Abstract: Described are a concentrate, a working solution and a process for iron phosphating of metals, in which the solution contains nitrobenzene sulfonic acid and substituted short-chain monocarboxylic acids of the amino acid and/or hydroxycarboxylic acid type as the accelerators.
Abstract: A process for producing unsaturated fatty compounds having improved low-temperature properties bya) splitting lauric oils into fatty acids and glycerol,b) subjecting the fatty acids to fractional crystallization to obtain a fraction of unsaturated fatty acids, andc) hydrogenating the unsaturated fatty acids, optionally after converting the unsaturated fatty acids into their lower alkyl esters, to form unsaturated fatty alcohols having an iodine value of from about 85 to about 100.
Type:
Grant
Filed:
June 10, 1997
Date of Patent:
June 29, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Michael Koehler, Alfred Westfechtel, Guenter Demmering, Horst-Dieter Komp, Christiane Boehr, Achim Ansmann, Udo Steinberner
Abstract: A process for controlling the deposition of stickies from paper stock suspensions during papermaking by adding to the paper stock suspensions from 0.001% to 5.0% by weight based on the weight of fibrous paper stock, of alkoxylation products obtained by reaction of alkylene oxides with C.sub.10-22 carboxylic acid derivatives or C.sub.10-22 carboxylic acids containing functional groups with at least one OH group in the 9, 10, 13 or 14 position.
Type:
Grant
Filed:
October 24, 1997
Date of Patent:
June 22, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Bernhard Nellessen, Rita Koester, Klaus Hornfeck, Berthold Schreck, Peter Daute
Abstract: A liquid composition comprisingA) at least one sulosuccinic acid diester of the formula: ##STR1## in which M is an inorganic or organic cation, R and R' independently of one another represent aliphatic or cycloaliphatic C.sub.3-22 alkyl, C.sub.2-22 alkenyl or optionally C.sub.1-8 alkyl-substituted C.sub.6-22 aryl;B) water as a solvent; andC) a cosolvent consisting essentially of at least one polymer containing alkylene oxide units which is liquid at 10.degree. C.
Type:
Grant
Filed:
February 1, 1996
Date of Patent:
June 1, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Dieter Feustel, Uwe Held, Joachim Meyer
Abstract: In washing agents containing tensides and cellulase, the properties of the cellulase which are relevant to the application were to be improved. This was essentially achieved in that use was made of a cellulase mixture in which the first component, with a CMCase activity of 1 U per liter and a protein concentration of a most 3 mg per liter, gives an increase in remission of at least 5 units in the secondary washing test and the second component, with a CMCase activity of 20 U per liter gives an increase in absorption in the cellulose decomposition test of at least 0.075.
Abstract: Carotene is recovered from a native fat or oil in five process steps in an economical industrial process. The native fat or oil is catalytically reacted in known manner with an alkanol containing up to 4 carbon atoms to form fatty acid alkyl ester and glycerol. The ester phase of the reaction mixture is subjected to distillation to remove the fatty acid alkyl ester. The distillation residue obtained in the second process step is saponified, carotene is extracted from the product obtained in the third process step and the extract phase is concentrated by evaporation. A yield of at least about 80% is achieved. At the same time, a fatty acid alkyl ester suitable for further processing to fatty alcohol is provided.
Type:
Grant
Filed:
October 22, 1997
Date of Patent:
May 11, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Michael Nitsche, Wilhelm Johannisbauer, Volkmar Jordan
Abstract: A filling compound for electrical and optical equipment in the form of cables, connectors, plugs etc. and to assemblies thus produced, is provided. Electrical and optical equipment in the form of cables, connectors, plugs etc. have to be protected against harmful influences penetrating from outside, particularly water, and also against mechanical damage during laying or as a result of exposure to heat. The filling compound is based on a stellate substance, i.e. a substance having a branched molecular structure in which, ideally, 3 or more branches, more particularly polymeric chains, radiate from a single branching point. The filling compound is flexible at very low temperatures but, on the other hand, does not run out, even at extremely high temperatures.
Type:
Grant
Filed:
November 12, 1996
Date of Patent:
May 11, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Reimar Heucher, Juergen Wichelhaus, Johannes Andres
Abstract: A cosmetic or pharmaceutical composition containing an emulsifier comprising an ester of palmitic acid and technical grade triglycerol with the proviso that the monoester content of the ester is from 30% to 50% by weight.
Abstract: A tablet composition containing 2% to 100% by weight of amorphous crystalline or partly crystalline layer-form sodium silicates corresponding to the formula Na.sub.2 Si.sub.x --O.sub.2x+1.yH.sub.2 O wherein x is a number of 1.9 to 4 and y is a number of 0 to 20, with the proviso that the tablet composition only contains water in a quantity such that the maximum theoretical water-binding capacity of the components of the composition is not exceeded.
Type:
Grant
Filed:
October 10, 1996
Date of Patent:
May 4, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Wolfgang Seiter, Dieter Jung, Otto Koch, Birgit Stevermann
Abstract: A phosphate-free mildly alkaline, dishwashing detergent composition containing:(a) from 20 to 60% by weight of sodium citrate;(b) from 5 to 50% by weight of alkali metal hydrogen carbonate;(c) from 7 to 12% by weight of alkali metal carbonate;(d) from 2 to 20% by weight of a bleaching agent;(e) from 1 to 8% by weight of a bleaching agent activator; and(f) from 0.2 to 4% by weight of an enzyme, all weights being based on theweight of the composition wherein the composition in the form of a 1% by weight aqueous solution has a pH value of from about 8 to less than 10.
Type:
Grant
Filed:
August 1, 1997
Date of Patent:
April 27, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Birgit Burg, Juergen Haerer, Peter Jeschke, Willi Buchmeier, Helmut Blum, Christian Nitsch, Heinz-Juergen Voelkel, Horst-Dieter Speckmann
Abstract: The proposal is for novel polymer dyestuffs obtained by condensing cationic biopolymers, e.g. chitosame, with dyestuffs which have a basic group, preferably a halogen function. The dyestuffs spread as a film on the fibers and can easily be washed out.
Type:
Grant
Filed:
September 30, 1997
Date of Patent:
April 6, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien (KGaA)
Abstract: A process for producing solid polycarboxylic acid salts from polysaccharides with gaseous nitrogen dioxide and dinitrogen tetroxide to at least partially convert the primary alcohol groups of the polysaccharides into carboxyl groups and form a solid polycarboxylic acid and then mixing the polycarboxylic acid with a solid neutralizing agent to at least partially neutralized the carboxylic acid groups of the polycarboxylic acid.
Abstract: A process for sealing anodized metals without using any heavy metals comprises a first step in which the anodized metal is contacted for a period of between 3 and 30 minutes (for an anodized layer thickness of 20 .mu.m) with an aqueous solution which has a temperature from 15.degree. to 35.degree. C. and a pH between 5.0 and 6.5 and contains from 0.1 to 3 g/l of lithium ions and from 0.1 to 5 g/l of fluoride ions and a second step in which the anodized metal is contacted for a period from 5 to 30 minutes (for an anodized layer thickness of 20 .mu.m) with water or an aqueous solution of substances which prevent the formation of a sealing coating, the solution having a pH from 5.5 to 8.5 and a temperature from 80.degree. to 100.degree. C.
Type:
Grant
Filed:
January 7, 1998
Date of Patent:
April 6, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Torsten Koerner, Josef Kresse, Juergen Lindener, Wolf-Achim Roland
Abstract: The invention relates to opacifiers containing waxes and a mixture of two emulsifiers with different HLB values. The low-viscosity opacifier concentrates are based on waxes with a solids content of 40 to 60% by weight which are characterized that they contain at least one hydrophilic nonionic surfactant with an HLB value above 10 and at least one hydrophobic nonionic surfactant with ab HLB value below 10 as emulsifiers.
Abstract: A process for inhibiting the corrosion of silver in a dishwashing detergent solution by adding to the solution an inorganic redox-active substance.
Type:
Grant
Filed:
August 28, 1997
Date of Patent:
March 30, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Juergen Haerer, Helmut Blum, Birgit Burg, Thomas Holderbaum, Willi Buchmeier, Peter Jeschke, Horst-Dieter Speckmann, Frank Wiechmann, Christian Nitsch
Abstract: Increased production of a heterologous cellulase is achieved by transforming Bacillus subtilis and Bacillus licheniformis with genetic constructs containing a Bacillus licheniformis ATCC 53926 protease promoter and signal sequence to express alkalophilic cellulase genes.
Type:
Grant
Filed:
August 7, 1996
Date of Patent:
March 30, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
C. Ron Wilson, Maria R. Tang, Terri Christianson, Karl-Heinz Maurer, Albrecht Weiss
Abstract: A process for producing quaternized fatty acid triethanolamine ester salts having improved solubility in water, by esterifiying a fatty acid mixture containinga) 40% to 60% by weight of linear fatty acids containing 6 to 22 carbon atoms, andb) 60% to 40% by weight of branched fatty acids containing 6 to 22 carbon atoms,wherein the esterifying step is conducted with triethanolamine or ethylene oxide adducts of triethanolamine, and the resultant esters are then quaternized.
Type:
Grant
Filed:
April 8, 1996
Date of Patent:
March 23, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Nuria Bonastre, Joaquim Bigorra Llosas, Rafael Pi Subirana
Abstract: Pumpable water-containing surfactant concentrates containing alkyl glycosides, sulfosuccinates and amphoteric and/or zwitterionic surfactants, and to their use for the production of surface-active formulations.
Type:
Grant
Filed:
April 4, 1997
Date of Patent:
March 16, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Hermann Hensen, Renate Lindner, Joerg Kahre, Werner Seipel
Abstract: A composition of matter useful as a hotmelt adhesive is provided. The composition is comprised of a polyamide based on dimerized fatty acid and having an amine value higher by at least two units than the acid value of said polyamide and a filler comprised of a carbonate. The filler is preferably comprised of fine particles of calcium carbonate. The adhesive is particularly useful for bonding metals, e.g. to plastics and the bonding of cables with multilayer sheaths, e.g. in optical cables and power cables.
Abstract: A substantially non-aqueous, free-flowing, storable liquid washing or cleaning formulation comprising:A) from more than 20 to less than 78% by weight of at least one nonionic surfactant;B) from 0.1 to 25% by weight of at least one anionic surfactant;C) from 1 to less than 20% by weight of at least one water-soluble builder; andD) from more than 20 to 35% by weight of at least one bleaching agent.
Type:
Grant
Filed:
February 14, 1997
Date of Patent:
March 9, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Hans-Josef Beaujean, Christian Block, Rainer Hofmann, Dieter Legel, Rudolf Lind, Josef Penninger, Bernd Richter, Reiner Schackmann, Karl Schwadtke