Abstract: A novel class of growth regulator compounds of the structural formula ##STR1## is disclosed, in which Y is --COOH or an agriculturally acceptable salt thereof, --COOR, --CH.sub.2 OH, --CHO, --R, --OR or halogen and R is C.sub.1 to C.sub.4 alkyl or alkenyl.
Abstract: Acrylate monomers useful as a component of U.V. curable resin compositions and anaerobic adhesive compositions are provided and have the structure: ##STR1## where the phenanthrene ring contains up to three (3) double bonds, where R.sub.1 is a divalent radical, where R.sub.2 is a divalent radical, and where R.sub.3 is a hydrogen atom or an alkyl group.
Type:
Grant
Filed:
June 20, 1980
Date of Patent:
January 5, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Thomas F. Huemmer, Pallavoor R. Lakshmanan
Abstract: Improved anaerobic adhesives are provided which contain two monomer types. The first is a polyacrylate terminated ester of 3,4,3',4'-benzophenone tetracarboxylic acid. The second is an acrylate terminated urethane prepolymer that is prepared in part from abietyl alcohol.
Type:
Grant
Filed:
June 20, 1980
Date of Patent:
January 5, 1982
Assignee:
Gulf Oil Corporation
Inventors:
Thomas F. Huemmer, Pallavoor R. Lakshmanan
Abstract: Compounds of the general structural formula, ##STR1## in which R.sup.1 is C.sub.1 to C.sub.4 lower alkyl, cycloalkyl or alkylamino and R.sup.2 is H or lower N-alkylcarbamyl are made from corresponding m-aminophenylacetylenic compounds by conventional methods and are useful as selective herbicides.
Abstract: A group of heat curable resins are provided which have good physical properties, which properties are retained to a surprising degree after prolonged exposure to temperatures as high as 300.degree. C. The products are acetylene end-capped esterimides having the structure: ##STR1## where R is an arylene group or a group having the structure: ##STR2## where X is ##STR3## R.sub.1 is an alkyl group containing 1 or 2 carbon atoms and R.sub.2 is hydrogen or an alkyl group containing 1 or 2 carbon atoms; and where R' is a phenylene group.
Abstract: The products of the invention are partial acetylene end-capped oligomers which have the structure as shown in FIG. 3 in which terminal R" group is derived from a mixture consisting of about 14-40 mol % of an aromatic monoamine and the balance an acetylene substituted aromatic monoamine. The products are prepared from either of two (2) precursors. The first precursor has the structure shown in FIG. 2. The second precursor is a complex amine salt having the structure shown in FIG. 5.
Type:
Grant
Filed:
May 3, 1979
Date of Patent:
November 10, 1981
Assignee:
Gulf Oil Corporation
Inventors:
Patricia A. Antonoplos, William J. Heilman
Abstract: A method of regulating the growth of plants, including combating unwanted vegetation, comprises applying to the plants, either on seed, the soil or directly on the plants an effective amount of a novel compound of the class having the general structural formula ##STR1## in which one of Q.sub.1, Q.sub.2, Q.sub.3 or Q.sub.4 is N, X is --OH or --O--(C.sub.1 -C.sub.4 alkyl) and Y is H or X and Y together represent a bond between carbon and nitrogen atoms and R is H or one or two of the following substituents: --Br, --Cl, --F, --I, --CF.sub.3, --CH.sub.3, --NO.sub.2 or --C.tbd.N, or an agriculturally acceptable salt thereof.
Type:
Grant
Filed:
January 23, 1981
Date of Patent:
September 29, 1981
Assignee:
Gulf Oil Corporation
Inventors:
Jerry L. Rutter, Charles G. Gibbs, Loren W. Hedrich
Abstract: A novel class of compounds which are useful as plant growth regulators is disclosed, having the general structural formula: ##STR1## In which R is cyano C.sub.1 to C.sub.5 alkyl, alkenyl or alkynyl to which may be attached phenyl, halophenyl, methylphenyl, pyridyl, benzoyl, trimethylacetyl, phenoxy, halophenoxy, halobenzoyl, N-phenylcarbamyl, N-alkylcarbamyl, N-trifluoromethylthiadiazolylcarbamyl, carboxy, carbalkoxy or halo substituents,R.sup.1 is H, acetyl C.sub.1 to C.sub.3 alkyl, alkenyl or alkynyl to which may be attached phenyl, halophenyl, carbethoxy, vinyloxy or phenoxy groups, or R and R.sup.1 together may be C.sub.2 to C.sub.4 alkylene,Ar is phenyl or benzoyl,R.sup.2 is C.sub.1 to C.sub.
Type:
Grant
Filed:
April 10, 1980
Date of Patent:
September 29, 1981
Assignee:
Gulf Oil Corporation
Inventors:
Joel L. Kirkpatrick, Natu R. Patel, Jerry L. Rutter
Abstract: A novel class of compounds which are useful as plant growth regulators is disclosed, having the general structural formula: ##STR1## R.sup.1 is C.sub.1 to C.sub.4 alkyl, nitro or halo and n is zero or an integer from 1 to 4R.sup.2 is hydrogen, C.sub.1 to C.sub.4 alkyl, allyl or benzyl; n' is zero, 1 or 2 and Ar is naphthyl, phenoxybenzyl, phenyl or phenyl bearing thereon from one to three of the substituents: cyano, phenoxy, nitro, bromo, chloro, fluoro and C.sub.1 to C.sub.4 alkyl, alkenyl, alkoxy, alkylthio, carbalkoxy or alkyl-substituted amino.
Abstract: Novel catalysts are provided for the polymerization of olefins such as ethylene. The catalysts consist essentially of a chromium compound supported upon an inorganic carrier containing aluminum and phosphorus moieties, at least a portion of the chromium having a valence of less than 6. The inorganic carrier is an amorphous precipitate of aluminum phosphate or an amorphous precipitate containing aluminum and phosphorus moieties in an atomic ratio in the range of about 5:1 to 1:1. The catalysts are particularly useful for polymerizing ethylene in a Particle Form Process in that the catalyst has essentially no polymerization induction period and provides ethylene polymers having a desirably broad molecular weight distribution and a desirably high melt flow shear ratio.
Type:
Grant
Filed:
April 4, 1980
Date of Patent:
September 15, 1981
Assignee:
Gulf Oil Corporation
Inventors:
Robert W. Hill, William L. Kehl, Thomas J. Lynch
Abstract: Alkali-soluble hot melt adhesive compositions are provided which contain (a) about 10-40 weight % of an alkenyl succinic anhydride, (b) a carboxyl group containing ethylene copolymer, and (c) about 10-50 weight % of rosin.
Abstract: A compatible blend of polymers is disclosed and consists essentially of 100 parts by weight of a low density ethylene polymer and about 0.2 to 3 parts by weight of either poly(ethylene adipate) or poly(trimethylene adipate). The polymer blends have a lower sealing temperature than the low density ethylene polymer contained therein.
Abstract: A compatible blend of polymers is disclosed and consists essentially of 100 parts by weight of an ethylene-alkyl acrylate copolymer and about 0.2 to 3 parts by weight of either poly(ethylene adipate) or poly(trimethylene adipate). The polymer blends have a lower sealing temperature than the ethylene-alkyl acrylate copolymer contained therein.
Abstract: A group of heat curable resins are provided which have good physical properties, which properties are retained to a surprising degree after prolonged exposure to temperatures as high as 300.degree. C. The products are acetylene end-capped polyesters prepared by reacting a hydroxyphenylacetylene with a diacid chloride of an aromatic dibasic acid such as 4,4'-benzophenone dicarboxylic acid dichloride.
Type:
Grant
Filed:
September 13, 1979
Date of Patent:
August 11, 1981
Assignee:
Gulf Oil Corporation
Inventors:
Wai Y. Chow, Daniel J. Hurley, James H. Rea, S. Paul Thackaberry
Abstract: The present invention is directed to a class of novel 1-benzoyl-3-thiosemicarbazides which are useful as plant growth regulants. The present invention is also directed to methods and formulations for plant growth regulation.
Abstract: Acrylate monomers useful as a component of U.V. curable resin compositions and anaerobic adhesive compositions are provided and have the structure: ##STR1## where R.sub.a is an alkyl group containing up to about 18 carbon atoms, or an alkoxy ether moiety having the structure: ##STR2## where R.sub.c is an alkyl group containing up to about 18 carbon atoms, R.sub.c is hydrogen or a methyl group, and n is zero or a small integer, and R.sub.b has the structure: ##STR3## or ##STR4## where R.sub.e is hydrogen or an alkyl group and n' is a small integer.
Type:
Grant
Filed:
June 20, 1980
Date of Patent:
July 28, 1981
Assignee:
Gulf Oil Corporation
Inventors:
Thomas F. Huemmer, Pallavoor R. Lakshmanan
Abstract: The novel compound having the structural formula ##STR1## is disclosed, as well as its use by pre-emergent application to control noxious grasses and some broadleaf weeds in cool season crops such as rape, sugar beets and flax.
Abstract: Dimethylcarbamyltriazole insecticides of the type disclosed in U.S. Pat. Nos. 4,054,664 and 4,066,774 are stabilized against decarbamylation in the presence of clay minerals, either in the soil or in pesticide formulations by incorporating with the dimethylcarbamyltriazole at least one part by weight of nonionic aliphatic polyol per 10 parts of insecticide.
Abstract: New compounds which are herbicide antagonists that are useful for protection of plants from various herbicides are members of the group having the general structural formulas: ##STR1## in which R is hydrogen or C.sub.1 to C.sub.4 alkyl, alkenyl or alkynyl, branched or straight chain, R.sup.1 is C.sub.1 to C.sub.3 alkyl, alkenyl or alkynyl, branched or straight chain, with the total number of carbon atoms in R and R.sup.1 being less than six, preferably less than four, on compounds with both R and R.sup.1 substituents. The novel plant protection agents may be applied both to seeds and to the soil.