Abstract: The invention relates to expanded graphite and methods of making the graphite and products that can be made from the graphite made from the inventive process. The invention includes the step of introducing a fluid into at least one of a plurality of interstices of graphite flake, wherein the fluid comprises at least one of a sub-critical point fluid, a near critical point fluid, or a supercritical fluid. The graphite flake is also intercalated with an intercalant and optionally an oxidizing agent. The invention may further include novel techniques of exfoliating the graphite. The invention may be practiced to make nano-sized graphite particles and also graphite composites. Preferred composites which may be made in accordance with the invention include conductive polymeric composites (thermally or electrically), paint composites, battery composites, capacitor composites, and pollution abatement catalyst support composites.

Abstract: The invention may be practiced to make graphite composites. Preferred composites which may be made in accordance with the invention include conductive polymeric composites (thermally or electrically), paint composites, battery composites, capacitor composites, and pollution abatement catalyst support composites. One method of making the graphite aforementioned composites includes introducing an intercalant into at least one interstice of at least one flake of natural graphite. The method also includes introducing a fluid into the at least one interstices of the flake. Preferably, the fluid comprises at least one of a sub-critical fluid, near critical point fluid, or a supercritical fluid. Furthermore the method includes blending the flake with a polymer, thereby forming a graphite-polymeric composite.

Abstract: A heat sink apparatus is constructed from alternating longer and shorter sheets of graphite material sandwiched together such that the longer sheets extend beyond the shorter sheets to define fins. The directions of higher thermal conductivity of the anisotropic graphite material are oriented in the plane of the sheet. The longer and shorter sheets have base ends aligned together to define a generally planar base surface for engaging an electronic device to be cooled.

Abstract: A composite heat sink apparatus includes a metal base which has a thermal conductivity of at least about 200 W/m° K. The metal base is preferably constructed either of copper of aluminum. The heat sink apparatus further includes a plurality of fins attached to the base, the fins being constructed of anisotropic graphite material having a direction of relatively high thermal conductivity perpendicular to the base.

Abstract: Partially expanded graphite flake having a specific volume of no more than about 50 cm3/g, more preferably, about 10-25 cm3/g has excellent sheet forming properties and is readily moldable to form molded products, such as gaskets. The partially expanded graphite flake may be produced by a low temperature process, in which the flakes are first intercalated with an intercalation solution, then subjected to a low temperature exfoliation of below about 500° C. In an alternative process, the flakes are intercalated with no more than about 40 pph of an intercalation solution (less if the particles are not subjected to a subsequent washing step) and then exfoliated at conventional exfoliation temperatures of about 800° C.

Abstract: The invention relates to tubular fuel cells and methods of making such fuel cells. The inventive fuel cells include at least one fluid permeable structure having a plurality of perforations or channels. The perforations allow fluids, e.g., hydrogen or oxygen, to flow through the structure. The inventive methods include forming at least one perforated structure and forming the perforated structure into a tubular fuel cell or at least a potential component of a tubular fuel cell.

Abstract: The invention relates to tubular fuel cells and methods of making such fuel cells. The inventive fuel cells include at least one fluid permeable structure having a plurality of perforations or channels. The perforations allow fluids, e.g., hydrogen or oxygen, to flow through the structure. The inventive methods include forming at least one perforated structure and forming the perforated structure into a tubular fuel cell or at least a potential component of a tubular fuel cell.

Abstract: Apparatus and methods are provided for the embossing of a sheet of flexible graphite material between a pair of embossing rollers. The embossing rollers include a primary embossing roller and a backup roller. The primary embossing roller has an embossing pattern defined thereon. One or both of the rollers include a raised stabilization area adjacent a periphery of the embossing pattern. The raised stabilization area preferably has a roughened outer surface for better gripping the sheet of flexible graphite material. The raised stabilization areas apply a stabilizing force to the sheet adjacent the periphery of the embossing pattern, thereby limiting egress of the material laterally away from the embossing pattern. The roughened surfaces increase the grip of the raised areas upon the sheet, thus aiding in pulling the sheet between the rollers and also aiding in the application of lateral stabilization forces to the sheet.

Abstract: Flexible graphite sheets having enhanced surface area prepared from materials comprising expanded graphite particles and activated carbon particles on phenol resin. The sheets with enhanced surface area are useful in the formation of articles adapted for use in supercapacitors.

Abstract: Components for use in electrochemical double-layer capacitors utilize at least one layer of a flexible graphite sheet material in an electrode or current collector or utilize a tanged metal layer in a current collector.

Abstract: Graphite sheets having enhanced surface area are prepared from flexible graphite sheets to which an activated carbon precursor has been added, followed by activation of the precursor. The sheets with enhanced surface area are useful in the formation of articles adapted for use in supercapacitors.

Abstract: An anode for a lithium-ion battery is presented as well as a process for producing an anode for a lithium-ion battery. The anode is formed from a generally continuous sheet of particles of exfoliated graphite having a thickness of no more than about 350 microns, itself or in a laminate with a metallic substrate. The process involves laminating particles of exfoliated graphite to a metallic substrate, such that the particles of exfoliated graphite form a generally continuous sheet of graphite having a thickness of no more than about 350 microns. The inventive anode reduces or eliminates capacity fading due to contact loss and has superior permeability to lithium.

Abstract: Fluid permeable graphite article in the form of a perforated flexible graphite sheet having increased electrical and thermal conductivity transverse to the surfaces of the sheet.

Abstract: A radial finned heat sink assembly for an electrical component is constructed from a graphite material, which may be resin impregnated. The assembly includes a base, and a plurality of spaced parallel planar fin members supported by the base. Each fin member includes a planar fin of an anisotropic graphite material having graphite layers aligned primarily with the plane of the fin. In a first construction the fin members include integral core portions. In a second construction the core portions are separately formed so that the graphene layers of the core portion are aligned primarily parallel to the core axis so that heat is efficiently transmitted from the base to the plate members along the core axis.

Abstract: A graphite article in the form of a flexible graphite sheet having transverse fluid channels passing through the sheet and a groove formed in one of the surfaces of the sheet communicating with a plurality of the transverse fluid channels is presented.

Abstract: An electrode for an electrochemical fuel cell is provided. More particularly, an electrode formed of a sheet of a compressed mass of expanded graphite particles having a plurality of transverse fluid channels passing through the sheet between first and second opposed surfaces of the sheet, is provided. The size, shape and/or placement of the channels, and/or the density of the sheet, is engineered so as to reduce or minimize flooding in the fuel cell.

Abstract: A catalyst support material useful in a membrane electrode assembly is presented. The support catalyst material is elongate electrically anisotropic particles of flexible graphite, and the membrane electrode assembly includes a pair of electrodes, an ion exchange membrane having opposed surfaces positioned between the electrodes and a catalyst material on the inventive support, at least a portion of an opposed surface of the ion exchange membrane being adjacent the catalyst which is supported on the elongate electrically anisotropic particles of flexible graphite sheet.

Abstract: An method for producing a material useful for forming a component for an electrochemical fuel cell is provided. More particularly, the component is formed of a sheet of a compressed mass of expanded graphite particles. The component is treated with a water resistant additive sufficient to provide utility as a component in an electrochemical fuel cell. Preferably, the water resistant additive is a fluoropolymer material. More preferably, the water resistant additive is a polytetrafluoroethylene material. The treatment preferably occurs by coating and/or impregnating the water resistant material in the sheet of graphite particles.

Abstract: Fluid permeable graphite article in the form of a perforated flexible graphite sheet having increased electrical and thermal conductivity transverse to the surfaces of the sheet.

Abstract: A method of manufacturing an electrode for an electrochemical fuel cell is disclosed, comprising providing a sheet of compressed mass of expanded graphite particles having a plurality of perforations defined by walls of the expanded graphite particles, and the perforations passing through the sheet between first and second opposed surfaces of the sheet; coating the sheet with a thermosettable organic resin, said coating step comprising filling a portion of said perforations with the thermosettable organic resin; curing and baking the sheet, and reopening a portion of the filled perforations during the curing and baking step; activating the thermosettable organic resin to form a high surface area carbon on the walls of the perforations; and loading a catalyst onto the high surface area carbon.