cracking, alkylation, disproportionation of toluene, isomerization, and transalkylation reactions. The catalyst comprises a first zeolite having particles of greater than about 0.1 micron average particle size and a binder comprising second zeolite particles having an average particle size less than said first particles.
Type:
Grant
Filed:
May 19, 1998
Date of Patent:
March 21, 2000
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Gary David Mohr, Johannes Petrus Verduijn
Abstract: A continuous process for functionalizing polymers is disclosed, wherein (A) a liquid comprising the polymer and a gas comprising a functionalizing agent are continuously introduced into a dispersing zone operated in laminar flow with high intensity mixing of the liquid and the gas under functionalization conditions, wherein the mixing is conducted for a period of the dispersing zone residence time at a shear rate effective to form a stable gas-liquid dispersion in which the gas is substantially dissolved or dispersed in the liquid for functionalization, and wherein the shear rate is less than about 5 s.sup.-1 for no more than about 30% of the residence time; (B) the gas-liquid dispersion is continuously passed to a blending zone operated in laminar flow with low intensity mixing under functionalization conditions, wherein the mixing is conducted at a shear rate effective to further dissolve the gas into the liquid for further functionalization; and (C) continuously recovering functionalized polymer.
Type:
Grant
Filed:
December 30, 1997
Date of Patent:
March 14, 2000
Assignees:
Exxon Chemical Patents, Inc., Koch-Glitsch, Inc.
Inventors:
David C. Dankworth, Chris F. Meyer, William B. Eckstrom, Ramesh R. Hemrajani, Salvatore Rea, Jon E. Stanat
Abstract: A gas conveying system capable of conveying a solid material without pushing or compressing the solid material. The system comprising: at least one conduit assembly comprising a conduit, a lance assembly disposed about a first end of the conduit which is capable of removing the solid material from a holding device, and a first eductor which is capable of entraining the solid material in a gas stream and moving the solid material through the conduit; a cyclone disposed about a second end of the conduit, the cyclone being capable of separating the solid material from the gas stream; and a second eductor disposed to receive the solid material from the cyclone, the second eductor being capable of entraining the solid material in a second gas stream which has a solid-material-to gas mass ratio which is greater than that of the first eductor. The second stage eductor transports the particles further downstream for storage, additional transport, or for further treatment, such as burning in an incinerator.
Abstract: The invention provides a process for improving the conversion of a hydrocarbon feedstock to light olefins comprising the steps of first contacting the hydrocarbon feedstock with a light olefin producing cracking catalyst and subsequently thermally cracking the unseparated stream to produce additional ethylene. Preferably the zeolite catalyst is selected from the group consisting of ferrierite, heulandite, phillipsite, faujasite, chabazite, erionite, mordenite, offretite, gmelinite, analcite, ZSM-5, ZSM-11, ZSM-25, gallium silicate zeolite, zeolite Beta, zeolite rho, ZK5, titanosilicate, zeolites having a silica to alumina molar ratio within the range of about 2.0:1 to 2000:1 ferrosilicate; zeolites such as those described in U.S. Pat. No. 4,238,318; borosilicate zeolites such as those described in Belgian Pat. No. 859656; zeolites designated by the Linde Division of Union Carbide by the letters of X, Y, A, L; zeolites such as those described in U.S. Pat. No.
Abstract: The invention pertains to oil soluble copolymers derived from ethylene and 1-butene which have a number average molecular weight between about 1,500 and 7,500, at least about 30 percent of all polymer chains terminated with ethylvinylidene groups, and ethylene-derived content of not greater than about 50 weight percent, and which form solutions in mineral oil free of polymer aggregates, as determined by light scattering measurements. Lubricating oil additives, particularly dispersants, produced by the functionalization and derivatization of these copolymers have enhanced performance (e.g., improved dispersancy and pour point) in lubricating oil compositions, attributable in part to the combination of properties characterizing the copolymers.
Type:
Grant
Filed:
May 14, 1997
Date of Patent:
February 29, 2000
Assignee:
Exxon Chemical Patents Inc
Inventors:
Jacob Emert, Albert Rossi, Salvatore Rea, Jeffrey William Frederick, Mahn Won Kim
Abstract: A composition, suitable for use in producing a tire carcass, is provided. The composition comprises a halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene; a rubber such as a blend of natural rubber and a copolymer of styrene and butadiene; carbon black, and a plasticizer oil. Tires comprising carcasses made of the composition are also provided.
Abstract: Sulfur-containing boroester compounds useful as antiwear additives for oleaginous compositions including alicyclic borate thioesters having the general formula (I): ##STR1## wherein R.sub.1 is a hydrocarbyl radical having 4 to 12 carbon atoms, R.sub.2 and R.sub.3 are independently selected from --(OR.sub.4).sub.n SR.sub.1 and --(OR.sub.4).sub.n SR.sub.1 OH; R.sub.4 is a hydrocarbyl radical having 1 to 6 carbon atoms; n is an integer of from 1 to 4; and l and m are independently 0, 1 or 2; thioalkyl-substituted cyclic meta borate esters having the general formula (II): ##STR2## wherein n, R.sub.1 and R.sub.4 are defined as in formula (I); and mixtures of the alicyclic compounds of formula (I) and the cyclic compounds of formula (II).
Type:
Grant
Filed:
November 25, 1998
Date of Patent:
February 22, 2000
Assignee:
Exxon Chemical Patents, Inc.
Inventors:
Raymond F Watts, Ricardo A. Bloch, Jack Ryer, deceased, Roger K. Nibert, James S. Puckace
Abstract: The present invention relates to methods for selectively converting oxygenates to light olefins, preferably ethylene and propylene, in which desirable carbonaceous deposits are maintained on a total reaction volume of catalyst by totally regenerating only a portion of the total reaction volume of catalyst and mixing the regenerated portion with the unregenerated total reaction volume of catalyst.
Type:
Grant
Filed:
July 3, 1997
Date of Patent:
February 8, 2000
Assignee:
Exxon Chemicals Patents Inc.
Inventors:
James Richardson Lattner, Hsiang-ning Sun, Stephen Neil Vaughn, Keith H. Kuechler, David C. Skouby
Abstract: The present invention includes related methods and uses, including composition comprising the polymer derived from a monomer having the formula:H.sub.2 C.dbd.CHR; (1)and optionally at least one monomer selected from the group consisting of monomers having the formula:R.sup.1 HC.dbd.CHR.sup.2 ; and (2)H.sub.2 C.dbd.CR.sup.2 R.sup.3 (3)wherein R is a hydrocarbon or substituted hydrocarbon having from 2 to 22 carbon atoms, and R.sup.1, R.sup.2 and R.sup.3 are the same or different hydrocarbons or substituted hydrocarbons having 1 to 22 carbon atoms. R is preferably an ethyl group (--CH.sub.2 CH.sub.3) and R.sup.1, R.sup.2 and R.sup.3 are preferably methyl groups (--CH.sub.3).
Type:
Grant
Filed:
July 23, 1998
Date of Patent:
February 8, 2000
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Frank Joung-Yei Chen, Jon Edmond Randolph Stanat, Cezar S. Baula
Abstract: Polymers (including copolymers) derived from one or more olefins, such including ethylene and C.sub.3 -C.sub.20 .alpha.-olefins such as propylene and 1-butene, which polymers have (a) an average ethylene sequence length, ESL, of from about 1.0 to less than about 3.0; (b) an average of at least 5 branches per 100 carbon atoms of the polymer chains comprising the polymer; (c) at least about 50% of said branches being methyl and/or ethyl branches; (d) at least about 30% of said polymer chains terminated with a vinyl or vinylene group; (e) a number average molecular weight, Mn, of from about 300 to about 15,000 when the polymer is intended for dispersant or wax crystal modifier uses and up to about 500,000 where intended for viscosity modifier uses; and (f) substantial solubility in hydrocarbon and/or synthetic base oil.
Type:
Grant
Filed:
July 2, 1998
Date of Patent:
January 25, 2000
Assignee:
Exxon Chemical Patents Inc
Inventors:
Albert Rossi, Jacob Emert, David Edward Gindelberger, Jon Edmond Stanat, James Peter Stokes, Jaimes Sher
Abstract: A fuel oil composition comprising: (A) a major proportion of a middle distillate petroleum fuel having a wax content of less than 2 wt % at 10.degree. C. below the wax appearance point of the fuel, and either: (i) a final boiling point of greater than 355.degree. C. and either a (90-20%) distillation range of greater than 115 .degree. C. or a (FBP-90%) distillation range of 30.degree. C. or greater; or (ii) a final boiling point of greater than 360.degree. C. and either a (90-20%) distillation range of greater than 110.degree. C. or a (FBP-90%) distillation range of 25.degree. C. or greater; or (iii) a final boiling point of greater than 370.degree. C. and either a (90-20%) distillation range of greater than 100.degree. C. or a (FBP-90%) distillation range of 250.degree. C.
Type:
Grant
Filed:
September 30, 1997
Date of Patent:
January 18, 2000
Assignee:
Exxon Chemical Patents, Inc.
Inventors:
Gerald Ivan Brown, Kevin John Morton, Martin John Flannigan