Abstract: Process for dehydrogenation of alkanesor alkylbenzenes by using metal sulfide catalyst under the presence of small amounts of hydrogen sulfide.
Type:
Grant
Filed:
September 23, 2015
Date of Patent:
December 11, 2018
Assignee:
Haldor Topsoe A/S
Inventors:
Poul Erik Højlund Nielsen, John Bøgild Hansen
Abstract: A float valve for a chemical reactor has a central pipe which glides around a liquid transfer pipe when a liquid level rises and falls, thereby opening for fluid transfer through liquid transfer apertures in the transfer pipe when the liquid level is rising and shutting off for fluid transfer when the float lowers and seals against a sealing ring placed on the transfer pipe below the liquid transfer apertures.
Type:
Grant
Filed:
February 18, 2016
Date of Patent:
December 11, 2018
Assignee:
Haldor Topsoe A/S
Inventors:
Emir Zahirovic, Klaus Risbjerg Jarlkov, Flemming Plougstrup Nielsen
Abstract: Process and catalyst for upgrading gasoline comprising durene (1,2,4,5-tetramethylbenzene) and pseudodocumene, the process comprises hydroisomerization of durene (1,2,4,5-tetramethylbenzene) and pseudocumene (1,2,4-trimethylbenzene) contained in the gasoline in presence of a catalyst comprising a sulfided base metal supported on an acidic carrier, thereby converting durene (1,2,4,5-tetramethylbenzene) to isodurene (1,2,4,5-tetramethylbenzene) and prehnitene (1,2,3,4-tetramethylbenzene) and converting pseudocumene (1,2,4-trimethylbenzene) to mesitylene (1,3,5-trimethylbenzene).
Abstract: A novel process for synthesis gas generation comprises treating a hydrocarbon feed in a primary reformer (PR), compressing at least part of the flue gas from the primary reformer in a compressor (C1), and feeding the compressed flue gas to a secondary reformer (SR) together with the primary reformer effluent. In the process, enriched air (EA) is added either to the primary reformer, to the secondary reformer or both. The process is especially suited for co-production of ammonia and methanol or for production of either ammonia or methanol. The total CO2 emission is lowered considerably by using the process of the invention.
Abstract: A method for removing sulphur compounds from a process stream by contacting the process stream with an aqueous solution containing glycolaldehyde as the predominant compound.
Type:
Application
Filed:
October 14, 2016
Publication date:
November 1, 2018
Applicant:
HALDOR TOPSOE A/S
Inventors:
Esben TAARNING, Christian Mårup OSMUNDSEN
Abstract: A reactor system for dehydrogenation of alkanes in a given temperature range upon bringing a reactant stream including alkanes into contact with a catalytic mixture. The reactor system includes a reactor unit arranged to accommodate the catalytic mixture, where the catalytic mixture includes catalyst particles and a ferromagnetic material. The catalyst particles are arranged to catalyze the dehydrogenation of alkanes. The ferromagnetic material is ferromagnetic at least at temperatures up to an upper limit of the given temperature range. The reactor system moreover includes an induction coil arranged to be powered by a power source supplying alternating current and being positioned so as to generate an alternating magnetic field within the reactor unit upon energization by the power source, whereby the catalytic mixture is heated to a temperature within the temperature range by means of the alternating magnetic field. Also, a catalytic mixture and a method of dehydrogenating alkanes.
Type:
Application
Filed:
October 24, 2016
Publication date:
November 1, 2018
Applicant:
HALDOR TOPSØE A/S
Inventors:
Poul Erik HØJLUND NIELSEN, Rasmus Munksgård NIELSEN, John Bøgild HANSEN, Burcin TEMEL MCKENNA
Abstract: The present application relates to a process for production of hydrocarbons comprising the steps of: converting a feed stream comprising alcohols, ethers or mixtures hereof over a Zn-containing zeolite based catalyst wherein Zn is at least partly present as ZnAl2O4, active in dehydrogenation of hydrocarbons, in a conversion step thereby obtaining a conversion effluent, separating said effluent to obtain an aqueous process condensate stream, a liquid hydrocarbon stream and a gaseous stream, removing part of the hydrogen formed in the conversion step, and recycling at least part of the gaseous and/or liquid hydrocarbon stream to the conversion step.
Abstract: A bifunctional catalyst for conversion of oxygenates, said catalyst comprising zeolite, alumina binder and Zn, wherein the Zn is present at least partly as ZnAl2O4.
Abstract: In a process for methanol production from synthesis gas, which comprises the steps of providing a make-up gas containing hydrogen and carbon monoxide, in which the content of carbon dioxide is less than 0.1 mole %, mixing the make-up gas with a hydrogen-rich recycle gas and passing the gas mixture to a methanol synthesis reactor, optionally via a sulfur guard, and subjecting the effluent from the synthesis reactor to a separation step, thereby providing crude methanol and the hydrogen-rich recycle gas, the customary addition of carbon dioxide to the make-up gas is replaced by addition of water in an amount of 0.1 to 5 mole %. This way, a CO2 compressor is saved, and the amount of poisonous sulfur in the make-up gas is markedly reduced.
Type:
Application
Filed:
May 10, 2016
Publication date:
October 25, 2018
Applicant:
Haldor Topsøe A/S
Inventors:
Per Juul Dahl, Hassan Modarresi, Max Thorhauge
Abstract: The present invention relates to a process for heating an ATR or POX comprising the steps of heating a process stream by at least one heating means, admitting the heated process stream to an ATR or POX reactor through a main burner, and heating the ATR or POX reactor to or above autoignition temperature of the process stream via the heated process stream.
Type:
Grant
Filed:
April 8, 2015
Date of Patent:
October 23, 2018
Assignee:
Haldor Topsoe A/S
Inventors:
Per Juul Dahl, Thomas Sandahl Christensen
Abstract: Ceramic candle filter and use of the filter in the removal of particulate matter in form of soot, ash, metals and metal compounds, together with hydrocarbons and nitrogen oxides being present in process off-gas or engine exhaust gas, the filter comprises a combined SCR and oxidation catalyst arranged at least on the dispersion side and/or within wall of the filter, the combined SCR and oxidation catalyst comprises palladium, a vanadium oxide and titania.
Type:
Grant
Filed:
March 20, 2015
Date of Patent:
October 23, 2018
Assignee:
HALDOR TOPSØE A/S
Inventors:
Francesco Castellino, Lars Storm Pedersen
Abstract: The present relates to a method for controlling the inlet temperature Ti to a conversion process, said method comprising the steps of: Providing a feed for a conversion process; In a first temperature control step regulating the temperature of the feed in a waste heat boiler; In a second temperature control step injecting a water stream into the feed downstream the waste heat boiler in an amount and/or at a temperature to obtain the desired inlet temperature into the conversion process.
Type:
Application
Filed:
December 7, 2016
Publication date:
October 18, 2018
Applicant:
Haldor Topsøe A/S
Inventors:
Christian Henrik Speth, Emil Andreas Tjärnehov
Abstract: A method and a system to assemble a plurality of filter bags within one another by means of a pole and a pulling guide, and a filter bag unit comprising a plurality of assembled filter bags with creases and stitches oriented relative to each other.
Abstract: A continuous flow process for the preparation of one or more esters of lactic acid and 2-hydroxy-3-butenoic acid or ?-hydroxy methionine analogs from a sugar in the presence of a solid Lewis acid catalyst and a solvent comprising an organic solvent and water. The invention provides a means for stabilizing a Lewis acid catalyst for use in a continuous reaction process wherein the water is present in an amount of up to or equal to 10 vol. % of the organic solvent.
Abstract: Process for the production of synthesis gas by catalytic steam reforming of a hydrocarbon containing feedstock in parallel in an autothermal steam reformer and heat exchange reformer, the heat for the steam reforming reactions in the heat exchange reformer being provided by indirect heat exchange with the combined effluent of the heat exchange reformer and a portion of the autothermal steam reformer.
Abstract: Method for the preparation of a metal-exchanged zeolites or mixtures of metal-exchanged zeolites, such as Cu-SSZ-13, Cu-ZSM-5, Cu-beta, or Fe-beta, comprising the steps of providing a dry mixture of a) one or more microporous zeotype materials that exhibit ion exchange capacity and b) one or more metal compounds; heating the mixture in a gaseous atmosphere containing ammonia to a temperature lower than 300° C. for a time sufficient to initiate and perform a solid state ion exchange of ions of the metal compound and ions of the zeolite material; and obtaining the metal-exchanged zeolite material.
Type:
Grant
Filed:
October 15, 2014
Date of Patent:
September 25, 2018
Assignee:
Haldor Topsoe A/S
Inventors:
Ton V. W. Janssens, Peter N. R. Vennestrøm
Abstract: A burner with a plurality of oxidant gas pipes distributed throughout the cross section of the burner and process gas in plug flow provides even mixing of the oxidant and the process gas.
Abstract: Ceramic candle filter and use of the filter in the removal of particulate matter in form of soot, ash, metals and met-al compounds, together with hydrocarbons and nitrogen oxides being present in process off-gas or engine exhaust gas, the filter includes a combined SCR and oxidation catalyst being arranged on the dispersion side and within wall of the filter; and a palladium including catalyst arranged on the permeation side and within wall of the filter facing the permeation side.
Type:
Grant
Filed:
March 20, 2015
Date of Patent:
September 18, 2018
Assignee:
HALDOR TOPSØE A/S
Inventors:
Francesco Castellino, Lars Storm Pedersen
Abstract: A process for the preparation of ethylene glycol comprising the steps of pyrolyzing a monosaccharide and hydrogenating the product composition in the presence of a catalyst and a solvent, wherein the pressure of the hydrogenation reaction is 40 bar or greater.
Abstract: In a broad aspect the present disclosure relates to a process plant and a process for upgrading a hydrocarbon mixture, withdrawn as a direct stream from a crude distillation unit and an initial boiling point below 200° C., and a fraction of at least 5% boiling above 500° C., 550° C. or 650° C. comprising the steps of a. directing said hydrocarbon mixture to a vacuum flasher unit, b. withdrawing a heavy hydrocarbon fraction from said vacuum flasher unit, c. withdrawing a light hydrocarbon mixture for hydrocrackingfrom said vacuum flasher unit, d. directing said light hydrocarbon mixture for hydrocracking and a stream rich in hydrogen to con-tact a material catalytically active in hydrocracking, e. withdrawing a hydrocracked stream of hydrocarbon from said hydrocracker. with the associated benefit of limiting the amount of asphaltenes, metals and other heavy components contacting said material catalytically active in hydrocracking.