Abstract: Process for the preparation of 3,4-methylenedioxymandelic acid, wherein glyoxylic acid is reacted with 1,2-methylenedioxybenzene in a strongly acid medium.
Abstract: Aromatic hydroxy aldehydes are prepared by the simultaneous oxidation and decarboxylation of hydroxy aryl glycolic acids by reacting same with oxidizing agents in aqueous-acid medium.
Type:
Grant
Filed:
May 9, 1977
Date of Patent:
August 7, 1979
Assignee:
Haarmann & Reimer Gesellschaft mit beschrankter Haftung
Abstract: The invention concerns a new process for the production of 2-alkoxy-4-propen-1-yl phenols of the formula ##STR1## in which R represents the methyl or ethyl radical wherein 2-alkoxy phenols of the formula ##STR2## in which R is as defined above, are initially condensed with propionaldehyde in the presence of acid catalysts, and the resulting condensation product is subsequently split by heating in the presence of a basic catalyst to form the phenols of formula I.
Type:
Grant
Filed:
March 21, 1977
Date of Patent:
May 15, 1979
Assignee:
Haarmann & Reimer GmbH
Inventors:
Kurt Bauer, Reiner Molleken, Rudolf Hopp
Abstract: Process for the preparation of alkyl aryl ethers by reacting aromatic hydroxy compounds with aliphatic alcohols in the presence of strongly acidic cation exchangers based on synthetic resins using the aromatic hydroxy compound in excess of the aliphatic alcohol.
Type:
Grant
Filed:
November 18, 1977
Date of Patent:
May 8, 1979
Assignee:
Haarmann & Reimer GmbH
Inventors:
Rainer Neumann, Hans-Helmut Schwarz, Karl-Heinz Arnold
Abstract: The invention concerns a germ-inhibiting, microbicidal or deodorizing composition comprising p-isopropyl- and/or p-tert.butyl-.alpha.-methyl hydrocinnamic alcohol, together with a carrier or diluent.
Type:
Grant
Filed:
January 22, 1975
Date of Patent:
August 29, 1978
Assignee:
Haarmann & Reimer GmbH
Inventors:
Rudolf Hopp, Wolfgang Sturm, Fritz Steinfatt
Abstract: The invention concerns new 2-alkoxy-4-alkenyl phenols of the formula ##STR1## wherein R.sub.1 is methyl or ethyl andR.sub.2 and R.sub.3 are different from one another and mean hydrogen or methyl;A process for the preparation of said 2-alkoxy-4-alkenyl phenols comprising condensing 2-alkoxy phenols with butyraldehyde or isobutyraldehyde in the presence of an acid catalyst and thermal splitting the condensation product in the presence of a catalyst; and the use of the new 2-alkoxy-4-alkenyl phenols as odorants.
Type:
Grant
Filed:
April 14, 1975
Date of Patent:
January 31, 1978
Assignee:
Haarmann & Reimer Gesellschaft mit beschrankter Haftung
Inventors:
Kurt Bauer, Reiner Molleken, Fritz Exner
Abstract: The invention relates to a new process for the production of anethole (4-methoxy propen-1-yl benzene), wherein anisole is condensed with propionaldehyde in the presence of an acid catalyst and the resulting condensation product is subsequently split in the presence of an acid at a temperature in the range from 100.degree. to 300.degree. C.
Abstract: Glyoxylic acid is selectively extracted from its aqueous mixture with glyoxal by means of aliphatic or cycloaliphatic alcohol containing about 4 to 8 carbon atoms, a ketone containing about 4 to 8 carbon atoms, and an ester of an aliphatic carboxylic acid and aliphatic alcohol each containing up to about 6 carbon atoms, the esters containing a total of about 3 to 8 carbon atoms, allowing the mixture to stratify and separating the solvent layer enriched in glyoxylic acid.
Type:
Grant
Filed:
December 29, 1975
Date of Patent:
May 31, 1977
Assignee:
Haarmann & Reimer GmbH
Inventors:
Kurt Bauer, Reiner Molleken, Alfred Krempel
Abstract: The invention concerns the new tricyclic compound, 4-(tricyclo [5.2.1.0.sup.2,6 ] decyl-8)-butanal, a process for its preparation and its use as a perfume.
Abstract: A process for the separation of optically active d- and l-isomers of a compound selected from the group consisting of menthol, neomenthol and isomenthol, which comprises esterifying a d,l-isomeric mixture of the compound with an acid selected from the group consisting of benzoic acid optionally carrying at least one substituent on the benzene ring and hexahydrobenzoic acid; forming a supersaturated solution or a supercooled melt of the d,l-ester; inoculating the solution or melt with crystals of the d- or l-form of the ester to effect selective crystllization of one of the two optical isomers; separating the crystals and subjecting them to hydrolysis to yield the corresponding enantiomorph of the starting compound.
Type:
Grant
Filed:
September 3, 1974
Date of Patent:
March 9, 1976
Assignee:
Haarmann & Reimer Gesellschaft mit beschrankter Haftung
Inventors:
Jurgen Fleischer, Kurt Bauer, Ruldolf Hopp