Patents Assigned to Haldor Topsoe A/S
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Publication number: 20250146142Abstract: A method for the generation of a gas mixture including carbon monoxide, carbon dioxide, and hydrogen for use in hydroformylation plants, including: evaporating water to steam; feeding the steam to a solid oxide electrolysis cell (SOEC) while supplying an electrical current to the SOEC to effect a partial conversion of steam to hydrogen; utilizing the effluent SOEC gas including H2 together with CO2 from an external source as feed for a RWGS reactor in which the RWGS reaction takes place, converting some of the CO2 and H2 to CO and H2O; removing some of or all the remaining steam from the raw product gas stream by cooling the raw product gas stream allowing for condensation of at least part of the steam as liquid water and separating the remaining product gas from the liquid; using the gas mixture for liquid phase hydroformylation, while recycling CO2 to the RWGS reactor.Type: ApplicationFiled: December 19, 2024Publication date: May 8, 2025Applicant: HALDOR TOPSØE A/SInventors: Niels Christian SCHJØDT, Rainer KÜNGAS, Berit HINNEMANN, Bengt Peter Gustav BLENNOW
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Patent number: 12291453Abstract: A method for upgrading a hydrocarbon feed gas to methanol, including the steps of: providing a hydrocarbon feed gas; optionally, purifying the hydrocarbon feed gas in a gas purification unit; optionally, prereforming the hydrocarbon feed gas together with a steam feedstock in a prereforming unit; carrying out steam methane reforming in a reforming reactor heated by means of an electrical power source; providing the synthesis gas to a methanol synthesis unit to provide a product including methanol and an off-gas. Also, a system for upgrading a hydrocarbon feed gas to methanol.Type: GrantFiled: June 4, 2020Date of Patent: May 6, 2025Assignee: HALDOR TOPSØE A/SInventors: Peter Mølgaard Mortensen, John Bøgild Hansen, Kim Aasberg-Petersen, Charlotte Stub Nielsen
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Patent number: 12286721Abstract: In a method for chromium upgrading of interconnects made of ferritic steel to be used in solid oxide cell stacks, comprising the steps of shaping the interconnect, depositing a coating comprising Cr on at least one surface of the shaped interconnect and performing one or more thermal treatments at a temperature below 1000° C., the resulting Cr concentration near the surface of the interconnect is higher than the Cr concentration in the ferritic steel before shaping. Specifically, the average Cr concentration of the shaped interconnect is increased to 26 wt % Cr or higher.Type: GrantFiled: July 13, 2020Date of Patent: April 29, 2025Assignee: HALDOR TOPSØE A/SInventors: Tobias Holt Nørby, Rainer Küngas, Bengt Peter Gustav Blennow, Jeppe Rass-Hansen, Thomas Heiredal-Clausen
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Publication number: 20250128244Abstract: A process for producing a catalyst, comprising the steps of modifying a carrier by a first impregnation with at least one alkaline earth metal in a first metal precursor solution, the first metal precursor being decomposed to form at least one metal oxide or metal hydroxide, thereby obtaining a modified carrier. A second impregnation is carried out by incipient wetness by a second precursor solution comprising at least one metal Me in a second solution. Finally, the second precursor is decomposed, thereby obtaining a catalyst body having an enrichment of the at least one metal Me in the outer shell of the catalyst body, the metal being present in a concentration having either as an egg-shell profile or a hammock profile.Type: ApplicationFiled: September 4, 2024Publication date: April 24, 2025Applicant: Haldor Topsoe A/SInventors: Charlotte Vinding OVESEN, Fernando Morales CANO, Jens Henrik HYLDTOFT, Michael BRORSON
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Publication number: 20250121344Abstract: A process for carrying out an endothermic reaction of a feed gas in a reactor system including a pressure shell housing a structured catalyst arranged for catalyzing the endothermic reaction of a feed gas, the structured catalyst including a macroscopic structure of electrically conductive material, the macroscopic structure supporting a ceramic coating, the ceramic coating supporting a catalytically active material.Type: ApplicationFiled: December 20, 2024Publication date: April 17, 2025Applicant: Haldor Topsøe A/SInventors: Peter Mølgaard MORTENSEN, Robert KLEIN, Kim AASBERG-PETERSEN
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Publication number: 20250091862Abstract: A plant, such as a hydrocarbon plant, is provided, which has a syngas stage for syngas generation and a synthesis stage where the syngas is synthesized to produce syngas derived product, such as hydrocarbon product. The plant makes effective use of various streams; in particular, CO2 and H2. The plant does not comprise an external feed of hydrocarbons. A method for producing a product stream, such as a hydrocarbon product stream is also provided.Type: ApplicationFiled: December 2, 2024Publication date: March 20, 2025Applicant: Haldor Topsøe A/SInventors: Sudip DE SARKAR, Thomas Sandahl CHRISTENSEN, Martin ØSTBERG, Kim AASBERG-PETERSEN
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Patent number: 12246298Abstract: An offshore installation or offshore vessel is provided which comprises a reactor system for carrying out steam reforming of a feed gas comprising hydrocarbons.Type: GrantFiled: September 24, 2020Date of Patent: March 11, 2025Assignee: HALDOR TOPSØE A/SInventors: Peter Mølgaard Mortensen, Per Juul Dahl, Kasper Emil Larsen, Kim Aasberg-Petersen, Robert Klein
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Patent number: 12246965Abstract: A reactor system and a process for carrying out the methanol cracking and reverse water gas shift reaction of a feedstock comprising methanol to synthesis gas are provided, where the heat for the endothermic methanol cracking and reverse water gas shift reaction is provided by resistance heating.Type: GrantFiled: September 24, 2020Date of Patent: March 11, 2025Assignee: HALDOR TOPSØE A/SInventors: Peter Mølgaard Mortensen, Robert Klein, Kasper Emil Larsen, Kim Aasberg-Petersen
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Patent number: 12246964Abstract: A reactor system and a process for carrying out the methanol cracking reaction of a feedstock comprising methanol to hydrogen are provided, where the heat for the endothermic methanol cracking reaction is provided by resistance heating.Type: GrantFiled: September 24, 2020Date of Patent: March 11, 2025Assignee: HALDOR TOPSØE A/SInventors: Peter Mølgaard Mortensen, Kasper Emil Larsen, Kim Aasberg-Petersen, Robert Klein
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Patent number: 12246970Abstract: A reactor system and a process for carrying out the reaction of a feed gas comprising an alkane such as methane, and ammonia to hydrogen cyanide and/or a nitrile are provided, where the heat for the endothermic reaction is provided by resistance heating. In particular, the reaction is the BMA (Blausäure aus Methan und Ammoniak) reaction.Type: GrantFiled: September 24, 2020Date of Patent: March 11, 2025Assignee: HALDOR TOPSØE A/SInventors: Peter Mølgaard Mortensen, Kasper Emil Larsen, Kim Aasberg-Petersen, Robert Klein
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Patent number: 12246299Abstract: A reactor system and a process for carrying out steam cracking of a feed gas comprising hydrocarbons is provided, i where the heat for the reaction is provided by resistance heating by means of electrical power, so that a product stream comprising at least one olefin compound is obtained.Type: GrantFiled: November 11, 2020Date of Patent: March 11, 2025Assignee: HALDOR TOPSØE A/SInventor: Peter Mølgaard Mortensen
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Publication number: 20250066193Abstract: A plant and process for producing a hydrogen rich gas are provided, the process including the steps of: reforming a hydrocarbon feed in a reforming step thereby obtaining a synthesis gas including CH4, CO, CO2, H2 and H2O; shifting the synthesis gas in a shift configuration including a high temperature shift step; removal of CO2 upstream hydrogen purification unit, such as a pressure swing adsorption unit (PSA), and recycling off-gas from hydrogen purification unit and mix it with natural gas upstream prereformer feed preheater, prereformer, reformer feed preheater or ATR or shift as feed for the process.Type: ApplicationFiled: November 14, 2024Publication date: February 27, 2025Applicant: HALDOR TOPSØE A/SInventors: Steffen Spangsberg CHRISTENSEN, Arunabh SAHAI
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Patent number: 12227414Abstract: A reactor system and a process for carrying out the ammonia cracking reaction of a feed gas comprising ammonia to hydrogen are provided, where the heat for the endothermic ammonia cracking reaction is provided by resistance heating.Type: GrantFiled: September 24, 2020Date of Patent: February 18, 2025Assignee: HALDOR TOPSØE A/SInventors: Peter Mølgaard Mortensen, Kasper Emil Larsen, Kim Aasberg-Petersen, Robert Klein
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Patent number: 12227473Abstract: A process for the production of glycolaldehyde by thermolytic fragmentation of a carbohydrate feedstock including mono- and/or di-saccharide(s) and a system suitable for performing the process. The process and the system are suitable for industrial application, and the process may be performed in a continuous process. The salt-depleted carbohydrate feedstock may include one or more impurities selected from the group of arsenic, lead, sulfate, sulfur dioxide, and 5-(hydroxymethyl)furfural.Type: GrantFiled: August 24, 2022Date of Patent: February 18, 2025Assignee: HALDOR TOPSØE A/SInventors: Christian Mårup Osmundsen, Morten Boberg Larsen
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Patent number: 12215432Abstract: A method for the generation of a gas mixture including carbon monoxide, carbon dioxide and hydrogen for use in hydroformylation plants, including the steps of evaporating water to steam; feeding the steam to a solid oxide electrolysis cell (SOEC) or an SOEC stack at a sufficient temperature for the cell or cell stack to operate while effecting a partial conversion of steam to hydrogen; utilizing the effluent SOEC gas including H2 together with CO2 from an external source as feed for a RWGS reactor in which the RWGS reaction takes place, converting some of the CO2 and H2 to CO and H2O; removing some of or all the remaining steam from the raw product gas stream; using said gas mixture comprising CO, CO2 and H2 for liquid phase hydroformylation utilizing carbon monoxide and hydrogen as reactants, while recycling CO2 to the RWGS reactor.Type: GrantFiled: April 11, 2019Date of Patent: February 4, 2025Assignee: HALDOR TOPSØE A/SInventors: Niels Christian Schjødt, Rainer Küngas, Berit Hinnemann, Bengt Peter Gustav Blennow
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Patent number: 12214327Abstract: A reactor system for carrying out an endothermic reaction of a feed gas, including: a structured catalyst arranged for catalyzing the endothermic reaction of a feed gas, the structured catalyst including a macroscopic structure of electrically conductive material, the macroscopic structure supporting a ceramic coating, wherein the ceramic coating supports a catalytically active material; a pressure shell housing the structured catalyst; heat insulation layer between the structured catalyst and the pressure shell; at least two conductors electrically connected to the electrically conductive material and to an electrical power supply placed outside the pressure shell, wherein the electrical power supply is dimensioned to heat at least part of said structured catalyst to a temperature of at least 200° C. by passing an electrical current through the electrically conductive material. Also, a process for performing an endothermic reaction of a feed gas.Type: GrantFiled: May 15, 2019Date of Patent: February 4, 2025Assignee: HALDOR TOPSØE A/SInventors: Peter Mølgaard Mortensen, Robert Klein, Kim Aasberg-Petersen
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Patent number: 12201954Abstract: A reactor system and a process for carrying out reverse water gas shift reaction of a feedstock comprising CO2 and H2 to a first product gas comprising CO are provided, where a methanation reaction take place in parallel to the reverse water gas shift reaction, and where the heat for the endothermic reverse water gas shift reaction is provided by resistance heating.Type: GrantFiled: December 3, 2020Date of Patent: January 21, 2025Assignee: HALDOR TOPSØE A/SInventors: Peter Mølgaard Mortensen, Kim Aasberg-Petersen, Michael Hultqvist, Robert Klein, Kasper Emil Larsen
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Patent number: 12194452Abstract: A process for large scale and energy efficient production of oxygenates from sugar is disclosed in which a sugar feedstock is introduced into a thermolytic fragmentation reactor including a fluidized stream of heat carrying particles which are separated from the reaction product and directed to a reheater comprising a resistance heating system.Type: GrantFiled: May 9, 2022Date of Patent: January 14, 2025Assignee: HALDOR TOPSØE A/SInventors: Lars Storm Pedersen, Morten Boberg Larsen, Peter Mølgaard Mortensen
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Patent number: 12180072Abstract: A plant, such as a hydrocarbon plant, is provided, which has a syngas stage for syngas generation and a synthesis stage where the syngas is synthesized to produce syngas derived product, such as hydrocarbon product. The plant makes effective use of various streams; in particular CO2 and H2. The plant does not comprise an external feed of hydrocarbons. A method for producing a product stream, such as a hydrocarbon product stream is also provided.Type: GrantFiled: March 27, 2023Date of Patent: December 31, 2024Assignee: HALDOR TOPSØE A/SInventors: Sudip De Sarkar, Thomas Sandahl Christensen, Martin Østberg, Kim Aasberg-Petersen
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Patent number: 12172896Abstract: A plant and process for producing a hydrogen rich gas are provided, said process comprising the steps of: reforming a hydrocarbon feed in a reforming step thereby obtaining a synthesis gas comprising CH4, CO, CO2, H2 and H2O; shifting said synthesis gas in a shift configuration including a high temperature shift step; removal of CO2 upstream hydrogen purification unit, such as a pressure swing adsorption unit (PSA), and recycling off-gas from hydrogen purification unit and mix it with natural gas upstream prereformer feed preheater, prereformer, reformer feed preheater or ATR or shift as feed for the process.Type: GrantFiled: April 22, 2020Date of Patent: December 24, 2024Assignee: HALDOR TOPSØE A/SInventors: Steffen Spangsberg Christensen, Arunabh Sahai