Patents Assigned to Haldor Topsoe A/S
  • Patent number: 11952287
    Abstract: In a method for the precipitation of particles of a metal carbonate material comprising nickel and manganese in an atomic ratio of 0?Ni:Mn?1:3, aqueous solutions comprising sulfates or nitrates of nickel and manganese are mixed with aqueous solutions of carbonates or mixtures of carbonates and hydroxides of sodium or potassium in a stirred reactor at pH>7.5 without the use of a chelating agent. Thereby agglomerated particles are formed without any subsequent process steps, in particular no subsequent process at temperatures higher than the precipitation temperature.
    Type: Grant
    Filed: July 11, 2017
    Date of Patent: April 9, 2024
    Assignee: HALDOR TOPSØE A/S
    Inventors: Line Holten Kollin, Rainer Küngas, Steen Henrik Olsen, Anni Stahl, Søren Dahl
  • Patent number: 11945762
    Abstract: In a process for the catalytic conversion of lower hydrocarbons to aromatic compounds comprising benzene, toluene and xylenes, a process stream containing lower hydrocarbons is contacted with a zeolitic catalyst having an MFI framework and containing 0.1 to 10 percent by weight of a zinc compound. The process stream further contains one or more sulfur compounds, especially hydrogen sulfide, for improving the selectivity.
    Type: Grant
    Filed: October 15, 2020
    Date of Patent: April 2, 2024
    Assignee: HALDOR TOPSØE A/S
    Inventor: Finn Joensen
  • Patent number: 11932538
    Abstract: The invention relates to a process for reforming a hydrocarbon feed stream comprising a hydrocarbon gas and steam, said process comprising the steps of: a) in a synthesis gas generation reactor carrying out a reforming reaction of the hydrocarbon feed stream over a first catalyst, thereby forming a first synthesis gas; b) providing a heated CO2 rich stream to a post converter comprising a second catalyst; and c) in said post converter carrying out a methanation, steam reforming and reverse water gas shift reactions of the first synthesis gas and the heated CO2 rich stream to produce a product synthesis gas, wherein said second catalyst is heated electrically by means of an electrical power source. The invention moreover relates to a system arranged to carry out the process of the invention.
    Type: Grant
    Filed: November 15, 2018
    Date of Patent: March 19, 2024
    Assignee: Haldor Topsøe A/S
    Inventors: Peter Mølgaard Mortensen, Martin Østberg
  • Patent number: 11932951
    Abstract: In a method for generating ammonia synthesis gas by electrolysis, comprising feeding a mixture of steam and compressed air into the first of a series of electrolysis units and passing the outlet from one electrolysis unit to the inlet of the next electrolysis unit together with air, the electrolysis units are run in endothermal mode and the nitrogen part of the synthesis gas is provided by burning the hydrogen produced by steam electrolysis by air in or between the electrolysis units. The electrolysis units are preferably solid oxide electrolysis cell (SOEC) stacks.
    Type: Grant
    Filed: October 1, 2018
    Date of Patent: March 19, 2024
    Assignee: HALDOR TOPSØE A/S
    Inventor: John Bøgild Hansen
  • Patent number: 11918991
    Abstract: A reformer furnace is provided for use in converting a hydrocarbon feed into a synthesis gas stream. The reformer furnace includes at least one bayonet reformer tube located at least partly within an enclosed volume. The reformer furnace includes a first support arranged to support the second end portion of the at least one bayonet reformer tube against the second endwall of the reformer furnace.
    Type: Grant
    Filed: September 1, 2020
    Date of Patent: March 5, 2024
    Assignee: HALDOR TOPSØE A/S
    Inventor: Steffen Spangsberg Christensen
  • Publication number: 20240059563
    Abstract: A plant and process for producing a hydrogen rich gas are provided, said process comprising the steps of: reforming a hydrocarbon feed in a reforming step using an autothermal reformer (ATR) thereby obtaining a synthesis gas comprising CH4, CO, CO2, H2 and H2O; shifting said synthesis gas in a shift configuration including a high temperature shift step; passing the shifted syngas to a first hydrogen purification unit, e.g. a PSA unit; passing a portion of the off-gas from the first hydrogen purification unit to a second hydrogen purification unit, and using off-gas from the first and second hydrogen purification unit as e.g. fuel for a preheater unit before the ATR.
    Type: Application
    Filed: September 18, 2020
    Publication date: February 22, 2024
    Applicant: HALDOR TOPSØE A/S
    Inventors: Steffen Spangsberg CHRISTENSEN, Arunabh SAHAI
  • Patent number: 11905173
    Abstract: A reactor system for carrying out steam reforming of a feed gas comprising hydrocarbons, including: a structured catalyst arranged for catalyzing steam reforming of a feed gas including hydrocarbons, the structured catalyst including a macroscopic structure of electrically conductive material, the macroscopic structure supporting a ceramic coating, wherein the ceramic coating supports a catalytically active material; a pressure shell housing the structured catalyst; heat insulation layer between the structured catalyst and the pressure shell; at least two conductors electrically connected to the macroscopic structure and to an electrical power supply placed outside the pressure shell, wherein the electrical power supply is dimensioned to heat at least part of the structured catalyst to a temperature of at least 500° C. by passing an electrical current through the macroscopic structure. Also, a process for steam reforming of a feed gas comprising hydrocarbons.
    Type: Grant
    Filed: May 15, 2019
    Date of Patent: February 20, 2024
    Assignee: HALDOR TOPSØE A/S
    Inventors: Peter Mølgaard Mortensen, Robert Klein, Kim Aasberg-Petersen
  • Patent number: 11882852
    Abstract: New process of producing alpha-hydroxy compounds from sustainable resources useful as platform chemicals, such as hydroxy analogues of amino acids or polymer precursors.
    Type: Grant
    Filed: January 23, 2019
    Date of Patent: January 30, 2024
    Assignee: HALDOR TOPSØE A/S
    Inventors: Søren Tolborg, Juan Salvador Martínez Espín, Esben Taarning
  • Patent number: 11807527
    Abstract: A process and a process plant for production of elemental sulfur from a feedstock gas including from 15 vol % to 100 vol % H2S and a stream of sulfuric acid, the process including a) providing a Claus reaction furnace feed stream with a substoichiometric amount of oxygen, b) directing s to a reaction furnace operating at elevated temperature, c) cooling, d) directing to contact a material catalytically active in the Claus reaction, e) withdrawing a Claus tail gas and elemental sulfur, f) directing to a means for sulfur oxidation, g) directing to contact a material catalytically active in SO2 oxidation to SO3, h) converting to concentrated sulfuric acid, i) recycling to the Claus reaction furnace, wherein an amount of combustibles, in the Claus tail gas, is oxidized in the presence of a material catalytically active in sulfur oxidation, at an inlet temperature below 400° C.
    Type: Grant
    Filed: April 29, 2020
    Date of Patent: November 7, 2023
    Assignee: HALDOR TOPSØE A/S
    Inventors: Morten Thellefsen, Martin Møllerhøj, Mads Lykke
  • Patent number: 11806705
    Abstract: The invention relates to a catalytic reactor comprising a combustion reaction chamber with catalytic reactor tubes filled with catalyst elements and metal radiation surfaces arranged in the chamber to improve heat transfer.
    Type: Grant
    Filed: June 24, 2019
    Date of Patent: November 7, 2023
    Assignee: HALDOR TOPSØE A/S
    Inventor: Martin Østberg
  • Patent number: 11780798
    Abstract: A method and a system for producing glycolic acid and/or glycolate from sustainable resources. A method for catalytic production of glycolic acid and/or glycolate including the step of: oxidation of a starting material including between 0.1-100 wt/wt % glycolaldehyde at a temperature of between ?10° C. and 100° C. with an oxidant in the presence of a metal-based catalyst including a catalytically active metal, which is selected from the group of palladium and platinum; or mixtures thereof.
    Type: Grant
    Filed: November 22, 2017
    Date of Patent: October 10, 2023
    Assignee: HALDOR TOPSØE A/S
    Inventors: Christian Mårup Osmundsen, Esben Taarning
  • Patent number: 11760718
    Abstract: The invention relates to a process for producing a product gas comprising acetonitrile and/or hydrogen cyanide from a feed stream comprising ammonia and methanol over a solid catalyst comprising a support, a first metal and a second metal on the support, wherein the first metal and the second metal are in the form of a chemical compound, wherein the first metal is Fe, Ru or Co and the second metal is Sn, Zn, or Ge. The pressure is ambient pressure or higher and the temperature lies in a range from about 400° C. to about 700° C. Thus, the process for producing acetonitrile and/or hydrogen cyanide from ammonia and methanol may be catalyzed by a single catalyst and may be carried out in a single reactor. The invention also relates to a catalyst, a method for activating a catalyst and use of a catalyst for catalysing production of acetonitrile and/or hydrogen cyanide from ammonia and methanol.
    Type: Grant
    Filed: February 1, 2018
    Date of Patent: September 19, 2023
    Assignee: HALDOR TOPSØE A/S
    Inventors: Poul Erik Højlund Nielsen, Rasmus Munksgård Nielsen, Brian Kjærgaard Olsen
  • Patent number: 11753700
    Abstract: The content of oxygen in molten metallic copper is reduced during the copper refining process by adding pure carbon monoxide, produced by electrolysis of carbon dioxide in a solid oxide electrolysis cell (SOEC), thereby removing oxygen through the reduction of CuO to Cu. This way, the purity of the metallic copper is increased.
    Type: Grant
    Filed: April 16, 2018
    Date of Patent: September 12, 2023
    Assignee: HALDOR TOPSØE A/S
    Inventors: Artem Tarasenko, Niklas Bengt Jakobsson, Bengt Peter Gustav Blennow, Casper Hadsbjerg
  • Patent number: 11731097
    Abstract: A catalytic system is provided which comprises a tubular reactor and at least one catalyst particle located within the tubular reactor. The catalyst particles have a particular geometric form which promotes heat transfer with the tubular reactor. Certain specific catalyst particles are also provided.
    Type: Grant
    Filed: November 19, 2019
    Date of Patent: August 22, 2023
    Assignee: HALDOR TOPSØE A/S
    Inventors: Moritz Bo Belstrup, Peter Rahbek, Martin Østberg
  • Publication number: 20230234842
    Abstract: A plant, such as a hydrocarbon plant, is provided, which has a syngas stage for syngas generation and a synthesis stage where the syngas is synthesized to produce syngas derived product, such as hydrocarbon product. The plant makes effective use of various streams; in particular CO2 and H2. The plant does not comprise an external feed of hydrocarbons. A method for producing a product stream, such as a hydrocarbon product stream is also provided.
    Type: Application
    Filed: March 27, 2023
    Publication date: July 27, 2023
    Applicant: HALDOR TOPSØE A/S
    Inventors: Sudip DE SARKAR, Thomas Sandahl CHRISTENSEN, Martin ØSTBERG, Kim AASBERG-PETERSEN
  • Publication number: 20230226516
    Abstract: A structured catalyst for catalyzing an endothermic reaction of a feed gas to convert it to a product gas is provided.
    Type: Application
    Filed: July 15, 2021
    Publication date: July 20, 2023
    Applicant: HALDOR TOPSØE A/S
    Inventors: Peter Mølgaard MORTENSEN, Sebastian Thor WISMANN, Kasper Emil LARSEN, Anders Helbo HANSEN
  • Patent number: 11691877
    Abstract: A process plant and a process for production of sulfur from a feedstock gas including from 15% to 100 vol % H2S and a stream of sulfuric acid, the process including a) providing a Claus reaction furnace feed stream with a substoichiometric amount of oxygen, b) directing to a Claus reaction furnace operating at elevated temperature, c) cooling to provide a cooled Claus converter feed gas, d) directing to contact a material catalytically active in the Claus reaction, e) withdrawing a Claus tail gas and elementary sulfur, f) directing a stream comprising said Claus tail gas to a Claus tail gas treatment, wherein sulfuric acid directed to said Claus reaction furnace is in the form of droplets with 90% of the mass of the droplets having a diameter below 500 ?m, with the associated benefit of such a process efficiently converting all liquid H2SO4 to gaseous H2SO4 and further to SO2.
    Type: Grant
    Filed: April 30, 2020
    Date of Patent: July 4, 2023
    Assignee: HALDOR TOPSØE A/S
    Inventors: Morten Thellefsen, Per Aggerholm Sørensen, Martin Møllerhøj, Mads Lykke
  • Patent number: 11649164
    Abstract: A synthesis gas plant for producing synthesis gas, said synthesis gas plant including an electrically heated reforming reactor system including a first catalyst active for catalyzing steam methane reforming reaction, said electrically heated reforming reactor system being arranged to receive a feed gas comprising hydrocarbons and outletting a first synthesis gas stream. The synthesis gas plant also includes a post converter downstream the electrically heated reforming reactor system, said post converter housing a second catalyst active for catalyzing steam methane reforming/methanation reactions and reverse water gas shift reaction, said post converter being arranged to receive at least part of said first synthesis gas stream and outletting a second synthesis gas stream. Furthermore, the synthesis gas plant includes means for adding a heated CO2 rich gas stream to the at least part of the first synthesis gas stream upstream the post converter and/or into the post converter.
    Type: Grant
    Filed: November 15, 2018
    Date of Patent: May 16, 2023
    Assignee: HALDOR TOPSØE A/S
    Inventor: Peter Mølgaard Mortensen
  • Patent number: 11649163
    Abstract: A plant, such as a hydrocarbon plant, is provided, which consists of a syngas stage for syngas generation and a synthesis stage where said syngas is synthesized to produce syngas derived product, such as hydrocarbon product. The plant makes effective use of various streams; in particular CO2 and H2. The plant does not comprise an external feed of hydrocarbons. A method for producing a product stream, such as a hydrocarbon product stream is also provided.
    Type: Grant
    Filed: April 7, 2020
    Date of Patent: May 16, 2023
    Assignee: HALDOR TOPSØE A/S
    Inventors: Sudip De Sarkar, Thomas Sandahi Christensen, Martin Østberg, Kim Aasberg-Petersen
  • Patent number: 11618677
    Abstract: A revamp process for modifying a sulfur abatement plant including a Claus process plant, the Claus process plant including a Claus reaction furnace and one or more Claus conversion stages, each Claus conversion stage including a conversion reactor and a means for elemental sulfur condensation, and a means of Claus tail gas oxidation configured for receiving a Claus tail gas from said Claus process plant and configured for providing an oxidized Claus tail gas, the process revamp including: a) providing a sulfuric acid producing tail gas treatment plant producing sulfuric acid, and b) providing a means for transferring an amount or all of the sulfuric acid produced in said sulfuric acid producing tail gas treatment plant to said Claus reaction furnace, wherein the moles of sulfur in the transferred sulfuric acid relative to the moles of elemental sulfur withdrawn from the Claus process plant is from 3% to 25%.
    Type: Grant
    Filed: April 29, 2020
    Date of Patent: April 4, 2023
    Assignee: HALDOR TOPSØE A/S
    Inventors: Morten Thellefsen, Mads Lykke, Martin Møllerhøj