Patents Assigned to Haldor Topsoe A/S
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Patent number: 12139673Abstract: A process plant and a process for production of a hydrocarbon fraction suitable for use as jet fuel from a feedstock being a renewable feedstock or an oxygenate feedstock, including combining the feedstock with an amount of a hydrocracked intermediate product and optionally an additional liquid diluent, to form a combined feedstock, directing the combined feedstock to contact a material catalytically active in hydrodeoxygenation under hydrotreating conditions to provide a hydrodeoxygenated intermediate product, separating the hydrodeoxygenated intermediate product in at least two fractions; a vapor fraction and a liquid fraction, directing at least an amount of the liquid fraction to contact a material catalytically active in isomerization under isomerization conditions to provide an isomerized intermediate product, fractionating said isomerized intermediate product to provide at least a hydrocarbon suitable for use as jet fuel and a bottom fraction, hydrocracking the bottom fraction to provide the hydrocrackType: GrantFiled: October 23, 2019Date of Patent: November 12, 2024Assignee: HALDOR TOPSØE A/SInventors: Asbjørn Sune Andersson, Ole Frej Alkilde, Thi Hong Diep Duong
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Publication number: 20240350996Abstract: A chemical reactor including reformer tubes for reforming a first feed stream including a hydrocarbon gas and steam. The chemical reactor includes one or more reformer tubes arranged to being heated by an electrically driven heat source. The reformer tube includes a first inlet for feeding said first feed stream into a first reforming reaction zone of the reformer tube, and a feed conduit arranged to allow a second feed stream into a second reforming reaction zone of the reformer tube. The second reforming reaction zone is positioned downstream of the first reforming reaction zone. The feed conduit is configured so that the second feed stream is only in contact with catalyst material in the second reforming reaction zone. A process of producing CO rich synthesis gas at low S/C conditions.Type: ApplicationFiled: July 1, 2024Publication date: October 24, 2024Applicant: HALDOR TOPSØE A/SInventors: Peter Mølgaard MORTENSEN, Kim AASBERG-PETERSEN
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Patent number: 12122965Abstract: A porous material including alumina, the alumina including alpha-alumina, the porous material including one or more metals selected from Co, Mo, Ni, W and combinations thereof, and the porous material having a BET-surface area of 1-110 m2/g, a total pore volume of 0.50-0.80 ml/g, as measured by mercury intrusion porosimetry, and a pore size distribution (PSD) with at least 30 vol % of the total pore volume being in pores with a radius ?400 ?, suitably pores with a radius ?500 ?. A process for removing impurities such as phosphorous (P) from a feedstock, by contacting the feedstock with a guard bed including the above porous material. A guard bed for a hydrotreatment system including the porous material, a hydrotreatment system including a guard bed which includes the porous material and a downstream hydrotreatment section including at least one hydrotreatment catalyst.Type: GrantFiled: July 6, 2021Date of Patent: October 22, 2024Assignee: HALDOR TOPSØE A/SInventors: Christian Frederik Weise, Michal Lutecki, Frank Bartnik Johansson
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Patent number: 12109554Abstract: A process for producing a catalyst, comprising the steps of modifying a carrier by a first impregnation with at least one alkaline earth metal in a first metal precursor solution, the first metal precursor being decomposed to form at least one metal oxide or metal hydroxide, thereby obtaining a modified carrier. A second impregnation is carried out by incipient wetness by a second precursor solution comprising at least one metal Me in a second solution. Finally, the second precursor is decomposed, thereby obtaining a catalyst body having an enrichment of the at least one metal Me in the outer shell of the catalyst body, the metal being present in a concentration having either as an egg-shell profile or a hammock profile.Type: GrantFiled: November 16, 2018Date of Patent: October 8, 2024Assignee: HALDOR TOPSØE A/SInventors: Charlotte Vinding Ovesen, Fernando Morales Cano, Jens Henrik Hyldtoft, Michael Brorson
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Patent number: 11999617Abstract: In a process for steam reforming of oxygenates, especially at low steam-to-carbon (S/C) ratios, a feed gas containing oxygenates, such as ethanol, is converted into syngas over a ternary carbide catalyst. Then the reformed gas is either transformed into desired chemicals or mixed into the feed stream to the reformer in a plant, such as an ammonia or methanol plant. The preferred ternary carbide is nickel zinc carbide.Type: GrantFiled: October 17, 2022Date of Patent: June 4, 2024Assignee: HALDOR TOPSØE A/SInventors: Poul Erik Højlund Nielsen, Brian Kjærgaard Olsen, Lived J. Lemus-Yegres
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Patent number: 11986804Abstract: The invention relates to a structured catalyst for catalyzing steam methane reforming reaction in a given temperature range T upon bringing a hydrocarbon feed gas into contact with the structured catalyst. The structured catalyst comprises a macroscopic structure, which comprises an electrically conductive material and supports a ceramic coating. The macroscopic structure has been manufactured by 3D printing or extrusion and subsequent sintering, wherein the macroscopic structure and the ceramic coating have been sintered in an oxidizing atmosphere in order to form chemical bonds between the ceramic coating and the macroscopic structure. The ceramic coating supports catalytically active material arranged to catalyze the steam methane reforming reaction, wherein the macroscopic structure is arranged to conduct an electrical current to supply an energy flux to the steam methane reforming reaction.Type: GrantFiled: May 15, 2019Date of Patent: May 21, 2024Assignees: HALDOR TOPSØE A/S, GRUNDFOS HOLDING A/SInventors: Peter Mølgaard Mortensen, Flemming Buus Bendixen, Peter Valler, Alexandru Sorea
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Patent number: 11952287Abstract: In a method for the precipitation of particles of a metal carbonate material comprising nickel and manganese in an atomic ratio of 0?Ni:Mn?1:3, aqueous solutions comprising sulfates or nitrates of nickel and manganese are mixed with aqueous solutions of carbonates or mixtures of carbonates and hydroxides of sodium or potassium in a stirred reactor at pH>7.5 without the use of a chelating agent. Thereby agglomerated particles are formed without any subsequent process steps, in particular no subsequent process at temperatures higher than the precipitation temperature.Type: GrantFiled: July 11, 2017Date of Patent: April 9, 2024Assignee: HALDOR TOPSØE A/SInventors: Line Holten Kollin, Rainer Küngas, Steen Henrik Olsen, Anni Stahl, Søren Dahl
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Patent number: 11945762Abstract: In a process for the catalytic conversion of lower hydrocarbons to aromatic compounds comprising benzene, toluene and xylenes, a process stream containing lower hydrocarbons is contacted with a zeolitic catalyst having an MFI framework and containing 0.1 to 10 percent by weight of a zinc compound. The process stream further contains one or more sulfur compounds, especially hydrogen sulfide, for improving the selectivity.Type: GrantFiled: October 15, 2020Date of Patent: April 2, 2024Assignee: HALDOR TOPSØE A/SInventor: Finn Joensen
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Patent number: 11932951Abstract: In a method for generating ammonia synthesis gas by electrolysis, comprising feeding a mixture of steam and compressed air into the first of a series of electrolysis units and passing the outlet from one electrolysis unit to the inlet of the next electrolysis unit together with air, the electrolysis units are run in endothermal mode and the nitrogen part of the synthesis gas is provided by burning the hydrogen produced by steam electrolysis by air in or between the electrolysis units. The electrolysis units are preferably solid oxide electrolysis cell (SOEC) stacks.Type: GrantFiled: October 1, 2018Date of Patent: March 19, 2024Assignee: HALDOR TOPSØE A/SInventor: John Bøgild Hansen
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Patent number: 11932538Abstract: The invention relates to a process for reforming a hydrocarbon feed stream comprising a hydrocarbon gas and steam, said process comprising the steps of: a) in a synthesis gas generation reactor carrying out a reforming reaction of the hydrocarbon feed stream over a first catalyst, thereby forming a first synthesis gas; b) providing a heated CO2 rich stream to a post converter comprising a second catalyst; and c) in said post converter carrying out a methanation, steam reforming and reverse water gas shift reactions of the first synthesis gas and the heated CO2 rich stream to produce a product synthesis gas, wherein said second catalyst is heated electrically by means of an electrical power source. The invention moreover relates to a system arranged to carry out the process of the invention.Type: GrantFiled: November 15, 2018Date of Patent: March 19, 2024Assignee: Haldor Topsøe A/SInventors: Peter Mølgaard Mortensen, Martin Østberg
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Patent number: 11918991Abstract: A reformer furnace is provided for use in converting a hydrocarbon feed into a synthesis gas stream. The reformer furnace includes at least one bayonet reformer tube located at least partly within an enclosed volume. The reformer furnace includes a first support arranged to support the second end portion of the at least one bayonet reformer tube against the second endwall of the reformer furnace.Type: GrantFiled: September 1, 2020Date of Patent: March 5, 2024Assignee: HALDOR TOPSØE A/SInventor: Steffen Spangsberg Christensen
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Publication number: 20240059563Abstract: A plant and process for producing a hydrogen rich gas are provided, said process comprising the steps of: reforming a hydrocarbon feed in a reforming step using an autothermal reformer (ATR) thereby obtaining a synthesis gas comprising CH4, CO, CO2, H2 and H2O; shifting said synthesis gas in a shift configuration including a high temperature shift step; passing the shifted syngas to a first hydrogen purification unit, e.g. a PSA unit; passing a portion of the off-gas from the first hydrogen purification unit to a second hydrogen purification unit, and using off-gas from the first and second hydrogen purification unit as e.g. fuel for a preheater unit before the ATR.Type: ApplicationFiled: September 18, 2020Publication date: February 22, 2024Applicant: HALDOR TOPSØE A/SInventors: Steffen Spangsberg CHRISTENSEN, Arunabh SAHAI
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Patent number: 11905173Abstract: A reactor system for carrying out steam reforming of a feed gas comprising hydrocarbons, including: a structured catalyst arranged for catalyzing steam reforming of a feed gas including hydrocarbons, the structured catalyst including a macroscopic structure of electrically conductive material, the macroscopic structure supporting a ceramic coating, wherein the ceramic coating supports a catalytically active material; a pressure shell housing the structured catalyst; heat insulation layer between the structured catalyst and the pressure shell; at least two conductors electrically connected to the macroscopic structure and to an electrical power supply placed outside the pressure shell, wherein the electrical power supply is dimensioned to heat at least part of the structured catalyst to a temperature of at least 500° C. by passing an electrical current through the macroscopic structure. Also, a process for steam reforming of a feed gas comprising hydrocarbons.Type: GrantFiled: May 15, 2019Date of Patent: February 20, 2024Assignee: HALDOR TOPSØE A/SInventors: Peter Mølgaard Mortensen, Robert Klein, Kim Aasberg-Petersen
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Patent number: 11882852Abstract: New process of producing alpha-hydroxy compounds from sustainable resources useful as platform chemicals, such as hydroxy analogues of amino acids or polymer precursors.Type: GrantFiled: January 23, 2019Date of Patent: January 30, 2024Assignee: HALDOR TOPSØE A/SInventors: Søren Tolborg, Juan Salvador Martínez Espín, Esben Taarning
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Patent number: 11807527Abstract: A process and a process plant for production of elemental sulfur from a feedstock gas including from 15 vol % to 100 vol % H2S and a stream of sulfuric acid, the process including a) providing a Claus reaction furnace feed stream with a substoichiometric amount of oxygen, b) directing s to a reaction furnace operating at elevated temperature, c) cooling, d) directing to contact a material catalytically active in the Claus reaction, e) withdrawing a Claus tail gas and elemental sulfur, f) directing to a means for sulfur oxidation, g) directing to contact a material catalytically active in SO2 oxidation to SO3, h) converting to concentrated sulfuric acid, i) recycling to the Claus reaction furnace, wherein an amount of combustibles, in the Claus tail gas, is oxidized in the presence of a material catalytically active in sulfur oxidation, at an inlet temperature below 400° C.Type: GrantFiled: April 29, 2020Date of Patent: November 7, 2023Assignee: HALDOR TOPSØE A/SInventors: Morten Thellefsen, Martin Møllerhøj, Mads Lykke
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Patent number: 11806705Abstract: The invention relates to a catalytic reactor comprising a combustion reaction chamber with catalytic reactor tubes filled with catalyst elements and metal radiation surfaces arranged in the chamber to improve heat transfer.Type: GrantFiled: June 24, 2019Date of Patent: November 7, 2023Assignee: HALDOR TOPSØE A/SInventor: Martin Østberg
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Patent number: 11780798Abstract: A method and a system for producing glycolic acid and/or glycolate from sustainable resources. A method for catalytic production of glycolic acid and/or glycolate including the step of: oxidation of a starting material including between 0.1-100 wt/wt % glycolaldehyde at a temperature of between ?10° C. and 100° C. with an oxidant in the presence of a metal-based catalyst including a catalytically active metal, which is selected from the group of palladium and platinum; or mixtures thereof.Type: GrantFiled: November 22, 2017Date of Patent: October 10, 2023Assignee: HALDOR TOPSØE A/SInventors: Christian Mårup Osmundsen, Esben Taarning
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Patent number: 11760718Abstract: The invention relates to a process for producing a product gas comprising acetonitrile and/or hydrogen cyanide from a feed stream comprising ammonia and methanol over a solid catalyst comprising a support, a first metal and a second metal on the support, wherein the first metal and the second metal are in the form of a chemical compound, wherein the first metal is Fe, Ru or Co and the second metal is Sn, Zn, or Ge. The pressure is ambient pressure or higher and the temperature lies in a range from about 400° C. to about 700° C. Thus, the process for producing acetonitrile and/or hydrogen cyanide from ammonia and methanol may be catalyzed by a single catalyst and may be carried out in a single reactor. The invention also relates to a catalyst, a method for activating a catalyst and use of a catalyst for catalysing production of acetonitrile and/or hydrogen cyanide from ammonia and methanol.Type: GrantFiled: February 1, 2018Date of Patent: September 19, 2023Assignee: HALDOR TOPSØE A/SInventors: Poul Erik Højlund Nielsen, Rasmus Munksgård Nielsen, Brian Kjærgaard Olsen
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Patent number: 11753700Abstract: The content of oxygen in molten metallic copper is reduced during the copper refining process by adding pure carbon monoxide, produced by electrolysis of carbon dioxide in a solid oxide electrolysis cell (SOEC), thereby removing oxygen through the reduction of CuO to Cu. This way, the purity of the metallic copper is increased.Type: GrantFiled: April 16, 2018Date of Patent: September 12, 2023Assignee: HALDOR TOPSØE A/SInventors: Artem Tarasenko, Niklas Bengt Jakobsson, Bengt Peter Gustav Blennow, Casper Hadsbjerg
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Patent number: 11731097Abstract: A catalytic system is provided which comprises a tubular reactor and at least one catalyst particle located within the tubular reactor. The catalyst particles have a particular geometric form which promotes heat transfer with the tubular reactor. Certain specific catalyst particles are also provided.Type: GrantFiled: November 19, 2019Date of Patent: August 22, 2023Assignee: HALDOR TOPSØE A/SInventors: Moritz Bo Belstrup, Peter Rahbek, Martin Østberg