Abstract: Process for the co-production of methanol and ammonia together with urea production from a hydrocarbon feed without venting to the atmosphere carbon dioxide captured from the methanol or ammonia synthesis gas and without using expensive air separation units and water gas shift. Carbon dioxide removal from flue gas from reforming section to convert partially or fully all ammonia into urea. Synergi of having methanol, ammonia and urea production to produce coating material for the urea production.
Abstract: The invention relates to a catalytic reactor suited for exothermal reactions with a radial process fluid flow and process fluid flow guides which ensures an extended fluid flow path and higher flow velocity and thereby enhanced cooling of the catalyst bed in the reactor.
Type:
Grant
Filed:
June 30, 2016
Date of Patent:
March 17, 2020
Assignee:
Haldor Topsoe A/S
Inventors:
Anders Lindhard Christensen, Emil Andreas Tjärnehov
Abstract: In a process for increasing the sulfuric acid concentration of 90-98 wt % sulfuric acid, comprising stripping water from the sulfuric acid by contacting it with hot stripping media in a sulfuric acid concentrator column to increase the concentration of the acid leaving the column, the concentration of the acid is increased further by recycling a fraction of the acid, which is leaving the column, through an acid recirculation loop back to the inlet of the column, and the acid is optionally heated during its passage through the acid recirculation loop.
Abstract: A process for large scale and energy efficient product of oxygenates from sugar is disclosed in which a sugar feedstock is introduced into a thermolytic fragmentation reactor comprising a fluidized stream of heat carrying particles. The heat carrying particles may be separated from the fluidized stream prior to cooling the fragmentation product and may be directed to a reheater to reheat the particles and recirculate the heated particles to the fragmentation reactor.
Type:
Grant
Filed:
June 15, 2017
Date of Patent:
February 25, 2020
Assignee:
HALDOR TOPSØE A/S
Inventors:
Morten Boberg Larsen, Christian Mårup Osmundsen, Esben Taarning
Abstract: The present disclosure relates to a precursor for a catalytically active material or a catalytically active material comprising platinum, a molecular sieve and a metal oxide support, characterized in at least 80%, 90% or 95% of said platinum being dispersed on said molecular sieve and at least 80%, 90% or 95% of said platinum being dispersed in clusters having a size below 2 nm or 1 nm, as well as a method of producing such materials and process for hydroisomerization involving such materials. The disclosure has the associated benefit of such a catalytically active material being highly active and selective towards hydroisomerization.
Abstract: A catalytic reactor comprises a floating tray fluid distributor and optionally also an integrated particle separator which is modular build to be assembled inside the reactor and which has support members enabling the floating tray to be floating supported by the catalyst bed inside the reactor.
Abstract: The present invention relates to multi-bed catalytic reactor with a cylindrical shape comprising a mixing device mounted between two catalyst beds in the reactor, said mixing device has a circular outer rim which corresponds to the inner wall of the reactor, the mixing device comprises; collecting means disposed in a collecting section for collecting fluid from an up¬stream catalytic bed, mixing means disposed in a mixing section for mixing the collected fluid comprising guide vanes and guide ramps, and discharging means disposed in a discharging section for discharging the mixed fluid to a down-stream catalytic bed; wherein the collecting section, the mixing section and the discharging section are disposed outside the center of the circular cross-section of the reactor, as well as associated methods for mixing and the use of such a mixing device in catalytic reactors.
Type:
Application
Filed:
November 3, 2017
Publication date:
February 6, 2020
Applicant:
Haldor Topsøe A/S
Inventors:
Olav Holm-Christensen, Karthik Gopal Manoharan, Klaus Risbjerg Jarlkov, Jacob Brix
Abstract: In a novel process for methanol production from low quality synthesis gas, in which relatively smaller adiabatic reactors can be operated more efficiently, some of the inherent disadvantages of adiabatic reactors for methanol production are avoided. This is done by controlling the outlet temperature in the pre-converter by rapid adjustment of the recycle gas, i.e. by manipulating the gas hourly space velocity in the pre-converter.
Abstract: A plant for the production of sulfur trioxide from a feed stream containing sulfur-containing compounds and dissolved metals and alkali metals by a process, which involves gas quenching, comprises an incineration furnace, a mixing device and/or a dilution air heater, a dust removal device and an SO2 converter. The plant may further comprise a condenser for the purpose of producing sulfuric acid.
Abstract: A method and a system to assemble a plurality of filter bags within one another using a pole and a pulling guide, and a filter bag unit which includes a plurality of assembled filter bags with creases and stitches oriented relative to each other.
Abstract: Process for the co-production of methanol and ammonia from a hydrocarbon feed without venting to the atmosphere carbon dioxide captured from the methanol or ammonia synthesis gas and without using expensive air separation units and water gas shift.
Abstract: The invention relates to a boiling water reactor for an exothermal reaction. The reactor comprises reactant by-pass inserts arranged on top of the upper tube sheet to provide for a catalyst layer on top of the upper tube sheet and also a cooling stream of reactant by-passing the upper layer of catalyst and cooling the upper tube sheet from the temperature rise due to the exothermal reaction taking place in the upper layer of catalyst.
Abstract: The present invention regards new adipate-type compounds suitable as an intermediate in organic chemistry, a platform chemical for the production of other chemicals, and as a monomer and co-monomer useful for the preparation of polymers and copolymers. The invention also regards the process of preparing the new adipate-type compounds from bio-based raw materials such as sugars.
Abstract: A process for hydrodesulfurizing an olefinic naphtha feedstock while retaining a substantial amount of the olefins, which feedstock has a T95 boiling point below 250° C. boils and contains at least 50 ppmw of organically bound sulfur and from 5% to 60% olefins, said process including (a) selective diolefin hydrogenation, under reaction conditions to convert at least 50% or 90% of the diolefins to paraffins or mono-olefins providing a pre-treated feedstock, (b) hydrodesulfurizing the pre-treated feedstock in a sulfur removal stage in the presence of hydrogen and a hydrodesulfurization catalyst, at hydrodesulfurization reaction conditions to convert at least 50% of the organically bound sulfur to hydrogen sulfide and to produce a desulfurized product stream containing from 0 ppmw to 50 ppmw organically bound sulfur, with the associated benefit of such a process providing a lower octane loss, compared to a process with a lower gas to oil ratio.
Type:
Grant
Filed:
November 23, 2017
Date of Patent:
January 7, 2020
Assignee:
HALDOR TOPSØE A/S KGS.
Inventors:
George Hoekstra, Christian Ejersbo Strebel
Abstract: A process for producing an ammonia synthesis gas, said process comprising the steps of: —Reforming a hydrocarbon feed in a reforming step thereby obtaining a synthesis gas comprising CH4, CO, CO2, H2 and H2O, —Shifting the synthesis gas in one in or more shift steps in series, —Optionally wash the synthesis gas leaving the shift section with water, —Sending the process condensate originating from cooling and washing the synthesis gas leaving the shift section to a process condensate stripper wherein the dissolved shift byproducts and dissolved gases are stripped out of the process condensate using steam resulting in a steam stream containing more than 99% of the dissolved methanol in process condensate. —Adding all or part of said steam stream from the process condensate stripper to the synthesis gas downstream the reforming step, prior to the last shift step, wherein —The steam/carbon ratio in the reforming step and the shift step is less than 2.6.
Type:
Application
Filed:
March 7, 2018
Publication date:
December 19, 2019
Applicant:
Haldor Topsøe A/S
Inventors:
Christian Henrik Speth, Per Juul Dahl, Annette E. Krøll Jensen, Niels Christian Schjødt, Marcus Symreng
Abstract: In a process for hydrotreatment of a gas stream containing both olefins and diolefins as well as organic sulfur compounds, the gas stream is introduced into a pre-treatment reactor, where diolefins are reacted with hydrogen in the presence of a supported Mo-catalyst not containing Co or Ni, whereby the diolefins are substantially converted to olefins. Then the gas stream is introduced into a hydrotreater reactor having a higher inlet temperature than the pre-treatment reactor, in which the gas stream is reacted with hydrogen in the presence of a hydrotreating catalyst under hydrodesulfurisation process conditions, whereby the olefins are substantially converted to paraffins and the organic sulfur compounds are converted to H2S, which is removed by subjecting the hydrotreated gas to a chemisorption or physisorption treatment.
Type:
Application
Filed:
November 22, 2017
Publication date:
December 19, 2019
Applicant:
HALDOR TOPSØE A/S
Inventors:
Karin MADSEN, Henrik Junge MORTENSEN, Jens Michael POULSEN, Mads Kristian KAARSHOLM
Abstract: The present invention relates to a method and a system for catalytic oxidation of a lean H2S stream. More specifically, the invention concerns a novel way of removing sulfur dioxide (SO2) formed by catalytic oxidation of hydrogen sulfide (H2S) with the purpose of removing H2S from a gas. This catalytic oxidation of H2S yields sulfur dioxide (SO2) through the use of known catalysts, so-called SMC catalysts.
Type:
Application
Filed:
January 11, 2018
Publication date:
December 5, 2019
Applicant:
HALDOR TOPSØE A/S
Inventors:
Hans Qiongxiao WU, Tommy Bian XIANG, Niklas Bengt JAKOBSSON, Rasmus TRANE-RESTRUP, Souheil SAADI
Abstract: The invention concerns a process for producing carbon monoxide (CO) from carbon dioxide (CO2) in a solid oxide electrolysis cell (SOEC) or SOEC stack, wherein CO2 is led to the fuel side of the stack with an applied current and excess oxygen is transported to the oxygen side of the stack, optionally using air or nitrogen to flush the oxygen side, and wherein the product stream from the SOEC, containing CO mixed with CO2, is subjected to a separation process. The process further comprises heating the inlet gas on both the fuel side and the oxygen side by means of separate heating units, so as to supply heat to the SOEC, where the operation temperature of said heating units is at least equal to the operation temperature of the cell stack minus 50° C., preferably at least equal to the operation temperature of the cell stack.
Type:
Grant
Filed:
March 26, 2013
Date of Patent:
December 3, 2019
Assignee:
Haldor Topsoe A/S
Inventors:
Niklas Bengt Jakobsson, Claus Friis Pedersen, John Bøgild Hansen
Abstract: A method in which flue gas or exhaust gas containing harmful carbon monoxide, organic compounds (VOC) and NOx is contacted with a layered catalyst. A first layer of the catalyst comprises an oxidation catalyst. An underlying layer of the catalyst comprises a NH3-SCR catalyst for the simultaneous removal of the carbon monoxide and NOx.
Type:
Grant
Filed:
May 2, 2018
Date of Patent:
December 3, 2019
Assignee:
Haldor Topsoe A/S
Inventors:
Francesco Castellino, Viggo Lucassen Hansen
Abstract: In a method for the hydroprocessing of renewable feeds in a hydroprocessing unit (unit A), comprising the use of sour waste water from the same or another unit (unit B), which is processing feeds containing sulfur and nitrogen, as wash water in unit A, thereby changing the pH of the waste water from unit A to lower the risk of carbonic acid corrosion of corrodible steel parts in unit A, the renewable material in unit A is directed to contact a material that is catalytically active in hydrogenating the renewable material in the presence of hydrogen, and the effluent is combined with the wash water stream which contains hydrogen sulfide and/or ammonia.