Abstract: The invention relates to a chemical reactor and reformer tubes for reforming a first feed stream comprising a hydrocarbon gas and steam. The chemical reactor comprises a shell with a heat source and one or more reformer tubes. The reformer tube is arranged to house catalyst material and is arranged to being heated by the heat source. The reformer tube comprises a first inlet for feeding said first feed stream into a first reforming reaction zone of the reformer tube, and a feed conduct arranged to allow a second feed stream into a second reforming reaction zone of the reformer tube. The second reforming reaction zone is positioned downstream of the first reforming reaction zone. The feed conduct is configured so that the second feed stream is only in contact with catalyst material in the second reforming reaction zone. The invention also relates to a process of producing CO rich synthesis gas at low S/C conditions.
Type:
Application
Filed:
June 7, 2017
Publication date:
May 23, 2019
Applicant:
HALDOR TOPSØE A/S
Inventors:
Peter Mølgaard MORTENSEN, Martin ØSTBERG, Per Juul DAHL
Abstract: In a cooled axial/radial flow converter, in which process gas passes from an outer annulus via a catalyst bed to an inner centre tube, the catalyst bed is divided into identical modules stacked on top of each other. The process gas reaches the catalyst through openings facing the outer annulus, passes axially down the catalyst bed of each module, leaves the module through collectors in the bottom thereof, and flows to the centre tube. The catalyst bed is cooled by cooling panels, in which the process gas is pre-heated to the reaction temperature, while at the same time the heat of reaction is partly removed from the catalyst bed. The converter is especially suitable as ammonia converter.
Abstract: Method for the preparation of a monolithic catalyst for the reduction of nitrogen oxides VOC and carbon monoxide in an off-gas, the catalyst comprises at least one platinum group metal, vanadium oxide, titania and optionally tungsten oxide.
Type:
Application
Filed:
June 19, 2017
Publication date:
May 16, 2019
Applicant:
Haldor Tøpsoe A/S
Inventors:
Kim Hougaard Pedersen, Viggo Lucassen Hansen, Francesco Castellino
Abstract: The present invention regards new adipate-type compounds suitable as an intermediate in organic chemistry, a platform chemical for the production of other chemicals, and as a monomer and co-monomer useful for the preparation of polymers and copolymers. The invention also regards the process of preparing the new adipate-type compounds from bio-based raw materials such as sugars.
Abstract: In a process for the synthesis of a nitrile by endothermic catalyzed reaction of ammonia with a hydrocarbon using heating obtained by passing an alternating current through a metallic coil, the endothermic reaction between ammonia and the hydrocarbon takes place in a reactor with direct inductive heating in the reaction zone. The heating is extremely fast, which makes the reaction practically instantaneous.
Type:
Application
Filed:
April 24, 2017
Publication date:
May 16, 2019
Applicant:
HALDOR TOPSØE A/S
Inventors:
Poul Erik HØJLUND NIELSEN, Burcin TEMEL MCKENNA, John Bøgild HANSEN, Rasmus Munksgård NIELSEN
Abstract: Method for removal of soot, ash and metals or metal compounds, together with removal of NOx and SOx being present in process off-gasses or engine exhaust gasses.
Abstract: A continuous flow process for the preparation of one or more esters of lactic acid and 2-hydroxy-3-butenoic acid or ?-hydroxy methionine analogs from a sugar in the presence of a solid Lewis acid catalyst and a solvent comprising an organic solvent and water. The invention provides a stabilized Lewis acid catalyst for use in a continuous reaction process, where the water is present in an amount of up to or equal to 10 vol. % of the organic solvent.
Abstract: A process layout for large scale methanol synthesis comprises one or more boiling water reactors and one or more radial flow reactors in series, the boiling water reactor(s) being fed with approximately fresh make-up syngas. The methanol synthesis loop comprises a make-up gas compressor K1, a recycle gas compressor K2, two or more boiling water converters for methanol synthesis (A1, A2, . . . ), a radial flow converter (B) for methanol synthesis, a steam drum (V1), a high pressure separator (V2), a low pressure separator (V3), feed effluent heat exchangers (E1 and E2), a wash column (C), an air cooler (E3) and a water cooler (E4).
Abstract: A process for hydrodesulfurizing an olefinic naphtha feedstock while retaining a substantial amount of the olefins, which feedstock has a T95 boiling point below 250° C. boils and contains at least 50 ppmw of organically bound sulfur and from 5% to 60% olefins, said process including (a) selective diolefin hydrogenation, under reaction conditions to convert at least 50% or 90% of the diolefins to paraffins or mono-olefins providing a pre-treated feedstock, (b) hydrodesulfurizing the pre-treated feedstock in a sulfur removal stage in the presence of hydrogen and a hydrodesulfurization catalyst, at hydrodesulfurization reaction conditions to convert at least 50% of the organically bound sulfur to hydrogen sulfide and to produce a desulfurized product stream containing from 0 ppmw to 50 ppmw organically bound sulfur, with the associated benefit of such a process providing a lower octane loss, compared to a process with a lower gas to oil ratio.
Type:
Application
Filed:
November 23, 2017
Publication date:
May 2, 2019
Applicant:
HALDOR TOPSØE A/S
Inventors:
George Hoekstra, Christian Ejersbo Strebel
Abstract: A method for the purification of a raw gas stream by selective catalytic oxidation, in which organic and inorganic sulfur compounds, halogenated and non-halogenated volatile organic compounds are selectively oxidized without substantially oxidizing the lower hydrocarbons and the sulfur containing compounds present in the gas to sulfur trioxide and excess of oxygen is removed by oxidation of lower alcohols, ethers or hydrogen added to the raw gas stream upstream the catalytic oxidation.
Abstract: Oxygen is removed from a gas feed such as a landfill gas, a digester gas or an industrial CO2 off-gas by removing sulfur-containing compounds and siloxanes from the feed gas, heating the feed gas, injecting one or more reactants for oxygen conversion into the heated feed gas, carrying out a selective catalytic oxygen conversion in at least onesuitable reactor and cleaning the resulting oxygen-depleted gas. The reactants to be injected comprise one or more of H2, CO, ammonia, urea, methanol, ethanol and dimethylether (DME).
Abstract: Filter bag assembly for use in cleaning of process gas comprising an outer filter bag and one or more inner filter bags separately arranged within the outer filter bag, and said one or more inner filter bags also separately arranged within each other, the one or more inner filter bags and the outer filter bags are provided with catalytically active material.
Type:
Application
Filed:
July 3, 2017
Publication date:
April 25, 2019
Applicant:
Haldor Topsøe A/S
Inventors:
Thomas Holten Kollin, Kim Hougaard Pedersen, Viggo Lucassen Hansen
Abstract: A process for large scale and energy efficient product on of oxygenates from sugar is disclosed in which a sugar feedstock is introduced into a thermolytic fragmentation reactor comprising a fluidized stream of heat carrying particles. The heat carrying particles may be separated from the fluidized stream prior to cooling the fragmentation product and may be directed to a reheater to reheat the particles and recirculate the heated particles to the fragmentation reactor.
Type:
Application
Filed:
June 15, 2017
Publication date:
April 25, 2019
Applicant:
HALDOR TOPSØE A/S
Inventors:
Morten Boberg Larsen, Christian Mårup Osmundsen, Esben Taarning
Abstract: In a process for producing hydrogen or syngas by methanol cracking, whereby methanol is catalytically decomposed into hydrogen and carbon monoxide in an endothermal reaction, said reaction takes place in a reactor with direct inductive heating in the reaction zone. The heating is obtained by passing an alternating current through a metallic coil located inside the reactor or by using induction heated catalyzed hardware in the shape of a ferromagnetic structure, which is coated with an oxide impregnated with the catalytically active phase.
Type:
Application
Filed:
April 24, 2017
Publication date:
April 18, 2019
Applicant:
HALDOR TOPSØE A/S
Inventors:
Peter Mølgaard MORTENSEN, Martin ØSTBERG, Poul Erik HØJLUND NIELSEN
Abstract: In a process for co-production of ammonia and methanol, the outlet stream from the reformer is split into two parts, one of which is subjected to shift, carbon dioxide removal, methanation, compression and ammonia synthesis, while the other part is compressed and fed to a once-through methanol synthesis section. Methanol is withdrawn from the methanol synthesis section, and the remaining effluent from said section is divided into two streams comprising hydrogen, of which one is fed to the shift section, while the other is recycled to the desulfurization unit. This way a favourable co-production method is obtained because recycle hydrogen for the desulfurization is provided, and furthermore a compression step is avoided.
Abstract: The present application relates to a vessel support beam comprising two or more beam elements wherein each beam element comprises a first and second opposing long side connected by a top side, a lower side and two opposing end sides, said beam elements are arranged parallelly with at least one long side of one beam element facing a long side of another beam element, thereby forming a reactor support beam having a first and second opposing long side surface, a top surface and a lower surface.
Abstract: Method and system for thermal regeneration of a catalyst by inlet turbine exhaust gas from a diesel engine, where a gas split stream (08) is led from the engine exhaust (02) through an eductor (04) and further to regeneration of a catalyst, wherein a cold air stream (09) is used to keep the regeneration gas stream at a desired constant temperature range.
Abstract: The present application relates to a process for production of hydrocarbons comprising the steps of: converting a feed stream comprising alcohols, ethers or mixtures hereof over a Zn-containing zeolite based catalyst wherein Zn is at least partly present as ZnAl2O4, active in dehydrogenation of hydrocarbons, in a conversion step thereby obtaining a conversion effluent, separating said effluent to obtain an aqueous process condensate stream, a liquid hydrocarbon stream and a gaseous stream, removing part of the hydrogen formed in the conversion step, and recycling at least part of the gaseous and/or liquid hydrocarbon stream to the conversion step.
Abstract: A grid module (2a, 2b) for a catalyst support comprising one or more sides arranged with a module connecting part (11) to engage in a tongue/groove connection with a matching receiving connecting part (8a, 8b) on an external structure (7a, 7b).
Abstract: Ceramic candle filter and use of the filter in the removal of particulate matter in form of soot, ash, metals and metal compounds, together with hydrocarbons and optionally nitrogen oxides being present in process off-gas or engine exhaust gas, wherein a noble metal comprising catalyst is arranged on the permeation side of the filter and/or on the dispersion side of the filter and/or within wall of the filter, said noble metal comprising catalyst contains a noble metal in an amount of between 20 and 1000 ppm/weight of the filter.
Type:
Grant
Filed:
April 28, 2015
Date of Patent:
March 19, 2019
Assignee:
HALDOR TOPSØE A/S
Inventors:
Joakim Reimer Thøgersen, Francesco Castellino, Lars Storm Pedersen